The Central Indian Tectonic Zone (CITZ) trending E W to ENE WSW is a suture zone between the North Indian Block (NIB), which includes Aravalli Craton and Bundelkhand Craton, and the South Indian Block (SIB), which includes Dharwar Craton, Singhbhum Craton and Bastar Craton. It consists of three supracrustal basins viz. Mahakoshal Basin, Betul Basin and Sausar Basin from north to south, respectively. The Mahakoshal Basin is the oldest basin among them. It is conjectured that the opening of the Mahakoshal Basin took place at ~2.1 Ga and closed at ~1.8 Ga. The granite gneiss is the basement of the Mahakoshal Group. The Mahakoshal Group consist of three formations viz Saleemnabad Formation, Parsoi Formation and Dudhmaniya Formation from lower to upper, respectively. The lowermost formation (Saleemnabad Formation) mainly consists of metabasalts and meta argillites, with subordinate amount of ultramafic rocks, banded iron formations (BIF), chert and carbonates. The middle formation (Parsoi Formation) mainly consists of meta
argillites and meta greywackes, with subordinate amount of pyroclastic rocks. The meta argillites are intercalated with the thin bends of pyroclastic rocks. The uppermost formation (Dudhmaniya Formation) consists of quartzites and BIF. The Mahakoshal Group is intruded by several small granite and granite gneiss plutons, lamprophyre dykes and quartz veins.
The present work focuses on the geochemical studies of the Mahakoshal metabasalts, which include major oxides and trace elements data, clastic metasedimentary rocks (meta argillites, meta greywackes and quartzites), which include major oxides, trace elements and Sr Nd isotopic data and Sidhi granite gneiss and Madanmahal granite, which includes major oxides, trace elements and zircon U
Pb geochronology. The geochemical studies of the metabasalts were carried out to understand the genesis and the tectonic settings in which they were emplaced. The geochemical studies of the clastic metasedimentary rocks were carried out to identify the probable source rocks, paleoweathering conditions and their tectonic setting. Earlier studies suggest that the Sidhi granite gneiss is the probable source of the meta
argillites. So, to verify it, I carried out geochemical studies of Sidhi granite gneiss and Madanmahal granite, including major oxide and trace elements data along with zircon U Pb geochronology.
The Mahakoshal metabasalts are restricted in the lowermost formation i.e. the Saleemnabad Formation. They are intercalated with meta sedimentary rocks (meta
argillites and chert). These metabasalts show pillow structures in some places, and in some places, massive meta basalts are found. Petrographic studies exhibit that the Mahakoshal metabasalts are fine to medium grained. They are dominantly composed of plagioclase, actinolite and chlorite. The epidote is present as an alteration product. The mineralogy of the Mahakoshal metabasalts suggests that they have undergone up to greenschist facies metamorphism. The elongated chlorite and actinolite in a preferred orientation suggest that the studied rocks have suffered metamorphic foliation.
Geochemically, the Mahakoshal metabasalts range in SiO2 from 43.02 wt% to 59.54 wt%, and MgO ranges from 4.56 wt% to 6.52 wt%. The Mahakoshal metabasalts show a high concentration of Fe2O3T, ranging from 12.45 wt% to 17.81 wt%. The magnesium number (Mg#) varies from 0.2 to 0.3, suggesting that the studied metabasalts are evolved in nature. The Mahakoshal metabasalts have a high concentration of Cr, ranging from 121 to 889 ppm; Co, ranging from 19 to 77 ppm; Sc, ranging from 26 to 43 ppm; and Ni, ranging from 70 to 273 ppm. The Mahakoshal metabasalts are sub alkaline and belong to the tholeiitic series. Moreover, they show high Fe tholeiite basalt signatures.
The chondrite normalized rare earth elements (REE) patterns show different degrees of fractionation of the light rare earth elements (LREE) patterns. Some samples show highly enriched LREE patterns (fractionation in LREE), and other samples show flat LREE patterns (no fractionation in LREE). However, all samples show similar flat, heavy rare earth elements (HREE) patterns. The REE patterns show no significant anomaly. In the primitive mantle (PM) normalized multi element diagram, the studied rocks do not show any significant anomaly of Nb (Nb/Nb* ranges from 0.7 to 1.3; average = 1.0; except for sample KP 144 which is 0.1) and Ti (Ti/Ti* ranges from 0.8 1.1; average = 0.9; except for sample KP 144 which is 0.1), suggesting that these rocks are not affected by any crustal input and show their pristine nature.
The crustal contamination is assessed by using various geochemical proxies, such as Nb/Th, Nb/La and LaN/SmN. The Nb/Th ratios of the Mahakoshal metabasalts range from 5.41 to 11.87, which is close to the primitive mantle (Nb/Th = 8). Further, to evaluate the crustal input, I have plotted Nb/Th vs Nb/La and Nb/Th vs LaN/SmN bivariate diagrams, which show that Mahakoshal metabasalts are not affected by the crustal inputs except for sample KP 144.
