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A Review of Moringa Oleifera Lam Seed Oil Prospects in Personal Care Formulations

Authors:
  • Federal University, Gusau, Nigeria.

Abstract and Figures

Moringa seed oil found application in skin preparations and ointments since the time of ancient Egypt. The clear yellow oil has a pleasant taste, and has been compared, in terms of quality with other seed oils. The oil of excellent quality similar to the olive oil, the Moringa seed oil finds wide application in cosmetic industry. The review focused mainly on the quality assessment of Moringa oleifera seed oil extracted through solvent and aqueous-enzymatic techniques based on previous research reports and utilization of the seed oil in personal care formulations.
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RESEARCH AND REVIEWS: JOURNAL OF PHARMACEUTICS
AND NANOTECHNOLOGY
A Review of Moringa Oleofera Lam Seed Oil Prospects in Personal Care
Formulations.
AA Warra*.
Department of Biochemistry, Kebbi State University of Science and Technology, P.M.B. 1144, Aliero,
Nigeria.
Review Article
Received: 26/04/2014
Revised: 12/04/2014
Accepted: 16/04/2014
*For Correspondence
Department of
Biochemistry, Kebbi
State University of
Science and Technology,
P.M.B. 1144, Aliero,
Nigeria.
Keywords: Moringa seed,
oil extraction, quality
assessment, cosmetics.
ABSTRACT
Moringa seed oil found application in skin preparations and
ointments since the time of ancient Egypt. The clear yellow oil has a
pleasant taste, and has been compared, in terms of quality with other
seed oils. The oil of excellent quality similar to the olive oil, the Moringa
seed oil finds wide application in cosmetic industry. The review focused
mainly on the quality assessment of Moringa oleofera seed oil extracted
through solvent and aqueous-enzymatic techniques based on previous
research reports and utilization of the seed oil in personal care
formulations.
INTRODUCTION
Moringa oleifera Lam {Syn M.pterygosperma Gaertn} usually mentioned in the literature as
Moringa, is a natural as well as cultivated variety of the genus Moringa belonging to family Moringaceae [1]
Moringa oleifera Lam. (MO) is a small size tree with approximately 5 to 10 m height. It is cultivated all over
the world due to its multiple utilities [2]. Moringa oleifera Lam (Moringaceae) is a highly valued plant,
distributed in many countries of the tropics and subtropics [3].
The Moringa tree, Moringa oleifera is native to India but has been planted around the world and is
naturalized in many locales. Moringa goes by many names. In the Philippines, where the leaves of the
moringa are cooked and fed to babies, it is called “mother‟s best friend” and “malunggay.” Other names
for it include the benzolive tree (Haiti), horseradish tree (Florida), Nebedey (Senegal) and drumstick tree
(India) [4]. In northern Nigeria it is known in Hausa language as “Zogale” [5]. There are about 13 species of
moringa trees in the family Moringaceae. They are native to India, the Red Sea and/or parts of Africa
including Madagascar. Of these species, Moringa oleifera is the most widely known. It is a multipurpose
tree known as nature‟s medicine cabinet [6]. Almost all parts of the plant are potentially useful. The seeds
are probably the most useful part of the plant, containing a significant percentage of high quality oil [7 ]. The
seeds of moringa contain about 35- 40% oil.
This oil is of excellent quality similar to the olive oil, and is slow to become rancid [4]. It gave high oil
yield, which has good antioxidant capacity with potential for industrial , nutritional and health applications
[8]. The oil that is extracted from them, which is sometimes known as „ben oil‟, is used for a variety of
purposes [9, 10]. It is used as fuel for cooking purpose and burnt for light in developing countries [11] .It is
also used in perfumes, as lubricant in watches and other farm machinery and for making soap [9, 10, 4, 12]
The Romans, Greeks and Egyptians extracted edible oil from the seeds and used it for perfume and skin
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lotion. In the 19th century, plantations of moringa in the West Indies exported the oil to Europe for
perfumes and lubricants for machinery [13].
