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Strategic metal recycling: adaptive metallurgical processing infrastructure and technology are essential for a Circular Economy

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  • Material Recycling and Sustainability (MARAS) B.V., The Netherlands

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Recycling forms the heart of the Circular Economy (CE) system. Ultimately all products will have to be recycled at their End-of-Life (EoL). Maximizing the recovery of materials and also especially strategic elements from EoL products requires a deep understanding of the fundamental limits and the dynamics of the evolving system, thus an adaptive processing and metallurgical infrastructure is critical to recover all metals and materials. Paramount is the quantification of the “mineralogy”, the complex and interlinked composition of products, to trace and quantify specifically all the losses of materials, metals, alloys, etc. due to thermodynamic and other non-linear interactions. We named this product centric recycling. The recycling potential and performance must be quantified and demonstrated for products, collection systems, waste separation and recovery technologies, and material supply. Emphasis is also placed on informing the consumer through iRE i.e. informing Resource Efficiency in an easy-to-understand way. System Integrated Metal Processing (SIMP) using big-data, multi-sensors, simulation models, metallurgy, etc. links all stakeholders through Circular Economy Engineering (CEE), an important enabler to maximize Resource Efficiency and thus iRE.
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62 RESPONSABILITÉ & ENVIRONNEMENT - AVRIL 2016 - N°82
Strategic metal recycling: adaptive
metallurgical processing
infrastructure and technology are
essential for a Circular Economy
By Markus A. REUTER
Director Helmholtz Institute Freiberg for Resource Technology
and Antoinette VAN SCHAIK
Director/owner/founder Material Recycling and Sustainability (MARAS) B.V.
Circular Economy (CE)
The EU has recently published its ambitious plan on Cir-
cular Economy (CE) (EU, 2015). Recycling plays a key role
in CE. If all products were constructed from one material
and recyclates were 100% pure CE would be an easy en-
deavour. However, if society would reduce drastically its
consumption, the complicating issues of a CE will become
trivial, in fact a CE could become irrelevant. However, pre-
sent reality is that consumer products are complex, crea-
ting complex recyclates, have an often short life span and
are intensively produced and consumed.
In addition, variability of products and materials demands
a dynamically changing processing infrastructure. For me-
tals, this means that for a CE, to be realized requires for
example a high-tech adaptive metallurgical infrastructure
that interlinks all materials processing industries (i.e. all
carrier metals infrastructures must - for example in the EU -
be able to interchange materials if there is an economic
incentive to do so).
Realizing the full potential, challenges and fundamental
innovations to achieve a CE system requires an unders-
tanding of the social, technological, economic and envi-
ronmental opportunities and limits thereof. The innova-
tions, tools and challenges to move towards a CE include
among others:
l The use of minerals and metallurgical processing know-
how and tools in the analysis of the CE system. The inno-
vation lies in further developing these tools for recycling
and linking these to the already established tools used
for optimizing metallurgical systems (REUTER, 1998;
VAN SCHAIK and REUTER, 2010, MENAD et al., 2016).
We have called this product centric recycling (REUTER
and VAN SCHAIK, 2012).
l Quantifying the data of the CE for both products and re-
cycling in a manner that acknowledges the complexity of
a product centric approach, that takes all materials of the
consumer product (i.e. from the Urban Mine) into consi-
deration, much like a complex mineral from a Geological
Mine. This approach captures the full non-linear effects
Recycling forms the heart of the Circular Economy (CE) system. Ultimately all products will have
to be recycled at their End-of-Life (EoL). Maximizing the recovery of materials and also espe-
cially strategic elements from EoL products requires a deep understanding of the fundamental
limits and the dynamics of the evolving system, thus an adaptive processing and metallurgical
infrastructure is critical to recover all metals and materials. Paramount is the quantification of the
“mineralogy”, the complex and interlinked composition of products, to trace and quantify speci-
fically all the losses of materials, metals, alloys, etc. due to thermodynamic and other non-linear
interactions. We named this product centric recycling. The recycling potential and performance
must be quantified and demonstrated for products, collection systems, waste separation and
recovery technologies, and material supply. Emphasis is also placed on informing the consumer
through iRE i.e. informing Resource Efficiency in an easy-to-understand way. System Integrated
Metal Processing (SIMP) using big-data, multi-sensors, simulation models, metallurgy, etc. links
all stakeholders through Circular Economy Engineering (CEE), an important enabler to maximize
Resource Efficiency and thus iRE.
