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Light weight concrete of Yangshao Period of China: The earliest concrete in the world

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Abstract

During 1970s, the residential remains of the Yangshao Period were discovered at the Dadiwan site in Qin’an County, Gansu Province, China. With carbon-14 dating, scanning electron microscope (SEM), thermal expansion analyzer, polarizing microscope (PLM), and X ray diffraction (XRD), the microstructures and chemical compositions of the pottery shard, floor materials of the housing site, kunkur, calcined kunkur, ginger nut (calcium concretion) from the Dadiwan site were analyzed and researched. Analysis and simulation tests were also carried out to study the hydratability of calcined ginger nut and calcined kunkur, and the manufacturing process of the residential floors. The research shows that the floor was made of a light concrete formed by the mixture of aggregate of calcinated ginger nut (locally deposited), red clay and kunkur. The dicalcium silicate (C2S) from the floor material of the housing site is one of the main constituents of modern cement, and the floor is also similar to modern concrete in nature. Therefore, the floor material of the housing site at the Dadiwan site was the earliest man-made concrete in the world ever discovered.

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Monitoring experiments of soil air in column show that relative humidity (RH) of air in the soil of the Loess Plateau fluctuates with atmospheric pressure (AP), which is barometric pumping resulting in the vertical movement of soil air and the change of its RH. When AP increases, soil air is compressed and atmospheric air enters the soil, causing RH to decrease. When AP decreases, soil air expands and rises, causing the flow of moist air outwards from the soil and increasing RH. Therefore, RH fluctuates reversely with AP (the correlation coefficient between RH and AP can reach –0.74). This paper studies the effect of barometric pumping on RH in the loessal soil of the Loess Plateau, and reveals the mechanism responsible for the vertical movement of soil air. On a yearly timescale, the volume of soil air expands with a general decrease in AP from January to July, then compresses with an increase in AP from July to December. On a daily timescale, the air in soil shows bimodal fluctuations. Barometric pumping is the driving force underpinning the soil air movement, and therefore dominating its fundamental characteristics. From a preliminary establishment of model calculation, the volume of soil air movement occurring in the Loess Plateau is proportional to the amplitude of AP fluctuations, aerated porosity, and thickness of the local loess layer. The amplitude of air fluctuations in the soil is independent from the aerated porosity.
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... Similar to NHL, a kind of ancient lime-based binder named calcined ginger nut (CGN) was 53 first discovered at the Dadiwan site (3000 BC) in China. Studies have shown that CGN is formed 54 by ginger nut (GN) calcined at 1000 °C for 2 h, and it also has two hardening phases: a hydration 55 phase and a carbonation phase [24, 25]. As the raw material of CGN, GN is common in Northwest 56 ...
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... (II) Strong alkaline environment The ionization of calcium hydroxide (Ca(OH) 2 ) generates hydroxyl ions (OH  ) (eq. (2)) [16], which provide a strong alkaline environment with a typical pH value as high as 12.4 [17]. 2 2 Ca(OH) CO 2OH (pH=12.4) ...
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In this study, calcined ginger nuts (CGN) grouts admixed by fly ash (F) and quartz sand (S) was investigated on its suitability for anchoring use in earthen sites. According to requirement for the consistency of grout, the mix proportions were determined with 0.45 for CGN_F, 0.33 for CGN_S and 0.35 for CGN_F_S, by mass, to study their physical and mechanical property and durability. Test results indicated that use of fly ash can prolong the initial setting time of grout and admixture by fly ash and quartz sand leaded to lowest density and shrinkage, higher porosity, and highest strength. Accelerated aging tests indicated that admixture by fly ash led to a high resistance to fluctuation of temperature and humidity, sulfate attack and alkali environment; meanwhile, admixture by quartz sand resulted in high resistance to freeze-thaw action and water environment. As a compromise, CGN_F_S can get predominant durability. The paper shows that CGN_F_S grout is basically compatible to earthen sites and suitable for anchoring use in the conservation of earthen sites in terms of workability and durability.
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Concrete, the most widely used construction material, is evolving. Modern concrete is more than simply a mixture of cement, water, and aggregates; modern concrete contains more and more often mineral components, chemical admixtures, fibres, etc. Of course the utility market will stay the major market of concrete but niche markets implying the use of “à la carte” smart concretes will also develop. The development of these smart concretes results from the emergence of a new science of concrete, a new science of admixtures and the use of sophisticated scientific apparatus to observe concrete microstructure and even nanostructure.
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