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Toxic Emissions from Crematories
Abstract
In recent years, the cremation ratio of cadavers has increased dramatically in many countries. Crematories have been identified as sources of various environmental pollutants, being polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs), and mercury those raising most concern. In contrast to other incineration processes for which the number of studies on their toxic emissions is considerable, references related to PCDD/F and mercury emissions from crematories and their health risks are very limited. In this paper, the scientific information concerning these issues, using the databases PubMed, Scopus and Scirus, is reviewed. Results show that in comparison with PCDD/F emissions from other sources, those corresponding to crematories are significantly lower, while those of mercury should not be underrated.
... In Europe, over 150,000 cremations occur each year in the 1,000+ crematories in operation. 103 Temperatures of 800 °C or higher are required over a time period of between 1-2 hours. During the cremation process of human cadavers, a number of emissions are released into the environment. ...
Pollution arises from all human activity and the provision of oral healthcare using resin-based composite restorative materials (RBCs) should be considered. This paper aims to provide a comprehensive review of the potential pollutant risk to the environment from the chemical compounds found in resin-based restorative materials, by including: 1) the principal pollutant compounds present in the resin matrix; 2) the degradation process of RBCs and its consequences; 3) the methods used for the detection and quantification of monomer elution and RBC microparticles; and 4) a review of the release mechanisms of eluates and RBC microparticles into the environment.
RBCs are pollutants by virtue of the compounds created during the degradation processes. These are in the form of the constituent eluted monomers and microparticles. Their impact on the environment and biodiversity is unknown. These materials are currently one of the main direct-placement restorative materials and their success is unquestionable when used and maintained correctly. Mitigation strategies for reducing the impact of pollution on the environment should be considered and implemented by all stakeholders and processes in the supply chain, from manufacturing, clinical use and waste management.
... The ecological concerns about cremation, among the most popular options for corpse WOMEN, GENDER & RESEARCH NO. 3-4 2019 disposal because of lower costs and less material waste, sound not less alarming. Cremation consumes considerable amounts of energy and releases carbon dioxide, mercury, and dioxin among other air pollutants, which are both problematic for residents and the biosphere at large (Mari and Domingo 2009;Doughty 2014). In the days of Anthropocene discourses, funeral practices are no longer exempt from larger questions of ecologically responsible citizenship. ...
In a world conceptualised as Anthropocene, in which human activities are transforming every part of the biosphere, funerals have become political and ethical activities in new and unforeseen ways. The use of formaldehyde in embalming practices and the release of air pollutants during cremation are only two of many points of criticism which have led to the rise of alternative ‘greener’ burial methods. The ‘infinity burial project’ is one such alternative, but it exceeds discourses on sustainable funerals by highlighting the toxicity of human bodies and challenging cultural taboos surrounding corporeal decomposition. Infinity burial employs ‘mycoremediation’, the usage of fungi for decomposing and cleaning up contaminated bodies and landscapes. Departing from Donna Haraway’s call for embracing situated technical projects in order to make ‘oddkin’, this article explores how the infinity burial project engenders queer communities which dismiss taxonomical lines between species as well as ontological claims about life and death. Drawing on new materialisms’ work on the radical openness of bodies, I explore how the infinity burial project sheds light on the material reality of decaying and the implications of dying in a polluted world.
... They did not identify which medical devices emitted the most dioxin. Nonetheless, local factors such as the length of the chimneystack, proximity to residential areas and topography of the surrounding land are important variables, which may influence the effects of crematorium emissions to public health [2]. Mercury is emitted with cremation since dental fillings are made with dental amalgam containing more than 0.5 grams of mercury [19]. ...
PurposeThe purpose of this study was to investigate the issues surrounding the cremation of medical devices in deceased patients.Materials and methodsA systematic review was conducted of published and unpublished databases. All publications related to the cremation of patients with medical devices were included. Areas under investigation included the incidence of different types of medical devices cremated, detection of implants, the environmental and health dangers associated with cremation of various medical devices, and recommendations for clinical and crematorium practices to manage these possible hazards. Two authors independently assessed publication eligibility and extracted data. A narrative review was conducted based on the data extracted.ResultsTwenty publications were eligible. These indicated that pacemakers and expandable orthopaedic nails are two potential dangers to cremation staff. However, there remains confusion regarding the potential dangers of radionuclide exposure, especially with regard to the effect of time between the introduction of the radionuclide material and death with respect to its handling, storage and cremation. There is limited evidence of public health problems surrounding mercury emissions from the cremation of dental amalgams.Discussion/conclusionsThere is evidence that clinicians, funeral directors, mortuary and crematorium teams are well aware of the hazards of pacemakers and cremation. However the miniaturisation of pacemakers and other electronic devices, the increasing use of radioactive treatments in oncology and the use of expandable nails in orthopaedics need to be recognised to allow safe disposal should cremation be considered for the deceased where these materials have been used.
... Incineration of hazardous (and also harmless) waste may cause emissions of substances, which pollute the air, water and soil, having potential harmful effects on human health. Although most evaluations on stack emissions have been focused on three classes of pollutants (metals, semivolatile, and volatile compounds), polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/Fs), which are characterized by their toxicity to humans and animals, their ability to bioaccumulate, and their persistence in the environment have raised the greatest concern (Kulkarni et al., 2008; Mari and Domingo, 2010). Once emitted to the atmosphere, PCDD/Fs are dispersed through the environment and accumulate in soils and vegetation, thereby easily reaching the food chain (Domingo et al., 1999a,b; Esposito et al., 2009; Lin et al., 2012). ...
From the perspectives of longevity, mechanical performance, and economics, amalgam has long been considered the material of choice, especially for certain types of restorations in posterior teeth, including replacement therapy for existing amalgam fillings. In spite of numerous advantages over other filling materials, its use has been decreasing in recent years and the alternative tooth-colored filling materials are increasingly used. There is a trend towards minimal interventional, adhesive, techniques in dentistry, which are based on adhesion to tooth structure by chemical interaction and/or micromechanical retention. At the same time, the quality and durability of alternative materials have improved. Mercury is the metallic element of concern used in dental amalgam. Mercury is a well-documented toxicant, with reasonably well-defined characteristics for the major forms of exposure, involving elemental mercury as well as organic and inorganic mercury compounds. Looking into the kind of practice and its popularity among dentists and the patients in India, even we have to comply with the use of amalgam by implementing the best possible ways to minimize the extent of damage to nature.
Over the past three decades, a silent revolution in funerary practices and cemetery design known as the ‘natural burial movement’ has swept over various national contexts and created a transnational narrative that is embedded in local funerary cultures. Seeking out environmentally-friendly burial alternatives, new cemetery and commemoration concepts take into account the urban lack of space and changing family structures and combine these with a desire for autonomy from economically and ecologically costly burial practices. A salient feature of these new burial sites are their naturalistic design and enchanting appeal. Presenting ethnographic research at France’s first natural cemetery« Cimetière naturel de Souché », which opened in 2014, this chapter examines and reflects on the changes in material as well as immaterial funeral settings within a contemporary European context. The research reveals insights into a heterogenous set of values concerning human body disposal, nature and culture, gift giving and reciprocity, and purity and respect. The main objectives of the cemetery officials originally were geared towards the creation of a place as close to nature’s makeup as possible, a reduction of the ecological footprint of burials, and cost decrease. The most significant aspects for the bereaved and other visitors are, however, an appeal beyond economic and ecologic objectives. Spiritualities, therapeutic death contemplation, and continuous kin care point to an enduring enchantment: meditations veiled in a green hue.
In densely populated countries like Italy, cremation is promoted for the final disposition of the dead. However, many families still choose inhumation or entombment. In ordinary (traditional) tombs, bodies skeletonize slowly and partially, and often need a second disposal after the exhumation. The aim of this study was to experimentally test the functionality of a new type of tomb, defined as “aerated”. Aerated tombs feature an aerating system, absorbing materials and a purifying filter, which collectively maintain ventilation, process putrefactive fluids and gases and neutralize odors. In an experimental cemetery area with pristine soil, limbs of piglets were wrapped in cotton sheets and were either inhumed, placed in ordinary tombs or placed in aerated tombs. Following exhumation after planned time intervals (1, 3, 6, 9, 12, 18, 24 months), all samples were macro- and microscopically examined. The inhumed samples were completely skeletonized by 9 months after burial, and after 12 months showed initial bioerosion in bone Haversian canals. The traditionally entombed samples developed progressive adipocere formation, whereas the samples disposed in aerated tombs became mummified. Despite this outcome, aerated tombs represent a more energy-effective, environmentally-friendly and economical choice when compared to ordinary tombs. A mummified body is lighter and drier than a body entombed traditionally and, as such, it is easier to exhume and quicker to cremate. Overall, in the absence of alternative burials, aerated tombs are more suitable than ordinary tombs for the final disposition of the dead in cemeteries with limited space. The results of this experiment add to the knowledge of taphonomical processes in temperate climates and urban environments, potentially benefitting the forensic and medico-legal community.
The modernization of crematoria and replacement of existing fuel requirements for better air quality is a key challenge in view of the associated religious beliefs in India where conventional open pyre funeral practices are followed. Unlike developed nations, the lack of appropriate site selection criteria, combustion efficient crematorium oven designs, and pollution control devices at these facilities necessitates formulation of appropriate policy measures to reduce emissions. The existing practices do not address such localized sources that affects the micro air pollution patterns owing to their marginal contribution in the total air pollution load of the city. The present study is thus an attempt to estimate emissions from 51 cremation grounds identified in NCT of Delhi. The study considers both particulate and gaseous pollutants which are released due to burning of fuels like wood, CNG, and cow dung. It is estimated that cremation activities contributed 393 tons/year of PM2.5, 142 tons/year of NOx, 29 tons/year of SO2, and 2686 tons/year of CO in year 2019. The maximum load was emitted from Central district as only Nigambodh Ghat crematoria receives on an average 60 bodies per day. Furthermore, air quality impact zone around crematoria has been demarcated using dispersion modelling considering crematorium with minimum and maximum number of bodies burnt in a day. The study also suggests control measures for reduction of pollution from cremation activities and delineates a buffer zone that could aid policymakers in establishing a site selection criterion to prevent the immediate population from likely exposure.
