ArticlePDF Available

Hypogenic caves of Sicily (Southern Italy)

Authors:
HYPOGENIC CAVES OF SICILY (SOUTHERN ITALY)
Marco Vattano1, Philippe Audra2, Fabrizio Benvenuto3, Jean-Yves Bigot4, Jo De Waele3, Ermanno Galli5,
Giuliana Madonia1, Jean-Claude Nobécourt6
1Department of Earth and Sea Sciences, University of Palermo, Via Archirafi 22, 90123 Palermo, Italy,
marco.vattano@unipa.it, giuliana.madonia@unipa.it
2Polytech’Nice-Sophia, Engineering School of Nice – Sophia Antipolis University, & I’CiTy (IMREDD), 930 route des
Colles, 06903 Sophia-Antipolis, France, audra@unice.fr
3Department of Biological, Geological and Environmental Sciences, Bologna University, Via Zamboni 67, 40126
Bologna, Italy, fabrizio.benvenuto2@studio.unibo.it; jo.dewaele@unibo.it
4Association Française de Karstologie (AFK), 21 rue des Hospices, 34090 Montpellier, France,
catherine.arnoux@club-internet.fr
5Department of Earth Sciences, University of Modena and Reggio Emilia, Largo S. Eufemia 19, 41121 Modena, Italy,
gallier@unimore.it
6CRESPE, Le Hameau de l’Ara, 259 Bd Reine Jeanne, 06140 Vence, France, jcnobecourt@free.fr
First results of a study on hypogenic caves in Sicily are presented. Inactive water-table sulphuric acid caves and 3D maze
caves linked to rising of thermal waters rich in H2S were recognized. Cave patterns are guided by structural planes, medium
and small scale morphological features are due mainly to condensation-corrosion processes. Calcite and gypsum represent
the most common cave minerals. Different types of phosphates linked to the presence of large bat guano deposits were
analyzed.
1. Introduction
Hypogenic caves are recognised as generated by water
recharging from below independently of seepage from the
overlying or immediately adjacent surface. Waters are often
thermal and/or enriched in dissolved gases, the most
common are CO2and H2S. Hypogenic caves can be thermal
caves, sulphuric acid caves, and basal injection caves. They
differ from epigenic caves in many ways, such as:
speleogenetic mechanisms, morphological features,
chemical deposits, and lack of alluvial sediments
(Klimchouk 2007; Klimchouk and Ford 2009; Palmer 2011).
Several studies were conducted to evaluate the hypogenic
origin of a large number of caves (Klimchouk and Ford
2009; Stafford et al. 2009; Audra et al. 2010; Plan et al.
2012; Tisato et al. 2012). A significant contribution was
given by the work of Klimchouk (2007) that systematically
provided instruments and models to better understand and
well define the hypogenic karst processes and landforms.
Studies on hypogenic caves in Italy were carried out since
the 90s in different karst systems, especially in the central
and southern Appenines. These studies mainly concerned
chemical deposits related to sulphuric ascending water and
micro-biological action (Galdenzi and Menichetti 1995;
Galdenzi 1997; Piccini 2000; Galdenzi and Maruoka 2003;
Forti and Mocchiutti 2004; Galdenzi 2012; Tisato et al.
2012).
This paper aims to describe preliminary the first results of
a study conducted in some hypogenic caves in Sicily,
highlighting their main features such as pattern,
morphology, mineralogy and speleogenesis. These are
Monte Inici karst system and Acqua Fitusa Cave. For this
purpose topographic and geomorphological surveys were
carried out, and about 40 samples of cave minerals were
taken in different parts of the caves. In addition, a brief
description of Monte Kronio karst system is given. It
represents one of the most important hypogenic karst
systems of Sicily, characterized by flows of hot air and
vapor rising from below.
2. Karst in Sicily
Karst in Sicily is widespread and exhibits a great variety of
surface and underground landforms related to the wide
distribution of soluble rocks (Di Maggio et al. 2012). About
20% (more than 6,000 km2) of the land area consists of
carbonates and evaporites, primarily gypsum (Fig. 1).
Carbonate karst lies mainly in the northwestern and central
sectors of the Apennine chain and the foreland area in
southeastern Sicily; gypsum karst occurs chiefly in the central
and southern areas of the island, though evaporite landscapes
are also present in the northern and western parts of Sicily.
Carbonate and gypsum karst systems develop under
unconfined conditions and in most cases constitute
epigenetic systems fed by meteoric waters. Hypogene caves
are located only in carbonate rocks and are linked to the
presence of deep thermal waters.
Figure 1. Gypsum (white) and carbonate karst areas (grey) and
localization of investigated hypogenic karst systems. 1. Monte
Inici; 2. Acqua Fitusa. 3. Monte Kronio.
Karst and Caves in Carbonate Rocks, Salt and Gypsum – oral 2013 ICS Proceedings
144
3. Hypogenic caves
3.1. Acqua Fitusa Cave
Acqua Fitusa Cave opens in the eastern section of the Sicani
Mounts (west-central Sicily), along the north-eastern fault
scarp of a N-S anticline, westward vergent, forming the Mt.
La Montagnola (Fig. 1). The cave formed in the Upper
Cretaceous Rudist breccias member of the Crisanti Fm.,
composed of conglomerates and reworked calcarenites with
rudist fragments and benthic foraminifera (Catalano et
al. 2011).
At present it is inactive with a thermal spring occurring
300 m north and 30 m below the cave. The waters have a
temperature of about 25 °C, and are indicated as chlorine-
sulphate alkaline (Grassa et al. 2006 and references therein).
During the spring-summer-early autumn the cavity hosts a
large colony of bats, including Myotis myotis and
Miniopterus schreibersii species (Mucedda pers. comm.),
that produce significant amounts of guano.
The first explorations of Acqua Fitusa were carried out in
the early XXth century by some inhabitants of the
neighboring villages, but the first human frequentations of
the cavity have to go back to the Paleolithic and
Chalcolithic periods, as evidenced by the discovery of
numerous lithic fragments, remains of food and burials
(Bianchini and Gambassini 1973). Lombardo et al. in 2007
gave a description of the cave and some studies concerned
the hydrogeochemistry and isotopic composition of the
nearby spring waters (Grassa et al. 2006 and references
therein).
According to the survey made in 2011, the cave consists in
at least three stories of subhorizontal conduits, displaying
a total length of 700 m, and a vertical range of 25 m
(Fig. 2). The main passages are generally low and narrow
and follow sets of joints oriented in ENE-WSW, E-W and
N-S directions. Very small passages develop from these
galleries making incipient mazes.
The conduits breach the fault scarp in more points at
different heights. The main entrance leads to a large
chamber enlarged both by corrosion and breakdown
processes, connected to an upper subhorizontal passage that
likely formed during a past higher karst base level.
Acqua Fitusa Cave represents a clear example of inactive
water table sulphuric acid cave (Audra et al. 2009). Despite
the small size, the cave is very interesting for the abundance
and variety of morphologies and deposits formed at and
above the water table where H2S degassing and thermal
convection produced strong condensation-corrosion
processes.
