Article

Kinetic Modeling of Quartz Cementation and Porosity Loss in Deeply Buried Sandstone Reservoirs

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Abstract

A mathematically simple kinetic model simulates quartz cementation and the resulting porosity loss in quartzose sandstones as a function of temperature history. Dissolved silica is considered to be sourced from quartz dissolution at stylotites or individual quartz grain contacts containing clay or mica, and diffuses short distances to sites of precipitation on clean quartz surfaces. The modeled sandstone volume is located between stylolites, and no quartz dissolution or grain interpenetration takes place within this volume. After quartz cementation starts, compactional porosity loss is typically minor, and porosity loss within the modeled sandstone volume is therefore considered to be equal to the volume of precipitated quartz cement. The quartz cementation process is modeled as a precipitation rate-controlled reaction where quartz precipitation rate per unit time and surface area can be expressed by an empirically determined logarithmic function of temperature. When the sandstone`s temperature history is known, precipitation rate per unit time and surface area can be expressed as a function of time, and the amount of quartz cement precipitated within a certain time interval can be calculated by multiplying the precipitation rate function with the surface area available for quartz precipitation and integrating with respect to time. Because quartz surface area will change as quartz cement precipitation proceeds, the calculations are performed for short time steps, and quartz surface area is adjusted after each time step. The total amount of quartz cement precipitated during a sandstone`s burial history and the corresponding porosity loss are found by taking the sum of the increments of quartz cement precipitated during each time step.

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... Furthermore, chlorite itself is a highly chemically-reactive mineral, while the dissolution of chlorite coat is rarely mentioned in past studies (Waldmann and Gaupp, 2016;Higgs et al., 2015). Fourthly, in addition to chlorite coat, the precipitation of secondary quartz is controlled by multiple factors, such as temperature (Ganor et al., 2005;Oelkers et al., 2000;Walderhaug, 1996); sandstone porosity is also a result from multiple factors such as compaction (Paxton et al., 2002;Pittman and Larese, 1991;Ehrenberg, 1989). Therefore, the relative importance of chlorite coat may be minor in certain conditions. ...
... Subsequently, it has been suggested and widely accepted that chlorite coat inhibits quartz cements mainly through reducing the surface area of detrital quartz (Worden et al., 2020;Ajdukiewicz and Larese, 2012;Billault et al., 2003;Walderhaug et al., 2000). The following equation has been employed to account for the surface area reduction of quartz by chlorite coats (Li et al., 2024a;Lander et al., 2022;Taylor et al., 2015;Lander and Walderhaug, 1999;Walderhaug, 1996): ...
... Analogously, Bello et al. (2022) However, a precise estimation of the coat coverage threshold using petrography remains challenging. This may be mainly due to the fact that the precipitation of quartz cements is simultaneously controlled by multiple other factors, such as temperature (Du et al., 2024;Dong et al., 2024;Gluyas et al., 2000;Lander and Walderhaug, 1999;Walderhaug, 1996), effective stress (Renard et al., 1997;Elias and Hajash, 1992), grain size (Makowitz and Sibley, 2001;Houseknecht, 1984), differentiated silica supply capabilities Feng et al., 2023;Li et al., 2023c;Eichhubl et al., 2009), and early hydrocarbon emplacement . In this way, since the estimations of coat coverage thresholds in the studies of Busch et al. (2020) and Bello et al. (2022) did not consider and exclude the influence of above factors, the conclusions may not be universally applicable. ...
Article
Chlorite coats are believed to inhibit quartz cementation and preserve deeply-buried sandstone porosity. However, geologists face numerous challenges in evaluating the influences of chlorite coats in real cases. To tackle these challenges, this work reviewed a large number of case studies to discuss the proper way to evaluate their role using petrography. The following five main conclusions were drawn: (1) Compared to other coat parameters, coat coverage is more reliable in evaluating the influence of chlorite coats on quartz cements; (2) In addition to chlorite coats, quartz growth is influenced by multiple factors such as temperature, while sandstone porosity is affected by various factors including mechanical compaction; therefore, when evaluating the influence of chlorite coats, geologists should take these factors into account; (3) Even if no negative correlation exists between chlorite coats and quartz cements, and no positive correlation is observed between chlorite coats and sandstone porosity, one cannot simply conclude that chlorite coats do not inhibit quartz cements and protect sandstone porosity; (4) Chlorite coats can significantly occupy pore space, leading to a net porosity decrease; (5) Chlorite coats can undergo significantly dissolution, while whether this phenomenon is ubiquitous remains underexplored.
... The compaction simulations, within these coupled-effect models, can consider mean particle size and sorting, the mechanical properties of the framework grains and matrix, and effective stress [2]. The cementation simulations within these coupled-effect models are typically based on kinetic models for quar cementation [29,62], with reports of the inclusion of rates of plagioclase albitisation [63], transformation of kaolinite to fibrous illite [64,65], and the reaction of volcanic rock fragments to form grain-coating chlorite [66]. To achieve a meaningful result, a coupled-effect model should be calibrated or optimised so that the model data matches samples with petrographic and core analysis data [2]. ...
... First, the surface area of quar was defined using an equation from Walderhaug [62]: ...
... In this approach, we have followed consensus and assumed that quar cementation is controlled by quar precipitation rate [28,29,61,62]. The volume of quar cement precipitated in a 1 cm 3 volume of sandstone can be defined using an equation from Walderhaug [62]: ...
Article
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Reservoir quality prediction in deeply buried reservoirs represents a complex challenge to geoscientists. In sandstones, reservoir quality is determined by the extent of compaction and cementation during burial. During compaction, porosity is lost through the rearrangement and fracture of rigid grains and the deformation of ductile grains. During cementation, porosity is predominantly lost through the growth of quartz cement, although carbonate and clay mineral growth can be locally important. The degree of quartz cementation is influenced by the surface area of quartz available for overgrowth nucleation and thermal history. Clay grain coats can significantly reduce the surface area of quartz available for overgrowth nucleation, preventing extensive cementation. Using a coupled-effect compaction and cementation model, we have forward-modelled porosity evolution of surface sediments from the modern Ravenglass Estuary under different maximum burial conditions, between 2000 and 5000 m depth, to aid the understanding of reservoir quality distribution in a marginal marine setting. Seven sand-dominated sub-depositional environments were subject to five burial models to assess porosity-preservation in sedimentary facies. Under relatively shallow burial conditions (<3000 m), modelled porosity is highest (34 to 36%) in medium to coarse-grained outer-estuary sediments due to moderate sorting and minimal fine-grained matrix material. Fine-grained tidal flat sediments (mixed flats) experience a higher degree of porosity loss due to elevated matrix volumes (20 to 31%). Sediments subjected to deep burial (>4000 m) experience a significant reduction in porosity due to extensive quartz cementation. Porosity is reduced to 1% in outer estuary sediments that lack grain-coating clays. However, in tidal flat sediments with continuous clay grain coats, porosity values of up to 30% are maintained due to quartz cement inhibition. The modelling approach powerfully emphasises the value of collecting quantitative data from modern analogue sedimentary environments to reveal how optimum reservoir quality is not always in the coarsest or cleanest clastic sediments.
... Since cementation is temperature-dependent (Huang et al., 1993;Walderhaug, 1996), it will not cease unless the temperature drops below the threshold required for cementation to occur. ...
... The effect of quartz cementation on porosity is calculated using the kinematic model proposed by Walderhaug (1996). The model assumes that mechanical compaction ceases upon the onset of cementation, and pore space is reduced solely due to a continuous quartz precipitation within a time period: ...
... where is the porosity resulting from phase 1 mechanical compaction, which can be Walderhaug (1996), where a = 1.98 × 10 −22 mol/cm 2 and b = 0.022 1/°C are used. 0 A is the initial surface area available for quartz cementation assuming spherical grains with diameter D for one unit volume, which equals to: ...