This review focuses on existing technologies for carcass and corpse disposal and potential alternative treatment strategies. Furthermore, key issues related to these treatments (e.g., carcass and corpse disposal events, available methods, performances, and limitations) are addressed in conjunction with associated environmental impacts. Simultaneously, various treatment technologies have been evaluated to provide insights into the adsorptive removal of specific pollutants derived from carcass disposal and management. In this regard, it has been proposed that a low-cost pollutant sorbent may be utilized, namely, biochar. Biochar has demonstrated the ability to remove (in)organic pollutants and excess nutrients from soils and waters; thus, we identify possible biochar uses for soil and water remediation at carcass and corpse disposal sites. To date, however, little emphasis has been placed on potential biochar use to manage such disposal sites. We highlight the need for strategic efforts to accurately assess biochar effectiveness when applied towards the remediation of complex pollutants produced and circulated within carcass and corpse burial systems.
Graphical Abstract
Human remains and corpses’ cremation is an increasing practice worldwide alternative to burials, which have increased their cost and reduced spaces in cemeteries. Alike to other combustion processes, cremation produces pollutant emissions that contribute to worsen air quality in modern cities. A 6-month sampling campaign was performed in order to characterize emissions from corpse cremation in three different crematorium ovens and develop emission factors which were used to determine the population exposure to those pollutants during cremation activities applying a dispersion model. The main difference among crematoria was the inclusion or non-inclusion of controlled air supply devices. Using isokinetic samplings in the chimneys crematoria, emissions were measured and characterized with different chemical analyses. No significant differences were found in arsenic and metal concentrations among different crematories, although carbon monoxide, particles, elemental carbon, organic carbon, and polycyclic aromatic hydrocarbon concentrations in facilities without controlled air supply were up to seven times higher than those with controlled air supply. Nevertheless, these pollutants exceeded standards in all crematoria. Except for elemental and organic carbon concentration that correlated with corpse weight, other recorded cadaver characteristics bear no relation with pollutant emissions. Emission factors among different ovens did not present significant differences; then, they were used for dispersion modeling of particles and mercury emissions over Mexico City when 35 crematoria operate simultaneously through an hour showing that PM2.5 and Hg increase 0.01–1 μg m−3 and 0.01–0.1 ng m−3, respectively, in that scenario.
Polychlorinated dibenzodioxins and polychlorinated dibenzofurans (PCDD/F) are highly bioavailable in humans, either through direct inhalation or indirectly by trophic transfer from contaminated food or water. The main sources of pollution with PCDD/F include industrial and non-industrial combustion sources, like domestic contaminated wood burning, house fires, burning of leaves from trees, etc. When looking for alternative energy sources and reduced energy costs, solid waste incineration plants are intended to be built in the vicinity of urbanized areas, and thus, the need emerges for examination and prediction of to what extent the solid waste incineration plants might affect the surrounding ecosystem, air pollution, and human health. Polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) (or simply PCDD/F congeners) belong to the group of semi-volatile organic compounds with environmental stability and long-range transfer in the ambient air. Dioxin isomers are highly toxic and may have carcinogenic and mutagenic effects in humans. PCDD/F is detected in air, water, sediment, plants and animals. PCDD/F is generally distributed in the particulate phase in ambient air. For solid waste incineration plant emissions, the distribution of PCDD/F particles into particles with a diameter of <10 μm is more than 81% of the total particulate matter, and more than 54% of the PCDD/F is distributed into particles with a diameter of <2.5 μm. The aim of this study is to investigate the sources of PCDD/F, emissions and potential hazards, i.e., a toxic equivalent in Lithuania. The measurements were performed in two largest cities of Lithuania Vilnius and Kaunas, where the level of PCDD/F discovered was from 0.015 to 0.52 pg/m3 and from 0.02 to 0.05 pg/m3, respectively. The sites for the monitoring were selected based on their proximity to the locations of the planned cogeneration power plants in these cities.
This paper applies social justice frameworks to "cemetery systems," which here denotes the framework by which each nation state orders the disposal of the dead, and which generally includes burial, cremation and the interment or scattering of cremated remains. An application of social justice theory indicates the desirability of certain key principles for all cemetery systems: decent disposal as a human right; democratic accountability; equality of access to services regardless of income; freedom of religious expression; and environmental sustainability. Achieving these principles is not necessarily straightforward, and conflict between principles is heightened by financialization and population densification.
In grappling for ways to respond to existence within permanently polluted worlds, this article asks: what does it mean to be good food for others? Where do all the chemicals and heavy metals go? What are the distributed effects? How might we hack legacies of toxic inheritance? What alternative practices and values are needed? This article explores the ways in which artists complicate death/food relations and nourishment through their express acknowledgement of chemically burdened bodies. In doing so, it draws on and extends Val Plumwood’s analytic of viewing humans as ‘being prey’ in the context of a feminist ethics of care and what Maria Puig de la Bellacasa refers to as ‘more caring affective ecologies’. Ultimately, it suggests that speculating on becoming prey and wanting to be good food for others – whether this is for a crocodile, fish, mushrooms or microbes in the soil – can propose new ways of configuring our relationships with human and more-than-human others in terms of toxicity and care.
Review
Mercury Contamination from Dental Amalgam
Anita Vazquez Tibau1 , Blanche D. Grube2
1 Center for Environmental and Toxicological Research, University of Puerto Rico, San Juan, Puerto Rico
2 The International Academy of Biological Dentistry and Medicine, Spring, Texas
Corresponding author: Anita Vazquez Tibau, anitatibau@hotmail.com
Background. Mercury in dental amalgam is a hidden source of global mercury pollution, resulting from the illegal diversion of dental mercury into the artisanal and small-scale gold mining sector, to crematoria emissions from the deceased and sewage sludge that is sold to farmers. These significant mercury sources result in air, water, and food contamination that consequently have a negative impact on human health.
Objectives. The aim of the present study was to investigate and report on all of the various pathways mercury in dental amalgam can enter the environment.
Methods. The present study searched the electronic data bases of PubMed and Google Scholar. Peer reviewed journals and references of studies included for full-text review were examined for potentially relevant studies. Articles published between 2000 to 2018 were searched and specifically screened for articles that referenced “Dental Amalgam,” and the following key words in various combinations: “Minamata Convention on Mercury Treaty,” “Sewage Sludge,” “Cremation,” and “Artisanal and Small-Scale Gold Mining.” Data were included on the most populous countries of China, India, the United States, Brazil, and the European Union collectively. We also included data on cremation statistics and current global trends, looking at populations where cremation is a common practice, such as Japan and India.
Discussion. Dental amalgam represents a significant, but understudied area of global mercury pollution that includes cremation, sewage sludge, burial, and small-scale gold mining.
Conclusions. Mercury used in products and processes, including dental amalgams, is a global pollutant. Even after the last mercury dental amalgam is placed, its toxic legacy will continue for decades, because of its pervasive bioaccumulation in the environment. Government regulatory agencies should make it mandatory to utilize available technologies, not only in developing countries, but also in developed countries, to reduce mercury contamination.
In 1996-1998, a wide surveillance program was initiated in the vicinity of a new hazardous waste incinerator (HWI) placed in Constantí (Catalonia, Spain), which started its regular operations in 1999. The program was aimed at assessing the environmental impact of the facility on the surrounding environment, as well as to evaluate the potential risks for the population living in the neighborhood. Since then, among other measurements, the concentrations of polychlorinated dibenzo-p-dioxins and furans (PCDD/Fs) have been periodically determined in soil and herbage samples. This study shows the results, corresponding to the period 2013-2016. Data were compared with those obtained in the baseline survey (1996-1998), as well as with those of the previous survey (2011-2012). The median PCDD/F concentrations in soils were 0.44 and 0.33 ng toxic equivalent (I-TEQ)/kg in 2015 and 2016, respectively, with a significant decrease in relation to the baseline survey, and a non-significant decrease between 2015 and 2016. In turn, PCDD/F levels in vegetation showed some fluctuations over time, being the concentrations of PCDD/Fs in 2013 very similar to those found in 2012 (1.11 and 1.23 ng I-TEQ/kg, respectively). These concentrations notably decreased along the three last campaigns (0.16, 0.23, and 0.17 ng I-TEQ/kg in 2014, 2015, and 2016, respectively). These changes would be more related to a number of environmental factors rather than to a variation of PCDD/F emissions by the HWI. With respect to human health risks, exposure to PCDD/Fs in the area under potential influence of the HWI is not of concern, as the current environmental concentrations of PCDD/Fs do not mean additional carcinogenic or non-carcinogenic risks for the local population.
Mineral Resources, Economics and the Environment - by Stephen E. Kesler October 2015
Cambridge Core - Applied Geoscience, Petroleum and Mining Geoscience - Mineral Resources, Economics and the Environment - by Stephen E. Kesler
The process of corpse cremation generates numerous harmful air pollutants, including particulate matter (PM), sulfur dioxide (SO2), nitrogen oxides (NOx), volatile organic compounds (VOCs), and heavy metals. These pollutants could have severe effects on the surrounding environment and human health. Currently, the awareness of the emission levels of harmful air pollutants from cremators and their emission characteristics is insufficient. In this study, we obtained the emission characteristics of flue gas from cremators in Beijing and determined the localized emission factors and emission levels of harmful air pollutants based on actual monitoring data from nine typical cremators. The results show that the emissions of air pollutants from the cremators that directly discharge flue gas exceed the emission standards of China and Beijing. The installation of a flue gas post-treatment system could effectively reduce gaseous pollutants and the emission levels of PM. After being equipped with a flue gas post-treatment system, the emission concentrations of PM10, PM2.5, CO, SO2 and VOCs from the cremators are reduced by 97.6, 99.2, 19.6, 85.2 and 70.7%, respectively. Moreover, the emission factors of TSP, PM10, PM2.5, CO, SO2 and VOCs are also reduced to 12.5, 9.3, 3.0, 164.1, 8.8 and 19.8 g/body. Although the emission concentration of VOCs from the cremators is not high, they are one of major sources of “odor” in the crematories and demand more attention. Benzene, a chemical that can seriously harm human health, constitutes the largest proportion (~50%) of the chemical components of VOCs in the flue gas from the cremators.
Objectives:
Nanoparticles (NPs), including hazardous substances, are generated in crematoriums due to the high temperatures during the combustion process. NPs are reported to greatly impact animals' health by reaching the alveoli and being carried to the entire body through the blood stream. However, studies in crematoriums have yet to assess workers' exposure to the generated NPs. The purpose of this study is to assess workers' exposure to NPs released in crematoriums.