The floor of some passages is breached for several meters
by an inactive thermo-sulphuric discharge slot that can
reach a depth of 7 m (Fig. 3). In some sections of the caves,
notches with flat roof, linked to lateral corrosion of a water
table with concentrated sulphuric acid, carve the walls at
different heights, recording past stages of base-level change.
Several forms of small and large sizes, generated by
condensation-corrosion processes above the water table, can
be observed along the ceiling and walls. Ceiling cupolas
and large wall convection niches occur in the largest rooms
of the cave. Here and in the upper gallery, pendants at
junctions of more cupolas or between braided channels are
widespread. Cave walls of many passages are carved at
different heights by deep wall convection niches that in
places form notches (Fig. 3). Condensation-corrosion
channels similar to ceiling-half tubes carve the roof of some
passages; replacements pockets due to corrosion-
substitution processes are widespread; boxwork created by
differential condensation-corrosion were observed in the
upper parts of the conduits.
Figure 2. Acqua Fitusa Cave: plan view and extended profile
(Survey: Ceresia, Inzerillo, Provenzano, Sausa, Scrima and
Vattano, 2011).
Figure 3. Acqua Fitusa. Passage with discharge slot at the floor
and different levels of wall convection niches.
The most abundant cave mineral is gypsum which displays
different shapes and colours. Replacement gypsum crusts
are common in many passages; the gypsum is located in
large vertical fissures along the walls, it can partially cover
wall convection notches, or replacement pockets. A gypsum
body of about 50 cm of thickness was found on the floor of
the biggest room in correspondence of which small ceiling
cupolas and pendants are associated on the roof.
Centimeter-sized euhedral gypsum crystals grew inside
mud sediments. Finally, the walls of a feeding fissure are
covered with a network of gypsum “roots” in which the
Karst and Caves in Carbonate Rocks, Salt and Gypsum – oral 2013 ICS Proceedings
145
3.2.1. Abisso dei Cocci
Abisso dei Cocci is an inactive 3D maze cave formed in
Lower Jurassic limestones and dolomitic limestones (Inici
Fm.), arranged in decimetric westward dipping beds. The
cave is one of the largest of Sicily, reaching a total length
of over 2,053 m and a vertical range of -300/+61m. It
consists of several stories of large subhorizontal galleries
and chambers connected by deep shafts. In plan view the
galleries are mainly oriented in NW-SE and NE-SW
direction, parallel with the main tectonic discontinuity lines.
Some conduits are gently inclined and follow the dip of
bedding planes, whereas the shafts develop along vertical
fissures or fault planes. Passages display sub-circular cross-
sections, sometimes with vadose entrenchments (Fig. 5).
Several features linked to rising thermal water and air flow
were recognized in many sections of the cave. Many
passages are characterized by large convection wall niches,
mega-scallops, ceiling cupolas, and ceiling spheres. In some
cases adjacent passages are separated by partitions (Fig. 5).
The cave lacks alluvial sediments; on the other hand
chemical deposits are abundant mainly in the middle level
of the cave, where dripping is still active. Here, a large
variety of calcite speleothems, such as stalactites,
stalagmites, flowstones, shelfstones, etc., occur. Calcite is
present also in the shape of powder, thin crusts, and
frostwork. Gypsum was recognized in the middle and
deepest sections of the cave in the form of tabular or
acicular colourless small crystals (Fig. 5).
biological control is obvious. Further investigation on these
apparently subaqueous gypsum speleothems is still
ongoing.
Phosphate minerals, such as apatite [Ca5(PO4)3(OH)], were
found in the form of thin crusts near large deposits of bat
guano.
3.2. Monte Inici Complex
Monte Inici karst system is situated in northwestern Sicily
(Fig. 1), in the eastern sector of the Trapani Mountains, and
opens along the southeastern slope of Mt. Inici, a gently
westward – dipping monoclinal relief affected by NW-SE,
NE-SW and NNW-SSE high angle faults. The karst system
is composed of two caves, Grotta dell‘Eremita (or Grotta
del Cavallo) and Abisso dei Cocci, formed in Jurassic
limestones and dolomitic limestones. Thermal waters
emerge from three hot springs east and at lower altitude
respect to the caves (Fig. 4). These are of chloride-sulphate
alkaline-earth type and have a temperature respectively of
48.3 °C (Gorga 1), 49.6 °C (Gorga 2), and 44.2 °C (Terme
Segestane) (Grassa et al. 2006 and references therein).
The caves preserve clear signs of prehistoric and medieval
human presence, such as several lithic and bone fragments,
food remains, ceramic finds typical of the Middle Neolithic-
Middle Chalcolithic (Grotta dell’Eremita), and large
amounts of medieval pottery (XIth–XVth century), identified
mainly within Abisso dei Cocci (Tusa 2004). These caves
were explored and described in the early 90s. On the basis
of morphological features a genesis linked to thermal waters
was supposed (Biancone 1993; Messana 1994).
Figure 4. Sketch of Monte Inici karst system and localization of
the thermal zone.
Figure 5. Abisso dei Cocci. Passages displaying sub-circular cross-
section with vadose entrenchment characterised by uncovered
ceiling and walls with cupolas and gypsum in the lower parts.
Different types of phosphate minerals were found in several
parts of the caves. Hydroxylapatite occurs as thin crusts or
powder above the bedrock, and even forms true stalactites.
Crandallite [CaAl3(PO4)2 (OH)5•H2O] is present as soft
white grains at the contact between weathered rock and bat
guano, in association with green small spherical masses of
montgomeryite [Ca4MgAl4(PO4)6(OH)4•12H2O].
Phosphates are linked to the presence of large fossil bat
guano deposits occurring in many parts of the cave.
3.2.2. Grotta dell’Eremita
Grotta dell’Eremita formed in Middle-Upper Jurassic
reddish-gray limestones with ammonites (Buccheri Fm.),
and in Lower Jurassic limestones and dolomitic limestones
(Inici Fm.) in its deepest parts. The cave is a relict 3D maze
cave, which reaches a total length of 2880 m, and a vertical
range of -306 m. The air temperature, measured in
Karst and Caves in Carbonate Rocks, Salt and Gypsum – oral 2013 ICS Proceedings
146
December 2011, was 17.6 °C in the passages near the
entrance area, gradually increasing up to 21.0 °C in deepest
chamber of the cave.
Grotta dell‘Eremita shows many morphological and
depositional features similar to Abisso dei Cocci, although
some differences were recognized. The cave is made up of
large subhorizontal passages and big chambers connected
by deep shafts, which are guided by the main tectonic
discontinuity planes. Some galleries are gently inclined
following the dip of bedding planes and display sub-circular
cross-sections. Along the walls of these passages, in
correspondence of the bedding planes, several small
conduits filled by well-cemented fine reddish sediment of
continental nature, are visible. Large convection niches,
mega-scallops, ceiling cupolas, ceiling spheres, and drip
holes are widespread in the chambers and in the largest
passages of the cavity (Fig. 6).
A breccia consisting of decimetric carbonatic clasts in a
reddish silt matrix characterized by thin laminas and
decantation structures is exposed at walls and ceiling of
some deep passages.
