Nowaday the natural ventilation rate decreases because the apartment housing is being air-tight. Therefore, Indoor Air Quality (IAQ) and indoor environment grow worse. Especially, Formaldehyde (HCHO), Volatile Organic Compounds (VOCs) which is emitted from the building materials and coating material etc. occur Sick House Syndrome that cause negative impact on resident's respiratory system and body. Therefore in construction field, it will be a important issues that development of a ventilation system with high effectiveness which can exhaust the contaminant out of the building quickly. In this research we evaluated 'wall attachable duct-less Heat Recovery Ventilation (HRV) system with air cleaning function'. We executed a synthetic evaluation about indoor air environment under various operating condition installing the system in real scale apartment house that is built in Anyang city. HRV system with air cleaning function showed good performance by removing HCHO, VOCs with less ventilation energy.