Methods:
Field surveys were conducted in three crematoriums with an emphasis on cremation, bone rearrangement and cleaning processes. The NP concentrations and size distributions were analyzed. The deposition of NPs in each respiratory region during each working process was calculated based on the measured data using the Human Respiratory Tract Model.
Results:
The mean particle number concentration was maximized momentarily during the bone rearrangement process. The concentration at the time a crematory's door was opened was 500,000 particle/cm(3). NPs aggregated to micro-sized particles within a few minutes, dust generated by the bone rearrangement, or both. As a result of model calculation, the mean ratios (alveolar per the other regions by a crematory) were approximately 3.0 (bronchus and bronchioles regions: except for the first survey in crematorium A which had the obstruction of measurement) and 4.3 (extrathoracic airways). The ratios were similar for all crematoriums.
Conclusions:
These results can be used for health risk assessments in crematoriums. In addition, these results should be applicable to estimate the inhalation unit risk of each respiratory organ such as lungs and nose.
Shortly after treatment with 7200 MBq of (131)I, a thyroid cancer patient died and was subsequently cremated. Calculations of the atmospheric emissions of (131)I from the crematorium flue were performed using a standard atmospheric pollution Gaussian Plume Dispersal model. Estimates of whole-body and thyroid dose of those potentially exposed were made using OLINDA/EXM dosimetry software. Under the meteorological conditions prevalent at the time of the cremation, and depending on the actual release rate of the (131)I, the Western Australian legal limit of 3.7 Bqm(-3) for atmospheric emissions of (131)I may have been exceeded for distances of up to 440 and 1610 m downwind of the crematorium chimney, with the maximum concentration being between 33 and 392 Bqm(-3). Assuming 16% of the inhaled (131)I was taken up in the thyroid with the balance in the remainder of the body, the radiation dose to maximally exposed individuals was calculated to be approximately 17.7 μSv to the thyroid and 0.04 μSv to the whole-body. Despite the maximum allowable atmospheric (131)I concentration of 3.7 Bqm(-3) being exceeded, as the number of people immediately downwind of the crematorium flue in the high concentration zones was very low, and considering the relatively high tolerable dose to the thyroid, the radiation dose to people was probably not a problem in this case. The local limit of 1000 MBq of (131)I for the cremation of a deceased patient is reasonable, but with adequate precautions could be significantly increased without any harmful effects to people or the environment.
Humans and other animals are exposed to a wide array of man-made toxicants, many of which act as endocrine disruptors that exhibit differential effects across the lifespan. In humans, while the impact of adult exposure is known for some compounds, the potential consequences of developmental exposure to endocrine disrupting chemicals (EDCs) is more difficult to ascertain. Animal studies have revealed that exposure to EDCs prior to puberty can lead to adult reproductive disease and dysfunction. Specifically, in adult female mice with an early life exposure to 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD), we demonstrated a transgenerational occurrence of several reproductive diseases that have been linked to endometriosis in women. Herein, we review the evidence for TCDD-associated development of adult reproductive disease as well as known epigenetic alterations associated with TCDD and/or endometriosis. We will also introduce new "Organ-on-Chip" models which, combined with our established murine model, are expected to further enhance our ability to examine alterations in gene-environment interactions that lead to heritable disease.
Background
The use of gold nanoparticles (Au-NP) based medical applications is rising due to their unique physical and chemical properties. Diagnostic devices based on Au-NP are already available in the market or are in clinical trials and Au-NP based therapeutics and theranostics (combined diagnostic and treatment modality) are in the research and development phase. Currently, no information on Au-NP consumption, material flows to and concentrations in the environment are available. Therefore, we estimated prospective maximal consumption of Au-NP from medical applications in the UK and US. We then modelled the Au-NP flows post-use and predicted their environmental concentrations. Furthermore, we assessed the environment risks of Au-NP by comparing the predicted environmental concentrations (PECs) with ecological threshold (PNEC) values.
Results
The mean annual estimated consumption of Au-NP from medical applications is 540 kg for the UK and 2700 kg for the US. Among the modelled concentrations of Au-NP in environmental compartments, the mean annual PEC of Au-NP in sludge for both the UK and US was estimated at 124 and 145 μg kg−1, respectively. The mean PEC in surface water was estimated at 468 and 4.7 pg L−1, respectively for the UK and US. The NOEC value for the water compartment ranged from 0.12 up to 26,800 μg L−1, with most values in the range of 1000 μg L−1.
Conclusion
The results using the current set of data indicate that the environmental risk from Au-NP used in nanomedicine in surface waters and from agricultural use of biosolids is minimal in the near future, especially because we have used a worst-case use assessment. More Au-NP toxicity studies are needed for the soil compartment.
Electronic supplementary material
The online version of this article (doi:10.1186/s12951-015-0150-0) contains supplementary material, which is available to authorized users.
Gone are the days wherein industries are considered as main culprits of air pollution. The industries chimneys with emissions are hardly symbol of development and most of the air pollution equipments are available at competent prices with good service backup. Apart from end of pipe pollution control equipment this manufacturers are adopting new methods. This chapter discusses extended producers responsibility, extended polluters responsibility, zoning atlas for siting industries, green technologies, green belt, environmental impact assessment and solutions in some important air polluting industries.
China is the most populous country in the world. The amount of death population has reached 9.65 million and 49.5% of human corpses are cremated by about 1700 crematories spread throughout the country in 2012, leading to considerable discharge of various hazardous air pollutants (HAPs) into the atmosphere and great concerns on regional air quality and health risks for surrounding residents. By using the practicable or best available emission factors, for the first time, a multiple-year emission inventory of typical hazardous air pollutants discharged from crematories in the Chinese mainland, has been established for the historical period of 1990-2012, and the future trends of HAPs emissions until 2030 are forecasted based on three scenarios analysis. Our results show that the total emissions have gradually increased to 906 t of NOX, 443 t of SO2, 2713 t of CO, 477.7 t of PM, 377 t of HCl, 36 t of H2S, 25 t of NH3, 62 t of NMVOCs, 592 kg of Hg, 48 kg of Pb, 14 kg of Cd, 53 kg of As, 40 kg of Cr, 37 kg of Cu, 51 kg of Ni, and 96 g of PCDD/Fs as TEQ (toxic equivalent quantity) by the year 2012. Under the business-as-usual (BAU) scenario, various HAPs emitted from cremators would continuously increase with an average growth rate of 3% till to 2030; whereas the emissions will peak at around 2015 and then decline gradually with varied speed under the two improved control scenarios. To mitigate the associated air pollution and health risks caused by crematories, it is of great necessary for implementing more strict emission standards, applying combustion optimization and requiring installation of best available flue gas purification system, as well as powerful supervision for sound operation of crematories.
Cremation poses difficulties to forensic practitioners because the body itself as evidence is completely lost. The burning of corpses is one of the oldest known ways to dispose of human remains. Cremation rates in Europe have constantly increased since the beginning of the 20th century due to changes of sociocultural and religious attitudes. Cremation is a trend that is expected to continue in the near future. This chapter describes the process of cremation and the modification of the corpse during cremation. Modern crematoria are highly specified engineered buildings, and incineration of a body occurs under controlled conditions where the body is subjected to a continuous source of heat. Organs and soft tissues are completely burned to fume and around 5% of the body weight remains as ‘ashes’ consisting of small or sometimes even larger calcined bone pieces, implanted structures and casket components.
Unlabelled:
Polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) are a group of dangerous compounds, emitted mostly from anthropogenic sources, that have negative effects on human health. Therefore, it is interesting to analyze the emission patterns of dioxins proceeding from different sources around the world, to observe the actual trend of the transmission of dioxins and furans into the atmosphere.For that reason, the main objective of the present document is to provide a general assessment about the dioxin problematic, analyzing the main parameters that influence the ambient concentration of dioxins worldwide, and describing the most characteristic features of the fingerprint from different sources, while making emphasis in the importance that non-industrial sources are gaining over the last years in front of the decreasing tendency of industrial sources. The description of the most important abatement technologies for dioxins is also included in this review.
Implications:
Given the negative effects of dioxins in human health, it is important to depict and locate the main sources of these dangerous compounds. Emissions proceeding from industrial facilities have decreased over the last years; however, other zones where nonindustrial sources used to be relevant contributors do not show the same decreasing tendency because it is more difficult to control this type of emissions. For that reason, future studies should focus on measuring and regulating this highly uncontrolled source of dioxins.
In order to evaluate the environmental impact of a hazardous waste incinerator (HWI) located in Constantí (Spain), during the period 2010-2012, 30 vegetation and soil samples were alternatively (herbage in 2010 and 2012, and soils in 2011) collected in the surroundings of the facility, and their contents of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) determined. Data were compared with those of previous campaigns, and especially with PCDD/F levels in the same monitors reported in the baseline study (1998), when the facility was being constructed. In general terms, a continuous decrease of PCDD/Fs in soils was observed, while in herbage the results indicated an increase since 2008. Anyhow, the health risks associated to environmental exposure of PCDD/Fs are currently within acceptable ranges.
Medicine in the second half of the nineteenth century takes on some characteristics of modernity. These characteristics are worthy of our attention because they help us to understand better some of the current problems of hygiene and public health. One of the topics that was most discussed in the scientific-academic milieu of the second half of the nineteenth century was cremation. There was a poetic precedent: the cremation of Percy Bysse Shelley (1792-1822). The earliest apparatus to completely destroy the corpse was made in Italy and Germany in the 1870s. As far as hygiene was concerned, the reasons for cremation were not to pollute the water-bearing strata and an attempt to streamline the cemetery structure. As in an apparent schizophrenia, scientists of the day worked to both destroy and preserve corpses. There is also the unusual paradox that when the first cremations took place, the corpses were first preserved then to be destroyed later. The catholic world (mainly in Italy) and forensic scientists opposed cremation. It was left to the hygienists to spread the practice of cremation. An analysis of scientific literature shows us that if we leave out the related forensic and ethical problems, recent years have seen attention paid to any harmful emissions from crematoria equipment which have poured into the environment. Another issue is the assessment of inadvertent damage which may be caused by the condition of the corpse. Some topics, however, such as the need for preventive autopsies (first proposed in 1884 in Milan) are still a subject of debate, and seem to pass virtually unchanged from one generation to the next.
