The occurrence of shock metamorphosed quartz is the most common
petrographic criterion for the identification of terrestrial impact
structures and lithologies. Its utility is due to its almost ubiquitous
occurrence in terrestrial rocks, its overall stability and the fact that
a variety of shock metamorphic effects, occurring over a range of shock
pressures, have been well documented. These shock effects have been
generally duplicated in shock recovery experiments and, thus, serve as
shock pressure barometers. After reviewing the general character of
shock effects in quartz, the differences between experimental and
natural shock events and their potential effects on the shock
metamorphism of quartz are explored. The short pulse lengths in
experiments may account for the difficulty in synthesizing the
high-pressure polymorphs, coesite and stishovite, compared to natural
occurrences. In addition, post-shock thermal effects are possible in
natural events, which can affect shock altered physical properties, such
as refractive index, and cause annealing of shock damage and
recrystallization. The orientations of planar microstructures, however,
are unaffected by post-impact thermal events, except if quartz is
recrystallized, and provide the best natural shock barometer in terms of
utility and occurrence. The nature of planar microstructures,
particularly planar deformation features (PDFs), is discussed in some
detail and a scheme of variations in orientations with shock pressure is
provided. The effect of post-impact events on PDFs is generally limited
to annealing of the original glass lamellae to produce decorated PDFs,
resulting from the exsolution of dissolved water during
recrystallization. Basal (0001) PDFs differ from other PDF orientations
in that they are multiple, mechanical Brazil twins, which are difficult
to detect if not partially annealed and decorated. The occurrence and
significance of shock metamorphosed quartz and its other phases (namely,
coesite, stishovite, diaplectic glass and lechatelierite) are discussed
for terrestrial impact structures in both crystalline (non-porous) and
sedimentary (porous) targets. The bulk of past studies have dealt with
crystalline targets, where variations in recorded shock pressure in
quartz have been used to constrain aspects of the cratering process and
to estimate crater dimensions at eroded structures. In sedimentary
targets, the effect of pore space results in an inhomogeneous
distribution in recorded shock pressure and temperature, which requires
a different classification scheme for the variation of recorded shock
compared to that in crystalline targets. This is discussed, along with
examples of variations in the relative abundances of planar
microstructures and their orientations, which are attributed to textural
variations in sedimentary target rocks. Examples of the shock
metamorphism of quartz in distal ejecta, such as at the K/T boundary,
and from nuclear explosions are illustrated and are equivalent to that
of known impact structures, except with respect to characteristics that
are due to long-term, post-shock thermal effects. Finally, the
differences between the deformation and phase transformation of quartz
by shock and by endogenic, tectonic and volcanic processes are
discussed. We confirm previous conclusions that they are completely
dissimilar in character, due to the vastly different physical conditions
and time scales typical for shock events, compared to tectonic and
volcanic events. Well-characterized and documented shock effects in
quartz are unequivocal indicators of impact in the natural environment.