The synthesis of luminescent heteropolynuclear complexes of 3,5-dimethylpyrazolate [pt2Au2(Me2pz) 8] (M=Ag, Cu), containing three transition elements, which exhibit synergetic effect of the three transition elements, was reported. The X-rat structural analysis showed the structure of the complex corresponds to the structure in which adjacent two protons among four protons in the complex were
... [Show full abstract] replaced by Au ions. The nuclear magnetic resonance (NMR) spectrum of the complex exhibits four H4 signals in the aromatic region and eight methyl signals, and it is concluded that the metal atoms takes cis configuration. The X-ray crystal structure analysis show that Au, Cu, and Ag atoms are disordered in the molecules and that the molecular structures are consistent with their NMR spectra, indicating that the solid state structures are retained in the solution.