This study was aimed at determining the concentrations of polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/Fs) in 15 samples of adipose tissue from subjects who had been living in the vicinity of a hazardous waste incinerator (HWI). The results were compared with levels obtained in previous surveys carried out in 1998 (baseline study), 2002 and 2007. The current (2013) concentrations of PCDD/Fs in adipose tissue ranged from 2.8 to 46.3 pg WHO-TEQ/g fat (mean and median concentrations: 11.5 and 7.4 pg WHO-TEQ/g fat, respectively), being significantly lower (64%) than those observed in 1998. In contrast, no significant differences in the mean PCDD/F concentrations were noted in the period 2002–2013. The significant decrease of the PCDD/F content in fat, also noted in other biological monitors such as plasma and breast milk, is in agreement with the reduction in the dietary intake of PCDD/Fs found in the same area of study. Similarly to other investigations across Europe, an increase of PCDD/F levels in adipose tissue in relation to age was observed, while no significant differences were noted according to gender. A multicompartmental physiologically-based pharmacokinetic (PBPK) model was also applied to estimate the levels of PCDD/Fs in adipose tissue. When comparing the modeled and experimental concentrations of PCDD/Fs in that tissue, very similar values were obtained for the four surveys, which indicates this can be a reliable tool to predict the internal dose of PCDD/Fs.
Dental amalgam is 50% metallic mercury (Hg0) by weight and causes Hg exposure. The first assessment of Hg exposure and risk from dental amalgam in Canada was published in 1996. Recent data provided the opportunity to update that assessment. During the Canadian Health Measures Survey (CHMS; 2007 to 2009) the number of tooth surfaces specifically restored with dental amalgam was recorded. Data were also collected on the concentration of Hg in urine of survey participants. These data were employed to determine Hg exposures in the Canadian population. Also determined was the number of amalgam-restored tooth surfaces that would not result in exposure exceeding the dose associated with Canada's reference exposure level (REL) for Hg0. Based on the CHMS data, 17.7 million Canadians aged ≥6 years collectively carry 191.1 million amalgam surfaces, representing 76.4 million amalgam-restored teeth. Average Hg exposures were: Children—0.065 μg Hg/kg-day; Teens—0.032 μg/kg-day; Adults—0.033 μg/kg-day; and Seniors—0.041 μg/kg-day. Of Canadians with dental amalgam restorations, 80.4% experience a daily dose of Hg that exceeds the Canadian REL-associated dose. The number of amalgam surfaces that will not result in exceeding the REL-associated dose varied from two amalgam surfaces (children, both sexes) to seven surfaces (adult males).
Risks to health posed by emissions of hazardous air pollutants from crematories are emerging concerns. The presence of silver-mercury amalgams in bodies results in airborne emissions of mercury; and the combustion of essentially any material results in emissions of polychlorinated dibenzodioxins and furans (PCDD/Fs; “dioxins”). These and other trace emissions from crematories are not regulated at the United States federal or (typically) state level, but neighborhood concerns may necessitate quantitative evaluations of potential local impacts, and local officials may need to rely on such evaluations in order to determine whether and under what conditions to grant (or deny) operating permits. Here we present a case study in which these and other issues were evaluated. Using air dispersion models and health risk assessment models, we predicted exposures that would be within health-based guidelines. Concerned citizens provided information that seemed to suggest otherwise. In the end, communication, education, and compromise led to a favorable result.
The objective of this study was to determine whether the fear of dioxin/furan emissions from waste-to-energy plants was justified by the 2007 status of emissions of French municipal solid waste incinerators (MSWIs). All emissions were examined, plant by plant, but this paper focuses on the incinerator emission that is most frequently mentioned in the French media, toxic dioxins and furans. The study showed that there are 85 large MSWI that generate electricity or heat, i.e., waste-to-energy (WTE) plants, and 39 smaller MSW incinerators. The results showed that all French MSWI are operated well below the EU and French standard of 0.1ngTEQNm(-3) (toxic equivalent nanograms per standard cubic meter) and that their total dioxin/furan emissions decreased from 435gTEQ in 1997 to only 1.2g in 2008. All other industrial emissions of dioxins have also decreased and the major source is residential combustion of wood (320gTEQ). It was extremely difficult to obtain MSWI emission data. This unwarranted lack of transparency has resulted in the public perception that MSWI plants are major contributors to dioxin emissions while in fact they have ceased to be so.
This study proposes the use of multi-activity network data envelopment analysis to appraise how incineration plants in Taiwan perform. Sample data from 2006 is used to examine the trade-offs between efficiency enhancement and pollution abatement. The respective efficiencies of the waste treatment and electricity generation are also assessed in a unified framework. The empirical results indicate that it is more important to improve the efficiency of waste treatment activity than of electricity generation activity in order to enhance the overall performance of Taiwan's incinerators. Since ownership, location and length of operations do not in general affect their performance, any improvement has to come from the careful monitoring of each process of the waste treatment operations. Furthermore, given that the policy in Taiwan has moved away from incineration to recycling, the problem of an over-supply of incinerators may become apparent in the near future. Our results indicate that the availability of capacity size may be an important factor when policy-makers consider whether to close down some existing incinerators.
Purpose
Although the funeral market is propagating new ‘green’ alternatives and exploring innovative techniques like resomation, very little is known about the environmental impact of funerals. This research aimed to develop a benchmark of funerals, by quantifying the environmental impacts of the most common funeral techniques, i.e. burial and cremation, by identifying where the main impacts originate from and by comparing these impacts to impacts of other activities during a person’s life.
Methods
The environmental impacts of funerals were analysed by means of a life cycle assessment (LCA), based on Dutch company information, literature and expert judgements. The results were analysed per impact category but also on an aggregated level by means of shadow prices. Two sensitivity analyses were performed: one examined the high impact of cotton in funeral coffins; the other checked the results by means of another weighting method.
Results and discussion
The results showed no significant difference between the two funeral techniques in five impact categories. Burial has the lowest impact in more than half of the categories, but its impact is many times higher in the two most differing categories than for cremation. The total shadow price of burial is about 30 % higher than the shadow price of cremation, but the main cause for this difference is a highly debated category, namely land use. If the results would be considered without the shadow prices of land impact categories, burial would score 25 % lower than cremation. These results are representing average practise and may deviate on certain aspects for other countries, but as a starting point for further studies, this benchmark is well applicable.
Conclusions and recommendations
This study delivered an environmental benchmark of funerals and insights in the impacts of the individual processes, which can be used in further assessment of ’green’ funeral options. The benchmark results show that the environmental impact of funerals is largely determined by secondary processes and that the total impact can be quite small in comparison to other human activities. Besides these environmental insights, it is important to take into account social, cultural, climatic, local, economical and ethical arguments before changing policies or giving recommendations.
The only hazardous waste incinerator (HWI) in Spain has been operating in Constantí (Tarragona County, Catalonia) since 1999. Before its construction, a surveillance program was initiated to monitor the concentrations of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) in the neighborhood of the facility. In 2008, 40 soil and 40 vegetation samples were collected and PCDD/F levels determined. The median PCDD/F concentration in soil was 0.49 ng international toxic equivalents (I-TEQ)/kg. Although it meant a nonsignificant decrease of 44% with respect to the preoperational survey, important fluctuations of the levels of PCDD/Fs through time were found in some specific sites. Therefore, a new survey was performed 1 year later (2009) by deleting those sampling sites with inconstant values, which mostly coincided with urban zones. In 2009, the median level of PCDD/Fs in soils was found to be 0.42 ng I-TEQ/kg. In contrast, median PCDD/F levels in vegetation were 1.11 ng I-TEQ/kg, a significant increase compared with previous surveys (range of the median 0.21-0.25 ng I-TEQ/kg). However, this increase was uniformly observed in the entire sampling area, suggesting that lack of rainfall was a key parameter for decreasing plant dilution and wash-up of pollutants on vegetation. This indicates that in surveillance programs, information must be obtained from different sources because the use of a single compartment may yield significant misinterpretation when evaluating temporal trends of environmental pollutants. Human health risks derived from exposure to PCDD/Fs were also assessed for the local population. The results indicated that current concentrations of these contaminants do not pose any additional carcinogenic or noncarcinogenic risk for those people living near the HWI.
In order to assess the pollutant load attributable to crematoria, a study was undertaken on the emissions from cremators sited in urban areas. This paper reports some preliminary results from the testing program on an urban cremator emission as it stands with current cremation practices in Italy. Results concern the concentration of the following parameters at the stack: total particulate matter, metals (As, Cd, Co, Cr, Cu, Hg, Mn, Ni, Pb, Sb, Sn, Tl, V, Zn), organic micropollutants such as dioxins (PCDDs), dibenzofurans (PCDFs), polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs).
PCDD/PCDF are trace contaminants in industrial and thermal processes, whose formation often cannot be avoided. Although the most important sources seem to be recognized within the last years new sources have been discovered. Very often only limited data are available. For the understanding of human exposure it is necessary to understand the pathways from the source to target organs or organisms. Environmental concentrations of dioxins have to be analyzed under ectoxicological aspects. Transfer and transformation mechanisms to be considered are: evaporation, deposition, erosion, photochemical degradation.
The crude recycling of electronic and electric waste (e-waste) is now creating a new set of environmental problems especially in developing countries such as China. The present study aimed to characterize the dioxin-like compounds in Taizhou area, one of the largest e-waste recycling centers in China, using both chemical analysis and in vitro bioassay. Agricultural soil samples were screened for aryl hydrocarbon receptor (AhR) activity with EROD bioassay in H4IIE cells, and the concentrations of the target AhR agonists including polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs), polychlorinated biphenyls (PCBs) and polycyclic aromatic hydrocarbons (PAHs) were determined by instruments. The bioassay-derived TCDD equivalents (TEQbio) and the chemical-calculated TCDD equivalents (TEQcal) were then compared, and mass balance analysis was conducted to identify the contributors of the observed response. Raw soil extracts from all locations induced significant AhR activities, where the TEQbio ranged from 5.3 to 210 pg/g dry weight soil (pg/g dw). The total concentrations of 17 PCDD/Fs, 36 PCBs and 16 PAHs varied from 210 to 850 pg/g dw, 11 to 100 ng/g dw, and 330 to 20,000 ng/g dw, respectively. Profile characterization of the target analytes revealed that there were similar sources originating from the crude dismantling of electric power equipments and the open burning of e-waste. There was a significant relationship between TEQcal and TEQbio (r = 0.99, p < 0.05). Based on the mass balance analysis, PCDD/Fs, PCBs and PAHs could account for the observed AhR responses in vitro elicited by soil extracts, though their respective contributions varied depending on sample location. In this study, the combination of chemical analysis and bioanalytical measurements proved valuable for screening, identifying and prioritizing the causative agents within complex environmental matrices.