Different chemical deposits were identified: besides calcite,
occurring in the form of white cigar-shaped crystals grown
under old bat guano, reddish laminae, or coralloids, gypsum
was found as tabular or fibrous crystals. Phosphate
minerals, such as hydroxylapatite and taranakite, occur
mainly in form of powders or crusts near or above deposits
of bat guano. Carbonate-apatite was recognised as crusts or
small stalagmites (Messana 1994). As in Abisso dei Cocci
clastic sediments are absent.
3.3. Monte Kronio karst system
Monte Kronio karst system opens in the southern scarp of
Mt. Kronio or Mt. San Calogero, north-east of Sciacca town
(southern Sicily) (Fig. 1). Mt. Kronio consists of an
imbricate fan system linked to ENE-striking, closely spaced
imbricate thrust sheets, involving Triassic to Miocene
platform and pelagic platform carbonate deposits (Monaco
et al. 1996). The karst system is made up of a series of
cavities characterized by rising of hot air and vapour flow
at temperature of about 38 °C, connected to the presence of
thermal waters. These waters, emerging along the southern
slope of Mt. Kronio at lower altitude respect to the cave
entrances, are of chloride-sulphate alkaline type and have a
temperature ranging between 32 and 55 °C (Grassa et al.
2006 and references therein; Capaccioni et al. 2011).
Actually they are used for aesthetic and therapeutic
purposes.
The caves were visited by man since the end of the
Mesolithic for residential use, place of worship, necropolis,
and from the Ist century BC for thermal purposes. The first
attempts to explore the caves date back to the end of the
XVIIth century; since the 40s several exploration campaigns
conducted by the Commission Grotte “E. Boegan” of
Trieste identified and surveyed the cave system nowadays
known. The explorations, carried out with great difficulty,
due to the critical environmental conditions with
temperatures of about 38 °C and humidity of 100%, have
allowed the discovery of an extended maze cave system
about 200 m deep (Perotti 1994).
The system is composed of more cavities, located at
different altitude, characterized by subhorizontal passages
connected by deep shafts or steep passages, but there is not
always a passable connection between the several branches
of the caves. Some galleries breach the southern scarp of
Mt. Kronio through small openings some of which emit hot
air, other ones aspire cold air from outside (Perotti 1994).
The upper section of the system, known also as Stufe di San
Calogero, consists of a series of chambers separated by
man-made walls, connected to a maze of narrow passages.
Some chambers are characterized by hot vapour flow rising
from a deep shaft which connects these passages with two
large hot galleries, oriented in NW-SE direction, where
abundant archeological finds were discovered. A small cave
(Grotta del Lebbroso), interested by rising of hot vapour
flow, develops eastward at the same altitude, but to date no
passable connection to the rest of the system was
recognized. The deepest part of the cave is represented by
a large and deep shaft (Pozzo Trieste), from which more
levels of narrow passages, both hot and cold, develop
breaching the southern cliff of Mt. Kronio (Fig. 7). A large
breakdown deposit occurs at the bottom of the shaft.
Walls and ceiling of the caves are weathered and important
gypsum deposits, in form of powders or crusts, were
observed (Perotti 1994).
Figure 6. Grotta dell’Eremita. Passage along a bedding plane
where filled protoconduits are visible. Walls and ceiling are
characterised by large convection niches and cupolas.
Figure 7. Monte Kronio. Forms linked to condensation-corrosion
(on the right); weathered flat roof affected by condensation (on
the left).
Karst and Caves in Carbonate Rocks, Salt and Gypsum – oral 2013 ICS Proceedings
147
4. Discussion and Conclusions
The study of the geological setting, cave pattern, medium
and small scale morphological features, and the analysis of
cave minerals allowed defining a hypogenic genesis for the
investigated karst systems. All the caves developed along
structural planes, such as bedding, fracture or fault planes,
whose enlargement is due to corrosion by H2S-rich thermal
waters, and to condensation-corrosion processes by air flow
in the cave atmosphere.
Acqua Fitusa cave is an inactive water-table sulphuric acid
cave linked to corrosion processes of carbonate rock with
replacement of gypsum by H2S-rich thermal water (Fig. 8).
Occurrence of notches with flat roof indicates lateral
corrosion processes by sulphuric thermal water fed through
discharge slots still open on the floor of some passages.
Ceiling cupolas, large wall convection niches,
condensation-corrosion channels, boxwork testify that
enlargement of voids occurred mainly above the water table
where H2S degassing in the cave atmosphere, oxidation of
sulphides and thermal convection produced strong
condensation-corrosion processes. In addition, large
amounts of gypsum, replacement pockets, in places
containing gypsum, suggest the corrosion of the carbonate
rock occurred with replacement of gypsum according to the
sulphuric acid speleogenesis (Galdenzi and Maruoka 2003;
Audra et al. 2010 and references therein). Like other
sulphuric acid systems (Galdenzi and Menichetti 1995) the
different levels of passages record past stages of the water
table, in relation to changes of the base-level.
Grotta dell’Eremita and Abisso dei Cocci caves were
identified as inactive 3D maze caves. Pattern and cross
sections of the main passages of Abisso dei Cocci suggest
the early speleogenetic phases to have occurred in phreatic
conditions by rising thermal water which formed a well
developed 3D maze system. An important role in the
evolution and widening of the subterranean voids was
played by air flow when the cave passages switched from
phreatic to vadose conditions, as a consequence of the uplift
phases of this sector of the Sicilian chain. In this case, the
processes of corrosion by condensation from air flow rich
in H2S, favoured on one hand the enlargement of the early
voids with the formation of large megascallops and ceiling
cupolas, on the other hand the deposition of gypsum in the
lower parts of the passages (Fig. 9).
The first speleogenetic phases in phreatic conditions of
Grotta dell’Eremita are recorded, beside the pattern, by the
presence of several filled anastomosed protoconduits visible
at the bedding plane, along which the passages develop. The
next phase of evolution of the system may have followed
two possible ways: a) enlargement of voids by
condensation-corrosion processes which destroyed the
network of protoconduits and formed the main passages as
testified by the presence of megascallops, ceiling cupolas,
etc. (Fig. 10); b) corrosion processes by a deep sulphuric
thermal water enlarging the early voids, destroying the
protoconduits and forming the main passages in phreatic
Figure 8. Acqua Fitusa. Genetic mechanism of cave passages due
to H2S degassing in the cave atmosphere.
Figure 9. Abisso dei Cocci. Enlargement of passages by widening
of pre-existing forms due to condensation-corrosion.
Figure 10. Grotta dell’Eremita. Genesis of passages along a
bedding plane with formation of protoconduits enlarged by
condensation-corrosion.
Karst and Caves in Carbonate Rocks, Salt and Gypsum – oral 2013 ICS Proceedings
148
conditions. Successively, condensation-corrosion processes
by acid sulphuric air flow enlarged the early phreatic voids
with the formation of megascallops, ceiling cupolas etc.,
and deposition of gypsum. The question is open, future
studies will clarify the issue.
Finally, in all the investigated caves the presence of
different types of phosphate minerals is linked to the large
deposits of bat guano (Hill and Forti 1997).
