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Recent Developments in the Methods of Estimating Shooting Distance

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A review of developments during the past 10 years in the methods of estimating shooting distance is provided. This review discusses the examination of clothing targets, cadavers, and exhibits that cannot be processed in the laboratory. The methods include visual/microscopic examinations, color tests, and instrumental analysis of the gunshot residue deposits around the bullet entrance holes. The review does not cover shooting distance estimation from shotguns that fired pellet loads.
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TheScientificWorldJOURNAL (2002) 2, 573–585
ISSN 1537-744X; DOI 10.1100/tsw.2002.140
*Corresponding author. Email: alzit@netvision.net.il
©2002 with author.
573
Recent Developments in the Methods of
Estimating Shooting Distance
Arie Zeichner* and Baruch Glattstein
Division of Identification and Forensic Science, Israel Police National Headquarters,
Jerusalem 91906, Israel
Received November 7, 2001; Revised January 16, 2002; Accepted January 23, 2002; Published March 7,
2002
A review of developments during the past 10 years in the methods of estimating
shooting distance is provided. This review discusses the examination of clothing
targets, cadavers, and exhibits that cannot be processed in the laboratory. The
methods include visual/microscopic examinations, color tests, and instrumental
analysis of the gunshot residue deposits around the bullet entrance holes. The
review does not cover shooting distance estimation from shotguns that fired
pellet loads.
KEY WORDS: shooting distance, firing distance, gunshot residue, GSR, Griess test,
MGT
DOMAINS: forensics, analytical chemistry, microscopy
INTRODUCTION
The range from which a weapon has been fired is an important component in the reconstruction
of firearm-related offenses (murder, suicide, and accident). The firing distance estimation is based
on the examination of the appearance of the bullet entrance hole and the examination of gunshot
residue (GSR) patterns around the hole using various techniques. Although many authors in the
field use the phrase “shooting distance determination”, we prefer to use the term “estimation”
instead of “determination” because of the intrinsic inaccuracy of the examination. The reason for
this is a high variability of the GSR patterns from shot to shot when using the same weapon and
ammunition. By GSR, we mean all the materials emitting from the muzzle during shooting and
accompanying the projectile. These include gunpowder and primer residues as well as metal
particles from the bullet and the cartridge case. In most of the shooting cases in which there is a
need for a firing distance estimation, the victim or the victim’s clothing has to be examined. In
many cases, bullets hit surfaces of various parts of the human body directly without passage
through any intermediate medium. In some instances, other exhibits that happened to be targets of
shooting have to be examined. Such exhibits may be cars, walls, doors, windows, furniture, etc.
Many of them cannot be processed in the laboratory.
In this review, we will report on the recent developments (in about the last 10 years, since
the two comprehensive treatises on the subject were published[1,2]) in the methods of
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visual/microscopic, color test, and instrumental analysis of the entrance bullet holes and GSR
patterns around them for shooting distance estimation. A comprehensive list of references on
advances made in the field over the last 3 years can be found elsewhere[3]. We will not deal here
with shooting distance estimation for targets shot by pellet loads from shotguns. In our view,
there were no significant developments recently in this area, which is described comprehensively
elsewhere[1,4,5].
VISUAL AND COLOR TESTS
Clothing Targets
GSR patterns around the entrance bullet holes consist of propellant residues, metallic residues
from bullets (e.g., lead and copper), as well as primer residues. These residues can be detected
visually/microscopically if the target cloth is of a light enough color. However, in most of the
cases, there is a need for color chemical tests or instrumental analysis to assess the GSR patterns
around the entrance bullet holes.