In recent years, mercury (Hg) pollution generated by municipal waste incinerators (MWIs) has become the subject of serious public concern. On Samui Island, Thailand, a large-scale municipal waste incinerator has been in operation for over 7 years with a capacity of 140 tons/day for meeting the growing demand for municipal waste disposal. This research assessed Hg contamination in environmental matrices adjacent to the waste incinerating plant. Total Hg concentrations were determined in municipal solid waste, soil and sediment within a distance of 100 m to 5 km from the incinerator operation in both wet and dry seasons. Hg analyses conducted in municipal solid waste showed low levels of Hg ranging between 0.15-0.56 mg/kg. The low level was due to the type of waste incinerator. Waste such as electrical appliances, motors and spare parts, rubber tires and hospital wastes are not allowed to feed into the plant. As a result, low Hg levels were also found in fly and bottom ashes (0.1-0.4 mg/kg and <or=0.03 mg/kg, respectively). Stack concentration of Hg were less than 0.4 microg/Nm(3). Since Hg emissions were at low concentrations, Hg in soil from atmospheric fallout near this incinerator including uptake by local weeds were very low ranging from non detectable to 399 micro g/kg. However, low but elevated levels of Hg (76-275 micro g/kg) were observed in surface soil and deeper layers (0-40 cm) in the predominant downwind direction of incinerator over a distance of between 0.5-5 km. Soil Hg concentrations measured from a reference/background track opposite of the prevailing wind direction were lower ranging between 7-46 micro g/kg. Nevertheless, the trend of Hg build up in soil was clearly seen in the wet season only, suggesting that wet deposition process is a major Hg pollution source. Hg concentrations in the sea bottom sediment collected next to the last station track was small with values between 35-67 micro g/kg. Based upon the overall findings, in terms of current potential environmental risk, the environment has not yet been appreciably contaminated from Hg emissions produced by this incinerator. However the increase of Hg measured in downwind direction of the incinerator should be monitored for future potential risk.
Calculated loading rates of trace metals into the three environmental compartments demonstrate that human activities now have major impacts on the global and regional cycles of most of the trace elements. There is significant contamination of freshwater resources and an accelerating accumulation of toxic metals in the human food chain.
Data on lipid levels of 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) in the general population in the United States, Canada, Germany, and France over the past 30 years were compiled from the literature. Mean lipid levels of TCDD exhibited a steady decrease by nearly a factor of 10 over this time period, with lipid-adjusted TCDD levels in 2000 about 2 parts per trillion (ppt). Pharmacokinetic modeling using a one-compartment model indicated that absorbed intake levels of TCDD must have decreased by more than 95% from levels in 1972 to result in the observed decrease in human lipid levels, with the bulk of this decrease occurring before 1980. Based on this modeling and the pharmacokinetic properties of TCDD in humans, we conclude that mean levels of TCDD in the general population are likely to decrease further over the next 15 years, to between 0.5 and 1 ppt, even if intake levels do not decrease further. Fewer data over a shorter time period are available for other dioxin and furan congeners in human lipid, but these data indicate substantial decreases as well, with general population TEQ lipid levels currently at least fourfold lower than in 1970 and still decreasing. Food sampling data are limited, but support these trends.
This review evaluates the epidemiological literature on health effects in relation to incineration facilities. Several adverse health effects have been reported. Significant exposure-disease associations are reported by two thirds of the papers focusing on cancer (lung and larynx cancer, non-Hodgkin's lymphoma). Positive associations were found for congenital malformations and residence near incinerators. Exposure to PCB and heavy metals were associated with several health outcomes and in particular with reduction of thyroid hormones. Findings on non-carcinogen pathologies are inconclusive. Effect of biases and confounding factors must be considered in the explanation of findings. Methodological problems and insufficient exposure information generate difficulties on study results. Research needs include a better definition of exposure in qualitative and quantitative terms in particular by developing the use of biomarkers and by implementing environmental measurements.
In 1997 the International Agency for Research on Cancer (IARC) classified 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD; the most potent dioxin congener) as a group 1 carcinogen based on limited evidence in humans, sufficient evidence in experimental animals, and extensive mechanistic information indicating that TCDD acts through a mechanism involving the aryl hydrocarbon receptor (AhR), which is present in both humans and animals. The judgment of limited evidence in humans was based primarily on an elevation of all cancers combined in four industrial cohorts. The group 1 classification has been somewhat controversial and has been challenged in the literature in recent years. In this article we review the epidemiologic and mechanistic evidence that has emerged since 1997. New epidemiologic evidence consists primarily of positive exposure-response analyses in several of the industrial cohorts, as well as evidence of excesses of several specific cancers in the Seveso accident cohort. There are also new data regarding how the AhR functions in mediating the carcinogenic response to TCDD. The new evidence generally supports the 1997 IARC classification.
From 1975 to 2004, a municipal solid waste incinerator (MSWI) was operating in Montcada (Barcelona, Catalonia, Spain). Because of the potential health risks derived from emission of pollutants by the facility, especially polychlorinated dibenzo-p-dioxins (PCDDs) and dibenzofurans (PCDFs), a long-term monitoring program focused on measuring the environmental levels of PCDD/Fs near the facility, and to assess the health risks for the population living in the neighborhood, was established between 1996 and 2002. A total number of 111 soil and 121 herbage samples were analyzed for PCDD/Fs during this period. Human health risks for the individuals living near the MSWI (500 and 1,000 m) were also assessed before (1998) and after modernization (2000) of the facility. It included PCDD/F inhalation, dermal contact, soil and dust ingestion, and food intake. All these data are here summarized. The environmental levels of PCDD/Fs showed that the MSWI was not the main responsible of the atmospheric pollution by these compounds. In turn, human health risks for the population living in the vicinity of the facility after introduction of a modern technology were negligible in comparison with the dietary PCDD/F exposure.
Polychlorinated dibenzo-p-dioxins (PCDDs), dibenzofurans (PCDFs) and biphenyls (PCBs) are lipophilic organic compounds whose origin comes from many different sources. PCDD/Fs and PCBs are ubiquitous and persistent environmental pollutants with a well known potential toxicity, which were included at the 1998 UN-EC POP protocol. Although human exposure to PCDD/Fs and PCBs can occur by various routes, food is the primary source. A number of studies have shown that the major food sources of these organic pollutants are fat-containing animal products, including fish and other seafood. Because of the frequent health recommendations concerning fish consumption, to determine the contribution to the dietary intake of chemical contaminants such as PCDD/Fs and PCBs through fish and other seafood consumption is an issue of special interest. This paper reviews the state of the science regarding recent literature on PCDD/F and PCB levels in marine species and human intake through fish and seafood consumption. The concentrations of these pollutants depend basically on the environment in which the respective species are caught. It is concluded that some groups of population frequently consuming high quantities of certain species could be significantly increasing health risks due to PCDD/F and PCB exposure.
This study was set out to characterize PCDD/F emissions from crematories and assess their impacts on the surrounding environment. Two crematories located in southern Taiwan were investigated, including the one (Cl) with no air pollution control device installed and the other (C2) installed with a bag filter. Results show the mean PCDD/F emissions (11% oxygen) from the stacks of C1 and C2 were 2.36 and 0.322 ng I-TEQ Nm(-3), respectively. The mean emission factors for C1 and C2 were 13.6 and 6.11 mug I-TEQ body(-1), respectively. The removal efficiency of the bag filter on PCDD/Fs was 55.1%. The estimated PCDD/F emission rate for all crematories in Taiwan was 0.838 g I-TEQ yr(-1) accounting for 227% and 112% of the annual emissions from all medical waste incinerators and municipal waste incinerators, respectively. The above results indicate that PCDD/F emissions from crematories were quite significant. To assess the impact of PCDD/F emissions from a crematory to the surrounding environment, ambient air samples were collected from the downwind site of C1 with the maximum ground concentration. We found the estimated maximum ground concentration at the downwind site of C1 (= 0.521 pg I-TEQ Nm(-3)) was much higher than that found at the background, rural area, residential area, urban area, and industrial area (= 0.006, 0.023, 0.052, 0.093, and 0.190 pg I-TEQ Nm(-3), respectively). The above results suggest that PCDD/F emissions from a crematory did significantly affect its surrounding environment. In conclusion, a proper control strategy should be taken immediately in order to eliminate PCDD/F emissions from crematories.
In Sweden there are no legislative regulations regarding mercury in fluegas emission from crematoria. The crematoria do not have treatment facilities to reduce mercury emissions, although they are the third highest emission source of mercury in Sweden. Included in this paper are the data on mercury emission during cremations with and without the addition of selenium for the reduction of mercury emission. Tests were carried out during 22 cremations. The use of selenium gave emission reductions of 80 to 85% in stack gases, and 20 to 50% in the emission peaks.
This study updates previous estimates of emissions to the UK atmosphere of polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs). Following a systematic screening of a range of industrial processes operating in the UK for the potential to release PCDDFs to atmosphere, 23 industrial processes were shortlisted for further consideration as potential emitters. To these processes were added six non-industrial sources of PCDDF emissions; domestic coal and wood combustion, crematoria, traffic, natural fires and accidental fires. For each shortlisted process emission factors were identified. Emission factors were combined with the quantity of material treated or produced to generate an estimate of the annual quantity of PCDDFs released to atmosphere. The total estimated current emissions to atmosphere ranged from 560 to 1100 g I-TEQ year−1, with industrial processes contributing 535–955 g I-TEQ year−1, an average of approximately 90% of the total inventory. Emissions from MSW incineration plants were dominant, contributing an average of 70% to the total emissions from industrial sources. Emissions from coal combustion, sinter plants, iron and steel plants, non-ferrous metals operations and incineration of clinical waste collectively contributed an average of 25% to total industrial emissions in roughly equal proportions. The effect of tightening emission controls was also examined. Assuming a situation when current regulations concerning PCDDF emissions are fully implemented, a reduction in emissions from 560–1100 g I-TEQ year−1 to 110–350 g I-TEQ year−1 is envisaged. The largest reduction is effected through the imposition of a 1 ng I-TEQ m−3 emission limit on MSW and clinical waste incinerators: the contribution from these sources falls from the present range of 60–85% to approximately 6–18% of total emissions.