Among the several fatty acids in Moringa oleifera, the most abundant of the unsaturated fatty
acids is oleic acid which was recommended for use in pharmaceutical preparation preferably in skin
treatment. Various extraction methods are employed in obtaining oil from moringa seeds. Quality
assessment of Moringa concanensis seed oil extracted through solvent and aqueous-enzymatic
techniques was reported [14]. Moringa oil is non-drying with a pale yellow consistency. It has various
cosmetic values and is used in body and hair care as a moisturizer and skin conditioner. Moringa oil is
useful in removing dirt out of the hair and is an efficient natural cleanser. Moringa oil blends easily with
essential oils and this combined with its non-drying quality and its ease of application on the skin makes it
excellent massage oil. Other uses include soap making and for use in cosmetic preparations such as lip
balm and creams. The oil can be considered having relative potential for cosmetics just like the African
shea nut butter [15] More recently, the ben oil has also been shown to be particularly effective in the
manufacture of soap producing a stable lather with high washing efficiency suitable for some African
countries [3].
Figure 1a: Moringa oleifera Lam plant
Figure 1b: Moringa oleifera seed
Oil extraction
The plant, its seeds (Figure 1a and b) and extraction methods are employed in obtaining the oil
from moringa seeds as shown in figures below. Traditional or local methods of extracting oil from seeds
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can be used, even though these are slow and inefficient compared to the use of modern machines. The
traditional methods involve extracting the oil from the seeds by grinding them and cooking them in water
for few minutes. After cooking, the seeds are pressed in a cloth and the liquid placed in a clean container.
This is then left for one day to allow the oil to separate from the water. It may be necessary to filter off
small pieces of seeds floating on the surface of the oil. For research purpose the laboratory extraction
using suitable solvents is employed.
Figure 1c: Hexane extract of moringa seed oil
Cosmetic application of Moringa oleifera seed oil
Moringa oleifera is the best known of the 13 species of the genus Moringaceae. It was highly
valued in the ancient world. The Romans, Greeks and Egyptians extracted edible oil from the seeds and
used it for perfume and skin lotion. In the 19th century, plantations of Moringa in the West Indies exported
the oil to Europe for perfumes. The oil from Moringa oleifera (INCI: Moringa oleifera Seed Oil) was used by
the ancient Egyptians as a potent cure for skin disorders. Moringa Oil is rich in essential fatty acids, making
it an ideal moisturizer and healing and soothing emollient for rough, dry skin and therapeutic massages.
Perfume manufacturers esteem the oil for its great power of absorbing and retaining even the most fugitive
odors and for it stability.
The fatty acid composition is considered to be similar to that for olive. The oil is light and spreads
easily on the skin making it good for massage or as carrier oil for aromatherapy. Moringa oil is utilizable in
creams, lotions, balms, scrubs, body oils, and hair care formulations. Moringa oil brings occlusive,
“cushiony” emolliency to hair and skin formulas. The presence of behenyl acid (see section 4.2.) provides a
much-sought rich emolliency without a greasy after-feel [16]. Determination of antioxidant of Moringa
oleifera seed oil and its use in the production of a body cream was reported [17]. Formulation and in vitro
evaluation for sun protection factor of Moringa oleifera Lam (family-moringaceae) oil sunscreen cream was
reported [18] Production of Soap from an Indigenous Moringa oliefera Lam Seed Oil was also reported [1 9].
(Warra, 2012)
Chemistry of Behenic Acid
Behenic acid [Figure 2] is a carboxylic acid the saturated fatty acid with formula C21H43COOH. In
appearance, it consists of white to cream color crystals or powder with a melting point of 80 °C and boiling
point of 306 °C. It is soluble in both ethanol and ether. It is a major component of Ben oil which is
extracted from the seeds of the Moringa oleifera tree.