Article
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Exhumation is the process that encompasses both uplift and erosion, leading to the removal of overburden and the release of effective stress exerted on rocks. When estimating exhumation magnitude using the compaction trend method, it is commonly assumed that the physical properties of rocks are insensitive to stress reduction. However, recent laboratory evidence has shown that porosity exhibits weaker sensitivity to stress release compared to velocity that can be significantly affected by stress release. This raises uncertainties regarding the assumption of irreversible compaction. It remains unclear whether the impact of stress release can be observed in real rocks in exhumed areas, as there is a lack of methods to directly measure the impact of stress release on field data. Additionally, studying real rocks is further complicated by the presence of rock diagenesis and its interaction with stress release. To address these knowledge gaps, this study employs stress-dependent burial and uplift modeling and interprets an extensive well log dataset using the modeling-derived evaluation metrics. We discover that the disparity between porosity sensitivity and velocity sensitivity to stress release can be leveraged to derive a metric “porosity inconsistency” which can serve as both a qualitative and quantitative measure for identifying and evaluating stress release in sandstone using geophysical field measurements. We have gathered a significant amount of sonic velocity and porosity data from normally compacted and uplifted clean sandstones in the Norwegian Sea and the Barents Sea. Notably, we observe significant porosity inconsistency in the exhumed well 6510/2-1 in the Norwegian Sea. In the Barents Sea, well data reveals a varying pattern of porosity inconsistency that not only aligns with the spatial variation of exhumation reported in various studies but also exhibits a positive correlation with the magnitude of exhumation. These observations provide support for the predictions made by the conceptual modeling.
... At greater depth, chemical compaction (pressure dissolution) becomes active, resulting in further porosity reduction (Bjørlykke 2014). Quartz is volumetrically the most important pore-occluding diagenetic cement in deeply buried clean sandstone reservoirs (McBride 1989;Ehrenberg 1990;Walderhaug 1996;Worden and Morad 2000;Molenaar et al. 2007;Gier et al. 2008;Worden et al. 2018a, b). Quartz cementation starts at around 70-80°C (McBride 1989;Bjørlykke and Egeberg 1993;Walderhaug 1994a;Storvoll et al. 2002;Lander et al. 2008;Ajdukiewicz and Lander 2010;Taylor et al. 2010;Oye et al. 2018). ...
... The ability of clay coats to effectively inhibit quartz cementation is primarily a function of its completeness or coverage (i.e. fraction of surface area of grains covered by clay minerals) and not just its presence (Ehrenberg 1993;Walderhaug 1996;Bloch et al. 2002;Billault et al. 2003;Lander et al. 2008;Ajdukiewicz and Larese 2012;Stricker and Jones 2016;Charlaftis et al. 2021). Detrital clay coats are often interpreted as precursors for authigenic clay coats in deeply buried sandstone reservoirs (Bahlis and De Ros 2013;Verhagen et al. 2020). ...
... Quartz cementation models for the Judy and Jade field sandstones (Judy and Joanne) were built using the approach of Walderhaug (1996). This mathematical kinetic model calculates the rate of quartz cementation using a logarithmic function, and assumes that compaction terminates at the onset of quartz cementation and the stabilization of framework grains (Walderhaug 1996(Walderhaug , 2000. ...
Article
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Clay-coated grains play an important role in preserving reservoir quality in high-pressure high-temperature (HPHT) sandstone reservoirs. Previous studies have shown that the completeness of coverage of clay coats effectively inhibits quartz cementation. However, the main factors controlling the extent of coverage remain controversial. This research sheds light on the influence of different depositional processes and hydrodynamics on clay coat coverage and reservoir quality evolution. Detailed petrographic analysis of core samples from the Triassic fluvial Skagerrak Formation, Central North Sea, identified that channel facies offer the best reservoir quality; however, this varies as a function of depositional energy, grain size and clay content. Due to their coarser grain size and lower clay content, high energy channel sandstones have higher permeabilities (100-1150 mD) than low energy channel sandstones (<100 mD). Porosity is preserved due to grain-coating clays, with clay coat coverage correlating with grain size, clay coat volume and quartz cement. Higher coverage (70-98%) occurs in finer-grained, low energy channel sandstones. In contrast, lower coverage (<50%) occurs in coarser-grained, high energy channel sandstones. Quartz cement modelling showed a clear correlation between available quartz surface area and quartz cement volume. Although high energy channel sandstones have better reservoir quality, they present moderate quartz overgrowths due to lesser coat coverage, thus prone to allowing further quartz cementation and porosity loss in ultra-deep HPHT settings. Conversely, low energy channel sandstones containing moderate amounts of clay occurring as clay coats are more likely to preserve porosity in ultra-deep HPHT settings and form viable reservoirs for exploration. Supplementary material: of data and technique used in this study are available at https://doi.org/10.6084/m9.figshare.c.6438450.v1
... Here, we report a detailed study of the Fulmar Formation in the Fulmar Field, UK Central North Sea. Buried to 130 • C and with a presentday pore pressure that is only 7 MPa above hydrostatic, these sandstones have low volumes of quartz cement that, at first sight, cannot be readily explained either by stress-related IPD or by temperature-driven cementation models (Lander and Walderhaug, 1999;Walderhaug, 1994aWalderhaug, , 1996. However, modelling of regional pore pressure data from the Fulmar, and proximal Clyde and Halley fields (Swarbrick et al., 2005), suggests a rapid deflation of pore pressure in the Fulmar Formation sands in this area, over the last ca. ...
... A quartz precipitation model was constructed for the Fulmar Field sandstones using the Walderhaug (1996) approach. Model inputs include grain size, mineralogy, and available quartz surface area which was determined using the mineralogical fraction of detrital quartz and grain coat (clay and microquartz) coverage area estimated from petrographic analysis (Oye et al., 2018;Oye, 2019;Oye et al., 2020). ...
... The δ 18 O value of the earliest-formed quartz cement is +27.9‰. If precipitation started in water with δ 18 O (water) of − 1‰, similar to the Jurassic seawater in which the Fulmar Formation was deposited, this corresponds to a temperature of 50 • C, which is below the commonly recognised 70-80 • C threshold for quartz cement (Walderhaug, 1994a(Walderhaug, , 1996. If cementation started at 80 • C, the water would have an isotopic composition of around 4‰, which is the same as the current water in the Fulmar Formation (+4.2‰; ...
Article
Upper Jurassic Fulmar Formation sandstones from the Fulmar Field in the Central North Sea are buried to 3.2 km and 128 °C but contain only 3.7 ± 1.7% (1σ) quartz cement, substantially less than volumes predicted by models based on temperature-related quartz precipitation kinetics. Oxygen isotope microanalysis of quartz overgrowths suggests that only limited cementation occurred at temperatures above 110 °C. We suggest that the anomalously low volumes of quartz cement are most readily explained by the effective stress history of the Fulmar Formation. Regional pore pressure analysis strongly suggests that pore fluid pressures in the Fulmar Formation decreased substantially in the last <0.5 Ma as a result of lateral seal failure, increasing effective stress from ca. 10 MPa to the current 31 MPa. A recent increase in effective stress is supported by the common occurrence of grains that are both fractured and unhealed by quartz cement. Intergranular pressure dissolution can account for around one third of the observed quartz cement, with the remainder from deep burial feldspar dissolution. We argue that the continuous history of low effective stress, until the very recent geological past, limited the rate of silica supply by intergranular pressure dissolution, and thus the rate of quartz cementation. Effective stress histories should be incorporated into predictive models of quartz cementation of sandstones.
... Despite of the favorable depositional character, diagenetic processes, especially quartz cementation, can significantly reduce porosity and permeability of aeolian sandstones (Bjørlykke et al., 1989). Understanding controls on diagenetic processes is thus crucial for predicting reservoir quality (e.g., Bjørlykke and Egeberg, 1993;Walderhaug, 1996;Lander and Walderhaug, 1999;Walderhaug, 2000;Taylor et al., 2022). ...
... Etjo sandstones averages 15.4 vol% (n = 5) and is significantly greater than at Waterberg where the average abundance (n = 7) is only 6.5 vol%. The rate of quartz cementation in a sandstone is controlled by the surface area that is available for quartz overgrowth development, quartz growth kinetics, and the thermal exposure (Walderhaug, 1996(Walderhaug, , 2000Lander & Walderhaug, 1999;Lander et al., 2008). Following Lander et al. (2008), the available nucleation surface area (S q ) for quartz overgrowth in a sample can be calculated as ...
... Therefore, previous studies mainly modelled the influence of chlorite coats on the precipitation of quartz cements by introducing a 'coating factor' (Eq. (18); Walderhaug, 1996;Lander and Walderhaug, 1999;Walderhaug et al., 2000;Lander et al., 2008). The 'coating factor' is equivalent to the coat coverage (C). ...