Monte Kronio system is an active hypogenic karst system
and is unique in Sicily and probably in the world. It owes
its peculiarity to the rising of hot air and vapour flow, linked
to a deep thermal aquifer, still not identified within the
system. Although this system is known since prehistoric
times, yet little is known about its real development and
speleogenetic mechanisms due to the harsh environmental
conditions that make exploration extremely difficult.
Multidisplinary studies are currently in progress.
Acknowledgements
G. Ceresia, S. Inzerillo, A. Provenzano, L. Sausa, A. Scrima
contributed to resurvey Acqua Fitusa cave. G. Ceresia, A.
Provenzano, P. Tordjman and G. Valdese helped sampling.
Mr. Mancuso helped visiting to Monte Inici karst system.
Commissione E. Boegan and La Venta for facilitating the
field activities in the Monte Kronio caves. Michal Philippi
and Jiří Bruthans for the review of this paper.
References
Audra P, D’Antoni-Nobecourt J-C, Bigot J-Y, 2010. Hypogenic
caves in France. Speleogenesis and morphology of the cave
systems. Bulletin de la Société Géologique de France, 181 (4),
327–335.
Audra P, Mocochain L, Bigot J-Y, Nobécourt J-C, 2009. The
pattern of hypogenic caves. Proceedings of the 15th
International Congress of Speleology, Kerrville (TX), 2,
795–800.
Bianchini G, Gambassini P, 1973. Le Grotte dell’Acqua Fitusa
(Agrigento) I – Gli scavi e l’industria litica. Rivista di Scienze
Preistoriche, 28 (1), 1–55.
Biancone V, 1993. Monte Inici. Una sorpresa tutta siciliana!
Speleologia, 29, 72–77.
Capaccioni B, Vaselli O, Tassi F, Santo AP, Huertas AD, 2011.
Hydrogeochemistry of the thermal waters from the Sciacca
Geothermal Field (Sicily, southern Italy). Journal of Hydrology,
396, 292–301.
Catalano R, Agate M, Avellone G, Basilone L, Gasparo Morticelli
M, Gugliotta C, Sulli A, Valenti V, Gibilaro C, Pierini S, 2011.
Walking along a crustal profile across the Sicily Fold and
Thrust Belt. AAPG International Conference & Exhibition,
Post conference field trip 4, 27–29 October 2011.
Di Maggio C, Madonia G, Parise M, Vattano M, 2012. Karst in
Sicily and its conservation. Journal of Cave and Karst Studies,
74(2), 157–172.
Forti P, Mocchiutti A, 2004. Le condizioni ambientali che
permettono l’evoluzione di speleotemi di zolfo in cavità
ipogeniche: nuovi dati dalle grotte di Capo Palinuro (Salerno,
Italia). Le Grotte d’Italia, 4 (5), 39–48.
Galdenzi S, 1997. Initial geological observations in caves
bordering the Sibari plain (southern Italy). Journal of Cave and
Karst Studies, 59 (2), 81–86.
Galdenzi S, 2012. Corrosion of limestone tablets in sulfidic
ground-water: measurements and speleogenetic implications.
International Journal of Speleology, 41 (2), 149–159.
Galdenzi S, Maruoka T, 2003. Gypsum deposits in the Frasassi
Caves, central Italy. Journal of Cave and Karst Studies, 65,
111–125.
Galdenzi S, Menichetti M, 1995. Occurrence of hypogenic caves
in a karst region: examples from central Italy. Environmental
Geology, 26, 39–47.
Grassa F, Capasso G, Favara R, Inguaggiato S, 2006. Chemical
and isotopic composition of waters and dissolved gases in some
thermal springs of Sicily and adjacent volcanic islands, Italy.
Pure and applied geophysics, 163, 781–807.
Hill C, Forti P, 1997. Cave mineral of the world. National
Speleological Society, Huntsville, 463.
Klimchouk AB, 2007. Hypogene Speleogenesis: hydrogeological
and morphogenetic perspective. National Cave and Karst
Research Institute, Special Papers, 1, Carlsbad, NM, 106.
Klimchouk AB, Ford DC (Eds) 2009. Hypogene Speleogenesis
and Karst Hydrogeology of Artesian Basins. Ukrainian Institute
of Speleology and Karstology, Special Paper, 1, Simferopol,
280.
Lombardo G, Sciumè A, Sollano G, Vecchio E, 2007. La Grotta
dell’Acqua Fitusa e l’area della Montagnola nel territorio di
San Giovanni Gemini (Ag). Speleologia Iblea, 12, 125–132.
Messana E, 1994. Il sistema carsico del gruppo montuoso di M.
Inici (Castellammare del Golfo, TP). Bollettino
dell’Accademia Gioenia Scienze Naturali, 27 (348), 547–562.
Monaco C, Mazzoli S, Tortorici L, 1996. Active thrust tectonics
in western Sicily (southern Italy): the 1968 Belice earthquake
sequence. Terra Nova, 8, 372–381.
Palmer AN, 2011. Distinction between epigenic and hypogenic
maze caves. Geomorphology, 134, 9–22.
Perotti G., 1994. Kronio. – Le stufe di San Calogero e il loro flusso
vaporoso. Bollettino dell’Accademia Gioenia Scienze Naturali,
27 (348), 435–475.
Piccini L, 2000. Il carsismo di origine idrotermale del Colle di
Monsummano (Pistoia – Toscana). Le Grotte d’Italia, 1 (5),
33–43.
Plan L, Tschegg C, De Waele J, Spötl C, 2012. Corrosion
morphology and cave wall alteration in an Alpine sulfuric acid
cave (Kraushöhle, Austria). Geomorphology, 169–170, 45–54.
Stafford KW, Land L, Veni G (Eds.) 2009. Advances in Hypogene
Karst Studies. National Cave and Karst Research Institute
Symposium, 1, 182.
Tisato N, Sauro F, Bernasconi SM, Bruijn R, De Waele J, 2012.
Hypogenic contribution to speleogenesis in a predominant
epigenic karst system: A case study from the Venetian Alps,
Italy. Geomorphology, 151–152, 156–163.
Tusa S, 2004. Grotta del Cavallo e la preistoria del comprensorio
di Inici. In: CAI Palermo (Ed.). I Tesori di Monte Inici, 85–95.
Karst and Caves in Carbonate Rocks, Salt and Gypsum – oral 2013 ICS Proceedings
149
... These investigations have allowed identifying several hypogenic karst systems, previously thought to be epigenetic caves fed by meteoric water. The analysis of pattern, large-and mid-scale morphologies, mineral deposits and the presence of warm springs in areas close to the cavities in fact suggest that the genesis of these caves is linked to hypogenic processes (Vattano et al. 2012(Vattano et al. , 2013(Vattano et al. , 2015De Waele et al. 2016). ...
... The caves are rich in phosphate minerals (i.e., hydroxylapatite, taranakite, crandallite, carbonateapatite, montgomeryite) derived from the transformation of large fossil bat guano deposits. Beside powders or crusts, apatite often occurs as small stalactites and stalagmites (Messana 1994;Vattano et al. 2013). ...