UNE PRIORITÉ : L’ÉCONOMIE CIRCULAIRE
Markus A. REUTER et Antoinette VAN SCHAIK
of the recovery and losses of all materials, elements,
strategic & critical raw materials (CRMs) (EU 2014) etc.
on each other (as well as the contamination of the ma-
terials on each other). This is analogous to processing
of polymetallic complex minerals from geology and en-
suring all elements, metals and gangue are processed
to economically valuable to environmentally benign final
products such as slag.
l Recyclates have to be quantified so that thermodynamic
and physical properties can be used in industry linked
simulation (REUTER et al., 2015) to optimize the com-
plete system. Properties of the recyclate particles and
flows include enthalpy, entropy & exergy, alloy and mate-
rial composition, conductivity, colour, magnetic suscep-
tibility, density, shape, odour, near infrared properties,
interlinkages of materials in scrap particles, brittleness,
ductility, etc.
l A real-time feedback loop, that links product design
and recycling system configurations to real-time grade
monitoring of recyclates with suitable multi-sensors (to
estimate possible contaminants and valuables in them)
while linking this to high quality material and metal pro-
duction processing – thus Design for Resource Efficien-
cy (DfRE).
- Use of real-time data to calibrate recycling and CE sys-
tem models that provide a basis to optimise the proces-
sing chain and providing the necessary detail to calculate
Capital Expenditure (CAPEX) and Operational Expendi-
ture (OPEX) as well as the environmental footprint. This
simulation basis provides the true economic potential of
CE as it rigorously maps all recoveries, losses and costs
due to these losses.
l Determining the baseline recovery rate and potential for
specific products based on a product centric approach.
This permits the understanding of what actions to take to
innovate in the CE system (REUTER, 1998; VAN SCHAIK
and REUTER, 2014). Industry calibrated simulation mo-
dels are key to optimizing the system i.e. methods will be
applied to quantify both of quality and recovery, as well
as opportunities and limits of recycling complex product
material mixtures.
l On the basis of these rigorous adaptive CE models
(REUTER and VAN SCHAIK, 2012), innovative circular
business models can be developed that will design a
closed loop system for material use preventing the loss
of materials from the economy and into the environment
including innovations to producer responsibility and new
product ownership models. These models provide a ba-
sis to develop innovative collection and organisational
approaches to increase the amount of sorted, collected
and reported EoL goods and their subsequent reuse, re-
covery and closed loop recycling gleaning from the fee-
dback from limits and critical issues in recycling learned
from industry process simulation (UNEP, 2013).
l Involving end-users (consumers and businesses) in both
the design of collection to maximise their participation in
the testing of potential approaches and their acceptance
to recycled and reused products.
In other words, business models will need to be connec-
ted to material science, underpinning policy with physics
and economics creating the field of Circular Economy En-
gineering. Ultimately energy and material efficiency should
be optimized as a function of product and recycling and
processing infrastructure design to fully reveal the op-
portunities and limits of the CE system. This is the key
challenge to understand the role of an adaptive infrastruc-
ture and process technology to innovate the true potential
of CE thinking. This adaptive infrastructure is called “Sys-
tem Integrated Metal and Materials Processing”.
System Integrated Metal
and Materials Processing (SIMP)
A substantial challenge for realizing CE is the production
of clean recyclates that can provide the physical material
properties that impart the required functional properties
in the consumer products these are applied. Complexity
of recyclates and the complex mix of material properties,
etc.: all affect the final recovery during physical and metal-
lurgical processing.
While metals can be refined to high purity metal alloys du-
ring metal refining, plastics have a limit to how much recy-
clate (containing a mix of more or less of all other metals
and materials in the EoL product) can be added to virgin
plastics to produce high quality plastics once again. Just
think of rheological, mechanical, thermal, visual properties
of recyclates that could affect their usage in high perfor-
mance electronic applications! (Figure 1 provides an over-
view of this interaction and the effect on quality on metals
and plastics respectively). Creating the highest quantity
and quality of recyclates for all materials at the same time
is the “simple” task that CE should achieve, but it gives no
indication of the complexity of the task at hand.