... Therefore, the accessible surface area of detrital quartz coated with chlorite can be represented by the following Eq. (18) (Walderhaug, 1996;Lander and Walderhaug, 1999;Walderhaug et al., 2000;Lander et al., 2008). This approach has been incorporated into the reservoir quality simulator, Touchstone™, and has been successfully validated by multiple case studies (e.g., Lander et al., 2008;Taylor et al., 2015;Busch et al., 2018). ...
Article
Chlorite coats are widely recognized as a key element in preserving sandstone porosity because it can inhibit the growth of quartz cements. However, the alteration of chlorite coats and its potential influences on sandstone porosity are rarely discussed. Therefore, this work used reactive transport models under different petrographic and geochemical conditions to investigate the influence of chlorite coats on sandstone porosity in a major dissolution window (100 °C). The HCO3-rich (CO2-charged) and HCO3-depleted (organic acids-charged) waters were injected to induce mineral dissolution and precipitation. The results indicate that the alteration of chlorite coats may result in sandstone porosity reduction. The HCO3-rich water leads to a porosity decrease mainly through the precipitation of magnesite and siderite resulting from chlorite dissolution. In contrast, the HCO3-depleted water causes a porosity decrease mainly through the redistribution of kaolinite and quartz cements. Factors, including pCO2, organic acid concentration, coat coverage, coat thickness, and grain size, have secondary influences on net porosity change. In comparison, factors, including chlorite mineralogy, detrital lithology, and the reduction of K-feldspar dissolution rate caused by chlorite coat, have negligible influences. The alteration of chlorite coats may introduce significant mis-interpretation to the analysis of the relationship between chlorite coats and sedimentary facies. Moreover, the actual impact of pore-filling chlorite on porosity reduction may be either underestimated or overestimated. Therefore, the alteration of chlorite coats should be taken into consideration in future studies.
... The mechanism behind illite-mica-induced dissolution (I-MID) is still not completely understood and is subject of much debate (Walderhaug et al., 2004;Sheldon et al., 2004;Bjørlykke et al., 2017). The I-MID mechanism was inferred from petrographic observations of dissolution textures at illite/mica-quartz interfaces and of the predominance of quartz dissolution at such interfaces over dissolution at quartzquartz contacts in quartzose sandstones (Heald, 1955(Heald, , 1959Dewers & Ortoleva, 1991;Walderhaug, 1994Walderhaug, , 1996Oelkers et al., 1996Renard et al., 1997Renard et al., , 2000Fisher et al., 2000;Walderhaug et al., 2000;Walderhaug & Bjørkum, 2003;Weber & Ricken, 2005;Cyziene et al., 2006;Baron & Parnell, 2007; and many others). Bjørkum (1996) determined that I-MID requires negligible stress, by means of theoretical calculations of the mechanical properties of observed micas at surfaces of which 'pressure dissolution' of quartz grains irrefutably had taken place but where they were not deformed, though not supported by adjacent grains. ...
... A more classic view of pressure dissolution calls upon the inhomogeneous distribution of normal stress over grain surfaces to provide a persistent gradient in chemical potential, and hence a persistent driving force for chemical compaction (Tada & Siever, 1989;Renard et al., 1999Renard et al., , 2000Sheldon et al., 2003). The supporters of the I-MID mechanism succeeded in constructing predictive quantitative models explaining the distribution of quartz cement in sandstones, based on the assumption that the silica source of cement is quartz surfaces adjoining mica and/or clay grains (Oelkers et al., 1996Walderhaug, 1996;Walderhaug et al., 2000). These models are in close agreement with field observations, and experimental studies (Bjørlykke et al., 2017) which evidently strengthens the idea that chemical compaction is controlled by I-MID. ...
Article
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The red beds of the Buntsandstein (Early Triassic) in the Campine Basin (NE Belgium) display porosities between 5.3–20.2% (average 13.7%) and permeabilities varying between 0.02–296.4 mD (average 38.7 mD). Knowledge of their reservoir controlling properties, which today are missing, is important in view of potential geological storage of CO2 or natural gas and geothermal reservoir potential within these sandstones. Therefore the effects of diagenesis were assessed based on petrography, stable isotope analyses, fluid inclusion microthermometry, X-ray diffraction, electron microprobe and porosity-permeability core analyses. These sandstones were deposited by a dryland river system, in a warm, mostly arid climate with episodic rainfall and high evaporation rates. During wetter periods especially feldspars were dissolved. Strong evaporation during dry periods led to reprecipitation of the dissolved species as K-feldspar and quartz overgrowths, smectite and calcite/dolomite. Sediment reworking resulted in framework grains becoming clay coated. The clay coats are better developed in finer than in coarser grained sediments. The original smectite composing the rims converted to illite during burial. The tangential orientation of the clay platelets in the rims led to illite-mica-induced dissolution of quartz during burial/compaction, which is manifested as bedding parallel dissolution seams that are filled with clays and micas, especially in the fine-grained sandstone/siltstone/claystone. These constitute important barriers to the vertical flow within the reservoir. The released silica did not really affect the red sandstones but was exported (often on mm to cm scale) to nearby bleached horizons, where nucleation inhibiting clay rims are less well developed. The red colour of the sandstones arises from the presence of small amounts of Fe-oxides in the inherited clay rims. Migration of fluids enriched in organic acids, expelled from underlying Carboniferous coal-bearing strata, resulted in local bleaching of coarser grained horizons. In the finer grained sediments, the red colour was mostly preserved, which suggests that the reductive capacity of the fluid was limited.
... The constant cement model is a combination of the friable sand model and the contact cement model. It is a useful model for a cemented sandstone reservoir at a given burial depth, assuming that the burial history is the same for the whole reservoir (cf., Walderhaug, 1996). In contrast, porosity will vary as a function of depositional porosity. ...
... However, the increasing cement volume from unit 1 to unit 2 could also be related to increasing depth (i.e., temperature) as the reservoirs have been exposed to continuous subsidence. The current reservoir temperature is around 75°C, slightly above the critical temperature for the onset of quartz cement (Walderhaug, 1996). ...
Chapter
Seismic and well log imaging are among the most important tools for subsurface characterization and reservoir delineation. The significance of these two tools has further increased as we have started exploring unexplored deepwater reservoirs. Seismic attributes help identify different geological features by revealing geomorphology, whereas the amplitude vs offset (AVO) can differentiate between the lithology and fluid effects. Different seismic attributes can highlight different characteristics of the seismic data, which can relate to different geological features. The case study of the Cretaceous Nanushuk-Torok sequence on the North Slope, Alaska, utilizes multiple seismic attributes as inputs to unsupervised machine learning (ML) for seismic facies classification. Two ML algorithms, such as self-organizing map (SOM) and generative topographic map (GTM) are used for seismic facies classification. GTM provides more details in different geomorphological features compared to SOM. However, reservoir identification and mapping solely based on seismic amplitude and other attributes, such as bright or dim spots, as direct hydrocarbon indicators can often be misleading. Rock physics and AVO feasibility modeling can provide a better understanding of the reservoir. In the case study from the Glitne Field, North Sea, Norway, we study seismic amplitude and AVO to characterize the Glitne submarine fan system. AVO feasibility modeling should be utilized in improved reservoir mapping and prospect derisking. Borehole images provide higher resolution than seismic and conventional wireline logs and can be correlated to core and outcrops. Borehole images can be used to identify lithologies, thin beds and fractures. An integrated analysis of all seismic attributes, rock physics and borehole imaging analysis results can provide a detailed subsurface characterization for deepwater reservoirs.
... . In this thermal window quartz and silicate diagenesis prevail with the twofold effect of, 1) expulsion of pore-fluid caused by quartz cement occluding pores and clay dehydration (Walderhaug, 1994(Walderhaug, , 1996, and 2) decrease of permeability because of changes in the pore-size distribution and the overall lowering of porosity by mineralogical reactions such as illite crystallization (Oelkers and others, 2000;Walderhaug and others, 2001;Nadeau, 2011). Via illitization, mudstone permeability is reduced by three orders of magnitude, from lD to nD, and seal capacity is significantly enhanced (Nadeau and others, 2002a and b;Schneider and others, 2003). ...
