[Show abstract][Hide abstract] ABSTRACT: ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
[Show abstract][Hide abstract] ABSTRACT: A new catalytic method for the synthesis of silyl enol ethers has been developed from the coupling reaction of ketones with CH2═CHSiMe3 by using a ruthenium hydride catalyst (PCy3)2(CO)RuHCl. The synthetic utility of silyl enol ethers was demonstrated for both Mukaiyama aldol condensation and aminomethylation reactions in forming β-hydroxyketones and β-aminoketones, respectively.
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