... Kronio through small openings, some of which emit hot air, while other ones let cold air in from outside. Walls and ceiling of the caves are weathered, characterized by condensation-corrosion forms and powdery and/or crusty gypsum deposits are present (Fig. 3c, d;Vattano et al. 2013). Multidisciplinary studies are currently in progress to improve our knowledge on the extent, speleogenesis and the evolution of this important cave system. ...
Chapter
Full-text available
Karst in Sicily develops in both Messinian gypsum and Mesozoic or Tertiary limestone rocks. Caves are also found in the basalts of Mount Etna. Except for some rare cases, until recently most caves developed in limestone were considered to be of epigenetic origin. The discovery of gypsum in some of these caves, and especially detailed morphological studies, have allowed defining a hypogenic origin for a dozen of caves up to now. In some of these, the hypogenic evidences are very clear, while others remain in doubt because of the widespread presence of well-developed condensation-corrosion morphologies not necessarily related to hydrothermal fluids. This paper reports the present knowledge of hypogenic caves in the Island of Sicily.
... Studi speleologici condotti nell'area studiata (VATTANO et al., 2012(VATTANO et al., , 2013DE WAELE et al., 2014) segnalano l'esistenza di una cavità ipogea di notevole interesse (Grotta dell'Acqua Fitusa) legata alla presenza di circuiti idrici profondi e alla risalita di fluidi sulfurei, che danno origine a due sorgenti d'acqua sfruttate in passato per scopi termali. ...
... L'approfondimento e la denudazione che hanno interessato l'area studiata durante la sua evoluzione, sono le cause che portano alla luce l'apertura della Grotta dell'Acqua Fitusa e che ne influenzano il suo sviluppo. La Grotta dell'Acqua Fitusa rappresenta un chiaro esempio di grotta ipogenica sulfurea, legata alla risalita di acque ricche in H 2 S degassato nell'atmosfera della grotta, e formatasi in corrispondenza della superficie piezometrica (VATTANO et al., 2012(VATTANO et al., , 2013DE WAELE et al., 2014). Con il termine di grotte ipogeniche vengono generalmente indicate quelle cavità la cui genesi è legata ad acque provenienti dal basso ed indipendenti dall'infiltrazione dalle superfici soprastanti o adiacenti. ...
... Proprio per i particolari meccanismi speleogenetici, la Grotta dell'Acqua Fitusa è molto ricca di forme e depositi chimici particolari (cupole e nicchie di convezione, canali di corrosione per condensazione, tasche da sostituzione, boxwork, speleotemi e cristalli di gesso). Ad oggi è stato pienamente compreso il meccanismo speleogenetico ed evolutivo (VATTANO et al., 2012(VATTANO et al., , 2013DE WAELE et al., 2014), che è legato ai processi di corrosione per condensazione della roccia carbonatica con la sostituzione del gesso ad opera di acque termali ricche in H 2 S. In particolare, l'allargamento dei vuoti e la formazione delle principali forme a piccola e grande scala, sono dovute al degassamento di H 2 S nell'atmosfera di grotta, all'ossidazione dei solfati e alla convezione termale che permette processi di condensazionecorrosione, sopra la tavola d'acqua. Il progressivo abbassamento di quest'ultima, collegata ai processi di approfondimento conseguenti ai fenomeni di sollevamento dell'area, ha poi permesso lo sviluppo su più livelli, fino al raggiungimento dell'attuale assetto della cavità. ...
Article
Full-text available
PROPOSTA DI UN GEOSITO RIASSUNTO Vengono presentati i risultati di uno studio multidisciplinare condotto nell'area de La Montag-nola (Sicilia centrale). L'area indagata presenta peculiari aspetti scientifici e culturali. Essa costitu-isce un settore rappresentativo della geologia e della geomorfologia dei Monti Sicani. In questo set-tore si riconoscono: successioni di carbonati di mare profondo, del Giurassico-Eocene (successione Imerese) e le coperture clastico-torbiditiche dell'Oligo-Miocene (flysch Numidico); successioni di depositi clastico-evaporitici di bacino di wedge-top, del Miocene Pliocene; culminazioni anticli-naliche e fronte SO delle unità Imeresi sovrascorse sulle unità Sicane; forme fluviali di approfondi-mento, forme strutturali derivate, forme gravitative e forme di ruscellamento diffuso o concentrato, quali tipiche morfologie dei rilievi collinari della Sicilia centrale. Dal punto di vista speleologico e carsologico, l'elemento più significativo presente nell'area indagata, che costituisce anche l'emer-genza di maggiore interesse, è la Grotta dell'Acqua Fitusa. Questa grotta è costituita da un sistema di cavità sotterranee la cui genesi è dovuta alla risalita di acque termali profonde di natura sulfurea. Al suo interno sono stati inoltre ritrovati resti scheletrici ed industriali di Homo sapiens, che con-feriscono a questa cavità un importante valore antropologico; così come di sicuro interesse antropo-logico è la Rocca del Vruaro, con i suoi reperti industriali. La totalità dei dati acquisiti mostra quin-di un'area con elementi geologici e antropologici significativi, di una certa importanza scientifica e culturale, tali da giustificare la proposizione di un Geosito. Parole chiave: Aspetti naturalistico-antropologici, Geosito, La Montagnola, Sicilia centrale SUMMARY Geological, geomorphological and anthropological aspects of La Montagnola (San Giovanni Gem-ini, Agrigento): proposal of a Geosite. We present the results of a multidisciplinary study conducted in the area of La Montagnola (central Sicily). The study area covers the eastern side of the Sicani Mts., where the deep-water carbonate thrust system outcrops. It consists both of a set of SW-ward
... In the following years, research on the hypogenic caves extended to new localities in western Umbria (Menichetti h closed valley with karstic drainage; i CO 2 -rich vent; j CO 2 -rich spring; k Apennines water divide; l geothermal anomaly-thick dotted line represents 100 mW/m 2011), Tuscany (Montecchio cave, Menichetti 2009;Piccini et al. 2015), Latium (Galdenzi 2003), Campania (Capo Palinuro, Forti and Mocchiuti 2004), and outside the Apennines in Sicily (Vattano et al. 2013;De Waele et al. 2016) and Sardinia (De Waele et al. 2013). New research also re-examined evidence for speleogenesis in the previously studied Monte Cucco system (Galdenzi 2004;Menichetti et al. 2008), Acquasanta Terme caves (Menichetti 2008;Galdenzi et al. 2010), and the Frasassi Caves (Galdenzi et al. , 2008Galdenzi 2012;Galdenzi and Campagnoli 2015). ...
Chapter
Hypogene speleogenesis is important for karstification in the Apennines because of widespread, aggressive groundwaters containing endogenic H2S and CO2. Evidence for karst processes can be found throughout the region, from solutional limestone caves to deposition of carbonate travertine. The caves are up to few tens of kilometers long and show different patterns, ranging from phreatic to almost ideal water table caves. The caves often have a maze pattern and contain large rooms, cupola roofs, blind pits, and anastomotic zones. Solutional processes prevailed in the phreatic zone, also in deep-seated conditions, but subaerial corrosion is developed as well and can play an important morphogenetic role. The main cave-forming processes are related to the H2S oxidation to sulfuric acid, a process that involves chemotrophic microbial activity, and are responsible for the diffuse deposition of replacement gypsum in subaerial conditions. The great variety of geological settings makes the Apennines a good place to study hypogene karst, and the existence of active branches in several caves also permits a direct study of the cave-forming processes and the comparison with the resultant morphologies.