... Comparison with independent experimental data (Mondol and others, 2008) the smectitic mineralogy of mudstone in the Uhalde indicates that M3 was probably a high quality seal when buried to 1000-1500 m, and an even better seal deeper in the basin where illite prevails (Mertz, 1988; see section: MINERALOGY AND PETROGRAPHY). The kinetics of temperature-driven reactions mean that they proceed at higher rates at higher temperatures, for example quartz cement precipitation is five times faster at 120°C than at 80°C (Walderhaug, 1994(Walderhaug, , 1996Walderhaug and others, 2001). Consequently, the rate of expulsion of formation fluids caused by chemical diagenesis reached its peak at the end of deposition of the Moreno Formation, when in a large area of the basin T max .100°C. ...
Article
Giant sand injection complexes form, intricate, basin-scale fluid plumbing systems and document the remobilisation and intrusion of several tens of cubic kilometres of sand within the shallow crust in stratigraphic units 100's metres thick. This is the first detailed and extensive account of the Panoche Giant Injection Complex (PGIG), a regionally significant outcrop (>300 km2) and part of a larger subsurface development (>4000 km2) identified in boreholes and on seismic reflection data. Magnificent exposure of the PGIC occurs along the north western margin of the San Joaquin Valley and presents the opportunity to examine the regional geological significance of a giant sand injection complex and its origin in the context of a late Cretaceous – early Paleocene forearc basin. Between 25 and 49 km3 of sand were remobilised and injected, at least 0.35 km3 of which extruded onto the paleo-seafloor. Large sandstone intrusions often >10 m thick and laterally extensive on a kilometer scale formed saucer-shaped intrusions, wing-like intrusions and a variety of sill geometries along with volumetrically smaller randomly oriented dikes in a 200–300 m thick interval. Dikes prevail below and above this interval, some reaching the paleo seafloor and extruding sand. Networks of propagating hydrofractures form intensely brecciated host strata, some of which were intruded by sand. All intrusions formed in a single pulsed event in which the most intense hydrofracturing caused by supra-lithostatic fluid pressure occurred approximately 600 to 800 m below the paleo seafloor. A crudely orthogonal arrangement of dikes is preserved with most oriented normal, and less commonly oriented parallel to the oceanic trench associated with the late Mesozoic to early Tertiary North Pacific subduction. Dikes orthogonal to the trench opened against the minimum horizontal stress, which was parallel to the trench. Dikes parallel to the trench opened against the regional maximum horizontal stress along minor faults formed in extension caused by shallow crustal deformation. There is no evidence that compressional tectonics influenced the onset of elevated pore fluid pressure necessary to promote sand injection. However, tectonic compression was responsible for creating the basin physiography that locally increased subsidence and accelerated chemical diagenesis in the basin centre. PGIC outcrop, located along the basin margins, was unlikely to have experienced heating above 70 °C, equivalent about 2 km burial, so the effects of chemical diagenesis in the host strata of the injection complex had negligible potential to evolve significant pore water volume. In a deeper part of the basin approximately 150 km to the south, lateral equivalents of the host strata were subjected to heating >100 °C and would expel significant volumes of water displaced by quartz cementation and clay dehydration that caused lateral pressure transfer to the north and western margin of the basin where the PGIC formed. Estimates of the total volume of water expelled from the deep basin suggest that a fluid volume equivalent to a gross rock volume reduction <1% would have provided a fluid budget sufficient to fluidise and inject the sand that forms the PGIC. In terms of areal and vertical extent, volume and architecture the PGIC shares strong similarity with the regionally developed giant injectite systems of Tertiary age in the North Sea basin. In both cases regional sand injection is genetically linked to pressure transfer toward the basin margin from more rapidly subsiding basin centres. Aqueous fluid is derived from thermally driven chemical diagenesis of thick deep water clastic sandstone and smectitic mudstone or from deeper, stratigraphically older, aquifers.
... Quartz precipitation is considered modeled following [43] As a consequence of equations (5)-(6), the porosity variation is then described by dφ = dφ M − dφ Q , where dφ M and dφ Q denote the porosity variation due to mechanical compaction and quartz precipitation, respectively. ...
Preprint
In this work we propose an Uncertainty Quantification methodology for sedimentary basins evolution under mechanical and geochemical compaction processes, which we model as a coupled, time-dependent, non-linear, monodimensional (depth-only) system of PDEs with uncertain parameters. While in previous works (Formaggia et al. 2013, Porta et al., 2014) we assumed a simplified depositional history with only one material, in this work we consider multi-layered basins, in which each layer is characterized by a different material, and hence by different properties. This setting requires several improvements with respect to our earlier works, both concerning the deterministic solver and the stochastic discretization. On the deterministic side, we replace the previous fixed-point iterative solver with a more efficient Newton solver at each step of the time-discretization. On the stochastic side, the multi-layered structure gives rise to discontinuities in the dependence of the state variables on the uncertain parameters, that need an appropriate treatment for surrogate modeling techniques, such as sparse grids, to be effective. We propose an innovative methodology to this end which relies on a change of coordinate system to align the discontinuities of the target function within the random parameter space. The reference coordinate system is built upon exploiting physical features of the problem at hand. We employ the locations of material interfaces, which display a smooth dependence on the random parameters and are therefore amenable to sparse grid polynomial approximations. We showcase the capabilities of our numerical methodologies through two synthetic test cases. In particular, we show that our methodology reproduces with high accuracy multi-modal probability density functions displayed by target state variables (e.g., porosity).
... Clay mineral dehydration during smectite to illite reactions, which proceeds by dissolution and precipitation rather than by a smectite interlayer- collapse mechanism (Nadeau et al. 1985), has been shown to play only a minor role in overpressure development (Colten-Bradley 1987). A second important process is porosity loss resulting from quartz cementation (Bjørkum and Nadeau 1998), the rate of which increases exponentially with temperature (Walderhaug 1996), and at c. 120°C becomes so rapid that the resulting porosity loss may contribute to the development of overpressure (Buller et al. 2005). Bolås et al. (2008) further suggested that chemical compaction and resulting calcite cementation, rather than disequilibrium compaction (Vejbaek 2008), may be the main process driving up fluid pressure in North Sea chalks. ...
Article
Our previous publication examined the estimated ultimate recovery (EUR) of conventionally recoverable oil, gas and condensate in 1175 of the Earth's largest reservoirs in relation to reservoir temperature and showed that 74% occurs within the "Golden Zone" (GZ) temperature range of 60 to 120 ± 2°C, with only 6% at higher temperatures. The present article examines the temperature distribution of EUR in 18 geographic regions not covered earlier, including six with EUR distributions skewed toward low temperature and three with distributions skewed toward high temperature. A fuller explanation is provided here as to why diagenetic processes are thought to be the main causes of overpressure in deeply buried reservoirs, and a new model is proposed for how opening of the Arctic and North Atlantic oceans led to uplift of Arctic continental margins, with possible negative consequences for Arctic exploration potential. Particular attention is given to examples of large reservoirs at temperatures outside the GZ in order to examine the possible factors favoring these occurrences. Most low-temperature cases can be ascribed to tectonic uplift and cooling subsequent to petroleum accumulation, whereas most of the high-temperature reservoirs have low to moderate fluid pressure consistent with preservation of hydrocarbon columns due to open lateral drainage. It is clear that reservoir temperature is a useful parameter for exploration risk analysis, but one that should be calibrated using available analogs relevant for each area of interest.
... Strongly cataclastic deformation bands, which only form in highly porous rocks, are characteristic of deformation at roughly 1-4 km depth (Fossen et al., 2007), although shallower depths (300-700 m) have been reported (Ballas et al., 2012). The amounts of quartz cement occur locally, indicating that the maximum burial temperature likely exceeded 80°C (i.e., 2.5-3.0 km) (Walderhaug, 1996;Worden & Morad, 2000). Burial of the Ilhas Formation occurred during rifting and again during postrift subsidence. ...
