The implementation of quantum communication protocols in long optical fibers is limited by several decoherence mechanisms. In this contribution we review this mechanisms and analysis their effect on the quantum states. Because of asymmetry in the real fibers, the two orthogonal polarization modes are propagated at different phase and group velocities. The difference in group velocities results in Polarization Mode Dispersion (PMD). It is created by random fluctuations of the residual birefringence in optical fibers, such that the State of Polarization (SOP) of an optical signal will turn randomly over time, in an unpredictable way. In optical quantum communication, quantum state measurement is necessary. The bottleneck for communication between far apart nodes is the increasing of the error probability with the length of the channel connecting the nodes. For an optical fiber, the value of absorption and depolarization of a photon (i.e., the qubit) increases exponentially with the length of the fiber.