Figure 2: Structure of Behenic acid
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Other names for Behenic acid are Docosanoic acid; 1-Docosanoic acid; n-Docosanoic acid, n-
Docosanoate, Glycon B-70, Hydrofol Acid 560, Hydrofol 2022-55, Hystrene 5522, Hystrene 9022, Prifrac
2989, C22:0 (Lipid number).
Industrially, Behenic acid is manufactured by hydrolysis of high erucic acid rapeseed oil at a high
temperature (at 'least 20OoC) under steam pressure, and subsequent hydrogenation of erucic acid to
behenic acid in the presence of a nickel catalyt.
Behenic acid is often used to give hair conditioners and moisturizers their smoothing properties.
Also used as anti-foam in the manufacturing of detergents.
CONCLUSION
The tremendous cosmetic value of Moringa oliefera seed oil from the review of previous literature
included but not limited to body and hair care and as a moisturizer and skin conditioner.
REFERENCES
1. Mahmood KT, Mugal T, Ikram Ul Haq. Moringa oleifera: a natural gift-A review. J Pharm Sci Res.
2010; 2(11):775-781
2. Farooq F, Rai M, Tiwari A, Khan A, Farooq S. Medicinal properties of Moringa oleifera: An overview
of promising healer. J Med Plants Res.2012; 6(27): 4368-4374
3. Mehta J, Shukla A, Bukhariya V, Charde R. Int J Biomed Adv Res. 2011; 2(5): 215-227
4. http://www.chenetwork.org/files_pdf/Moringa.pdf.ECHO,North Ft.Myers, FL.U.S.A.2/5/2010
5. http://www.rogerblench.info/Ethnoscience%20data/Hausa%20plant%20names.pdf. p67.
6. Paliwal R, Sharma V, Pracheta. A Review on Horse Radish Tree (Moringa oleifera): A Multipurpose
Tree with High Economic and Commercial Importance. Asian J Biotechnol. 2011;3: 317-328.
7. http://www.dpi.qld.gov.au/document/Biosecurity_Environmentalpests/IPA-Horseradish-Tree-Risk-
Assessment.pdf. Brisbane, Queensland 12/5/2010
8. Ogbunugafor HA, Eneh FU, Ozumba AN, Igwo-Ezikpe MN, Okpuzor J, Igwilo IO, Adenekan SO,
Onyekwelu OA. Physico-chemical and Antioxidant Properties of Moringa oleifera Seed Oil. Pakistan
J Nutr. 2011;10: 409-414.
9. Qaiser M. 1973, Morigaceae. In : Flora of West Pakistan. No 38.(eds E Nasir and SI Ali).
Department of Botany, University of Karachi, Karachi, Pakistan.
10. Stanley TD. 1982, Morigaceae. In: Flora of Australia, Volume 8-Lecythidales to (ed.AS George).
Australian Bureau of Flora and Fauna, Australian Government Printing Service. (AGPS),Canberra,
ACT.
11. http://www.gardenorganic.org.uk/pdfs/international_programme/Moringa.pdf.HDRA-the Organic
Organization. Coventry, UK.
12. Ashraf F, Gilani SR. Fatty acids in Moringa oleifera oil. J Chem Soc Pakistan. 2007;29(4): 343-345
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13. Ashfaq M, SMA Basra, U Ashfaq. Moringa: A Miracle Plant of Agro- forestry. J Agr Soc Sci. 2012; 8:
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14. Latif S, Anwar F. Quality assessment of Moringa concanensis seed oil extracted through solvent
