The splat foils of Al-RE(=Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Er and Yb) binary alloys of 0.04-0.06mm thickness were made by arc-melting and hammer-anvil technique, the cooling rate is in 106 K/s order of magnitude. The metastable extended solid solubilities of these RE elements have been evaluated by measurements of the lattice spacings of the rapidly solidified (RS) Al-RE alloys, they are
... [Show full abstract] 0.4, 0.15, 0.21, 0.3, 0.5, 0.1, 0.6, 0.65, 0.7, 0.75, 0.2 at.-% for above individual RE elements, respectively. The secondary phase in RS AI-RE alloys were identified to be Al for alloys containing light RE and Eu elements and Al3RE for alloys containing heavy RE and Y elements. Some factors influencing the estension of solid solubility of AI-RE alloy were discussed.