... In Sardinia, the formation of many mine caves can be ascribed to this type of speleogenesis (De Waele et al., 2013a), while Montecchio Cave was studied in detail in Tuscany (Piccini et al., 2015). In Sicily, several caves host gypsum deposits or have typical SAS morphologies, such as Acqua Fitusa, Monte Inici, and Monte Kronio caves (Vattano et al., 2013;De Waele et al., 2014b). Typical SAS morphologies have also been described from epigenic caves in Veneto, in which the local oxidation of pyrite caused the formation of sulfuric acid (Tisato et al., 2012). ...
... The first detailed exploration, description and cave survey was produced by the Gruppo Speleologico Agrigento (Lombardo et al., 2007). According to a more recent survey made in 2011 (Vattano et al., 2013), the cave consists of at least three stories of sub-horizontal conduits, displaying a total length of 700 m, and a vertical range of 25 m (Fig. 6). The main passages are generally low and narrow and follow sets of joints oriented in ENE–WSW, E–W and N–S directions, except when they merge producing large volumes such as at the entrance room. ...
... More recently, in some of these caves detailed studies have been carried out including geomorphology, mineralogy, and geochemistry. Sulfuric acid caves are known from many regions along the Apennine chain (Tuscany, Umbria, Marche, Latium, Campania, Calabria) (Forti, 1985;Forti et al., 1989;Menichetti, 1989, 1995;Galdenzi, 1997Galdenzi, , 2001Galdenzi, , 2009Galdenzi et al., 2010;Piccini, 2000;Menichetti, 2009Menichetti, , 2011Mecchia, 2012;De Waele et al., 2013b), but also from Piedmont, Apulia, Sicily (Vattano et al., 2013) and Sardinia (De Waele et al., 2013a). In this last region ascending fluids have also formed a hypogene cave in quartzite rock. ...
Conference Paper
Full-text available
Although hypogene cave systems have been described since the beginning of the XXth century, the importance of ascending fluids that acquired their aggressiveness from in-depth sources in speleogenesis has been fully realized only in the last decades. Aggressiveness of waters can be related to carbonic and sulfuric acids and the related corrosion-dissolution processes give rise to different types of caves and underground morphologies. The abundance of hydrothermal springs and associated travertine deposits, and the widespread interaction between volcanic or sub-volcanic phenomena and karst in many sectors of the Italian peninsula are a strong evidence of hypogene speleogenesis. Furthermore, researches on secondary minerals have allowed to discover hypogene caves formed by highly acidic vapors in subaerial environments, also showing that most of these caves have extremely rich mineral associations. Despite this, until the late 80s the only known important cave systems of clear hypogene origin in Italy were considered to be the ones hosted in the Frasassi Canyon and Monte Cucco, in which important gypsum deposits undoubtedly showed that sulfuric acid played an important role in the creation of voids (Galdenzi, 1990, 2001; Galdenzi & Maruoka, 2003; Menichetti et al., 2007). Afterwards many other caves were categorized as formed by the sulfuric acid speleogenesis throughout the entire Apennines. Following the broad definition of hypogene caves by Palmer in 1991, and the even more general one of Klimchouk in the last decade (Klimchouk, 2007, 2009), the number of caves considered of hypogene origin in Italy has grown rapidly. Figure 1 shows the hypogene karst systems of Italy, including, besides the well-known and published ones, also the known and less studied, and presumed hypogene cave systems (see also Table 1). More recently, in a few of these caves detailed studies have been carried out including geomorphology, mineralogy, and geochemistry. Sulfuric acid caves are known from many regions along the Apennine chain (Tuscany, Umbria, Marche, Latium, Campania, Calabria) (Forti, 1985; Forti et al., 1989; Galdenzi & Menichetti, 1989, 1995; Galdenzi, 1997, 2001, 2009; Galdenzi et al., 2010; Piccini, 2000; Menichetti, 2009, 2011; Mecchia, 2012; De Waele et al., 2013b), but also from Piedmont, Apulia, Sicily (Vattano et al., 2013) and Sardinia (De Waele et al., 2013a). In this last region ascending fluids have also formed a hypogene cave in quartzite rock. Oxidation of sulfides can locally create hypogene cave morphologies in dominantly epigenic caves, such as in the Venetian forealps (this cave is not shown in Figure 1, being largely epigenic in origin)(Tisato et al., 2012). Ascending fluids have also created large solution voids in Messinian gypsum beds in Piedmont, and these can be defined hypogene caves according to the definition by Klimchouk (Vigna et al., 2010). Some examples of hypogene cave systems due to the rise of CO2-rich fluids are also known in Liguria and Tuscany (Piccini, 2000). In the Alps and Prealps (Lombardy), some ancient high mountain karst areas exhibit evidences of an early hypogene origin, deeply modified and re-modeled by later epigenic processes: hypogene morphologies are thus preserved as inactive features, and it is often difficult to distinguish them from epigenic ones. At almost twenty years distance from the first review paper on hypogene cave systems in Central Italy by Galdenzi and Menichetti (1995), we give a review of the state-of-the-art knowledge on hypogene caves actually known from the whole of Italy.
Article
Full-text available
Condensation corrosion is a natural process which enhances the chemical weathering of limestone cave chambers and speleothems. We evaluated the use of carbonate tablets for detecting condensation corrosion in Glowworm Cave, New Zealand, using local limestone and speleothem as experimental substrates (herein tablets). Evidence for condensation corrosion was assessed via three methods: gravimetric (mass wasting), microscopic (surface pitting, recrystallization) and isotopic (δ¹³C and δ¹⁸O changes). Our results show little evidence of tablet mass loss throughout a 6-month deployment period. However, SEM imaging and isotope analysis (δ¹³C and δ¹⁸O) of the upper ∼50 μm layer of the tablets, suggest that condensation corrosion operates in the cave, especially in sectors affected by large diurnal microclimate variations. Most notably, condensation water altered the tablet surface δ¹³C and δ¹⁸O values. Small, positive shifts in surface δ¹³C and δ¹⁸O values are considered to reflect pure dissolution (where dissolution favours the removal of lighter isotopologues). In contrast, tablets that exhibited large positive shifts in δ¹³C in tandem with large negative shifts in δ¹⁸O values, are interpreted as showing calcite recrystallization and the inheritance of higher DIC δ¹³C values (¹³C fractionation by CO2 degassing), lighter water δ¹⁸O values and/or kinetic fractionation of δ¹⁸O. This study therefore demonstrates that stable isotopes could be applied to detect paleoclimatic episodes of condensation corrosion in speleothems.