Wood waste and industrial wood residues often contain various preservatives. The waste management can be combustion, deposition or recycling, but combustion seems to be the most efficient way of disposal. To obtain detailed information about emissions of organic compounds with environmental impact, especially polychlorinated dibenzo-p-dioxins (PCDD) and furans (PCDF), different impregnated wood materials were incinerated in two furnaces after mixing with non-treated wood in a ratio of 1:4. It was found that the concentrations of PCDD and PCDF in the exhaust gas can be kept low under good combustion conditions. However, a non-regular incineration process strongly supports increased emissions of PCDD and PCDF.
The present study was intended to establish an inventory of PCDD/F emissions in Tarragona Province (Catalonia, NE Spain),
as a preliminary phase in the development of a flow analysis of PCDD/Fs in this Province. In 1999, global PCDD/F emissions
reached a value of 2.24 g I-TEQ/y, which means a density of 3.8 μg I-TEQ/inhabitant/y. The low amount of PCDD/Fs emitted to
air by the only municipal solid waste incinerator in the Province (approximately 0.04% of the total) has been one of the most
notable results. As a reflection of uncertainties in the estimates for individual sources, the 90th percentiles of PCDD/F
releases for 1999 ranged up to 4.1 g I-TEQ/y.
Taiwan is a small, densely populated island with unique experiences in the construction and operation of incinerators. In such a small area, Taiwan has built 22 incinerators over a short span of time, combusting large amount of municipal solid waste as much as 23,250 tons per day. This study focuses on the history of construction and development of incinerators in Taiwan as well as the characteristics of pollutants, such as heavy metals (Pb, Cd, and Hg), acid gases (NO
x
, SO
x
, CO, and HCl), and dioxins emitted from the incinerators. Furthermore, the study also covers the generation and composition of municipal solid waste (MSW), and the production of energy in Taiwan. According to Taiwan's data on pollutant emissions, the emission level of pollutants is under control and meets the stringent regulations of Taiwan Environmental Protection Administration (TEPA). Researches have shown that using air pollution control devices (APCDs) in the operation of incinerators provides effective measures for air pollutant control in Taiwan. The main advantage of using incinerators is the generation of electricity (waste-to-energy) during the incineration of municipal solid waste, producing energy that can be consumed by the general public and the industry. Taiwan's extensive experience in incinerator construction and operation may serve as an example for developing countries in devising waste treatment technology, energy recovery, and the control of contagious viral diseases.
Dioxins, formed in any combustion process where carbon, oxygen and chlorine are present, are a subject of major interest due to their carcinogenicity. Much research has been carried out to study emissions from hazardous and municipal waste incinerators. Dioxin emissions from wood combustion plants are also of interest, especially those due to the combustion of treated, varnished or PVC-coated wood, which can produce high PCDD/F emissions. This work reviews the available data about the levels of dioxins in gases and ashes produced in wood combustion.
The aim of the present study was to assess the human health risks (carcinogenic and non-carcinogenic) of PCDD/F exposure for the adult population living in two different areas (industrial and residential) of Tarragona (Catalonia, Spain), as well as to compare these risks according to the socioeconomic status of the population. Two pathways were considered for PCDD/F exposure: direct (air inhalation, dermal contact and ingestion from soils and dust) and dietary. Although environmental exposure was higher for the population living in the neighborhood of the industrial area (mainly lower socioeconomic group subjects), it only accounted 1.05%. On the other hand, PCDD/F exposure through dietary intake was more important for those individuals of an upper socioeconomic level. This was due to the fact that their diet is richer in those foodstuffs containing higher PCDD/F concentrations. Consequently, taking together direct and dietary exposure to PCDD/Fs, the result is that upper socioeconomic group populations are more exposed to these toxic pollutants. In any case, the current levels of PCDD/F exposure would not mean significant carcinogenic and non-carcinogenic risks for the population living in the industrial and residential areas of Tarragona.
This study strives to estimate the emission of dioxin and furthermore attempts to find the best technological control methods available for waste incinerators by investigating the emission status thereof. In order to incorporate the Stockholm Convention, a particular stringent law was promulgated in Korea and in recent years incinerators were forced to utilize better technological control. After the enforcement of special dioxin emission regulation in 2003, the average concentration of dioxin emitted from municipal and industrial waste incinerators decreased from 15.25 and 12.86 ng TEQ Nm(-3) to 5.53 and 4.96 ng TEQ Nm(-3) in 2001 and 2004, respectively. Based on test results at commercial plants, several best arranged sets of air pollution control devices (APCDs) were suggested in order to provide guidelines to help operators. These sets included combinations of spray dry absorbers, bag type filters, wet scrubbers, selective catalytic reductions and electrostatic precipitators. Different suggestions and real installations of APCD arrangement were investigated during the years around the regulation in effective. The results were presented depending on the capacity of the incinerators and different waste streams to observe the efforts to reduce dioxin emission by operators of incineration plants. The annual amount of dioxin emission from the incinerators is expected to be 212.5 g-TEQ in 2011 and 234.3g-TEQ in 2015, respectively, compared to 891.6g-TEQ recorded in 2001. The enforcement of new regulation and the installation of better APCDs showed the significant effect on such reduction. This reduction in dioxin emission from incinerators confirmed the nation's commitment to the regulatory requirement set by the Stockholm Convention.
The generation of waste in urban regions over time is seen to impact the balance of anthropogenic and natural resources. Various national and international initiatives to manage urban solid waste are in place and has thus have evolved at present to form an assortment of different subcomponents involving environmental, administrative, regulatory, scientific, market, technology, and socio-economic factors, which has increasing bearing on the US due to its volume and nature of discards. This paper draws together the various aspects of municipal solid waste (MSW) management as it evolved, particularly in the American society through reviewing works and findings. In many parts of the country, waste management at present, primarily involves landfilling, incineration with and without energy recovery, recycling and composting. Legislation, nature of wastes and market trends continue to redefine management operations and its responsibilities and impacts. Complexities are added to it by the nature of urban development as well. New studies and concepts like 3Rs, cradle-to-cradle, industrial ecology, and integrated waste management are adding new dimensions for solving waste problems towards achieving sustainable resource use. Local initiatives, both public and private are in the forefront of adopting alternate waste management procedures. The assistance from various government and private bodies, supporting shifts in waste management approaches, have immense value, as according to the new paradigms, nothing goes to waste.
The dental status of 130 deceased Zurich people was evaluated from radiographs of their maxillary and mandibular dentitions taken during their autopsies. A mean mass of mercury of 2.49 +/- 0.37 g was calculated per dentate deceased based on the analysis of 134 extracted premolars and molars with amalgam restorations. The mercury contamination due to cremation in 1988 in Switzerland was calculated to vary between 45.8 and 79.0 kg, based on both the data from the sample analyzed and the fact that 55.5% of Swiss funerals were cremations, the average age of death was 73 and that 70% of the people of that age retained some of their teeth. Mercury contamination by cremation, therefore comprised only 0.61 to 1.53% of the total mercury contamination produced by all waste incineration methods. The minimal contribution to the mercury contamination due to cremation can thus not be used as an argument to ban the use of dental amalgams.
The amount of mercury released during cremation was calculated in a major Swiss city at two crematoria. A total of 60 mercury "output" calculations were carried out by the Swiss Material Testing Institute (Empa). The amount of mercury initially present ("input") in the dentitions of 54 deceased persons was assessed from their post-mortem dental radiographs and by clinical examination. The correlation between the "input" and the "output" was 0.93, irrespective of the age at death. However, the "input" was calculated to be 1.8 times higher than the "output" for the deceased people with amalgam restorations. In the blind study, the difference was 1.3 times. The main source of mercury was undoubtedly the amalgam restorations. The amount of mercury recorded during the cremation of 88% of the deceased people without amalgam restorations was under the accepted level of 200 micrograms/m3. However, in 3 cases, the amount of mercury was slightly more than 200 micrograms/m3. In contrast, the amount of mercury recorded during the cremation of only 18% of the deceased people with amalgam restorations was less than the accepted level of 200 micrograms/m3. The amount of mercury contamination during cremation as a result of amalgam fillings is so low that no additional preventive measures are required at the crematoria.
Mercury in dental amalgam filling is released into the atmosphere by cremation and is a suspected source of mercury pollution. The amount of mercury released was measured at three crematoriums. First, mercury levels in the atmosphere were measured. Mercury existed mainly in the gaseous form in ambient air. The concentration of atmospheric mercury at the three crematoriums (S, T and M) ranged from 4.3 to 19.7ng/m3, which was nearly identical to levels in our university surveyed as the control area and also to the levels of atmospheric mercury in general in Japan. Secondly, the amount of mercury release from T crematorium was estimated using official published statistical data in Japan and calculated as follows: sigma[(age specific number of dead that were cremated) x (the number of restored teeth by age category) x (mercury content per amalgam filling (0.6 g))] x (prevalence rate of restoration with amalgam). The amount of mercury released from this crematorium was estimated to be approximately 9.4 kg per year, or a daily release of 26 g into the ambient air. These results indicate that mercury release by cremation is similar to that from other man-made sources.
A vast amount of research has been undertaken in the last 15-20 years on the corrosion reactions occurring in dental amalgam, release of mercury from amalgam restorations, and the toxic effects of this released mercury on the human body. However, one environmental aspect of amalgam dental restorations that has not received a great deal of attention is the release of mercury during cremation. Mercury is liberated during cremation both because dental amalgams are unstable at cremation temperatures (650-700°C) and because the free mercury metal is highly volatile. In New Zealand, 58% of deaths are followed by cremation and this figure is likely to rise in the future. This increasing use of cremation as the method of corpse disposal, coupled with the fact that each amalgam restoration is approximately 50% mercury, implies that a significant amount of mercury may be emitted into the environment every year. This study examines mercury released from crematoria in New Zealand. 20 refs., 2 figs., 5 tabs.