The source of the Mahakoshal metabasalts is constrained by using various geochemical proxies. The studied metabasalts are produced by the enriched Mid
Ocean Ridge Basalt (E MORB) type mantle. The E MORB type mantle source is suggested by Ce/Y vs LaN/YbN and Th/Yb vs Nb/Yb bivariate diagrams. In the Sm/Yb vs Sm bivariate plot, some samples of the Mahakoshal metabasalts are plotted near the spinel lherzolite field and show a higher degree of partial melting, whereas some other samples are plotted near the spinel garnet lherzolite field and show a low degree of partial melting. This may suggest that the studied metabasalts are produced at different depths by different degrees of partial melting.
The tectonic settings of the Mahakoshal metabasalt were ascertained by using field evidence clubbed with various tectonic discriminant diagrams. The Mahakoshal Group consists of basalts associated with dacite and rhyolite (pyroclastic rocks). This type of rock association is found in arc related environment. Further, TiO2 vs V and ThN vs NbN tectonic discriminate diagrams reveal that the studied metabasalts are emplaced in the back arc tectonic setting.
The clastic meta sedimentary rocks of the Mahakoshal Group include meta
argillites, which are present in the Saleemnabad Formation and the Parsoi Formation; meta greywackes, which are present in the Parsoi Formation; and quartzites, which are present in the Dudhmaniya Formation. The meta argillites of the Saleemnabad Formation are intercalated with the metabasalts, and meta argillites of the Parsoi Formation are intercalated with the pyroclastic rocks. The XRD analysis of meta
argillites of both formations suggests that they consist of chlorite, muscovite, illite and albite with subordinate amount of quartz. The petrographic studies of the meta
greywackes reveal that they are medium to coarse grained and show poor sorting. Mineralogically, they consist of quartz, feldspar, opaque minerals and rock fragments with 15 17% matrix. The quartzites are dominated by quartz with a subordinate amount of fuchsite.
Geochemically, the meta argillites of the Saleemnabad Formation consist of SiO2 varying from 48.72 wt% to 64.51 wt%, Al2O3 varying from 11.00 wt% to 20.44 wt%, and MgO ranges from 0.75 wt% to 2.98 wt%. The meta argillites and the meta
greywackes of the Parsoi Formation consist of SiO2 which ranges from 43.10 wt% to 68.28 wt% and 71.31 wt% to 82.68 wt%, respectively. The Al2O3 content in the metaargillites and the meta greywackes ranges from 6.01 wt% to 25.04 wt%, and 7.52 wt% to 13.32 wt%, respectively, and MgO content ranges from 0.73 wt% to 9.89 wt% and 0.64 wt% to 3.84 wt%, respectively. The quartzites of the Dudhmaniya Formation contain a high concentration of SiO2, ranging from 90.85 wt% to 97.88 wt%. The Al2O3 content in quartzites varies from 0.12 wt% to 4.43 wt%, and MgO concentration varies from 0.02 wt% to 0.98 wt%. The meta clastic rocks of the Mahakoshal Group (meta argillites of both the formations, meta greywackes and quartzites) are enriched in Cr, Co, V, and Sc, suggesting their affinity with mafic rocks. The REE patterns of the studied meta clastic rocks show highly fractionated patterns with no significant Eu anomaly. However, some meta argillites samples of the both formations (Saleemnabad and Parsoi formations) show prominent negative Ce anomalies.
The provenance characterization and tectonic setting of the meta clastic rocks of the Mahakoshal Group have been deciphered by using major oxides, trace elements and Sr Nd isotopic constraints. Th/Sc, La/Sc, La/Co, Th/Co, and Th/Cr ratios suggest that the sources of the meta clastic rocks are heterogeneous. In the La Th Sc ternary diagram, the studied meta clastic rock samples plot along the La Sc array, which suggests that the sediments are contributed from felsic as well as mafic sources. In the V Ni 10*Th ternary diagram, the studied meta clastic rock samples plot along the V
10*Th array, which endorses that the sediments are contributed from felsic as well as mafic sources. The sediments also show arc signatures such as high LILE concentration and low HFSE concentration. The isotopic signatures also suggest the contribution of sediments from the arc as well as the older Archean crust. The εNd(1.894 Ga) vs Th/Sc diagram reveals that the sediments are contributed from the mafic arc and older Archean crust. The f(Sm/Nd) vs εNd(1.894 Ga) also endorse the contribution from the mafic arc and older Archean crust. Moreover, in the La Th Sc tectonic discriminant diagram, most of the studied meta clastic rock samples are plotted in the continental island arc and passive margin field. Hence, we conclude that the mafic component is derived from the continental arc and the felsic component is derived from the Bundelkhand gneiss and granite.
