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ChemInform Abstract: Palladium-Catalyzed Preparation of Silyl Enolates from α,β-Unsaturated Ketones or Cyclopropyl Ketones with Hydrosilanes

Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto-daigaku Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.
The Journal of Organic Chemistry (Impact Factor: 4.72). 09/2009; 74(20):7986-9. DOI: 10.1021/jo901513v
Source: PubMed

ABSTRACT

Alpha,beta-unsaturated ketones and cyclopropyl ketones undergo palladium-catalyzed hydrosilylation with hydrosilanes to yield (Z)-silyl enolates.

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