Hydrogen Isotope Separation by Catalyzed Exchange Between Hydrogen and Liquid Water
Separation Science and Technology (Impact Factor: 1.17). 04/1980; 15(3):371-396. DOI: 10.1080/01496398008068488
The discovery, at Chalk River Nuclear Laboratories, of a simple method of wetproofing platinum catalysts so that they retain their activity in liquid water stimulated a concentrated research program for the development of catalysts for the hydrogen-water isotopic exchange reaction. This paper reviews 10 years of study which have resulted in the development of highly active platinum catalysts which remain effective in water for periods greater than a year.The most efficient way to use these catalysts for the separation of hydrogen isotopes is in a trickle bed reactor which effects a continuous separation. The catalyst is packed in a column with hydrogen and water flowing countercurrently through the bed. The overall isotope transfer rate measured for the exchange reaction is influenced by various parameters, such as hydrogen and water flow rates, temperature, hydrogen pressure, and platinum metal loading. The effect of these parameters as well as the improved performance obtained by diluting the hydrophobic catalyst with inert hydrophilic packing are discussed.The hydrophobic catalysts can be effectively used in a variety of applications of particular interest in the nuclear industry. A Combined Electrolysis Catalytic Exchange - Heavy Water Process (CECE-HWP) is being developed at Chalk River with the ultimate aim of producing parasitic heavy water from electrolytic hydrogen streams. Other more immediate applications include the final enrichment of heavy water and the extraction of tritium from light and heavy water. Pilot plant studies on these latter processes are currently in progress.
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ABSTRACT: A method is described for heavy water recovery as a valuable by-product from combined electrolytic and non-electrolytic hydrogen streams. The process is based on an important modification of the ombined lectrolysis and atalytic xchange-eavy ater rocess (CECE-HWP). The CECE-HWP is now in the small pilot plant stage of development. A highly dispersed platinum-carbon-Teflon catalyst on a ceramic carrier achieves efficient deuterium exchange between hydrogen gas and liquid water. The range of acceptable ratios of electrolytic to non-electrolytic hydrogen which may be chosen in the Modified CECE-HWP is discussed. Bench-scale results are presented which clearly demonstrate recovery of heavy water from both the electrolytic and non-electrolytic hydrogen streams. The potential application of the process to ammonia production is discussed and other possible applications are mentioned briefly. Advantages of adopting the process are outlined, including the important benefit of conserving fossil resources.
Article: CANDU with hydrogen[Show abstract] [Hide abstract]
ABSTRACT: How Canada's successful CANDU (CANada Deuterium Uranium) nuclear power reactors would benefit from an emerging hydrogen-electric economy and vice versa is discussed with reference to the Combined Electrolysis Catalytic Exchange (CECE) process for recovering byproduct heavy water from electrolytic hydrogen. At the heart of this process is a hydrophobic, dispersed-platinum catalyst which has been under development at Chalk River for about a decade. Other potential applications of the CECE process are presented, including tritium recovery from both light and heavy water. Based on preliminary data and cost estimates, the net heavy water dollar credit appears to be at least comparable to the byproduct oxygen credit of electrolytic hydrogen. The potential for byproduct heavy water production from hydrogen in general, and from electrolytic hydrogen in particular, is discussed in relation to Canada's present primary heavy water production capacity.
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