Article
The karst of Sorbas (SE Spain) is one of the most important gypsum areas worldwide. Its underground karst network comprises over 100 km of cave passages. Rounded smooth forms, condensation cupola and pendant-like features appear on the ceiling of the shallower passages as a result of gypsum dissolution by condensation water. Meanwhile, gypsum speleothems formed by capillarity, evaporation and aerosol deposition such as coralloids, gypsum crusts and rims are frequently observed closer to the passages floors. The role of condensation-dissolution mechanisms in the evolution of geomorphological features observed in the upper cave levels has been studied by means of long-term Micro-Erosion Meter (MEM) measurements, direct collection and analysis of condensation waters, and micrometeorological monitoring. Monitoring of erosion at different heights on gypsum walls of the Cueva del Agua reveals that the gypsum surface retreated up to 0.033 mm yr-1 in MEM stations located in the higher parts of the cave walls. The surface retreat was negligible at the lowest sites, suggesting higher dissolution rates close to the cave ceiling, where warmer and moister air flows. Monitoring of microclimatic parameters and direct measurements of condensation water were performed in the Covadura Cave system in order to estimate seasonal patterns of condensation. Direct measurements of condensation water dripping from a metal plate placed in the central part of the El Bosque Gallery of Covadura Cave indicate that condensation takes place mainly between July and November in coincidence with rainless periods. The estimated gypsum surface lowering due to this condensation water is 0.0026 mm yr-1. Microclimatic monitoring in the same area shows differences in air temperature and humidity of the lower parts of the galleries (colder and drier) with respect to the cave ceiling (warmer and wetter). This thermal sedimentation controls the intensity of the condensation-evaporation mechanisms at different heights in the cave.
Article
Full-text available
The Frasassi Caves are hypogenic caves in central Italy, where H2S-rich groundwater flows in the lowest cave level. Near the water table, the H2S is converted to sulfuric and by biotic and abiotic processes, which have enhanced cave development. The sulfate generally deposits above the water table as a replacement gypsum crust coating limestone walls or as large gypsum crystals. Although the oxidation of sulfide also occurs below the water table, sulfate saturation is not achieved, therefore, sulfate does not precipitate below the water table. In the upper dry levels of the cave, three main types of ancient gypsum deposits occurs: (1) replacement crusts, similar to the presently forming deposits of the active zone, (2) microcrystalline large and thick floor deposits, and (3) euhedral crystals inside mud. The study of the depositional setting and the analysis of sulfur isotopes in the gypsum and groundwater clearly demonstrate that all the sampled gypsum in the cave formed by H2S oxidation above the water table. Some fraction of small sulfur isotopic differences between H2S in the water and gypsum can be explained by isotopic fractionation during abiotic and/or biotic oxidation of H2S.
Article
Full-text available
Hypogenic caves develop by recharge from below, not directly influenced by seepage from the overlying land surface. Several processes of speleogenesis are combined, involving CO2 or H2S produced at depth. If the recharge from depth remains uniform, the growth of selected fissures is prevented, giving rise to maze cave systems with an upward development trend, which is defined as “transverse speleogenesis” [Klimchouk, 2003]. Hypogenic caves are much fewer than epigenic caves (i.e. developed downwards by meteoric water with aggressivity derived from soil). In France, as in the rest of the world, hypogenic caves were poorly recognized until recently because of their lower frequency, subsequent epigenic imprint often hiding the true origin, and the absence of a global conceptual model. However, about a hundred of hypogenic caves have been identified recently in France. The extreme diversity of hypogenic cave patterns and features is due to the variety of geological and topographic settings and types of flow. Thermal caves are a sub-set of hypogenic caves. Active thermal caves are few and small (Mas d’En Caraman, Vallon du Salut). Often, thermal influences only occur as point thermal infeeders into epigenic caves (Mescla, Estramar). In addition to the higher temperature, they may be characterized by CO2 (Madeleine) or H2S degassing, by warm water flowing in ceiling channels, or by manganese deposits. The Giant Phreatic Shafts locate along regional active faultlines. They combine all characteristics (thermal, CO2, H2S), due to the fast rising of deep water. The Salins Spring has been explored by scuba diving down to −70 m. Such a hyperkarstification is responsible for the development of the deepest phreatic shafts of the world: pozzo del Merro, Italy (−392 in). Inactive hypogenic caves may be recognized by their specific mineralization or by the presence of large calcite spar. Metallic deposits are due to the rising of deep waters that are warm, aggressive, and low in oxidation potential. Mixing with meteoric water generates Mississippi Valley Type (MVT) sulfidic ores. Iron deposits as massive bodies (Lagnes) or onto microbial media (Iboussières, Malacoste) making specific facies, such as “black tubes”, iron flakes, and iron pool fingers. Other frequent minerals are Mn oxides and Pb sulfur. In such low thermal conditions, calcite deposits occur as large spar in geodes or as passage linings. Other inactive hypogenic caves may also be recognized by characteristic patterns, such as mazes. The relatively constant recharge into confined karst aquifers suppresses fissure competition, so they enlarge at similar rates, producing a maze pattern. In horizontal beds, mazes extend centrifugally around the upwelling feeder. The juxtaposition of multiple discrete vertical feeders produces extended horizontal mazes. In gently tilted structures, 2D mazes extend below aquitards, or along bedding or more porous beds (Saint-Sébastien). In thick folded limestone the rising hypogenic flow alternatively follows joints and bedding planes, producing a 3D maze cave in a staircase pattern (Pigette). Isolated chambers are large cupola-like chambers fed by thermal slots. Thermal convection of air in a CO2-rich atmosphere causes condensation-corrosion that quickly produces voids above the water table (Champignons Cave). Sulfuric acid caves with replacement gypsum are produced by H2S degassing in the cave atmosphere. H2S oxidizes to H2SO4, which corrodes the carbonate rock and replaces it with gypsum. The strongest corrosion occurs above the water table, where sulfide degassing and thermal convection produce strong condensation-corrosion. Caves develop headward from springs and from thermo-sulfuric slots upward (Chevalley-Serpents System). The low-gradient main drains record base-level positions and even the slightest stages of water-table lowering (Chat Cave). Hypogenic speleogenesis provides better understanding of the distribution of karst voids responsible for subsidence hazards and the emplacement of minerals and hydrocarbons.
