in russian: SYNTHESIS, PHYSICAL CHEMICAL AND FIREPROOF PROPERTIES OF AMMONIUM METALLOPHOSPHATE
Abstract
It is shown, that the change of phase structure, chemical composition of metallophosphatic fire retardants and products of their heat treatment at 200 – 500 оС leads to the increase of heat-insulating abilities due to the formation of intumescent coverings and isolating melts. The compositions show optimum fireproof properties if they form on the surface of wood intumescent structures and thin melts, which do not block the liberation of volatile nitrogenated inhibitors of burning in a gas phase. The quantitative yield of volatile inhibitors of burning to a flaming zone is determined by features of processes of transformation of fire-retardant systems in a pre-ignition zone of the condensed phase.
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