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The metallic artifacts from Çatalhöyük are of particular im-
portance as they constitute some of the earliest examples
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c.
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c.-
sey et al.
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et al.
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the results.
Çatalhöyük
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et al.
et al.
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The earliest evidence for metal use
et al.
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Çemi
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Chapter 17
In: I. Hodder (ed) 2013: Substantive Technologies at Catalhöyük
Volume 9: Substantive Technologies at Çatalhöyük: Reports from the 2000–2008 Seasons
et al.
Earliest evidence for extractive metallurgy
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et al.
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th millennium
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Çatalhöyük are
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et al.
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Copper sources
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Sample Analysis Cu As Ag Bi Total
all in wt%
7575.x17-S2
198.9 0.028 0.040 bdl 99.0
296.8 0.028 bdl 0.022 96.9
397.2 0.025 0.057 0.020 97.4
497.4 0.015 0.047 bdl 97.5
598.5 0.023 0.064 bdl 98.6
697.3 bdl 0.028 0.006 97.3
798.4 bdl 0.023 bdl 98.5
898.2 0.077 0.017 0.024 98.3
997.4 0.087 0.076 bdl 97.5
10 98.1 0.021 0.021 bdl 98.1
Average 97.8 0.030 0.037 0.007 97.9
13079.x3-S1
195.9 0.004 bdl bdl 95.9
299.1 bdl 0.003 bdl 99.2
396.8 bdl 0.017 0.033 96.9
496.2 0.012 0.003 0.040 96.2
596.1 bdl 0.010 0.020 96.2
696.7 0.092 0.014 bdl 96.8
794.9 0.025 0.044 bdl 95.0
895.7 bdl bdl bdl 95.7
996.6 bdl bdl bdl 96.6
10 97.2 bdl bdl bdl 97.3
Average 96.5 0.013 0.009 0.009 96.6
13079.x3-S2
196.6 0.058 bdl 0.005 96.7
297.1 bdl 0.021 bdl 97.1
396.1 0.049 bdl bdl 96.2
497.6 bdl 0.037 0.069 97.7
595.1 0.066 bdl bdl 95.2
697.3 0.001 0.007 0.003 97.3
799.4 bdl 0.001 0.037 99.5
896.1 0.033 bdl 0.032 96.2
995.9 bdl bdl 0.046 95.9
10 95.0 0.037 0.021 bdl 95.0
Average 96.6 0.024 0.009 0.019 96.7
Table 17.1. Raw EPMA-WDS data for each spot analysis
conducted on the metal phase for each sample.
Table 17.2. Individual LA-ICPMS
analyses of samples 7575.x17 and
13079.x3. All values are expressed
as elements in µg/g. Signals unex-
pectedly high in iron and other ele-
ments are thought to include cor-
rosion material (asterisked). Co,
Ni, Pt and Bi were analysed and
routinely found only at levels of
less than 1 µg/g, with the exception
of two individual measurements
of 1.4 µg/g Pt in sample 7575.x17
(analysis d2 and e2).
Sample Analysis Fe Zn As Se Ag Sn Sb Te Pb
all in μg/g
7575-X17-S2
a* 35 <5 750 12.6 11 <1 1.5 4.2 3.9
b* 180 7 990 9.9 <1 <1 1.6 7.3 10.4
c* 77 6 1100 12.2 <1 <1 1.7 8.2 6.3
d1 <5 <5 15 7.0 390 <1 1.2 5.4 <1
d2 <5 <5 17 10.0 450 <1 1.2 6.5 <1