Book
Full-text available
This book provides an overview of the principal environments, main processes and manifestations of hypogenic speleogenesis, and refines the relevant conceptual framework. It consolidates the notion of hypogenic karst as one of the two major types of karst systems (the other being epigenetic karst). Karst is viewed in the context of regional groundwater flow systems, which provide the systematic transport and distribution mechanisms needed to produce and maintain the disequilibrium conditions necessary for speleogenesis. Hypogenic and epigenic karst systems are regularly associated with different types, patterns and segments of flow systems, characterized by distinct hydrokinetic, chemical and thermal conditions. Epigenic karst systems are predominantly local systems, and/or parts of recharge segments of intermediate and regional systems. Hypogenic karst is associated with discharge regimes of regional or intermediate flow systems. Various styles of hypogenic caves that were previously considered unrelated, specific either to certain lithologies or chemical mechanisms are shown to share common hydrogeologic genetic backgrounds. In contrast to the currently predominant view of hypogenic speleogenesis as a specific geochemical phenomenon, the broad hydrogeological approach is adopted in this book. Hypogenic speleogenesis is defined with reference to the source of fluid recharge to the cave-forming zone, and type of flow system. It is shown that confined settings are the principal hydrogeologic environment for hypogenic speleogenesis. However, there is a general evolutionary trend for hypogenic karst systems to lose their confinement due to uplift and denudation and due to their own expansion. Confined hypogenic caves may experience substantial modification or be partially or largely overprinted under subsequent unconfined (vadose) stages, either by epigenic processes or continuing unconfined hypogenic processes, especially when H2S dissolution mechanisms are involved. Hypogenic confined systems evolve to facilitate cross-formational hydraulic communication between common aquifers, or between laterally transmissive beds in heterogeneous soluble formations, across cave-forming zones. The latter originally represented low-permeability, separating units supporting vertical rather than lateral flow. Layered heterogeneity in permeability and breaches in connectivity between different fracture porosity structures across soluble formations are important controls over the spatial organization of evolving ascending hypogenic cave systems. Transverse hydraulic communication across lithological and porosity system boundaries, which commonly coincide with major contrasts in water chemistry, gas composition and temperature, is potent enough to drive various disequilibrium and reaction dissolution mechanisms. Hypogenic speleogenesis may operate in both carbonates and evaporites, but also in some clastic rocks with soluble cement. Its main characteristic is the lack of genetic relationship with groundwater recharge from the overlying or immediately adjacent surface. It may not be manifest at the surface at all, receiving some expression only during later stages of uplift and denudation. In many instances, hypogenic speleogenesis is largely climate independent. There is a specific hydrogeologic mechanism inherent in hypogenic transverse speleogenesis (restricted input/output) that suppresses the positive flow-dissolution feedback and speleogenetic competition in an initial flowpath network. This accounts for the development of more pervasive channeling and maze patterns in confined settings where appropriate structural prerequisites exist. As forced-flow regimes in confined settings are commonly sluggish, buoyancy dissolution driven by either solute or thermal density differences is important in hypogenic speleogenesis. In identifying hypogenic caves, the primary criteria are morphological (patterns and meso-morphology) and hydrogeological (hydrostratigraphic position and recharge/flow pattern viewed from the perspective of the evolution of a regional groundwater flow system). Elementary patterns typical for hypogenic caves are network mazes, spongework mazes, irregular chambers and isolated passages or crude passage clusters. They often combine to form composite patterns and complex 3- D structures. Hypogenic caves are identified in various geological and tectonic settings, and in various lithologies. Despite these variations, resultant caves demonstrate a remarkable similarity in cave patterns and meso-morphology, which strongly suggests that the hydrogeologic settings were broadly identical in their formation. Presence of the characteristic morphologic suites of rising flow with buoyancy components is one of the most decisive criteria for identifying hypogenic speleogenesis, which is much more widespread than was previously presumed. Hypogenic caves include many of the largest, by integrated length and by volume, documented caves in the world. The refined conceptual framework of hypogenic speleogenesis has broad implications in applied fields and promises to create a greater demand for karst and cave expertise by practicing hydrogeology, geological engineering, economic geology, and mineral resource industries. Any generalization of the hydrogeology of karst aquifers, as well as approaches to practical issues and resource prospecting in karst regions, should take into account the different nature and characteristics of hypogenic and epigenic karst systems. Hydraulic properties of karst aquifers, evolved in response to hypogenic speleogenesis, are characteristically different from epigenic karst aquifers. In hypogenic systems, cave porosity is roughly an order of magnitude greater, and areal coverage of caves is five times greater than in epigenic karst systems. Hypogenic speleogenesis commonly results in more isotropic conduit permeability pervasively distributed within highly karstified areas measuring up to several square kilometers. Although being vertically and laterally integrated throughout conduit clusters, hypogenic systems, however, do not transmit flow laterally for considerable distances. Hypogenic speleogenesis can affect regional subsurface fluid flow by greatly enhancing initially available crossformational permeability structures, providing higher local vertical hydraulic connections between lateral stratiform pathways for groundwater flow, and creating discharge segments of flow systems, the areas of lowfluid potential recognizable at the regional scale. Discharge of artesian karst springs, which are modern outlets of hypogenic karst systems, is often very large and steady, being moderated by the high karstic storage developed in the karstified zones and by the hydraulic capacity of an entire artesian system. Hypogenic speleogenesis plays an important role in conditioning related processes such as hydrothermal mineralization, diagenesis, and hydrocarbon transport and entrapment. An appreciation of the wide occurrence of hypogenic karst systems, marked specifics in their origin, development and characteristics, and their scientific and practical importance, calls for revisiting and expanding the current predominantly epigenic paradigm of karst and cave science.
Article
Full-text available
The measurement of the weight loss in limestone tablets placed in the Grotta del Fiume (Frasassi, Italy) provided data on the rate of limestone dissolution due to the sulfidic water and on the influence of local environmental conditions. A linear average corrosion rate of 24 mm ka-1 was measured in stagnant water, while the values were higher (68-119 mm ka-1) where the hydrologic conditions facilitate water movement and gas exchanges. In these zones the increase in water aggressivity is due to mixing with descending, O2-rich, seepage water and is also favored by easier gas exchange between ground-water and the cave atmosphere. Very intense corrosion was due to weakly turbulent flow, which caused evident changes in the tablets shape in few months. A comparison between the measured corrosion rates and the cave features showed that the values measured in the pools with stagnant water are too low to account for the largest solutional cave development, while the average values measured in the zones with moving water are compatible with the dimension of the cave rooms in the main cave levels, that must have developed when the base level was stable and hydrologic conditions favored the increase of water aggressivity.
Article
Full-text available
Geologic investigation of caves in the northern Calabria region of Italy has clarified their origin and irregular distribution. Caves and surface karst landforms are not widespread, despite the fact that the local limestones are widely exposed and surface drainage is poorly developed. The caves are located in small limestone hills and mountains around the Sibari Plain and are surrounded by low-permeability rocks. Among them is a significant shaft cave fed by a sinking stream that drains a non-karst recharge area. However, most of the caves are predominantly horizontal and have entrances at low altitudes at several levels. Their origin is due to the rising of thermal waters, which are mineralized after passing through the Neogene formations of the Sibari Plain. The caves can be considered relict hypogenic out- flow caves. The main cave-forming process was probably the oxidation of H 2S, favored by the mixing of thermal water and infiltrating fresh water. Oxidation of H 2S has resulted in gypsum deposits within the caves.
Article
Full-text available
The Monsummano hill is a small karst area in the northern Tuscany. The interest of this area concerns the occurrence of active hydrothermal karst phenomena. A thermal spring in the NW part of the hill has a mean discharge of 500 l/min. The total amount of water can not be justify with the local infiltration, thus an hallogenic recharge area must be found. Surface karst forms and caves occur on the carbonate outcrops. The largest caves is the famous Grotta Giusti, which is exploited from 1850 for therapeutic use. This cave and other smaller caves were formed by the action of thermal water rising along a normal fault system. Different types of speleothemes, phreatic or vadose in the origin, are present in all the investigated caves. Some of these are due to the gravity sedimentation of floating calcite. The progressive lowering of the hydrothermal water table was caused by the erosion of impermeable rocks around the carbonate structure. This led to the formation of a new generation of speleothemes by cold percolation water.
Book
Txtbook on cave minerals and speleothems