The linkage of all technologies and systems from product
design to metal recovery we call System Integrated Metal
and Materials Processing (SIMP) can help achieve these
challenging goals. This requires new rules for physical
recycling tied to product design and design for recycling
linked via process metallurgy to high grade metal based
materials. This involves reconsideration and where ne-
cessary redesigning the whole value chain to minimise
material losses and reducing the unnecessary mixing
of materials to reduce energy use and costs. Various
base metals, steel, plastics etc. are the carriers to be un-
derstood to quantify interaction and recovery possible of
all materials in the product as among others shown by the
metal wheel (VERHOEF et al., 2004). Digitalizing the CE
and specifically the metals processing through SIMP is a
key to recovering all materials (CRMs among others) from
EoL products.
In SIMP, real-time data and big-data analysis will be used
to calibrate the simulation models that will be used to
quantify and provide the data for the business models
and plans to innovate the CE system. Included must be
environmental assessment linked to simulation as shown
by Reuter et al. (2015). Crucial in innovating in the CE
system is the comprehension of the baseline on a funda-
mental physics basis to innovate the future. Essential to
SIMP and CE is a close communication and cooperation
RESPONSABILITÉ & ENVIRONNEMENT - AVRIL 2016 - N°82 63
64 RESPONSABILITÉ & ENVIRONNEMENT - AVRIL 2016 - N°82
between the original equipment manufacturers (OEMs)
and the recycling industries (both recyclers and metallur-
gical and plastic recycling industries) in the value chain.
Key enablers of System Integrated Materials Processing
are:
l Adaptive metallurgical infrastructure: To maximize
metals and CRMs from diverse changing EoL products
requires a high-tech metallurgical infrastructure. Only
where there are “holes” in the system should technology
innovation take place, system innovation should be pa-
ramount and policy should be an enabler.
l Metallurgical system optimization: Optimal recycling
routes supported by innovative developments in separa-
tion and real-time digitalization (i.e. on-line measurement
technologies) are key: they will minimise the inclusion of
contaminating materials affecting the properties of recy-
clates, hence enhancing the quality and uptake of se-
condary/recycled materials into new products.
l Quantifi cation of recycling rates - The recycling Index
(RI): Physics based rigorous process simulation tools to
quantify and predict recycling rates and limits thereof for
current and future products/systems will be calibrated
based on the industry trials and real-time data derived
from innovative sensor based measurements. This quan-
tifi es the limiting factors and options for improvements in
resource effi ciency/reduction and reduction of genera-
tion of residual waste (See Figure 2)
l Real-time big-data acquisition and analysis: Based on
detailed insights derived from real-time data acquisition
and quality control and simulations, the physical limits
of recycling can be translated into technology and in-
dustry driven Design for Recycling innovations of various
products. Redesigns and innovated recycling routes will
be addressed and quantitatively assessed on improved
recyclability (i.e. process data are linked via simulation to
computer aided design (CAD) supporting both product
and process redesign for improved resource effi ciency).
l Criticality of process infrastructure: Maintaining, in-
novating and simulating the metallurgical and recycling
processing infrastructure enables the maximum recove-
ry of all metals from the EoL products. This facilitates the
redesign of the value and supply chain supplying CAPEX
and OPEX data for the whole system, the basis for eva-
luating the business potential of CE.
l Cross-sectorial symbiosis: Incorporating quantifi able
targets for measuring sustainable recovery, recycling
and re-use of resources (including energy and mate-
rial qualities) in the overall material ow chain from re-
sources to consumer products in a data format which
can be applied for all stakeholders allows for quantifi ed
symbiosis between different sectors.
l Eco-innovative system analysis is realised by the im-
provement of recycling and uptake of recycled materials
into products. The relationships between stakeholders
along the material and product value chain (such as col-
lection systems, producers, recyclers and processers)
are linked with quality monitoring and environmental life
cycle assessment.