Article
Deformation bands are common constituents of porous clastic fluid reservoirs. Various techniques have been used to study deformation band structure and the associated changes in porosity and permeability. However, the use of electron backscatter diffraction technique is limited. Thus, more information is needed regarding the crystallographic relationships between detrital crystals, which can significantly impact reservoir rock quality. We employ microscopic and microstructural investigation techniques to analyze the influence of cataclastic deformation bands on pore space. Porosity measurements of the Cretaceous Ilhas Group sandstone in NE Brazil, obtained through computerized microtomography, indicate that the undeformed domains exhibit a total porosity of up to 13%. In contrast, this porosity is slightly over 1% in the deformation bands. Scanning electron microscopy analyses revealed the presence of grain fragmentation and dissolution microstructures, along with cement-filling pre-existing pores. The electron backscatter diffraction analyses indicated extensive grain fragmentation and minimal contribution from intracrystalline plasticity as a deformation mechanism. However, the c axes of quartz crystals roughly align parallel to the orientation of the deformation band. In summary, we have confirmed and quantified the internal changes in a deformation band cluster, with grain size reduction and associated compaction as the main mechanism supported by quartz cementation.
... Understanding and correctly assessing these processes can enable the prediction of reservoir properties. The effect of GTI coating coverage on syntaxial quartz precipitation are already well understood and included in simulation tools such as Touchstone™ (Makowitz et al., 2006;Lander et al., 2008;Tamburelli et al., 2022) or Exemplar™ (Walderhaug, 1996;Lander et al., 1997;Lander and Walderhaug, 1999;Walderhaug et al., 2000). These simulation approaches also include the assessment of mechanical compaction based on grain rigidities and the effect of compaction on reservoir properties (Lander and Walderhaug, 1999). ...
... Important sources of variability between the numerical modelling and the analytical calculation in Fig. 16 are: changes in the velocity gradient with depth, 3-D wave propagation and CO 2 layer geometry, and time-shift picking challenges. In general, lithological variations, depth-varying compaction regimes (Walderhaug 1996 ;Lander & Walderhaug 1999 ), and overpressure (Marcussen et al. 2009 ), lead to a large velocity heterogeneity that can be hard to simplify with a constant gradient trend. The linear trend parameters v o and g, control the penetration depth of the diving waves, and the offsets at which the various interaction patterns occur. ...
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We have derived an analytical approximate expression to estimate the delay in diving seismic waves due to thin layers of CO2. The expression is valid for high frequencies and can be used to estimate the delay in diving waves at seismic frequencies for large separations between the source and receiver (offset). The approximation may be used to assess CO2 detection limits using diving waves and to support survey planning for CO2 monitoring and full-waveform inversion (FWI) cycle skipping analysis. In this study, we analyze the diving-wave response to a thin layer of CO2 for band-limited data using acoustic finite-difference modeling, and compare the results against the analytical calculations. We find that the responses are offset-dependent and related to double- and single-leg interactions between the diving waves and the CO2. To test the methods, we created a synthetic representation of the 2010 subsurface conditions for the top CO2 layer at the Sleipner storage complex in the North Sea, by combining base and monitor post-stack seismic data with field velocity trends. Using the acoustic finite-difference method, we model pre-stack data that captures the complexity of field data and demonstrate the use of the diving-wave delay for CO2 migration monitoring and CO2 thin layer detection.
... Dissolution of framework grains that results in intragranular porosity in feldspars or plutonic rock fragments must predate quartz precipitation since quartz overgrowths form in those dissolved rock fragments (Fig. 7a). Quartz overgrowth is typically the dominant cement type in sandstones at temperatures above 70-100°C (Bjørlykke and Egeberg 1993;Walderhaug 1996). According to burial and heat flow reconstructions by Bruns et al. (2013), temperatures have exceeded 70°C since the Late Carboniferous/Early Permian to form quartz cement for nearly 20 Ma. ...
Article
Former coal mines hosted in Upper Carboniferous silt- and sandstones in the Ruhr Basin, NW Germany, are currently examined for post-mining applications (e.g., geothermal energy) and are also important tight-gas reservoir analogs. Core material from well Pelkum-1, comprising Westphalian A (Bashkirian) delta deposits, was studied. The sandstones and siltstones are generally tight (mean porosity 5.5 %; mean permeability 0.26 mD). Poor reservoir properties primarily result from pronounced mechanical compaction (mean COPL 38.8 %) due to deep burial and high contents of ductile rock fragments. Better reservoir properties in sandstones (> 8 %; > 0.01 mD) are due to (1) lower volumes of ductile grains (< 38 %) that deform during mechanical compaction and (2) higher volumes in feldspar and unstable rock fragments. During burial these form secondary porosity (> 1.5 %) resulting from acidic pore water from organic matter maturation. Still, sandstones with enhanced porosities only show a small increase in permeability since authigenic clays (i.e., kaolinite and illite) or late diagenetic carbonates (i.e., siderite and ferroan dolomite/ankerite) clog secondary porosity. Quartz cementation has a minor impact on reservoir properties. Evaluating the Si/Al ratio can be a suitable proxy to assess grain sizes and may be a convenient tool for further exploration. Supplementary material: https://doi.org/10.6084/m9.figshare.c.7003156
... 14 Not only are the minerals in a rock complex and variable, 15,16 but also the different cementation states may have a significant effect on its various properties. 17,18 In view of different diagenetic facies that had different petrology, diagenesis, and physical properties, 19,20 these characteristics directly determine the size of rock mechanics parameters (including compressive strength, Poisson's ratio, and elastic modulus) and the reasonable evaluation of rock brittleness. 21 It is of great significance to the effective prediction of formation fracture pressure and the evaluation of wellbore stability during coalbed methane development. ...
Article
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The structural fracture of the coal seam with its low permeability is the dominant reason for the “difficult gas out” of the broken soft coal seam. The brittleness of the roof and floor rock stratum of the broken soft coal seam has a significant effect on the fracture extension pressure of the surrounding rock after casing perforation and hydraulic fracturing of the horizontal well for coalbed methane (CBM). In this paper, 15 rock samples were scientifically collected from the roof and floor of the main mining coal seam of the Early Permian coal-bearing series in the Xinxie-1 well of the Huainan Coalfield in Anhui Province, China. On the basis of mineral composition analysis of these samples, the influence of mineral composition on the mechanics properties of the rock at the roof and floor of the coal seam was investigated. The correlation analysis and gray correlation analysis were adopted to construct an evaluation method for the brittleness of the rock at the roof and floor of the coal seam based on the mineral content. The results indicated that the most significant compositions of the minerals in the rock at the roof and floor of the broken soft coal seam were quartz and clay minerals. The most significant types of rock cementation are quartz agglomeration and rhodochrosite cementation. Pore destruction as a result of cementation was much greater than that of compaction. In comparison to clay minerals, the variation in the content of brittle minerals such as quartz, plagioclase, and siderite in the rock showed more sensitivity to the mechanics properties of the rock. The more sensitive minerals for compressive strength (CS), shear strength (SS), modulus of elasticity (E), softening coefficient (K), and Poisson’s ratio (μ) are quartz, those for tensile strength (TS) are plagioclase and siderite, and those for Poisson’s ratio are clay minerals. Based on the established mineral content weighting analysis method, it was calculated that the brittleness index (BI) of the rocks at the roof of the 13-1, 11-2, 9-2, and 4-2 coal seams was larger, which was advantageous for the formation of longer fracturing crack networks. This is theoretical guidance for the optimization of horizontal well fracturing design in the deep coal beds of the Huainan Coalfield.
... The second process is quartz cementation in sandstones and siltstones, which is limited mainly by the rate of precipitation of quartz (Walderhaug, 1996;Harwood et al., 2013), a parameter that increases exponentially with temperature (Fig. 18). It must be emphasized here that the rate of quartz cementation is key to pressure generation, and not the amount of quartz cement. ...
Article
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We present a straightforward empirical correlation between petroleum occurrence in sedimentary basins and reservoir temperature that can be integrated with other methods of analysis to reduce exploration risk. Global amounts of recoverable oil, gas, and gas-condensate in 1175 well characterized reservoirs from 954 of the world’s largest fields, constituting 54% of the world’s documented recoverable conventional oil and 50% of gas, are examined in terms of present-day reservoir temperature. Most volumes (74%) occur within the range of 60–120 ± 2 ◦ C (140–248 ±4 ◦F), corresponding with the isotherm-bounded depth interval in petroliferous basins previously defined as the “Golden Zone” for exploration. Only 6% of the global total occurs at higher temperatures and 20% at lower temperatures.