and aqueous-enzymatic techniques. Grasasy aceites.2008;59 (1): 69-75,
15. Warra AA. Cosmetic Potentials of African Shea nut( vitellaria paradoxa) butter. Curr Res Chem.
2011;3(2): 80-86
16. International Flora Technologies. 2008, Moringa Oil Product Information Bulletin. P1
17. Ojiako EN, Okeke CC. Determination of antioxidant of Moringa oleifera seed oil and its use in the
production of a body cream. Asian J Plant Sci Res. 2013;3(3):1-4
18. Kale S, Megha G. Formulation and in vitro evaluation for sun protection factor ofMoringa oleifera
Lam (family-moringaceae) oil sunscreen cream. Int J Pharm Pharm Sci. 2011;3(4): 371-375
19. Warra AA. Production of Soap from an Indigenous Moringa oliefera Lam Seed Oil. J Raw Mater Res.
2012;7(1&2): 23-30
... All the composite cookies had significantly (p<0.05) higher fat contents than the 100% wheat flour cookies (CTLC) as a result of contribution of fats from Moringa oleifera seeds flour (Warra, 2014). Functions of fats include: rich sources of energy, carriers of fat soluble vitamins (A, D, E and K), flavour improvement and retention, and even extension of shelf lives of food products. ...
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... In addition, recently, its seeds have gained a attention as a source of plant oil rich in oleic fatty acid. This oil is semi-solid and yellowish-brown with a bitter almond-like odor [4]. High-oleic oils are gaining importance, especially as a replacement for polyunsaturated vegetable oils, and have been reported to exhibit good oxidative stability during frying [5]. ...
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A shortages of soil nutrients resources and a lack of accessibility to them especially in calcareous soil are considered some of the main factors that limit plant production. In particular, the cultivation of the Moringa oleifera trees in this type of soil is of special interest given the increasing demand for every part of this tree. Several studies have focused on the production of its leaves as an herbaceous plant and not as a tree, but there has not been extensive research on its pods, seeds, and fixed oil production. In this sense, in this study, we provide an assessment of the use of fertilizers , vermicompost and NPK (as traditional minerals and as nanoparticles), in order to improve pods, seeds, and fixed oil contents, as indicators of the quality of the production of the Moringa oleifera trees in calcareous soil conditions. In this experiment, it was observed that all parameters and the yield of pods, seeds, and fixed oil of the Moringa oleifera tree were significantly improved by increasing the level of vermicompost and using NPK fertilization and combination treatments in both seasons of the study. The combination treatments of 10 and 20 ton ha −1 vermicompost plus NPK control produced the highest percentage of oleic acid with insignificant differences between them.
... All the composite cookies had significantly (p<0.05) higher fat contents than the 100% wheat flour cookies (CTLC) as a result of contribution of fats from Moringa oleifera seeds flour (Warra, 2014). Functions of fats include: rich sources of energy, carriers of fat soluble vitamins (A, D, E and K), flavour improvement and retention, and even extension of shelf lives of food products. ...
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Native starches extracted from selected roots and tubers (white yam, trifoliate yam and sweet potato) were physically and chemically modified through heat moisture treatment and acetylation respectively while nutritious flour was processed from Moringa oleifera seeds. Composite flours of 85% wheat flour, 10% native/modified starch and 5% Moringa oleifera seed flour blends were developed for production of composite cookies. Nutritional compositions and baking properties of these composite cookies were investigated against those of control samples (i.e. 100% wheat flour cookies). Nutritionally, composite cookies were significantly (p<0.05) higher than control cookies while in terms of baking properties, the control cookies did not significantly (p<0.05) differ from composite cookies. Cookies sample NSPC (i.e. made from composite flour of 85% wheat flour: 