l Quantifi cation of regulatory barriers will become evident
through the systemic integrated approach in which criti-
cal and limiting issues (as well as physics based limits to
recycling and resource effi ciency) are pinpointed. As the
product centric approach addresses recovery of both
commodities (materials and metals), as well as CRMs
and other materials (such as plastics and other non-me-
tals), regulatory barriers are addressed as a trade-off
between these, taking cognisance of functional product
specifi cations.
l Improve environmental assessment (LCA) methodolo-
gy: The detailed analysis and simulation of all streams in
terms of compounds, recyclates, residue mineralogy etc.
provides the detail to improve LCA methodology as well
as environmental databases (REUTER et al., 2015).
l iRE - informing Resource Effi ciency requires both a ri-
gorous analysis of energy and material effi ciency. Ana-
lysis is based both on material and energy fl ow, entropy
(exergy) in addition to life cycle assessment tools.
l Redesigning of collection and sorting systems for CE:
Understanding on how to minimise contamination and
losses during recycling (e.g. critical issues in processing
and decreased recyclate quality due to undesired mate-
rial mixtures) that limit the recycling and arise as a conse-
quence of product mixtures provides direct input to re-
design the way EoL materials and products are collected
and treated. This will result in well-designed collection
Figure 1: Interaction between Plastics and Metals: Miscibility charts
(Van Schaik and Reuter, 2014) of different metal and polymer types.
UNE PRIORITÉ : L’ÉCONOMIE CIRCULAIRE
and sorting of the CE system with physical separation
and thermodynamic as well as metallurgical and plastic
processing options. This includes quality requirements
of recyclates and materials.
Resource effi ciency can be quantifi ed and optimised for
products by applying an innovative and unique combina-
tion of industrial model calibration, sensor based quality
measurement and a rigorous simulation basis, which are
key to realizing SIMP. This provides a quantitative, dyna-
mic and predictive basis for reducing material losses in the
chain as well as a reference for measuring improvements
against the status quo. This allows to rigorously and sys-
temically link product design with collection, recycling,
processing and the effectiveness thereof from a plastic
and metal quality point of view and required innovations
to move towards circularity.
Innovative redesign of recycling systems and processes
(e.g. metallurgical processing) will need to be combined
with Design for Resource Effi ciency for Circular Economy
by developing and integrating product design, collection,
processing, economics and environmental performance
on the basis of industry calibrated system models and ap-
plying these to innovate and quantify new concepts, pro-
cesses, technologies, designs and structure. We call this
discipline, with its comprehensive engineering toolbox,
Circular Economy Engineering.
Design for Recycling and
Resource Effi ciency
System Integrated Metal & Materials Processing (SIMP) will
result in an innovative eco-innovative systemic approach
producing improved resource effi ciency in the complexly
interlinked CE system. Digitalization will link and visualize
the complexity of interactions between consumers, Pro-
ducer Responsibility Organisations, collectors, recyclers
and processors, and producers and (re-)manufacturers.
SIMP will provide a real-time as well as predictive (in fu-
ture) quantifi cation of the physical and economic limits of
recycling and more specifi cally of critical technology ele-
ments.
Key to SIMP is to quantify design and ineffi ciency in se-
paration cross-contaminated recyclates. It will quantify
where metals and critical raw materials disappear into the
wrong material, recyclate or waste ows and how reco-
very of all materials could be optimised, i.e. ensuring that
for example plastic quality (i.e. purity) is maximized. SIMP
goes beyond state of the art as it:
l establishes a technological and economic baseline for
increased materials (plastics, metals and CRMs) recove-
ry to maximise the opportunities for resource effi ciency;
l acknowledges and includes the technological, economic
and physics detail of all recycling, metallurgical and pro-
cessing technology in the chain;
l provides the framework against which improvements in
redesign, collection and recycling will be established,
measured and quantifi ed and provides a rigorous and
measurable basis for innovation and business models
for a CE, now and in future;
l uses a product centric recycling system approach taking
into account the innovation potential of the main actors
and stakeholders in the material processing value chain;
RESPONSABILITÉ & ENVIRONNEMENT - AVRIL 2016 - N°82 65
Figure 2: SIMP permits the optimization of both material and energy effi ciency, thus providing the complete detail of informing Resource
Effi ciency (iRE), the sum of the Recycling Index (Reuter et al., 2015) and the accepted Energy Effi ciency calculation (EU, 2012).