Concentrations of PCDDs and PCDFs in emission gases from 10 crematories were measured. The relationship between PCDDs/DFs and several factors such as structure, equipment and operational state of the crematory is discussed. Furthermore, emission of PCDDs/DFs from all crematories in Japan is estimated. The following results are obtained: (1) total concentration of PCDDs/DFs was 2.2-290 ng/N m3, whose TEQ concentration was 0.0099-6.5 ng TEQ/N m3; (2) total concentration of PCDFs was higher than that of PCDDs; (3) T4CDFs was the highest in the homologue pattern and 2,3,7,8-T4CDF was the highest in the isomer pattern; (4) emission of PCDDs/DFs was the largest in the first 20 min of cremation; (5) concentration of PCDDs/DFs was related to the existence of a secondary combustion chamber and a dust collector, and the ratio of the numbers of main and secondary combustion chambers; (6) total emission of PCDDs/DFs from crematories in Japan was estimated to be 8.9 g TEQ/yr.
In this study, PCDDs/DFs and co-planar PCBs concentrations in flue gases from 17 crematories and in fly ashes and bottom ashes (mainly bone) from several crematories were measured to grasp the present state of PCDDs/DFs emissions from crematories. The effects of several factors were discussed to prevent PCDDs/DFs emissions from crematories. Total concentration (normalized by 12% O2) of PCDDs/DFs was ranged from 4.9 to 1200 ng/m3 N, and toxic equivalent concentration was ranged from 0.064 to 24 ng TEQ/m3 N. As the results obtained in this research, the following measures to reduce PCDDs/DFs emission are recommended for existing crematories: (1) keeping the temperature at 800 degrees C in main/secondary chambers during a whole cremation, and (2) lowering the temperature in the dust collector. For newly installed crematories, following measures to prevent PCDDs/DFs emission including the measures for existing ones are recommended: (1) connecting one secondary chamber to one main chamber, (2) installing the high efficiency dust collector and reducing dust concentration to less than 0.01 g/m3 N, and (3) installing the sampling point for monitoring of PCDDs/DFs.
Polychlorinated dioxins, furans and polychlorinated benzene constitute a family of toxic persistent environmental pollutants. In Europe, environmental concentrations increased slowly throughout this century until the late 1980s. Dioxins have been shown to be carcinogenic in animals and humans. In humans, excess risks were observed for all cancers, without any specific cancer predominating. In specific cohorts, excess risks were observed for reproductive cancers (breast female, endometrium, breast male, testis) but, overall, the pattern is inconsistent. In animals, endocrine, reproductive and developmental effects are among the most sensitive to dioxin exposure. Decreased sperm counts in rats and endometriosis in rhesus monkeys occur at concentrations 10 times higher than current human exposure. In humans, results are inconsistent regarding changes in concentrations of reproductive hormones. A modification of the sex ratio at birth was described in Seveso. There exist no data on effects such as endometriosis or time-to-pregnancy. Small alterations in thyroid function have occasionally been found. Increased risk for diabetes was seen in Seveso and a herbicide applicators cohort but, overall, results were inconsistent. Experimental data indicate that endocrine and reproductive effects should be among the most sensitive effects in both animals and humans. Epidemiological studies have evaluated only a few of these effects.
The present study was intended to establish an inventory of PCDD/F emissions in Tarragona Province (Catalonia, NE Spain), as a preliminary phase in the development of a flow analysis of PCDD/Fs in this Province. In 1999, global PCDD/F emissions reached a value of 2.24 g I-TEQ/y, which means a density of 3.8 micrograms I-TEQ/inhabitant/y. The low amount of PCDD/Fs emitted to air by the only municipal solid waste incinerator in the Province (approximately 0.04% of the total) has been one of the most notable results. As a reflection of uncertainties in the estimates for individual sources, the 90th percentiles of PCDD/F releases for 1999 ranged up to 4.1 g I-TEQ/y.
In June 1994 and 1997, the concentrations of a number of elements were determined in soil and herbage samples collected in the vicinity of a municipal solid waste incinerator (MSWI) (Tarragona, Catalonia, Spain). In August 1997, an adaptation to the EU legislation on pollutant emissions from the stack was carried out to the incinerator. In June 1999, soil and herbage samples were collected again at the same sampling points and the levels of arsenic (As), cadmium (Cd), chromium (Cr), lead (Pb), manganese (Mn), mercury (Hg), nickel (Ni) and vanadium (V) were measured by ICP-MS or AAS with graphite furnace. The results are compared with those obtained in the 1994 and 1997 surveys. In the period 1997-1999, the only significant changes in soil levels corresponded to Cd and Pb, with decreases of 21.0% and 53.5%, respectively. In vegetation, only Mn levels showed a significant reduction, which contrasts with the notable increases found in the concentrations of As, Hg and Ni. According to the results of this survey, it seems evident that other metal emission sources in the same area of study are masking the environmental improvements carried out in the MSWI.
Flue gas samples from eight different sources (industrial plants and crematories) have been analyzed for PCDD/Fs and PCBs and total Toxicity EQuivalents (TEQ) values have been calculated using the latest WHO toxicity equivalent factors from 1998. A contribution of PCBs to the Total TEQ up to 16% was found, within the 12 WHO-PCBs PCB-126 contributes mostly to the TEQ. Thermodynamic stability of PCBs was calculated semiempirically using the MOPAC program package and differences in the heat of formation (HoF) were compared to the distribution of PCBs in real samples. Partial correspondence between fact and theory could be found.
Dioxins are highly toxic by-products of incineration processes and of production of chloro-organic chemicals. Accidental poisonings have occurred repeatedly. The main human exposure is via the dietary route. Species comparisons of toxic effects on the basis of ingested doses are not possible because of the highly differing toxicokinetics between humans and experimental animals. On the basis of internal doses or body burdens acute toxic and tumorigenic responses are observed at similar levels in humans and rats. PCB/PCDD/F contamination at levels which have been reported of marketed chicken meat and eggs in 1999 in Belgium may have increased body burdens by approximately 10%. However, it is estimated that a several hundred-fold higher uptake would be necessary to reach body burdens leading to overt toxicity in normal human subjects.
Although incineration is an effective way of treating municipal solid waste (MSW), in many countries the potential health risks associated with stack emissions, particularly those of polychlorinated dibenzo-p-dioxins (PCDDs) and dibenzofurans (PCDFs), have become a cause of great controversy and concern. Given the interest and importance of this controversy, in the present paper a series of experimental data corresponding to a number of surveys made in the vicinity of three MSW incinerators (MSWIs) of Catalonia (Spain) are reviewed. In recent months, an adaptation to the EU legislation on pollutant emissions from the stack was carried out in these facilities. We assessed whether the pronounced reductions in the atmospheric PCDD/PCDFs emissions parallel the concurrent decreases in environmental matrices collected in the vicinity of the MSWIs. In comparison with other PCDD/PCDFs emission sources in the areas under direct influence of the MSWIs, the health risks from current emissions of PCDD/PCDFs by these incinerators would be of low significance for populations living in the neighborhood. For such populations, the daily intake of PCDD/PCDFs from direct and indirect (diet) exposure are currently within the rank recommended by the WHO as the maximum daily exposure to PCDD/PCDFs for non-carcinogenic adverse effects.
This study was set out to characterize PCDD/F emissions from crematories and assess their impacts on the surrounding environment. Two crematories located in southern Taiwan were investigated, including the one (C1) with no air pollution control device installed and the other (C2) installed with a bag filter. Results show the mean PCDD/F emissions (11% oxygen) from the stacks of Cl and C2 were 2.36 and 0.322 ng I-TEQ Nm(-3), respectively. The mean emission factors for C1 and C2 were 13.6 and 6.11 microg I-TEQ body(-1), respectively. The removal efficiency of the bag filter on PCDD/Fs was 55.1%. The estimated PCDD/F emission rate for all crematories in Taiwan was 0.838 g I-TEG yr(-1) accounting for 227% and 112% of the annual emissions from all medical waste incinerators and municipal waste incinerators, respectively. The above results indicate that PCDD/F emissions from crematories were quite significant. To assess the impact of PCDD/F emissions from a crematory to the surrounding environment, ambient air samples were collected from the downwind site of C1 with the maximum ground concentration. We found the estimated maximum ground concentration at the downwind site of C1 (= 0.521 pg I-TEQ Nm(-3)) was much higherthan thatfound atthe background, rural area, residential area, urban area, and industrial area (= 0.006, 0.023, 0.052, 0.093, and 0.190 pg I-TEG Nm(-3), respectively). The above results suggestthat PCDD/F emissions from a crematory did significantly affect its surrounding environment. In conclusion, a proper control strategy should be taken immediately in order to eliminate PCDD/F emissions from crematories.
To investigate the risk of stillbirth, neonatal death, and lethal congenital anomaly among babies of mothers living close to incinerators and crematoriums in Cumbria, north west England, 1956-93.
Retrospective cohort study. Logistic regression was used to investigate the risk of each outcome in relation to proximity at birth to incinerators and crematoriums, adjusting for social class, year of birth, birth order, and multiple births. Continuous odds ratios for trend with proximity to sites were estimated.
All 3234 stillbirths, 2663 neonatal deaths, and 1569 lethal congenital anomalies among the 244 758 births to mothers living in Cumbria, 1956-1993. Main results: After adjustment for social class, year of birth, birth order, and multiple births, there was an increased risk of lethal congenital anomaly, in particular spina bifida (odds ratio 1.17, 95% CI: 1.07 to 1.28) and heart defects (odds ratio 1.12, 95% CI: 1.03 to 1.22) around incinerators and an increased risk of stillbirth (odds ratio 1.04, 95% CI: 1.01 to 1.07) and anencephalus (odds ratio 1.05, 95% CI: 1.00 to 1.10) around crematoriums.
The authors cannot infer a causal effect from the statistical associations reported in this study. However, as there are few published studies with which to compare our results, the risk of spina bifida, heart defects, stillbirth, and anencephalus in relation to proximity to incinerators and crematoriums should be investigated further, in particular because of the increased use of incineration as a method of waste disposal.
Main results of the second stage of the so-called "European Dioxin Emission Inventory" are presented. They cover emission testing data gained from various facilities in the EU (among these the first emission measurements reported from Portugal and Greece) and some central European countries. Further, updated dioxin emission estimates for the most important emission sources in the 17 western European countries and an evaluation of the emission time trend from 1985 to 2005 are presented. The major conclusions are, that at present, iron ore sintering is likely to be the most important emission source type followed by the former "No. 1", municipal waste incineration; measurement data from a considerable number of installations are still missing, in particular from the metal industries in Spain and Italy; there still exist an unknown number of health care waste incinerators with flue gas PCDD/F concentrations above 100 ng I-TEQ/m3 which must be considered as important local sources; in general, considerable emission reduction has been achieved with respect to the industrial emission sources, whereas emissions from non-industrial sources hardly decreased; hence, in the near future the emissions from non-industrial sources are likely to exceed those from industrial installations; the goal of 90% emission reduction set in the 5th EU Action Programme will be achieved for some source types only.