e1 <5 <5 <1 7.8 340 <1 1.0 8.8 <1
e2 <5 <5 <1 <5 380 <1 <1 11.6 <1
f <5 <5 1 8.7 330 <1 1.1 9.0 <1
g <5 <5 2.9 11.0 300 <1 1.0 8.4 <1
h <5 <5 10 9.3 300 <1 1.5 10.5 <1
i <5 <5 3.1 8.1 320 <1 1.1 3.9 <1
j <5 <5 12 8.8 380 <1 1.2 5.4 <1
k1 <5 <5 <1 9.0 265 16 1.2 <5 <1
k2 <5 <5 3.9 11.4 2500 37 1.8 11.6 <1
l <5 <5 5.3 7.4 320 1.4 1.5 8.3 <1
m <5 <5 120 8.5 420 11 1.5 8.9 <1
n <5 <5 25 8.2 530 1.3 1.4 5.2 <1
o <5 <5 1 8.7 330 <1 1.1 9.0 <1
p <5 <5 2.9 11.0 300 <1 1.0 8.4 <1
-1 <5 <5 10 9.3 300 <1 1.5 10.5 <1
-2 <5 <5 3.1 8.1 320 <1 1.1 <5 <1
-3 <5 <5 12 8.8 380 <1 1.2 5.4 <1
-4 <5 <5 <1 9.0 265 16 1.2 <5 <1
-5 <5 <5 3.9 11.4 2500 37 1.8 11.6 <1
-6 <5 <5 5.3 7.4 310 1.4 1.5 8.3 <1
Median <5 <5 5.3 8.8 330 <1 1.2 8.4 <1
Sample Analysis Fe Zn As Se Ag Sn Sb Te Pb
all in μg/g
13079-X3-S1
a <5 <5 200 8.2 65 <1 1.1 6.8 <1
b <5 <5 120 10.1 65 <1 1.0 7.4 <1
c <5 <5 64 7.3 65 <1 <1 5.6 <1
d <5 <5 130 4.9 79 1.1 1.1 11.1 <1
e <5 <5 87 12.7 61 <1 1.2 9.7 <1
f <5 <5 120 6.9 74 <1 1.2 6.8 <1
g <5 <5 29 8.5 62 <1 <1 6.4 <1
h <5 <5 46 8.7 69 <1 1.1 7.2 <1
i <5 <5 92 10.7 76 <1 1.7 9.2 <1
Median <5 <5 92 8.5 65 <1 1.1 7.2 <1
13079-X3-S2
a <5 <5 210 7.9 81 <1 1.1 5.4 <1
b <5 <5 200 8.8 83 <1 1.1 5.9 <1
c <5 <5 210 8.5 75 <1 <1 5.8 <1
d <5 <5 16 8.0 90 2.6 1.3 6.2 <1
e <5 <5 35 10.6 110 13 <1 5.1 <1
f <5 <5 90 11.2 88 2.1 1.1 7.0 <1
g <5 <5 54 8.0 74 <1 1.3 6.9 <1
h <5 <5 92 10.7 76 <1 1.7 9.2 <1
i <5 <5 165 10.6 72 <1 1.3 6.2 <1
Median <5 <5 92 8.8 81 <1 1.3 6.2 <1
Volume 9: Substantive Technologies at Çatalhöyük: Reports from the 2000–2008 Seasons
ÇorumÇorum
Çorum
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Figure 17.1. Illustrations, showing the location of the sub-
samples obtained, with accompanying photographs of the
16248.x1 (for color version see CD).
Chapter 17: The Metallic Finds
Sample Image Location Cu OCl Ag S Si Total Formula
all in atom % (approx.)
7575.x17-S1 1
A (n=5) 50 50 99 CuCl
B (n=5) 69 29 1.5 0.5 97 Cu2O
C (n=5) 69 30 0.6 96 Cu2O
7575.x17-S2
2
A (n=3) 100 99 Cu
B (n=5) 69 31 97 Cu2O
C (n=5) 51 49 97 CuCl
D (n=5) 68 31 1.0 97 Cu2O
3
A (n=3) 69 31 98 Cu2O
B (n=3) 69 31 98 Cu2O
C (n=3) 50 50 99 CuCl
D (n=3) 100 99 Cu
E i 81 0.6 18.7 98 Cu-Ag
E ii 48 18.7 33 86 Cu-Ag-Cl
E iii 67 28 4.9 89 Cu-Ag-Cl
4 A 88 12.5 98 Cu-sulphide?
13079.x3-S1
5
A (n=5) 71 29 97 Cu2O
B (n=5) 50 0.7 50 96 CuCl
C (n=5) 71 28 1.4 95 Cu2O
D (n=3) 59 41 90 Cu-chloride?
6
A (n=3) 51 49 94 CuCl
B (n=3) 71 29 0.4 97 Cu2O
C (n=3) 100 99 Cu
13079.x3-S2
7A (n=5) 50 50 96 CuCl
B (n=5) 70 29 0.8 94 Cu2O
8
A (n=2) 50 50 97 CuCl
B (n=2) 68 31 0.8 95 Cu2O
C (n=3) 100 98 Cu
16248.x1-S2 9
A (n=2) 68 31 0.3 99 Cu2O
B (n=2) 21 53 0.3 25 89 CuSiO2
C (n=2) 36 47 17.6 93 Cu-oxy-chloride
D (n=2) 38 62 0.8 86 Cu-carbonate?
Table 17.3. Average EPMA-EDS data obtained from multiple area analyses from separate
phases (n=number of analyses).
Bibliography (excerpt)
Bar-Yosef Mayer, D. E. & N. Porat, 2008. Green stone
beads at the dawn of agriculture. Proceedings of the
National Academy of Sciences 105(25), 8548–51.
