For many years, first as a student and later as a teacher, we have observed graduate students in ecology and other environmental sciences who had been required as undergraduates to take calculus courses. Those courses have often emphasized how to prove theorems about the beautiful, logical structure of calculus, but have neglected applications. Most of the time, the students have come out of such courses with little or no appreciation of how to apply calculus in their own work. Based on these observations, we developed a course designed in part to re-teach calculus as an everyday tool in ecology and other environmental sciences. we emphasized derivations—working with story problems (sometimes quite complex ones)—in this book.
Its basic purpose is to describe various types of mathematical structures and how they can be apphed in environmental science.
Thus, linear and non-linear algebraic equations, derivatives, integrals, ordinary and partial differential equations are the basic kinds of structures, or types of mathematical models, discussed. For each, the discussion follows a pattern something like this:
1. An example of the type of structure, as apphed to environmental science, specialy contamination of the environment is given.
2. Next, a description of the structure is presented.
3. Usually, this is followed by other examples of how the structure arises in environmental science and contamination in environmental, specialy contamination soil.
4. The analytic methods of solving and learning from the structure are discussed.
5. Numerical methods for use when the going gets too rough analytically are described.
This book is not an introduction to calculus—it assumes that its readers will already have been introduced to the basic ideas of differential and integral calculus.
So far as we know, the combination of materials provided in the book is unique, but we believe it forms the basis for a useful and interesting course. In general, none of the material goes beyond what might be taught in a junior-level math or engineering course, but because the book covers ground from several such courses, the present material is appropriately taught at the graduate level.
Obviously then, parts of the material treated here could be selected for use in an undergraduate course.
In addition to its use as a text for a course, the material here should provide an interesting source for environmental scientists and managers to review forgotten math, and to learn some that is new.
The study of chemical transport in soils is important for a number of reasons. Some chemicals are important as they are required for soil and plant health (e.g. Micronutrients). Other chemicals may be highly toxic, particularly if they are present in high concentrations. A chemical becomes a Contaminate if its concentration exceeds some prescribed water quality standard, or if a beneficial water use has been impaired, and if the cause is induced by human activity. The study of the fate of chemicals and chemical Contamination in soil is vital for sustaining agricultural productivity and land utility.
The geological media between the land surface and the regional water table below is called the unsaturated zone or vadose zone (Stephens, 1996). The word “vadose” is derived from the Latin word vadosus meaning shallow (Looney and Falta, 2000a). In accord with its definition and meaning, the vadose zone includes the crop root layer, the intermediate zone between the root layer and the capillary fringe above the saturated water table. This zone therefore plays an integral role in the global hydrological cycle controlling surface water infiltration, runoff and evaporation and hence the availability of soil water and nutrients to plants. Initial investigations of this zone were focused on water availability to crops and optimal management of the root zone. However, in recent years much more attention has focused on chemical transport in and through this zone as a result of increased use of agrochemicals such as fertilizers and pesticides and increased demands to store and dispose of industrial and municipal wastes such as sewage. This zone is typically the first subsurface environment to encounter surface applied agrochemicals and contaminants and hence all surface and subsurface chemical concentrations and subsequent environmental impacts are inextricably linked to the physical, biological and chemical dynamics including sorption-desorption, volatilization, photolysis and degradation.
Our current understanding of physical and chemical processes in the vadose zone results largely from more than 70 years of mathematical modeling of variably saturated flow using Richards’ equation coupled with the Fickian-based convection-dispersion equation for solute transport. Analytical and numerical solutions of these classical equations are widely used to study and predict water flow and solute transport for specific laboratory and field experiments and to extrapolate these results for other experiments in different soils, crops and climatic conditions. However, many recent studies have demonstrated that the assumptions implicitly adopted in the Richards’ and convective- dispersion equations are limiting the scope and application of solutions to these equations for many agricultural and forestry management strategies. The spread of solute and Contaminates in soils is complicated by non-random spatial and temporal variations of physical, chemical and biological components of soils. One manifestation of spatial and temporal heterogeneity in soils is the phenomenon of preferential flow, a general term used to describe a variety of physical and chemical non-equilibrium flow processes.
In this book we describing the contamination of the environment and its types and we will talk extensively about the contamination of soil and its sources and that affect impact on humans, animals and plants and how to control soil contaminates, all this topices explained in chapter one .
In chapter two we describing the spread of Contamination through soils are discussed by using special models of that cause. The spread of Contamination in soils is controlled by the flow of water and, in most cases, is described by the convective-dispersive equation. First, we consider cases when the water velocity is assumed constant. Effects of boundary conditions, chemical reactions, adsorption and species competition are described in this case. Then two other cases are discussed; (1) when hydrology controls solute transport and (2) when the convective-dispersive equation is less important. In the former case, erosion due to raindrop impact and the transport of Contaminates adsorbed on fine particles is discussed. In the latter case, preferential flows, which can be linked to either structural voids in the soil (e.g. Macropores, cracks, etc.) or to flow instability are considered. Mathematical expressions describing these cases are presented. In the final section of this book we present a discussion of cases when Richards’ equation controls water movement. When Richards’ equation is used, it is difficult to analyze solute transport due to the strongly nonlinear nature of the equation. However, a few exact analytical solutions have been obtained recently and are presented here.