We present the calculations of the ground state and lowest excited
states of the one-dimensional periodic Anderson Hamiltonian with two
electrons per site and arbitrary magnitude of the repulsive interaction
U. We consider finite cells (up to N=4) and introduce a new method,
using modified periodic boundary conditions, to facilitate comparison of
calculations with different N. The ground state is
... [Show full abstract] found to be a
nonmagnetic singlet in all cases. The lowest-energy excitations for
adding or subtracting one electron show that the system is insulating
and the lowest spin-flip excitations indicate a near instability to
antiferromagnetism due to the "nesting" of the Fermi surface in one
dimension. The lowest excitations are shown to vary little with N and,
for N=4, the results agree well with infinite-cell calculations, both
for small U and for the Kondo-lattice regime. The primary results are
the continuous variation from U=0 to the Kondo-lattice and mixed-valence
regimes and the importance of correlations, which lead to the insulating
gap and dispersion in the electronic and spin excitations.