... Fluid inclusions contain rich information on reservoirs and minerals and provide the best records of the history of hydrocarbon migration and accumulation, thereby facilitating hydrocarbon accumulation chronology research [14][15][16]. The uniform temperature of the brine inclusions that coexist with hydrocarbon inclusions in the reservoir can represent the stratum temperature at the time when the oil and gas entered the reservoir [17]. ...
Article
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The source of oil and gas and the stages of oil and gas accumulation in the “double-Paleo” field of the HZ-A structure in the Pearl River Mouth Basin are analyzed, and the spatiotemporal coupling relationship of the key conditions of oil and gas accumulation are discussed to reconstruct the process of oil and gas accumulation. Based on previous research results, which are based the characteristics of biomarker compounds, the oil and gas in the HZ-A structure double Paleogene field came from the Paleogene Wenchang Formation hydrocarbon source rocks in the HZ26 sub-sag. By means of the casting thin section identification and inclusion homogenization temperature measurement, this paper reveals the three major hydrocarbon accumulation periods and corresponding fluid charging types in the “double-Paleo” field of the HZ-A structure in the Pearl River Mouth Basin. The results show that 13.8–10 Ma is the charging period of low mature crude oil, 10–5.3 Ma is the charging period of mature crude oil, and from 5.3 Ma is the natural gas charging period. Based on actual geological, drilling, logging, and seismic data, the key conditions for hydrocarbon accumulation in the HZ-A structure “double-Paleo” field are sorted out; that is, the source conditions are characterized by high-quality lacustrine source rocks generating early oil and late gas and a near-source continuous hydrocarbon supply. The reservoir conditions are characterized by weathering and superposition of a fracture zone that transforms into a reservoir, and a large-scale sandstone rock mass that transforms into a reservoir. The caprock conditions are characterized by the stacking of several thin mudstones that form a seal and the combination of multiple lithologies that block hydrocarbon migration. The trap conditions are characterized by multistage uplift structure traps and fracture-lithology combination control traps. The transport conditions are characterized by multi-stage cross-bed transport of source-connected faults and lateral differential transport of shallow sand in deep fractures. Finally, oil and gas accumulation models of the HZ-A structure double Paleogene field were established, and the accumulation process was reconstructed. The overall process involved three stages, with the first stage being the localized oil-displacing-water mode, the second being the large-scale oil-displacing-water mode, and the third being the late progressive gas-displacing-oil mode.
... Upon deep burial (>2 km; >70°C), sandstones typically develop diagenetic quartz cement which nucleates on the surface of detrital quartz grains and grows to occlude pore space (Walderhaug, 1996;Ajdukiewicz and Lander, 2010;Bjørlykke and Jahren, 2012). However, in deeply buried sandstones, grain-coating clay minerals have been shown to preserve porosity and permeability because they inhibit the growth of porosity-occluding quartz cement, leading to anomalously high reservoir quality (Ehrenberg, 1993;Taylor et al., 2010;Ajdukiewicz and Larese, 2012;Worden et al., 2020). ...
Article
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Sedimentary cores from the Ravenglass Estuary lack some of the sedimentary structures which can be seen in other estuarine sands due to their unconsolidated nature, making it difficult to meaningfully interpret depositional environments using standard sedimentological facies analysis. Here we explore how sediment texture, obtained from laser particle size analysis, and geochemistry, obtained from portable X-ray fluorescence, can be used independently, or in combination, to automatically classify sub-depositional environment and estuarine zone in a modern estuary. We have adapted an established Extreme Gradient Boosting workflow to select the most informative geochemical elements to be included in a training set to automatically classify sub-depositional environment at the surface of the Ravenglass Estuary, NW England, UK. Models that are trained exclusively on textural data significantly outperform those that use geochemical data when classifying sub-depositional environment but are comparable when classifying estuarine zone. However, the combination of textural and geochemical data in training sets improves model performance in all but one class when compared to separate textural and geochemical models. We have applied surface-calibrated combined textural and geochemical models to classify palaeo sub-depositional environment in three cores obtained from a tidal flat in the Ravenglass Estuary that are interpreted to record initial outer estuary deposition which transitioned to an inner estuary setting dominated by deposition from suspension. The subsurface classifications provide a framework to investigate the occurrence of reservoir quality-preserving detrital grain coats which vary in abundance as a function of sub-depositional environment at the surface. A review of literature suggests that the mixed flat sub-depositional environment is an ideal target for optimum clay grain coat occurrence, and we show that this sub-depositional environment is reliably identified by all models. We also discuss the implications of the modelling, how it compares to other machine learning approaches to understand reservoir quality in ancient systems, and how the workflow may be adapted for application to reservoir core. This study demonstrates value in utilising textural and geochemical data in conjunction with machine learning methods to help reveal the environmental evolution of marginal marine sands.
... Below the GZ (>120 • C) occurs the Expulsion Zone (EZ) whilst above the GZ (<60 • C) is the Compaction Zone (ComZ), which is also termed the Sealing Zone (SZ) and the Cold Zone (ColZ) (Fig. 8). Bjørkum and Nadeau (1998), Walderhaug (1996) and Nadeau (2011) have documented the impact of clay mineral diagenesis and quartz cementation on porosity and permeability evolution of the sediments, for sedimentary basins on the Norwegian Continental Shelf and the US Gulf of Mexico Basin. This concept has also been extended to include carbonate reservoirs with a slightly different temperature range for the GZ from 80 to 120 • C (e.g., offshore Madagascar) (Bassias and Bertagne, 2015;Roberts and Christoffersen, 2018). ...
... The change in porosity is given by empirical depthdependent compaction curves for the different lithologies (Sclater & Christie, 1980), and kinetic equations reflecting the degree of chemical compaction (e.g. effect of quartz cementation in the sandstone units using model by Walderhaug (1996)). The tool quantifies pressure dissipation using a model for lateral cross-fault fluid flow (Borge & Sylta, 1998) and Darcy flow equations in the vertical direction. ...
Article
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The smectite-illite transition in shales due to subsidence, temperature changes and diagenesis influences many processes in a sedimentary basin that can contribute to overpressure build up like reducing the shale permeability. The smectite-rich layers can form sealing barriers to fluid flows that will influence pore pressure prognosis for drilling campaigns, contribute to sealing caprocks for possible CO 2 storage and to sealing of plugging and abandonment wells. In this work, we have included the diagenetic smectite-illite transition into a three-dimensional pressure simulation model to simulate its effect on pressure build-up due to reduced shale permeabilities over geological time scale. We have also tested effect of thermal history and potassium concentration on the process of smectite-illite transition and the associated smectite-illite correction on perme-ability. A new smectite-illite correction has been introduced, to mimic how shale permeability will vary dependent on the smectite-illite transition. Stochastic Monte Carlo simulations have been carried out to test the sensitivity of the new correction parameters. Finally, a 3D Monte Carlo pore pressure simulation with 1000 drawings has been carried out on a case study covering Skarv Field, and Dønna Terrace offshore Mid-Norway. The simulated mean overpressures are in range with observed overpressures from exploration wells in the area for the Cretaceous sandy Lysing Formation and for the two Cretaceous Intra Lange Formation sandstones. The simulated smectite content versus depth is in line with published XRD dataset from wells. The corresponding modelled present-day permeabilities for the shales including the smectite-illite transition are two magnitudes higher than measured permeabilities on small samples in the laboratory using transient decay method. The measured permeabilities are in the range of 2.66·10 −18 to 3.94·10 −22 m 2 (2695 to 0.39 nD) for the North Sea database and represent the end members for shales-permeabilities with the lowest values, since the small samples are selected with no or minor natural fractures. This work
... (2) Pure sandstone forms cataclasite due to a high effective stress (cataclasis) or cementation; thus, the lateral sealing ability of the fault is relatively strong [57]. (3) Impure sandstones containing 15-40% clay form phyllosilicateframework fault rocks due to shear stress, quartz cementation, and pressure solution [58], which results in a relatively strong fault sealing ability. (4) Impure sandstone with a clay content greater than 40% develops clay smearing due to the effective stress, which results in a strong sealing ability of the fault [59,60]. ...