Markus A. REUTER et Antoinette VAN SCHAIK
66 RESPONSABILITÉ & ENVIRONNEMENT - AVRIL 2016 - N°82
l improves recycling performance and recyclate quality via
the development of optimised and new technologies and
processes, sensor technologies, dynamic quality control
and data interaction in simulation tools as well as the
optimisation of the value chain via innovative business
models;
l pinpoints and quantifies techno-economic limits to recy-
cling and a CE;
l links CAD software, sensor-based measurement and
recycling simulation tools to predict recycling rates and
recyclates qualities to maximise plastic inclusion based
on material properties affected (e.g. by CRMs and other
materials) in the product;
l links different actors together into one harmonized bu-
siness model which will require significant innovation in
business science and approaches;
l creates data structures using common formats which
can be communicated easily between designers and re-
cyclers, thus compatible with common thermodynamic
and material properties data formats; and
l enhances interaction between stakeholders in the value
chain, in particular between manufacturers, producer
compliance schemes, collectors, recyclers, legislators,
consumers etc. to ensure sufficient information and in-
telligence sharing on product composition, material use,
and product use, reuse and recycling.
In summary, SIMP leads to innovative product designs
for recycling, processes, processing routes and sensor
based real-time measurements linked to and integrated
in predictive simulation tools. Figure 2 provides the pre-
sent status of developing a Recycling Index-RI (REUTER
et al., 2015) combined with the accepted energy label for
products (EU, 2012). Combining these two symbols will be
a key to informing the consumer and guiding CE develop-
ment. This will help also to harmonize and integrate ener-
gy efficiency into the wider resource efficiency discussion.
SIMP is thus a rigorous engineering toolbox that permits
the calculation of a RI as well as RE, informing business
models with the required depth to quantify disruptive and
innovative CE business models.
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UNE PRIORITÉ : L’ÉCONOMIE CIRCULAIRE
Summary: Circular Economy
Engineering
SIMP, the basis of Circular Engineering, provides the
tools that will quantify evidence-based knowledge for
enabling framework conditions (such as the regulatory
or policy framework) to facilitate a broader transition to
the CE.
Circular Economy Engineering (CEE) thus provides the
engineering and economic tools that will help innovate
the CE system.
The outcome of CEE is to join energy and material ef-
ficiency into one symbol (Figure 2) that informs the
consumer and thus also guides the development, inno-
vation and business models of the CE system.
We call this outcome of informing the consumer on a
rigorous basis : iRE, thus Informing Resource Efficiency
with engineering based tools providing a rigorous basis
for developing new CE business models.
... Realizing the full potential, challenges and fundamental innovations to achieve a CE system requires an understanding of the social, technological, economic and environmental opportunities and limits thereof [11]: ...
... This provides a harmonised basis for the calculation of recycling rates, in which the entire recycling system from dismantling to end-processing is taken into account. RIs as developed by the authors (in analogy with the in use EU Energy Labels) [10,11] as well as the newly developed Material-RI will be presented providing a clear and transparent tool to visualise, communicate and give insight into the recycling performance of a product and its individual composing materials. This allows to link and pin-point the role of product design choices (in view of greener product design) and material usage to recycling performance in (BAT) recycling technology. ...
... This has had a long evolution as also shown by [13] and [11]. This work exceeds the relatively simplified approaches [24] and [25], which neglect the complexity of thermodynamics and technological differences in their analysis, thus the environmental impact of the detail of each stream in the system can hardly be considered and generalized. ...
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... A survey of the literature shows that in the modern world there is already a consensus on the importance of solving problems of optimizing the use of primary (natural) resources and increasing the efficiency of recycling of wastes and secondary resources in the mining and metallurgical industry (Hogland et al., 2014;NEA, 2019;Chernousov, 2011;Jishkariani et al., 2012;Chernousov et al., 2016;Sausheva, 2017;Allesch, and Brunner, 2015;Reuter, and Schaik, 2016;Brunner et al., 2017;Ndlovu, Simate, and Matinde, 2017;Matinde, Simate, and Ndlovu, 2018). Modern technologies for recycling and processing secondary resources create new opportunities for sustainable development. ...
