It is well known that the main SCF problem, if one leaves out the SCF solution itself, lies in the calculation and handling of bielectronic integrals needed when the LCAO forms of Fock operators are constructed. The problem can be considered alleviated and solved within the present knowledge through the efficient algorithms in use. However, if one looks ahead in time, then in some cases, such as
... [Show full abstract] the study of huge biological molecules, the use of approximate methods can still be useful. When dealing with approximate SCF procedures one needs to divide the methodology into two separate units: non-empirical and empirical methods.