The chemical weathering has been quantified by computing the Chemical Index of Alteration (CIA). The average corrected CIA value of the meta argillites of the Saleemnabad Formation is ~79, that of the meta argillites of the Parsoi Formation is ~78, the meta greywackes is ~66, and the quartzites is ~79, suggesting that these rocks have undergone moderate to intense chemical weathering. In the A CN K ternary diagram, the studied meta clastic rocks plot approximately perpendicular to the Al2O3 K2O axis, suggesting that the studied rocks are affected by the K
metasomatism. Another weathering index, ‘α’, is also used to assess the chemical weathering quantitatively. The weathering indices for the meta argillites of the Saleemnabad Formation are as follows: αAlCa = 6.50, αAlNa = 4.57, αAlK = 1.26, αAlSr = 8.16, αAlBa = 2.27 and for the meta argillites and the meta greywackes of the Parsoi Formation are αAlCa = 2.32 and 4.69, αAlNa = 6.61 and 1.20, αAlK = 0.98 and 1.54, αAlSr = 6.14 and 4.44, αAlBa = 1.20 and 0.97, respectively and for the quartzites of the Dudhmaniya Formation αAlCa= 8.40, αAlNa= 9.39, αAlK= 0.49, αAlSr= 0.62, αAlBa= 0.97. The studied rock samples have significantly higher values of αAlCa, αAlNa, αAlSr and αAlBa, which also endorse moderate to intense weathering. However, αAlK in the meta
argillites of the Parsoi Formation and the quartzites are 0.98 and 0.49, respectively, showing lower values, possibly due to K metasomatism.
Previous studies suggest that Sidhi granite gneiss is the source rocks for the meta clastic rocks of the Mahakoshal Group. To validate this and to check whether there is any contribution from Madanmahal granite, I have carried out a geochemical analysis, which includes major oxides and trace elements along with U Pb zircon geochronology of the Sidhi granite gneiss and Madanmahal granite.
The petrographic studies of Sidhi granite gneiss and Madanmahal granite show that they consist of plagioclase, quartz and K feldspar, with a subordinate amount of biotite and hornblende. The studied rocks show hypidiomorphic granular texture. The biotite grains show pleochroic haloes, indicating the presence of zircon and apatite as accessory minerals. Perthite texture is observed, which is due to the exsolution of plagioclase from K feldspar.
The Sidhi granite gneiss and Madanmahal granite are ferroan in character and categorized as moderate to strongly peraluminous in nature. The chondrite normalized REE patterns show that the studied granite gneiss and granite are highly fractionated and show significant negative Eu anomaly. The N MORB (normal mid ocean ridge basalts) normalized multi element diagram shows negative Ba, Nb, Sr and Ti anomalies and slightly positive anomalies are shown in Rb, Th, Zr and Hf.
The Sidhi granite gneiss and Madanmahal granite are akin to A type granite and have average zircon saturation temperatures (ZST) of 955 ˚C and 977 ˚C, respectively. These granite gneiss and granites are enriched in HFSE (Zr and Hf), total alkalis and LREE and depleted in CaO and compatible trace elements such as Ni, Cr and Co show their prominent A type character. These studied rocks are further classified as A2 type granites.
(Y/Nb)N>0.18, (Th/Nb)N>2, (Ce/Pb)N<1 and (La/Nb)N>2 accompanied by the Eu, Ba, Sr, Ti and Nb negative anomalies and slightly positive anomalies in Th, Rb, U and La suggest that the studied rocks are derived from the same source i.e. the preexisting crustal source. La/Yb vs La and Zr/Nb vs Zr bivariate diagram further verify that pre existing crust is a dominant source of the studied rock types.
To ascertain the tectonic setting in which Sidhi granite gneiss and Madanmahal granite are emplaced, I coupled field evidence with tectonic discriminant diagrams. In the field, deformational structures are observed in the Sidhi granite gneiss and Madanmahal granite, such as regional foliation and feldspar augens aligned in the regional foliation direction. Based on geochemistry, in the Nb vs Y tectonic discriminant diagram, the samples of the studied rocks plot in the WPG (within plate granite) field. This indicates that the studied rock types are emplaced in a rift environment, and the Rb vs Y+Nb tectonic discriminant diagram shows that the studied rock types are emplaced in a post collisional environment. Hence, we conclude that the studied granite gneiss and granite are formed in the post orogenic rift environment.
The Mahakoshal Basin which lies in the Bundelkhand Craton was opened during the retreating accretionary orogen. Later, the retreating orogen switched to the advancing orogen, causing the closure of the Mahakoshal Basin. After the closure of the basin, post orogenic rifting occurred in which Sidhi granite gneiss and Madanmahal granite were emplaced.