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Abstract

Investigations of wear resistance of polymers and polymers with additives, using the pin-on-disk apparatus with a campanula has been carried out in the present work. Normal load, velocity and air relative humidity were considered variable in the wear tests. The friction and the wear mechanisms are briefly reviewed. Various polymeric materials containing solid lubricants inside its microstructure were investigated. The self-lubricating characteristics of the added charge as well as the polymeric matrix were considered in the composite selection. Discs of pure PTFE (Teflon), composites PTFE + graphite, PTFE + MoS 2 + glass fibres, PTFE + bronze were tested against pins of quenched and tempered SAE 1045 steel. Pins of PTFE + MoS 2 + glass fibres were also tested against 1045 steel disks. In all tests, debris and flakes of worn materials were deposited on the pin counter face and these particles defined the wear mechanism. Through the analyses of micrograph taken by scanning electron microscopy, the following conclusion can be drawn: friction and wear in polymers are fundamentally different from the mechanisms which occurs in metals and ceramics, although they are due to the same wear micro-mechanisms: micro-plowing, micro-cutting and flake delamination. A very important conclusion on wear resistance of polymers and composites is its strong dependence on the environmental relative humidity and normal load. Variations observed in the relative air humidity from 50 to 70% can duplicate the lost volume by wear and, consequently, to double the wear rate. Among the tested materials, the composites PTFE with additive graphite or MoS 2 and glass fibres have shown the greatest sliding wear resistance.

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Article
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Article
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Article
New self-lubricating bronze matrix composites were prepared for seals and the tribological mechanisms in antiwear hydraulic oil were explored. The tribological behavior of bronze matrix composites tribotesting against an AISI 52100 steel ball was investigated with a ball-on-disc tribotester over a wide range of applied load and sliding speed. The obtained results showed that the tribological properties of composites were markedly improved. The alumina enhanced the strength and wear resistance of composites. However, the friction coefficient increased due to the addition of alumina. Silver was an effective solid lubricant. The tribological properties of the new self-lubricating composites were improved because of the synergistic effect of silver and Al2O3.
Conference Paper
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This paper presents an analysis of several 3D parameters based on bearing area curve in order to use the information for establishing the influence of sliding regime against steel on the tribological behavior of a composite class with polyamide matrix and 1% of black carbon. There were done pin-on-disk tests for different concentrations of micro glass spheres (MGS): 2.5, 5, 10, 20, 30 and 50% (wt), respectively. The polymer was tested under similar conditions in order to have a reference basis and to point out the improvement in tribological behavior when adding this reinforcement material. The surface topographies were registered with the help of PRO500 3D (stylus) Profilometer. The test parameters in dry regime were: sliding speed 0.5, 1.0 and 1.5 m/s, average pressure 1, 2 and 3 MPa, respectively. There were analyzed the influence of MGS concentration and sliding regime on wear as mass loss of the composite discs, after 10,000 m of sliding, the friction coefficient and several 3D parameters related to the bearing area curve, determined from raw profiles (surface bearing index – Sbi, core fluid retention index – Sci, valley fluid retention index, Svi, reduced summit height, Spk, core roughness depth, Sk, and reduced valley depth, Svk).
Article
Silver matrix composite brushes were fabricated by means of powder metallurgy, which included pressing at 300 MPa and then sintering for 1 h in pure H2 protec-tive atmosphere at 700 • C and repressing at 500 MPa. Four kinds composites with different compositions were produced, and the mechanical properties and electrical wear performance were investigated. The results showed that the composite added with carbon nanotubes had a higher hardness and strength, a lower contact voltage drop and an excellent anti-wear property in electrical sliding wear, because of the reinforcement ability of carbon nanotubes. Adding graphite to the composite also decreased the wear loss and contact voltage drop, because graphite had an electrical current conducting ability which not only made the current pass the lubricating films easily but also eliminated and reduced the arc and spark effectively.
Article
Modified PTFE oil seal is studied: non-linear finite element model of sealing interface is established to simulate the distribution of contact stress and the grinding condition. The friction and wear properties of PTFE composite are investigated in different loads under dry and oil-lubricated conditions. The worn surfaces of the tested samples and grinding ring are observed with optical microscope, as an effort to analyze the wear mechanisms. The result shows that forced location of oil seal can be visually displayed by finite element analysis. Radial force increases with increasing magnitude of interference. Simulant results fit well with the actual situation. Under dry condition, friction coefficient increases with load increasing at low speed and decreases at high speed but is stable and affected little by loads under oil-lubricated condition.
Article
Ag-MoS2 composite brushes were fabricated by means of powder metallurgy process. The composite was detected by the method of XRD after sintering, and the worn surface of the brush was analyzed by XPS after the wearing experiments with current. Results showed that the components of the composite didn't change during sintering, but the surface components of it changed upon wearing and some matters such as MoO3 and MoO2 were produced. At the same time, Cu2O, CuO and Cu2S were detected due to the adhesion transfer of elemental Cu from the slipping ring to the brush surface and the reaction between the elemental Cu and the ambient air molecules. During electrical sliding wearing, the surface film can reduce the friction coefficient and be beneficial to the frictional performance of the material.
Article
In the present work, friction coefficients and wear rates of polyester composites reinforced by graphite fiber with different diameters and impregnated by vegetable oils (Corn, Olives, and Sunflower oil) were measured to develop new engineering materials with low friction coefficients and high wear resistance which can be used in industrial applications as bearing materials. It was found thatcomposites of 10 vol.% corn oil and 10 vol.% graphite fibers show relatively low friction coefficientsand low wear rates. Corn and sunflower oil display good tribological behavior of the polyester composites.
