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THE EFFECT OF RRA ON THE MICROSTRUCTURE AND PROPERTIES OF A NOVEL Al-Zn-Mg-Cu-Zr ALLOY

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International Journal of Modern Physics B
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Abstract

A novel Al-7.5Zn-1.6Mg-1.4Cu-0.12Zr alloy was subjected to the retrogression and re-ageing (RRA) treatments at a lower range of retrogression temperatures from 170 to 200°C. The effect of RRA on the mechanical properties, electrical conductivity and the microstructure of the alloy has been investigated. The results indicate that an increase in the yield strength of the alloy can be achieved after RRA treatment. With increase of the retrogression temperature, the retrogression time for keeping the strength levels similar to T6 temper decreases rapidly. When submitted to RRA at 170°C for 90-120 min, the alloy can obtain a good performance on both SCC and mechanical strength; the electrical conductivity was above 40%IACS, reaching values typical for T76 condition and the tensile yield strength values were 552-570 MPa which is higher than that of the T6 temper. The microstructure is a very fine distribution of GP zones and η′ precipitates inside grains, similar to T6 condition and η precipitates on grain boundaries distributed similarly to T7 temper.
International Journal of Modern Physics B
Vol. 23, Nos. 6 & 7 (2009) 900–905
World Scientific Publishing Company
900
THE EFFECT OF RRA ON THE MICROSTRUCTURE AND PROPERTIES OF
A NOVEL Al-Zn-Mg-Cu-Zr ALLOY
XIWU LI
*
, BAIQING XIONG, YONGAN ZHANG, BAOHONG ZHU, HONGWEI LIU and ZHIHUI LI
State Key Laboratory for Fabrication and Processing of Non-ferrous Metals,
General Research Institute for Non-ferrous Metals,
Beijing, People’s Republic of China
*
xiwulee@yahoo.com.cn
A novel Al-7.5Zn-1.6Mg-1.4Cu-0.12Zr alloy was subjected to the retrogression and re-ageing
(RRA) treatments at a lower range of retrogression temperatures from 170 to 200°C. The effect of
RRA on the mechanical properties, electrical conductivity and the microstructure of the alloy has
been investigated. The results indicate that an increase in the yield strength of the alloy can be
achieved after RRA treatment. With increase of the retrogression temperature, the retrogression time
for keeping the strength levels similar to T6 temper decreases rapidly. When submitted to RRA at
170°C for 90-120 min, the alloy can obtain a good performance on both SCC and mechanical
strength; the electrical conductivity was above 40%IACS, reaching values typical for T76 condition
and the tensile yield strength values were 552-570 MPa which is higher than that of the T6 temper.
The microstructure is a very fine distribution of GP zones and η′ precipitates inside grains, similar to
T6 condition and η precipitates on grain boundaries distributed similarly to T7 temper.
Keywords: Al-Zn-Mg-Cu alloy; RRA; properties; microstructure.
1. Introduction
Al-Zn-Mg-(Cu) (7xxx series) alloys have been widely used as structural materials in the
aerospace industry, due to their desirable specific mechanical properties. The Cu-rich
7xxx series alloys include the highest strength conventional Al alloys currently in use on
commercial aircraft: AA7050, 7150, 7X49 and 7055, which are generally difficult to
satisfy the need for thicker components due to high quench sensitivity
[1]
. However, the
new generation aircraft uses thicker components than ever because of its large size and
today’s complex requirements. To meet these stringent requirements, some novel alloys –
such as AA7040, 7140 and 7085 have been recently developed for this application.
Particularly, AA7085 has even lower quench sensitivity and a much higher strength-
toughness combination
[1-3]
. To pursue the alloy development and achieve optimized
performance, a novel Al-7.5Zn-1.6Mg-1.4Cu-0.12Zr alloy has been investigated with
modifications in solute content and in particular in Zn/Mg/Cu ratios in the present work.
It is an increasingly important issues for applications that 7xxx Al alloys in T6
condition is very susceptibility to stress-corrosion cracking (SCC). Considerable research
indicated that susceptibility to SCC could be reduced by over-ageing the alloy. However,
this was achieved at the cost of a 10-15% reduction in strength compared to the T6
condition
[4-6]
. In the aerospace industry, such a loss represents a substantial decrease in
... Interestingly, the microstructure of RRA-treated alloy in grains interior and grain boundary regions are identical to that of T6treated and T7-treated counterparts, respectively, except that precipitates inside the grains are a bit coarser and less spaced. The precise phase analyses show that GP zones, h 0 and h phases are the main precipitates in RRA-treated alloys [129]. Similar observations have been reported for 7150 Al alloys. ...
... Depending on the RRA conditions, the electrical conductivity of RRA-treated Al-Zn-Mg-Cu alloys is higher than that of T6-and T76treated counterparts, but lower than that of T73-treated ones [128,129,132,133]. For instance, Su et al. [132] have measured the electrical conductivity values of T6-, T76-, T73-, and RRA-treated 7075 Al alloys as 31.6, ...
... The evaluation of electrical conductivity is an efficient way to monitor the performance of precipitation in high-strength Al alloys and their corrosion resistance, because it is directly associated with geometrical specifications and distribution of ageing precipitates [129]. [129,134]. ...
... For a precipitation-strengthened alloy, solution treatment, quenching, and aging treatment results in the precipitation of a second phase from α-Al matrix, which significantly enhances the overall performance of the alloy. Li et al. [13] investigated the impact of re-aging treatment (RRA) on the mechanical properties and microstructure of a novel Al-7.5Zn-1.6Mg-1.4Cu-0.12Zr alloy. ...
... As shown in Fig. 2(a), the microstructure of T6-treated alloy was characterized by fine η′ precipitates within the grain and continuous η precipitates at grain boundary. The semi-coherent η′ precipitates with the size of 3 nm to 8 nm are considered as the major precipitates of the T6-treated alloy 28 . As shown in Fig. 2(b), when the retrogression time was 30 min, the GBP was discontinuous with the size of 17 nm to 25 nm, whereas the η′ precipitates with the size of 4 nm to 12 nm homogeneously distributed in the matrix, similar to that of T6 condition. ...
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