The protection of environment from polychlorinated dibenzodioxin and -furan (PCDD/F) impacts, caused by a heterogeneous spectrum of thermal stationary sources and several others in chemical industry, bases on a comprehensive legislation in Germany. The results of this emission reduction strategy are presented by emission inventories for stationary, mainly industrial sources comparing in this paper data for emissions between 1994 and 2001. These results show that the implementation of best available techniques (BAT) at industrial sources for PCDD/F-reduction has been nearly fully exhausted at nearly all relevant sources and extensive overall emission reductions were achieved by the end of the 1990s. Further reductions for PCDD/F are needed for specific sources in metallurgical industries, especially sinter plants, and for domestic furnaces only. For coplanar PCBs (co-PCBs) almost no emission data are available from German sources; a few data from measurements of co-PCB have been published from two waste incineration plants. These measurements show that the emission limit value of 0.1 ng TEQ/m3 is not exceeded by co-PCBs in the waste gas in addition to the background PCDD/F concentration. As a consequence from the new appraisals for toxicity equivalences (TEQ) and tolerable daily intakes (TDI) of the World Health Organisation the Federal Environmental Agency in Germany discusses a level of 1 pg WHO TEQ/(kg(bw) d) as an acceptable limit value for adult's burden, taking into account, that this value is too much for children in the pre- and post-natal age and further action for PCDD/F- and co-PCB reduction is needed for the last sensitive group. As a summary can be reported that PCDD/F and co-PCB intakes into the nutrition chain could not have their origin from stationary industrial sources mainly. More attention should be given to more diffuse source such as residential combustion and others, which are more directly connected to the nutrition chain, like green food drying. Important effects could be expected by restrictions of PCDD/F impacts by regulations for control of feed, feed components and compounds feed for pigs and cattle.
Establishment of a country or region-based dioxin inventory was considered a crucial step toward elimination of worldwide dioxins/POPs contaminations, although no harmonized method for the preparation of an inventory is available at present. In this study, we used limited data and information to generate an inventory of dioxin emissions from some major sources in Taiwan. A total of 67.25 g I-TEQ of dioxins released annually was estimated. Unlike most of the industrialized countries, municipal waste incineration is not the highest contributor for dioxins released into the atmosphere. In contrast, secondary copper smelting accounts for more than 39% of the total dioxin emissions, and is higher than those from all waste incinerators combined (23.7%). Cement kilns and electric arc furnaces for steels also produced significant portion (both >10%) of dioxins into the environment, followed by secondary aluminum smelting (6.53%), industrial oil combustion (5.02%) and power plants fueled by coal (5.01%). Other known sources are either insignificant with respect to their dioxin emissions or not included in this inventory due to lack of information or uncertainty of the results. Data presented in this report provide a general picture of dioxin emissions in Taiwan, but were mostly based on less reliable or representative information, especially with respect to emission factors from different emission sources. It is necessary to establish background information relative to our own environment at present. Upon available, the inventory should be updated accordingly for proper environmental management on dioxins.
A highly persistent trace environmental contaminant and one of the most potent toxicants known is dioxin (2,3,7,8-tetrachlorodibenzo-para-dioxin or TCDD). TCDD induces a broad spectrum of biological responses, including induction of cytochrome P-450 1A1 (CYP1A1), disruption of normal hormone signaling pathways, reproductive and developmental defects, immunotoxicity, liver damage, wasting syndrome, and cancer. Its classification was upgraded from "possible human carcinogen" (group 2B) to "human carcinogen" (group 1) by the International Agency for Research on Cancer (IARC) in 1997. Exposure to TCDD may also cause changes in sex ratio, and tumor promotion in other animals. Because of the growing public and scientific concern, toxicological studies have been initiated to analyze the short- and long-term effects of dioxin. TCDD brings about a wide variety of toxic and biochemical effects via aryl hydrocarbon receptor (AhR)-mediated signaling pathways. Essential steps in this adaptive mechanism include AhR binding of ligand in the cytoplasm of cells associated with two molecules of chaperone heatshock protein (Hsp90) and AhR interactive protein, translocation of the receptor to the nucleus, dimerization with the Ah receptor nuclear translocator, and binding of this heterodimeric transcription factor (present in CYP1A) to dioxin-responsive elements upstream of promoters that regulate the expression of genes involved in xenobiotic metabolism.
The Angers municipal solid waste incineration plant, in operation since 1974, was upgraded in 2000 to comply with new European standards. This article discusses the risks associated with past and present emissions from the incinerator and its nearby furnace. Emissions of SO(2), HCl, particulate matter, lead, mercury, cadmium and dioxins were studied. We characterised the risks associated with exposure via inhalation and ingestion of locally grown products, before and after the upgrade. Emissions were estimated from regulatory measurements, and ambient air concentrations estimated with a Gaussian dispersion model. The CalTox multimedia model was used to calculate concentrations in the food chain. Food intake rates came from a nationwide survey. Inhalation exposure to respiratory irritants produced a hazard ratio less than 1 in all scenarios, except for SO(2) in the immediate neighbourhood of the incinerator, before the change in furnace fuel and in case of high-pressure weather conditions. The individual excess risk of cancer was less than 10(-6) and the hazard ratios for metals were less than 1. Before compliance, the average dioxin exposure attributable to the incinerator accounted for roughly one quarter of the average total exposure from traffic and other combustion activities. Although the corresponding hazard ratio was less than 1, the individual lifetime excess risk, assuming no change in emissions, was 2 x 10(-4). After compliance, all hazard ratios and future individual lifetime excess risks appear minimal. These results are consistent with environmental data and other studies, but many uncertainties remain, such as intermedia transfer coefficients for dioxins. Nevertheless compliance has vastly reduced the probability of health effects.
Polychlorinated dibenzo-para-dioxins (PCDD) and polychlorinated dibenzofurans (PCDF) are generated as unintentional by-products in a number of thermal and chemical-industrial processes. Biogenic formation through dimerization of chlorinated precursors, such as chlorophenols, is know but does not play a major role in national dioxin release inventories and in most cases is not quantified. PCDD/PCDF are semi-volatile substances and undergo long-range transport; they are persistent and accumulate in the environment and organismus; and they are toxic. They have become a global environmetnal problem. At the international level this issue is addressed by the Stockholm Convention on Persistent Organic Pollutants, a legally binding instrument to eliminate PCDD/PCDF through step-wise implementation of reduction measures. Within the Stockholm Convention, Parties have to develop national or regional dioxin inventories. First results show that in most industrialized countries, incineration of municipal solid waste does no longer represent the largest dioxin source; instead, certain processes in the metallurgical industry have become largest emitters. In developing countries, the situation is very different: open burning processes such as forest and grassland fires, burning of agricultural residues either before or after harvest as well as fires in waste dumps or the private fires to dispose of municipal waste represent the largest dioxin sources. First steps for a global environmental monitoring program under the Stockholm Convention have been initiated.
The purpose of this study, undertaken at a cremator representing an example of current equipment and cremation practices in use in Italy, is to assess the possible mercury emitted during cremation and substantiate the current data available. This paper reports some preliminary results concerning mercury and total particulate matter emissions during three cremation processes. The obtained results gave a mercury concentration ranging from 0.005 to 0.300 mg/m3 and a mercury emission factor ranging from 0.036 to 2.140 g/corpse cremated. The total particulate matter concentration range was 1.0 to 2.4 mg/m3.
While the sources of releasing dioxins have received much attention, the health risks of incinerators are studied considerably more than those of other sources, such as metallurgical industry. Furthermore, risk assessments focus primarily on the effects of single sources; few have addressed the aggregate risks from multiple sources in a region. When many sources of dioxins exist in an area, such as the Industrial Park located in the densely populated district-Siaogang District in southern Taiwan where 17 primary known PCDD/F stationary emission sources are clustered, is the aggregate exposure to these sources imposing high risks even though individual sources comply with emission standards? The study combined the multimedia and multiple pathway exposure modeling and site-specific exposure scenario to assess dioxin risks contributed by the 17 emission sources in the District, including municipal waste incinerators, medical waste incinerators, sinter plants, electric arc furnace, secondary aluminum smelters, cement kilns, etc. The average cancer risk of a resident living in the District was found to be 3.43E-04 under the site-specific exposure scenario. The top emission source is the sinter plant, followed by the electric arc furnace. The information has driven the local government to conduct more complete assessment and at the same time to consider enforcing a stricter local standard of dioxin emissions in the Siaogang District.
Incremental lifetime health risks due to polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/F) emitted from municipal waste incineration (MSWI) facilities were evaluated for resident population in the area of the plant. Risk assessment was performed through a multipathway combined probabilistic/deterministic approach for analyzing the effects of uncertainty and intrinsic variability of the main PCDD/F emission related parameters on final predicted values. Exposure through direct inhalation of contaminated air, soil ingestion, soil dermal contact and diet were considered, with the propagation of the variability of input parameters throughout the evaluation performed with Monte Carlo simulation techniques. The application to a case study representative of two different technological scenarios (modern facilities equipped with BAT - Best Available Technology - and older incinerators) in a location site typical of Northern Italy situation results in median values of the maximum individual excess risk on the order of 10(-9) and 10(-7) for most recent and older plant configurations, respectively. Corresponding ratios for the 90th and 10th percentile values are around 7 and 9. Individual risk estimates derived for the same scenarios from conventional deterministic approaches, where large conservative assumptions are normally adopted for compensating the lack of knowledge about uncertainty, are essentially comparable with maximum values resulting from the probabilistic approach, thus leading to situations with extreme and very low probabilities of occurrence. PCDD/F health risks from MSWI emissions might thus result largely overestimated if real emission characteristics are not properly considered in the assessment procedure. Sensitivity analysis for identifying the contribution of different input parameters on final predicted risk variance indicates, for the area considered in the simulation, a prevailing influence of PCDD/F stack concentration, with exposures arising from soil deposition phenomena substantially negligible: this latter result further points out the requirements for a very careful identification of base input data values for PCDD/F stack concentrations, at least for those situations where plants are located nearby urban areas.