Article
Metal matrix composite coatings with potential self-lubricating properties were produced on plain steel substrates using the plasma transferred arc technique (PTA). Layers of approximately 1mm thickness and with various compositions were obtained with additions of MoS2 and MnS compounds, which are known to act as solid lubricants in a number of applications. Following the microstructural characterization, the tribological behavior of the coatings was investigated using pin-on-disk experiments. Experimental results indicated that the addition of MnS was effective in reducing the friction coefficient and the wear rate of the coatings in comparison to the steel substrate, whereas the MoS2 was ineffective, due to its instability and subsequent redistribution of Mo and S elements during the solidification process.
Article
The effect of 20 wt% polytetrafluoroethylene (PTFE) fillers on the friction and wear properties of thermoplastic polyimides (TP) are investigated, under dry sliding in line contact against steel under 50 to 200 N, 0.3 to 1.2 m/s, and 60 to 260°C. Besides the lubricating mechanisms of PTFE based on mechanical shear, the thermal and tribophysical interactions in the sliding interface are considered in this research by using thermoanalytical measurements, Raman spectroscopy, and calculating the maximum polymer sliding temperature T*. The effect of hydrolysis of the TP bulk material, causing high friction at 100 to 140°C, is covered by PTFE. A transition at pv-values 2.2 MPa m/s (T* = 120°C) is due to thermally controlled sliding of PTFE, while a transition at pv-values 3.2 MPa m/s (T* = 180°C) remains controlled by degradation of the TP bulk material into monomer fractions. The reduced coefficient of friction in the presence of PTFE leads to smaller degradation and orientation of the molecular back-bone and side-chains within the TP structure. The formation of a homogeneously mixed transfer film is only observed at 180 to 260°C. The PTFE forms a fibrillar structure during wear at high sliding velocities, while they wear as separate particles at high normal loads. POLYM. COMPOS., 2009. © 2009 Society of Plastics Engineers
Article
The internal lubrication of 15 vol% graphite flakes added to polyimide was investigated during sliding at 50–200 N normal loads, 0.3 m/s and 23–260 °C, showing that chemical reactions in the polyimide bulk have an important effect on the sliding efficiency of the graphite. The latter are illustrated by Raman spectroscopy, thermo-analytical measurements and mass spectroscopy. At low temperatures (23–100 °C), transfer consists of pure graphite and mechanical shear prevails. At intermediate temperatures (120–180 °C), transfer consists of coexistent polyimide and graphite. A regime with decreasing friction is related to hydrolysis reactions in the bulk polyimide, lowering the effective water content in the sliding interface. At higher temperatures (180–260 °C), transfer consists of mixed polyimide–graphite. A low friction regime is related to imidisation of the bulk polymer and interfacial water supply, favouring the graphite lubricating properties. The graphite debris morphology occurs as flakes (low temperature) or powders (intermediate temperatures), likely resulting from cleavage between the basal planes or embrittlement across the basal planes.
Article
This book presents the current understanding of the influences of microstructural parameters on wear. The effects of microstructure become more pronounced as the surface contact of two solid bodies becomes closer and these effects can be substantially reduced by oxide layers and lubricant films. The chapters include a general review of microstructure and properties of materials; classification of wear processes, wear mechanisms for grooving wear, sliding wear in metals, polymers, ceramics and composites; and rolling sliding wear and erosive wear of metals. (H.C.B.)
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A novel materials-selection procedure has been developed and implemented in software. The procedure makes use of Materials Selection Charts: a new way of displaying material property data; and performance indices: combinations of material properties which govern performance. Optimisation methods are employed for simultaneous selection of both material and shape.
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The aim of this research was to investigate and analyze the wear of polymers by use of an empirical wear equation. A dimensional analysis was carried out to develop an equation in which the volume of polymer material worn during sliding on a horizontal pin-on-disk machine was expressed in terms of the operating conditions, properties of the polymer, and counterface roughness. Both a linear and a non-linear relationship of volume loss with other variables was considered in evaluating a dimensionless wear coefficient. It was concluded that a better correlation with the variables was obtained using a non-linear relationship.
Article
Preface * Introduction * Surface topography and surfaces in contact * Friction * Lubricants and lubrication * Sliding wear * Wear by hard particles * Wear and design * Surface engineering in tribology * Materials for bearings * Author index * Subject index.
Article
The application of advanced materials in various areas of contemporary technology can lead to improvements in the function, quality and performance of engineering components and systems. In this paper, an overview of the developments in high performance materials, both organic and inorganic based, is given. This includes thin hard coatings because of their increasing importance in tribological improvements. For these types of materials the requirements for tribo-engineering applications are analysed. Research results from BAM concerning ceramics and ceramic composites, polymers and polymer composites as well as hard coatings illustrate the friction and wear behaviour of these materials and their potential for tribo-engineering applications.
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Although wear resistance is not a materials property, many of the factors which determine the tribological behaviour of materials can be defined. This review discusses these factors, together with recent developments in bulk materials for tribological applications, including composites and intermetallics. Advances in surface engineering and the possibilities of “smart” tribological materials are also reviewed.
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Along with the extensive application of polymers for tribological purposes, the understanding of polymer tribology is becoming increasingly important. A broad overview of the general area of polymer tribology is presented in this paper. The progress in understanding the field over the past decade is reviewed under the three topics of rubber tribology, plastic tribology and tribology of polymer composites. It is hoped that this paper will serve as a valuable source of reference for future tribologists.
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A novel materials selection procedure containing a database of quantitative and qualitative data for a wide range of engineering materials was implemented in software. The management system provided an interactive graphical selection environment appropriate for mechanical engineering design using performance indices in the selection of materials with optimum properties and section shape.
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