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An improved methodology is presented for assessing the economic feasibility and effectiveness of recycling industrial waste. The methodology is based on the break-even control mechanism, but at the same time provides for the introduction of new evaluation criteria such as the threshold of conditionality and the degree of ore substitution. Based on an improved analysis, it becomes possible to more precisely predict recycling efficiency. A more refined determination of the lower limit of concentration of recoverable metals, at which technogenic waste can be assigned the status of secondary raw materials and processed profitably, leads to a significant expansion of the secondary raw material base suitable for recycling. The potential for recycling manganese-containing dust from the production of ferrosilicomanganese, dehydrated sludge from the hydro separation of slags, and cake from the production of electrolytic manganese dioxide at the Chiatura mining enterprise is used as an example. It is shown that with a threshold of-24% Mn content, the highest recycling efficiency can be achieved by the production of low-phosphorus manganese slag and conversion to ferrosilicomanganese using the above waste to replace 40-60% grade III and IV manganese concentrates in the feed.
... An analytical review of scientific literature devoted to assessing the efficiency of recycling of mining and metallurgical wastes showed that they are mainly focused on solving such problems as improving the methodology for predicting the amount and structure of the formation of these wastes, the selection of rational technological schemes and technical solutions for the extraction of metals containing in them, as well as -on a separate (individual) assessment of the expected economic, environmental or social efficiency (Anderson, 2016;Bartie et al., 2020;Dino et al., 2018;Friedrich, 2019;Garbarino et al., 2020;Jandieri, and Sakhvadze, 2013;Jandieri et al., 2019;Reuter, and Schaik, 2016;Markovaara-Koivisto et al., 2018;Natarajan, 2018;Sausheva, 2017;Van Schaik and Reuter, 2016;Rawashdeh at al., 2016;Van Long et al., 2016;Zhang and Xu, 2018). Studies on comprehensive, generalized assessment and improvement of waste recycling systems to optimize management decisions and increase the overall efficiency of the production processes is relatively rare (Abramov, 2009;Collins and Kumral, 2020;Gorin, 2017;Li et al., 2020;Lyaschuk et al., 2015;Sayadova et al., 2019;Schoeman at al., 2021;Upadhyay at al., 2021;Zanizdra, 2017), but even these studies do not provide specific functional solutions (algorithms) for the generalized assessment and intensification of the industrial recycling system. ...
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A generalized model for assessing the overall, techno-economic-ecological efficiency of recycling metal-bearing technogeneous resources has been developed, based on a mathematical model for analyzing the break-even point, specially improved for this purpose. An algorithm for theoretical calculations has been compiled, which also incorporates a sequence of techno-organizational operations for maximizing the efficiency of the recycling system. As a particular case, an example of assessing the effectiveness and the possibility of intensifying recycling of manufacturing waste of the manganese industry of Georgia was considered. It is shown that the intensification of the internal industrial recycling of manganese-bearing wastes is associated with the need for their preliminary treatment, bringing to the condition necessary for break-even processing. Through theoretical-computational analysis of the recycling efficiency index (REI), it is determined that in the case of pyrometallurgical processing , the condition of break-even is the presence of manganese in the recycled raw material in the amount not less than 24%. In the case of hydrometallurgical processing, this threshold is reduced up to 7%. Consequently, resources that satisfy these conditions or can satisfy them after pretreatment should be classified as suitable for recycling and included in the special state register of metal-bearing technogenic deposits. Only that part of industrial waste, in which it is technically impossible or economically unprofitable to provide the specified threshold concentrations, can be disposed of in other industries. The proposed approach to assessing and intensifying the efficiency of recycling will make it possible to significantly expand the resource base of metallurgical production in Georgia. Herewith, on average, the degree of beneficial use of manganese will be increased by 45-50%. Depending on the quality of currently consumed manganese concentrates (Mn 48-28%) the degree of reduction of their consumption rate will reach 30-60%. This will extend the life cycle of the Chiatura manganese mine by 25-30 years. Harmful anthropogenic impact on the environment will be reduced by 3.4-3.5 times.