Article
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The goal of this study was to accurately evaluate the lateral sealing ability of a fault in siliciclastic stratum based on previous analysis of the lateral sealing of faults by a large number of scholars in the published literature and physical simulation experiments. Content of the clay mineral phase and the diagenetic degree of fault rock were investigated as the main factors to evaluate the lateral sealing of faults. Based on this theory, the configuration relationship between the clay content and burial depth of fault rock (SGR&H) threshold evaluation method for the lateral sealing of faults was established. Then, we applied these results to evaluate the lateral sealing ability of faults in the Beixi, Beier, Wuerxun, and Surennuoer areas in the Hailar Basin, China. The variation in SGR boundary values with burial depth between the lateral opening and moderate sealing area, as well as between the moderate and strong sealing area of the faults, are obtained. Compared with the previous methods, the SGR&H threshold method transforms the static SGR value of a formation or even a region into a dynamic SGR value that changes with the burial depth, which can fully characterize the differences in the conditions required for sealing faults with different internal structures at different depths. In determining the lateral sealing ability of faults by comparing the evaluation results, we discovered the following. (1) In the same area, the sealing thresholds of faults within different layers are different because the deep strata are subjected to greater pressures and longer loading times, so these faults are more likely to seal laterally. (2) In the same layer, the sealing thresholds of faults in different areas are also different. The higher the thickness ratio between the sandstone and the formation (RSF), the smaller the entry pressure of the fault rock when it has reached a critical seal state, so the SGR&H thresholds are relatively small. Compared to the previous methods, the SGR&H threshold method in this article reduces the exploration risk of faults with relatively low diagenetic degree in shallow strata, and also increases the exploration potential of faults with relatively high diagenetic degree in deep strata. The evaluation results are more consistent with the actual underground situation.
... The assumption is that transport of mineralizing solutes is not rate-limiting, throughout the model. Instead, the precipitation step is assumed to be rate-limiting (Walderhaug, 1996;Lander et al., 2008). This case was called reaction-limited by Romano and Williams (2022). ...
... In the studied Gombe Sandstone almost all the samples are characterized by K-feldspar co-existing with kaolinite (Table 3), indicating that they have the essential ingredients to form illite but lack sufficient thermal exposure for the reaction to come to completion. Quartz cement is widely interpreted as a deep-burial diagenetic cement, with a formation temperature threshold ranging between 70 and 80 ○ C (Bello et al., 2021;Walderhaug, 1996). The occurrence of quartz overgrowths on quartz grains partially coated by siderite suggest that they postdate siderite (Fig. 10H), and most likely formed during deep-burial mesodiagenesis. ...
... Upper Carboniferous-Permian carbonate and silica-rich deposits (TSE 3 and TSE 4) are less predictable in an east-west trend, and are largely dependent on the depositional environment, the chemical history of the fluids (related to the burial and uplift history), karstification and dolomitization (Stemmerik and Worsley 1995;Ehrenberg et al. 2001;Blomeier et al. 2009;Sorento et al. 2020). Triassic sandstones (TSE 4) in the east potentially exhibit moderate porosities (12-18%) but low Fig. 9. Maturation trend of Mesozoic organic-rich marine mudstone (OMM) based on the available vitrinite, T max , geochemistry data for bitumen (Mørk and Bjorøy 1984;Abay et al. 2017;Ohm et al. 2019) and the degree of diagenesis of sandstones (Mørk 2013;Haile et al. 2018Haile et al. , 2021, degree of quartz cementation v. maturation (cf., Walderhaug 1996;Bjørlykke and Jahren 2015). Source: geological map from the Norwegian Polar Institute. ...
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In this chapter, we present a comprehensive and up-to-date overview of the geology and petroleum geology of the Svalbard Composite Tectono-Sedimentary Element, Barents Sea; SCTSE, herein defined as the Carboniferous–Paleogene sedimentary rock succession and its associated structural elements. As such, the underlying economic basement consisting of Devonian and older sedimentary rocks, as well as Precambrian igneous and metamorphic rocks, are not considered.
... The nature of these influences is briefly discussed in the following sections. Although the general effects of these factors can be appreciated by reference to various case studies, no quantitative predictive models are available for predicting carbonate porosity, such as have been so successfully developed for quartzose sandstones (Walderhaug, 1996;Bjørkum et al., 1998). ...
Article
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... Moreover, as we face the largest challenge of our time, climate change and over-consumption of resources, investigating proxies and processes driving climate change, both past and present, is a paramount task for any 21 st century geoscientist. As such, despite its impaired potential of ever becoming a petroleum province, Svalbard with its excellent exposures and nearly stratigraphically complete Carboniferous to Paleogene succession, will be a key asset in future regional resource estimates, prospect de-risking, and integrated endeavours to vitrinite, Tmax, geochemistry data of bitumen (Mørk & Bjorøy, 1984;Abay et al., 2017;Ohm et al., 2019), and diagenesis of sandstones (Mørk, 2013;Haile et al., 2017; and mostly based on degree of quartz cementation (c.f., Walderhaug, 1996;Bjørlykke & Jahren, 2015). *wells with reported gas shows †wells withreported liquid hydrocarbons ‡wells that tested gas in producible quantities SNSK/TA/ NH Surface mapping with some oil stains from airport planning. ...
Article
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The Svalbard Composite Tectono-Stratigraphic Element is located on the north-western corner of the Barents Shelf and comprises a Carboniferous to Pleistocene sedimentary succession. Due to Cenozoic uplift the succession is subaerially exposed in the Svalbard archipelago. The oldest parts of the succession consist of Carboniferous to Permian mixed siliciclastic, carbonate and evaporite and spiculitic sediments that developed during multiple phases of extension. The majority of the Mesozoic succession is composed of siliciclastic deposits formed in sag basins and continental platforms. Episodes of Late Jurassic and Early Cretaceous contraction are evident in the eastern part of the archipelago and in nearby offshore areas. Differential uplift related to the opening of the Amerasian Basin and the Cretaceous emplacement of the High Arctic Large Igneous Province created a major hiatus spanning from most of the Late Cretaceous and early Danian throughout the Svalbard Composite Tectono-Stratigraphic Element. The West Spitsbergen Fold and Thrust Belt and the associated foreland basin in central Spitsbergen (Central Tertiary Basin) formed as a response to the Eurekan orogeny and the progressive northward opening of the North Atlantic during the Palaeogene. This event was followed by formation of yet another major hiatus spanning the Oligocene to Pliocene. Multiple reservoir and source rock units are exposed in Svalbard providing analogues to the offshore prolific offshore acreages in southwest Barents Sea and are important for de-risking of plays and prospects. However, the archipelago itself is regarded as high-risk acreage for petroleum exploration. This is due to Palaeogene contraction and late Neogene uplift of particularly the western and central parts. In the east there is an absence of mature source rocks, and the entire region is subjected to strict environmental protection.
... The second process is quartz cementation in sandstones and siltstones, which is limited mainly by the rate of precipitation of quartz (Walderhaug, 1996;Harwood et al., 2013), a parameter that increases exponentially with temperature (Fig. 18). It must be emphasized here that the rate of quartz cementation is key to pressure generation, and not the amount of quartz cement. ...
... For the compaction trend estimation, we need to consider both mechanical and chemical compaction, which the latter occurs after the temperature of a certain depth reaches around 70 • C (Bjørlykke, 1989;Lander and Walderhaug, 1999;Goulty et al., 2012). The chemical compaction could be simulated by a quartz cementation model in sandstone, as proposed by Walderhaug (1996). ...
Thesis
Earth consists of heterogeneous layers due to the complex sedimentation processes, in which lithifies both unconsolidated sand and siliciclastic clays into sandstone and shale. These two sedimentary rocks are the most abundant in the hydrocarbon reservoir, usually in the form of shaly sand or sandy shale mixture. As the advantage of the technology, geophysicists can distinguish these sedimentary rocks by using a seismic reflection method that relies on their elastic properties; P-wave (Vp) and S-wave (Vs) velocities along with density. One option to estimate these velocities are from both compressional and shear sonic logs since these two are reciprocal to the elastic velocities. However, sonic logs may not be available or partially available at specific depth intervals. Lack of these measurements could potentially be problematic for geophysicists that need accurate velocity estimations. Many rock-physics-based empirical approaches are available for elastic velocities estimations, relying on other parameters such as porosity, clay volume, differential stress, et cetera. However, these empirical approaches are only valid and optimum in the dataset they are using. Therefore, these empirical approaches are susceptible to the robustness issue. We propose a methodology to estimate the vertical velocity depth trends for the three wells taken from the Norwegian Continental Shelf (NCS). The proposed methodology mainly utilizes the rock-physics analysis of Voight-Reuss Bounds and the Bounding Average Method (BAM). It also implements the petrophysical analysis to estimate the lithological volume fraction of sand, clay, and silt. We designed two different models, namely the implicit and explicit clay-bound water. The challenges of this proposed methodology are to simulate the depositional variations between (1) Clean sand and clay; (2) Consolidation states as the rock changes from freshly deposited and later compacted; and (3) Velocity stress-sensitivity along with the burial depth. This proposed methodology yield correlation coefficients and error percentages, respectively between 0.7326 - 0.9521 and 7.73% - 15.07% for Vp; and respectively between 0.7495 - 0.9585 and 16.2% - 27.66% for Vs. These values show that the methodology is reliable but straightforward enough to perform robust predictions for the vertically-propagating elastic velocity depth trends.