10% native sweet potato starch: 5% Moringa oleifera seed flour) took lead positions in crude fat content (19.30%), protein content (13.25%), calcium content (121.95 mg/100g), iron content (3.75 mg/100g), vitamin A content (4.910 µg/g), vitamin B 1 content (0.079 mg/100g), vitamin B 2 content (0.112 mg/100g), vitamin B 3 content (0.580 mg/100g), vitamin B 6 (0.480 mg/100g) and vitamin C content (14.710 mg/100g). Though NTYC (cookies of composite flour of 85% wheat flour: 10% native trifoliate yam starch: 5% Moringa oleifera seed flour) and CTYC (cookies of composite flour of 85% wheat flour: 10% acetylated white yam starch: 5% Moringa oleifera seed flour) shared the highest moisture content of 8.20%, NTYC had highest values in ash content (2.60%) and spread factor (62.37)) and toddled in carbohydrate content (55.45%). CWYC (i.e. cookies of composite flour of 85% wheat flour: 10% acetylated white yam starch: 5% Moringa oleifera seed flour) had best values in storage-ability potential (i.e. lowest moisture content of 2.50%) and energy content (467.30 Kcal), but had lowest values in magnesium (57.31 mg/100g) and phosphorus content (64.18 mg/100g). The 100% wheat flour cookies (CTLC) led in carbohydrate content (63.35%), magnesium content (64.71 mg/100g) and phosphorus content (69.28 mg/100g) but lagged behind in ash content (1.70%), crude fat content (1.25%), protein content (11.75%), iron content (2.45%), vitamin A (2.250 µg/g), vitamin B 1 (0.047 mg/100g), vitamin B 2 (0.073 mg/100g), vitamin B 3 (0.250 mg/100g), vitamin B 6 (0.290 mg/100g), vitamin C (13.530 mg/100g) and spread factor (41.47). PWYC (cookies of composite flour of 85% wheat flour: 10% heat moisture treated white yam starch: 5% Moringa oleifera seed flour) recorded lowest values in crude fat content (17.80%) and energy value (441.30 Kcal); whereas PTYC (cookies of composite flour of 85% wheat flour: 10% heat moisture treated trifoliate yam starch: 5% Moringa oleifera seed flour) made lowest values in crude fibre content (1.60%) and calcium (117.31 mg/100g). NWYC (cookies of composite flour of 85% wheat flour: 10% native white yam starch: 5% Moringa oleifera seed flour).led in crude fibre content (1.73%) and general acceptability (8.07) while CSPC (cookies of composite flour of 85% wheat flour: 10% acetylated starch: 5% Moringa oleifera seed flour) scored lowest in general acceptability (6.20).
... Fats play an important role as 'lubricants' in bread (Ihekoronye and Ngoddy, 1985) [13] . and oils from Moringa oleifera seeds are of premium quality, comparable to olive oil (Warra, 2014) [40] . [11,14]. ...
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Starches obtained from selected roots and tubers (white yam, trifoliate yam and sweet potato) were physically and chemically modified through heat moisture treatment and acetylation respectively while highly nutritious flour was processed from Moringa oleifera seeds. Composite flours of 85% wheat flour, 10% native/modified starch and 5% Moringa oleifera seed flour blends were developed for production of composite breads. Nutritional compositions and baking properties of these composite breads were investigated against those of control samples (i.e. 100% wheat flour bread). Nutritionally, composite breads were significantly (p<0.05) superior to control breads while in terms of baking properties, the control breads did not significantly (p<0.05) differ from composite breads. Composite bread sample NSPB (i.e. made from composite flour of 85% wheat flour: 10% native sweet potato starch: 5% Moringa oleifera seed flour) had highest values in crude fibre (1.35%), protein (11.75%), calcium (116.49 mg/100g), iron (2.81 mg/100g), magnesium (57.23 mg/100g), vitamin A (3.980 µg/g), vitamin B1 (0.067 mg/100g), vitamin B2 (0.096 mg/100g), vitamin B3 (0.400 mg/100g), vitamin B6 (0.440 mg/100g) and vitamin C (13.560 mg/100g); but had lowest values in carbohydrate (45.90%). NTYB (i.e. bread made from composite flour of 85% wheat flour: 10% native trifoliate yam starch: 5% Moringa oleifera seed flour) led in ash content (2.40%), crude fat content (1.80%) and phosphorus content (66.91 mg/100g); but toddled in height (5.23 cm). Sample PTYB (i.e. bread made from composite flour