Bayliss, A. & S. Farid, 2007. Interpreting chronology at
Çatalhöyük (Neolithic East Mound), in Çatalhöyük 2007
Archive Report. http://www.catalhoyuk.com/downloads/
Archive_Report_2007.pdf
Bayliss, A. & S. Farid, 2008. Modelling chronology, in
Çatalhöyük 2008 Archive Report. http://www.catal-
hoyuk.com/downloads/Archive_Report_2008.pdf
Bronk Ramsey, C., T. F. G. Higham, F. Brock, D. Baker &
P. Ditchfield, 2009. Radiocarbon dates from the Oxford
AMS system: ‘archaeometry’ datelist 33. Archaeometry
51(2), 323–49.
Çambel, H., 1980. Arkeometri Açisindan Çayönü Kazisi.
Arkeometri Ünitesi Bilimsel Toplantı Bildirileri
(TÜBİTAK) I, 20–45.
Cessford, C., 2001. A new dating sequence for Çatalhöyük.
Antiquity 75, 717–25.
Cessford, C., 2005c. Absolute dating at Çatalhöyük, in
Changing Materialities at Çatalhöyük: Reports from the
1995–99 Seasons, ed. I. Hodder. (McDonald Institute
Monographs.) Cambridge: McDonald Institute for
Archaeological Research; London: British Institute for
Archaeology at Ankara, 65–99 and 449–50.
Cessford, C. & J. Near, 2005. Fire, burning and
pyrotechnology at Çatalhöyük, in Çatalhöyük
Perspectives: Themes from the 1995–99 Seasons, ed. I.
Hodder. (McDonald Institute Monographs.) Cambridge:
McDonald Institute for Archaeological Research;
London: British Institute of Archaeology at Ankara,
171–182.
Craddock, P., 2000. From hearth to furnace: evidences for
the earliest metal smelting technologies in the Eastern
Mediterranean. Paléorient 26(2), 151–65.
de Jesus, P. S., 1980. The Development of Prehistoric
Mining and Metallurgy in Anatolia (BAR International
Series 74). Oxford: BAR.
Dougherty, R. C. & J. R. Caldwell, 1966. Evidence of early
pyrometallurgy in the Kerman Range, Iran. Science 153,
27–40.
Esin, U., 1999. Copper objects from the Pre-pottery
Neolithic site of Aşıklı (Kızılkaya Village, Province of
Aksaray, Turkey). in The Beginnings of Metallurgy, eds.
A. Hauptmann, E. Pernicka, Th. Rehren & Ü. Yalçın.
Bochum: Deutsches Bergbau-Museum, 23–30.
French, D. H., 1962. Excavations at Can Hasan: first
preliminary report, 1961. Anatolian Studies 12, 27–40.
French, D. H., 1967. Excavations at Can Hasan, 1966: sixth
preliminary report. Anatolian Studies 17, 165–78.
Harrison, K., 2008. Fire and burning at Çatalhöyük, 2008,
in Çatalhöyük 2008 Archive Report. http://www.catal-
hoyuk. com/downloads/Archive_Report_2008.pdf.
Kovacs, R., S. Schlosser, S. P. Staub, A. Schmiderer, E.
Pernicka & D. Günther, 2009. Characterization of
calibration materials for trace element analysis and
fingerprint studies of gold using LA-ICP-MS. Journal
of Analytical Atomic Spectrometry 24, 476–83.
Maddin, R., T. Stech Wheeler & J. D. Muhly, 1980.
Distinguishing artifacts made of native copper. Journal
of Archaeological Science 7, 211–25.
Maddin, R., T. Stech & J. D. Muhly, 1991. Çayönü Tepesi.
The earliest archaeological metal artifacts., in
Découverte du Métal, eds. J. P. Mohen & C. Eluère.
Paris: Mediterranée orientale et Proche-Orient, 375–86.
Maddin, R., J. D. Muhly & T. Stech, 1999. Early
metalworking at Çayönü, in The Beginnings of
Metallurgy, eds. A. Hauptmann, E. Pernicka, Th.
Rehren & Ü. Yalçın. Bochum: Deutsches Bergbau-
Museum, 37–44.
Majidzadeh, Y., 1979. An early prehistoric coppersmith
workshop at Tepe Ghabristan. Archäologische
Mitteilungen aus Iran 6, 82–92.
Mellaart, J., 1960. Excavations at Hacılar: third preliminary
report, 1959. Anatolian Studies 10, 83–104.
Mellaart, J., 1962. Excavations at Çatal Hüyük: first
preliminary report, 1961. Anatolian Studies 12, 41–65.
Mellaart, J., 1963. Excavations at Çatal Hüyük, 1962:
second preliminary report. Anatolian Studies 13, 43–
103.