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The Waste Electrical and Electronic Equipment (WEEE) is one of the fastest growing residual materials as a result of huge production of the Electrical and Electronic Equipment (EEE), its market expansion and technological progress in its conception. The complex compositions of WEEE (precious, strategic and rare elements, ferrous and non-ferrous metals, plastics, hazardous substances…) and its often miniature design lead to the technical and environmental difficulties to propose an efficient and viable flow-sheet for WEEE treatment and for the recovery process.
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Purpose This paper illustrates how a product-centric approach to recycling, building on the extensive expertise, knowhow and tools of the mineral-centric classical minerals and metallurgical processing, should be core to Design for Resource Efficiency (DfRE). Methods Process simulation (HSC Sim 1974-2014, Outotec's design tool) and environmental software (GaBi 2014) are applied to quantify resource efficiency (RE) in a rigorous manner. These digitalisation tools are linked and will be used to show how the environmental performance of copper primary production, the processing of residues and the recycling of e-waste, e.g. light emitting diode (LED) lamps as well as the production of nickel pig iron can be evaluated. The paper also shows how technologies can be compared relative to a precise thermodynamic and techno-economic baseline. Results The results include simulation-based environmental indicators, exergy, recycling and recovery rates, as well as the qualities and quantities of the recyclates, losses and emissions of materials during production recycling. The complete mass and energy balance simulation provides the mineralogical detail of all streams (both mineral and recyclate as well as offgas and dust) to define and improve environmental assessment, while at the same time revealing the aspects of LCA databases and their results that require improvement. Furthermore, this paper presents an approach for industry to implement life-cycle methods in practice. It shows that the DfRE is all about predicting stream grades and thus is equivalent to Design for Recyclate grade and quality (as this determines whether a recyclate or product stream has economic value and can be treated or processed further). DfRE also reveals especially the grade, composition, minerals etc. of the leakage streams, i.e. diffuse emissions, thus permitting a more precise evaluation of environmental impact. Conclusions The prediction of recyclate and stream compositions and grade makes the environmental analysis of systems more precise and will help to expand the detail that defines these flows on environmental databases. This is especially valuable for DfR, where the methodological rigour suggested in this paper is a very necessary addition and requirement for estimating the true environmental impact of product redesigns and the resource efficiency of processing technology and complete recycling systems. The methodology produces mass- and energy-consistent, economically viable best available technique (BAT) process blocks, the inclusion of which on environmental databases will be invaluable in benchmarking technology and systems in terms of estimating the achievable resource efficiency baseline.
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Ensuring the continued availability of materials for manufactured products requires comprehensive systems to recapture resources from end-of-life and wastewater products. To design such systems, it is critical to account for the complexities of extracting desired materials from multicomponent products and waste streams. Toward that end, we have constructed dynamic simulation–optimization models that accurately describe the recovery of materials and energy from products, residues, and wastewater sludges. These models incorporate fundamental principles such as the second law of thermodynamics, as well as detailed, empirically based descriptions of the mechanical separation of materials at the particulate level. They also account for the evolution of the recycling system over time. Including these real-world details and constraints enables realistic comparisons of recycling rates for different products and technological options and accurate assessments of options for improvement. We have applied this methodology to the recycling of complex, multimaterial products, specifi cally cars and electronic wastes, as well as wastewater and surface-water systems. This analysis clarifi es how product design, recycling technology, and process metallurgy affect recycling rates and water quality. By linking these principles to technology-based design-for-recycling systems, we aim to provide a rigorous basis to reveal the opportunities and limits of recycling to ensure the supply of critical elements. These tools will also provide information to help policymakers reach appropriate decisions on how to design and run these systems and allow the general public to make informed choices when selecting products and services.