of 85% wheat flour: 10% heat moisture treated trifoliate yam starch: 5% Moringa oleifera seed flour) recorded highest values in crude fibre content (1.35%), specific volume (2.20 cm3/g) and lowest in crude fat content (1.30%); while control bread sample CTLB (i.e. made from 100% wheat flour) got highest values in moisture content (38.40%), magnesium (58.15 mg/100g) and insignificantly (p<0.05) scored highest in general acceptability (6.75) but lagged behind in crude fat content (1.05%), crude fibre content (0.75%), protein content (10.80%), energy value (240.05 Kcal), calcium content (112.40 mg/100g), iron content (1.81 mg/100g), phosphorus content (63.88 mg/100g), vitamin A (1.84 µg/g), vitamin B1 (0.036 mg/100g), vitamin B2 (0.065 mg/100g), vitamin B3 (0.170 mg/100g), vitamin B6 (0.210 mg/100g), vitamin C (11.380 mg/100g) and shelf-stability potential (i.e. highest moisture content of 38.40%). Sample CWYB (i.e. bread made from composite flour of 85% wheat flour: 10% acetylated white yam starch: 5% Moringa oleifera seed flour) recorded best values in carbohydrate content (53.15%), energy content (270.05 Kcal) and shelf-stability potential (i.e. lowest moisture content of 31.00%) but lowest values in ash content (2.00%), magnesium content (55.23%) and general acceptability (5.75). Sample PWYB (i.e. bread made from composite flour of 85% wheat flour: 10% heat moisture treated white yam starch: 5% Moringa oleifera seed flour) also obtained highest value of 1.35% in crude fibre content.
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Moringa oleifera belongs to the Moringaceae family, which consists of 13 species. Moringa is associated with a decreased risk of coronary heart disease with a higher dietary intake of monounsaturated fatty acid (primarily oleic acid). People all over the world use this multipurpose herb both as food as well as for medicinal purposes. Researchers have described it as a plant with various health benefits, including nutritional and medicinal benefits. The important factors responsible for the medicinal use of M. oleifera are attributed to its wide range of vital antioxidants, antibiotics, vitamins, and minerals.
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The present work is intended to provide worthful information about the structure and half-metallicity of Co-based Heusler alloy. The first principle density functional theory was used to analyze Co2TiN. First, the structure of an alloy was optimized through the consideration of Cu2MnAl and Hg2CuTi, two structure types along with different magnetic phases. The resulting stable structure Hg2CuTi showed the metallic nature of an alloy in both spin configurations with GGA potential. However, an implication of Hubbard parameter (U) considerably affected the electronic structure and therefore bands got shifted with 100% polarization at Fermi level which increases the efficiency of spintronics. Under the effect of U, spin-up configuration showed semiconducting nature with 0.21 eV that revealed the half-metallicity in Co2TiN full-Heusler alloy.
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Lubricating oil based on mineral oils put forward a challenge of water contamination and prolonged toxicity to environment due to non-degradable nature. Further continuous depletion of fossil resources and higher cost of conventional oil motivate to explore alternative of mineral oil-based lubricants. Recent approach is to identify plant and animal derived oil as bio-lubricant. In the present study, moringa and amaranth oils are used as base oil for bio-lubricant as both have high unsaturated fatty acid composition. The rheological analysis is experimentally investigated for the plain base oil and with nanoparticles. MWCNT and CeO2 are used as nanoparticles for the development of bio-nanolubricants, both of which are dispersed in a 1% weight fraction with the base moringa and amaranth oil. The dispersion of MWCNT shows higher viscosity for the case of moringa oil, and CeO2 shows higher increment with amaranth oil. All the sample displayed Newtonian behavior. KeywordsBio-lubricantNanoparticlesMWCNTCeO2Rheological analysisBio-nanolubricants
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