Mellaart, J., 1964. Excavations at Çatalhöyük, 1963: third
preliminary report. Anatolian Studies 14, 39–119.
Muhly, J. D., 1988. The beginnings of metallurgy in the
Old World., in The Beginnings of the Use of Metals and
Alloys, ed. R. Maddin. Cambridge, Mass.: MIT Press,
2–22.
Neuninger, H., R. Pittioni & W. Siegl, 1964.
Frühkeramikzeitliche Kupfergewinnung in Anatolien.
Archaeologia Austriaca 35, 98–110.
Özdoğan, M. & A. Özdoğan, 1999. Archaeological
evidence on the early metallurgy at Çayönü Tepesi, in
The Beginnings of Metallurgy, eds. A. Hauptmann, E.
Pernicka, Th. Rehren & Ü. Yalçın. Bochum: Deutsches
Bergbau-Museum, 13–22.
Pernicka, E., 1990. Gewinnung und Verbreitung der
Metalle in prähistorischer Zeit. Jahrbuch des Römisch-
Germanischen Zentralmuseums Mainz 37, 21–129.
Pernicka, E., F. Begemann, S. Schmitt-Strecker, H.
Todorova & I. Kuleff, 1997. Prehistoric copper in
Bulgaria: its composition and provenance. Eurasia
Antiqua 3, 41–180.
Pigott, V. C., 1999. A heartland of metallurgy:
Neolithic/Chalcolithic metallurgical origins on the
Iranian plateau, in The Beginnings of Metallurgy, eds.
A. Hauptmann, E. Pernicka, Th. Rehren & Ü. Yalçın.
Bochum: Deutsches Bergbau-Museum, 107–20.
Pigott, V. C. & H. Lechtman, 2003. Chalcolithic copper-
base metallurgy on the Iranian plateau: a new look at
old evidence, in Culture Through Objects: Ancient Near
Eastern Studies in Honour of P.R.S. Moorey, eds. T.
Potts, M. Road. & D. Stein. Oxford: Oxford University
Press, 291–312.
Radivojevic, M., Th. Rehren, E. Pernicka, D. Šljivar, M.
Brauns & D. Boric, 2010. On the origins of extractive
metallurgy: new evidence from Europe. Journal of
Archaeological Science 37, 2775–87.
Roberts, B. W., 2011. Ancient technology and
archaeological cultures: understanding the earliest
metallurgy in Eurasia, in Investigating Archaeological
Cultures: Material Culture, Variability, and
Transmission, eds. B. W. Roberts & M. Vander Linder.
New York: Springer, 137–50.
Roberts, B. W., C. P. Thornton & V. C. Pigott, 2009.
Development of metallurgy in Eurasia. Antiquity 83,
1012–22.
Rosenberg, M. & M. K. Davis, 1992. Hallan Çemi Tepesi,
an early aceramic Neolithic site in eastern Anatolia.
Anatolica 18, 1–18.
Solecki, R. S., 1969. A copper mineral pendant from
northern Iraq. Antiquity 43, 311–4.
Sperl, G., 1990. Zur Urgeschichte des Bleies. Zeitschrift für
Metallkunde 81, 799–801.
Stech, T., 1999. Aspects of early metallurgy in Meso-
potamia and Anatolia, in The archaeometallurgy of the
Asian old world, ed. V. C. Pigott. Philadelphia:
University of Pennsylvania Museum, 59–71.
Twiss, K. C., A. Bogaard, D. Bogdan, T. Carter, M. P.
Charles, S. Farid, N. Russell, M. Stevanovic, E. Nurcan
Yalman & L. Yeomans, 2008. Arson or accident? The
burning of a Neolithic house at Çatalhöyük, Turkey.
Journal of Field Archaeology 33(1), 41–57.
Tylecote, R. F., 1976. A History of Metallurgy. London:
The Metal Society.
Tylecote, R. F., 1987. The Early History of Metallurgy in
Europe. London: Longman.
Wagner, G. A. & Ö. Öztunalı, 2000. Prehistoric copper
sources in Turkey, in Anatolian Metal I, ed. Ü. Yalçın.
Bochum: Deutsches Bergbau-Museum, 31–67.
Yalçın, Ü., 2000. Anfänge der Metallverwendung in
Anatolien, in Anatolian Metal I, ed. Ü. Yalçın. Bochum:
Deutsches Bergbau–Museum, 17–30.
Yalçın, U. & E. Pernicka, 1999. Frühneolithische
Metallbearbeitung am Aşıklı Höyük, Türkei, in The
Beginnings of Metallurgy, eds. A. Hauptmann, E.
Pernicka, Th. Rehren & Ü. Yalçın. Bochum: Deutsches
Bergbau-Museum, 45–54.