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A key principle in industrial ecology is the cyclic use of materials, a characteristic of natural ecosystems but a challenge in economic systems. Indeed, in society, metal retention, that is, the ongoing use or ready availability of metal in the economy between the life‐cycle stages of resource extraction and final disposal back into the lithosphere, is finite because of the limited grade of secondary (recycled) metals. Currently, the utility of metals is maintained through the addition of high primary (virgin) metals, bringing the concentration of the recycled metals to desired levels. This mixing with high‐grade primary metals keeps these recycled metals in the cycle. Long term, this practice of dilution of the undesired substances prevents a closure of the material cycles, whereas recovery without dilution reduces the quality (or quantity) of recycled metals. Metals participate in a system of linked cycles and thus cannot be produced or recovered independently from one another. The metal wheel is introduced in this article as a concise but powerful instrument for the communication of available process knowledge in process metallurgy, the science and technology of producing metals from natural ores and societal raw materials, residues, and end‐of‐life products. It summarizes the chemical and physical linkages between metals found in ores and the set of metallurgical processes that has been developed to accommodate these linkages. A dynamic mass‐flow model is introduced to characterize the global metal cycles. The model facilitates the visualization of the evolution of their structure and technological content. To illustrate the interdependency of metal cycles using the metal wheel and the dynamic model, the transition to lead‐free solder is evaluated. Neglect of metal‐cycle linkages and dynamics in policy formulation may lead to a shortage of lead substitutes. In case of an extended ban on lead, both the availability and recovery of a range of metals will be affected.
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The ISO 14000 norm provides a framework in which a continuous improvement of the environmental performance of a process may be realised. Life Cycle Assessment (LCA) forms an integral part of ISO 14000, however, its inventory analysis presently often simplifies process routes for metals processing to simple averaging black-boxes that represent whole processes. This approach hardly makes it possible to capture the detail of complex interconnected materials processing systems as found in metals processing. As a consequence the use of LCA in its present form as a tool to invoke improvement for metal processing and recycling systems may be questionable. As an alternative to the poor inventory analysis of LCA for the above mentioned systems, this paper discusses the architecture of a simulation model that permits the detailed simulation of interconnected material cycles in view of realising the ISO 14000 norm and other imposed environmental legislation. This means that interconnected routes such as for Cu, Sn, Zn, Pb, Al, Mg and Mn are simulated simultaneously. This would put the very useful LCA methodology for these applications on a more sound basis, rendering the subsequent improvement analysis better for these systems.
European Commission DG ENV, Plastic Waste in the Environment, Specific contract 07
EU (2011): European Commission DG ENV, Plastic Waste in the Environment, Specific contract 07.0307/2009/545281/ ETU/G2 under Framework contract ENV.G.4/ FRA/2008/0112, Revised final report April 2011, 171p.
On the review of the list of critical raw materials for the EU and the implementation of the Raw Materials Initiative
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EU (2014): COMMUNICATION FROM THE COMMISSION TO THE EUROPEAN PARLIAMENT, THE COUNCIL, THE EUROPEAN ECONOMIC AND SOCIAL COMMITTEE AND THE COMMITTEE OF THE REGIONS, On the review of the list of critical raw materials for the EU and the implementation of the Raw Materials Initiative, Brussels, 26.5.2014 COM (2014) 297 final.
Closing the loop -An EU action plan for the Circular Economy
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EU (2015): COMMUNICATION FROM THE COMMISSION TO THE EUROPEAN PARLIAMENT, THE COUNCIL, THE EUROPEAN ECONOMIC AND SOCIAL COMMITTEE AND THE COMMITTEE OF THE REGIONS, Closing the loop -An EU action plan for the Circular Economy, Brussels, 2.12.2015 COM (2015) 614 final.
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UNEP (2013): REUTER (M.A.), HUDSON (C.), VAN SCHAIK (A.), HEISKANEN (K.), MESKERS (C.) & HAGELÜKEN (C.): United Nations Environmental Protection (UNEP) Report " Metal Recycling: Opportunities Limits Infrastructure " re- port: http://www.unep.org/resourcepanel/Publications/ MetalRecycling/tabid/106143/Default.aspx VAN SCHAIK (A.) & REUTER (M.A.) (2014): Chapter 22: Material-Centric (Aluminium and Copper) and Product-Centric (Cars, WEEE, TV, Lamps, Batteries, Catalysts) Recycling and DfR Rules. In: Handbook of Recycling (Eds. WORREL (E.), REUTER (M.A)), Elsevier, 307-378.