Chapter
This volume constitutes the proceedings of the AAPG Hedberg conference on seals held in Barossa Valley, South Australia, in 2002. The key driver for both the Hedberg conference and this publication was the recognition that knowledge of risk in the estimation of sealing capacity and fault-seal potential is important in making judgments at the exploration, appraisal, and development stages of the petroleum business. In addition, incorporating seal risk in the overall assessment of hydrocarbons in place can affect decisions to drill prospects and the location of appraisal and development wells, as well as reserve estimation. Improved methods to estimate seal capacity and fault integrity can lead to savings in well costs, improved recoveries through optimum placement of wells, and improved estimates of hydrocarbon in place. This volume contains 18 chapters that reflect the spectrum of presentations at the conference. The knowledge imparted by these chapters will be a window on the state of seal knowledge at this juncture of time and includes topics such as seal failure related to basin-scale processes, the role of geomechanics in seals, and the economic evaluation of prospects with a top seal risk.
Chapter
This volume constitutes the proceedings of the AAPG Hedberg conference on seals held in Barossa Valley, South Australia, in 2002. The key driver for both the Hedberg conference and this publication was the recognition that knowledge of risk in the estimation of sealing capacity and fault-seal potential is important in making judgments at the exploration, appraisal, and development stages of the petroleum business. In addition, incorporating seal risk in the overall assessment of hydrocarbons in place can affect decisions to drill prospects and the location of appraisal and development wells, as well as reserve estimation. Improved methods to estimate seal capacity and fault integrity can lead to savings in well costs, improved recoveries through optimum placement of wells, and improved estimates of hydrocarbon in place. This volume contains 18 chapters that reflect the spectrum of presentations at the conference. The knowledge imparted by these chapters will be a window on the state of seal knowledge at this juncture of time and includes topics such as seal failure related to basin-scale processes, the role of geomechanics in seals, and the economic evaluation of prospects with a top seal risk.
Article
Deltaic siltstones and sandstones from the Pennsylvanian (Upper Carboniferous) in the Ruhr Basin are currently being examined for post-mining applications (e.g., geothermal) but are also an important tight-gas reservoir analog in NW Germany. Core material from two wells in the eastern Ruhr Basin, comprising Bashkirian delta deposits of the Langsettian and Duckmantian substages (Westphalian A and B), were studied using petrographic and petrophysical data to assess their reservoir properties and factors controlling these. The samples have low porosities and permeabilities (mean porosity 5.5% well Bork-1 and 5.1% well Haidberg-1; mean permeability 0.41 mD and 0.16 mD, respectively). Grain size and detrital mineralogy are the main factors affecting reservoir properties. The change in mineralogy from litharenites to lithic subarkoses corresponds to an increase in grain size from silt to sandstone and is associated with a general increase in porosity and permeability. Dissolution porosity largely contributes (up to 6%) to measured plug porosity. The dissolution porosity mostly is caused by the break down of detrital K-feldspar and plagioclase grains and affects low present-day feldspar contents (6.0 to 6.8%). Ductile rock fragments, such as shales and phyllites, cause porosity reduction due to facilitated mechanical compaction and are especially present in siltstones (ICOMPACT > 0.99). The study also used SiO2 and Al2O3 contents from XRF analyses as proxies for estimating reservoir properties and distinguishing between sandstones and siltstones. These findings help identify sections with better reservoir properties for potential exploration and production strategies in similar geological settings.
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Chapter
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The petrographic factors that most affect J sandstone porosity variability at a given level of thermal maturity are carbonate cementation and clay content. Carbonate cement, where present, reduces porosity. If previously more widespread, carbonate cement could also introduce porosity heterogeneity by temporarily preserving the pore network relative to uncemented intervals. Abundant detrital and authigenic clay reduces porosity by occupying pores. Low clay content indirectly reduces porosity because the inhibiting effects of clay upon quartz cementation and pressure solution are largely absent. -from Authors
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These sediments exhibit a close relationship between the pattern of mineral diagenesis and the physico-chemical conditions of the original depositional environment. Both marine and non-marine lithofacies have undergone a complex alternation of mineral cementation and grain dissolution. Prior to the entry of hydrocarbons during the Early Tertiary at a burial depth of between 6000 and 9000 ft, the sandstones experienced a major loss of pore-fluid pressure, localized collapse, and the precipitation of allochthonous baryte cement in both the marine and non-marine lithofacies. -from Authors
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Coarse sandstones were deposited during each of four transgressions across the shelf of the Lower Palaeozoic back-arc Welsh Basin. Hydrocarbon shows record porosity in the deposits of the Cambrian, Arenig, Caradoc and Llandovery transgressions. Hydrocarbons migrated from two sources: from Lower Palaeozoic source rocks within the basin, and later from Carboniferous rocks. Diagenesis and reservoir potential is related to the mineralogy of the sandstones, which reflects a balance between reworking of shelf sediment and an input from the eroded substrate. The substrate included Precambrian volcanic and plutonic rocks formed at the southern margin of the Iapetus Ocean. Quartz arenites are quartz-cemented or exhibit thick pore-linings of clay which restrict permeability. They have only minor reservoir potential. Arkoses do not exhibit macroporosity but have effective microporosity in the immediate vicinity of source rocks. Subarkoses have optimal reservoir potential, consisting of primary porosity about non-quartz grains (feldspars, glauconite) and secondary (intragranular) porosity in feldspars and lithics. The secondary porosity formed by leaching of clay alteration products in feldspars. Subarkoses retained sufficient framework stability to preserve the secondary porosity, whereas arkoses experienced widespread alteration and framework collapse. Limited secondary porosity after calcite dissolution may be due to surficial weathering of the Lower Palaeozoic rocks during Devonian/Lower Carboniferous exposure.
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Porosity in sandstones of the Kekiktuk Formation was successfully estimated prior to drilling of the 1 Leffingwell wildcat well (North Slope of Alaska). The estimate was based on a calibration data set used to evaluate the effects of (1) framework grain composition, (2) depositional facies, and (3) postdepositional processes on porosity of Kekiktuk sandstones. The sandstones of the Kekiktuk Formation are chert-bearing sublitharenites and quartzarenites characterized by a homogeneous composition of the detrital framework in the study area. Thus, mineral composition is not a major factor responsible for differences in reservoir quality. Based on outcrop and available core observations, the Kekiktuk Formation was interpreted to include several wet fan-deltas. The depositional model suggested that the 1 Leffingwell well would penetrate the distal, fine-grained facies of one such system. A petrographic study indicated that in fine- and very fine-grained Kekiktuk sandstones, such as those predicted in the wildcat, porosity was reduced primarily by silica cementation. Silica cementation, in turn, is related to burial history. Because of the relationship among porosity, silica cementation, and burial history, burial history diagrams provided a measure of the effect of burial history on porosity in available calibration wells. A synthetic burial history curve was constructed prior to drilling of the 1 Leffingwell well from available seismic data. This burial history curve was then used to estimate the wells porosity based on the previously established porosity-burial history relationship. 13 figs., 4 tabs.
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In discussion of papers by Land and Dutton (GeoAbstracts 79E/1052) and Boles and Franks (GeoAbstracts 79E/1980) Bj/orlykke calculates that ascending pore water derived from dewatering of shales cannot provide sufficient volumes of water in order to cement the sandstones unless they are only a few centimeters thick. He sugests that descending groundwater circulation may provide a high enough flux of water through the sandstones to supply the silica cement. -I.McTaggart