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Steel‐Related Porcelain Enamel Defects

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Abstract

Various after-the-fact porcelain enamel defects as discussed: surface laminations, melt blisters, outgassing as a result of base metal carbon, fishscale, warpage and/or sag of ware, surface contaminants, and rust. The discussion looks at these porcelain enamel problems as steel related defects. Although due to steel problems, they are not necessarily related to defective steel. The need to purchase the correct steel for the end use application is discussed.

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Article
The bubble structures, fishscaling resistance, adhesion and its mechanism of vitreous enamel to low carbon steels were evaluated by microscopic methods. The results show that the microalloying elements deteriorates the adhesion but suppress the fishscaling tendency, the enamel-steel interface adhesion could be explained as mainly the mechanical interlocking and chemical bonding during the firing process; the lower carbon substrate causes higher proportion of bigger bubbles in the enamel layer and subsequently causes the lower fishscaling susceptibility.
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