Interstitial negative-charged bismuth dimers, and , are suggested as a model of broadband near-IR luminescence centres in bismuth-doped glasses. The model is based on quantum-chemical calculations of equilibrium configurations, absorption, luminescence and luminescence excitation spectra of the dimers in an alumosilicate network and is supported by IR and visible luminescence observed for the
... [Show full abstract] first time in bismuth-doped polycrystalline magnesium cordierite and by Raman spectra measurements in optical fibres with bismuth-doped alumosilicate glass core.