In a series of three articles, Dillon reports[6,7,8] on the modified Griess test (MGT) as a
color test for nitrites and recommends a protocol for GSR
examinations in muzzle-to-target-
distance estimations. In the original procedure reported by Walker[9], Griess reaction is used. In
this test, Griess reagent consisting of sulphanilic acid and α-naphthyl amine in acetic acid
aqueous solution is used. The detection of free nitrite ions is based on the formation of diazonium
ion from sulphanilic acid and nitrite. The diazonium ion couples with α-naphthyl amine to form
an orange azo dye. In the modified test, Dillon proposes to use α-naphthol instead of α-naphthyl
amine (the Walker test) or N-(1-naphthyl)-ethylenediamine dihydrochloride. According to him,
both of the replaced reagents are carcinogenic. However, in the literature on the chemical safety
data[10], N-(1-naphthyl)-ethylenediamine dihydrochloride is not reported as a carcinogen. In fact,
we are using this reagent with sulphanilamide routinely for “our” MGT [11,12,13,14]. MGT does
not refer to one specific, defined test. In fact, it appears that every author who introduces any
modification to the original Griess test calls it MGT. The proposed protocol[8] includes visual,
microscopic, and chemical (lead and nitrites) tests. It recommends first conducting the MGT and
then the sodium rhodizonate test for lead. The reason for this sequence is because the rhodizonate
is applied directly on the target. Dillon contends that particulate lead is a random nonreproducible
phenomenon, whereas the presence of vaporous lead is quite significant in that it is found
principally at wounds from closer ranges.
Glattstein et al. reported on an improved method of determining shooting distance estimation
from clothing[12]. The novel part of the method includes transferring total nitrite (nitrite ions and
unburned smokeless powder residues) from the target to an adhesive lifter. After the transfer, lead
and copper deposits around the bullet entrance hole are partially extracted consecutively to the
Benchkote (Whatman) filter papers moistened with diluted acetic acid and ammonia solutions,
respectively. Their patterns are visualized by rhodizonate (lead) and rubeanic acid (copper). The
MGT is carried out after alkaline hydrolysis of the smokeless powder residues on the adhesive
lifter. The purpose of lifting gunpowder residues from the shot cloth target is to eliminate
interference caused by conducting MGT directly on the target, with or without the hydrolysis
step. It was found that almost a complete transfer of gunpowder residues to the adhesive lifter
was obtained, and the vaporous lead and copper are not transferred to the adhesive lifter. The
widely used MGT detects only free nitrite ions formed from the combustion of smokeless
powder. The unburned smokeless powder particles cannot be detected by this method. Alkaline
hydrolysis prior to the MGT has been proposed to increase the sensitivity of the test for
gunpowder residues[15]. The purpose of the alkaline hydrolysis is to cause disproportionation of
the unburned nitrocellulose and nitroglycerine (the main components of the smokeless powder) to
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FIGURE 1. A test shot on a white cotton cloth; ammunition 9-mm Winchester super-X FMJ, distance 50 cm. A color photograph of
the target after application of MGT: (left) without the hydrolysis prior to MGT, (right) with the hydrolysis prior to MGT.
carbonyl compounds and free nitrite ion, thus increasing the available amount of nitrite ions for
MGT. The importance of the hydrolysis step in the gunpowder residue visualization is
demonstrated in Fig. 1. As can be seen in this type of ammunition (Winchester Super-X), the
difference in patterns obtained with and without hydrolysis is very great. Thus, in such cases, it is
very important to carry out this step prior to the MGT. However, not all ammunition types
demonstrate such a difference. Before starting the estimation of the shooting distance, it is desirable
to determine that the hole is a bullet entrance hole. This can be done by applying methods for
chemical visualization of lead (rhodizonate) and copper (rubeanic acid) at the perimeter of the hole.
However, it was observed that the color tests do not give positive results in all shooting cases,
although it was known that a lead bullet or a full metal jacket (FMJ, brass) bullet was used.
In recent years, several ammunition companies have introduced lead-free ammunition. This
technology uses lead-free primers and totally metal-jacketed (TMJ) bullets. The lead bullet core is
encased in a metal alloy jacket, thus no lead is exposed at the base where hot gases can vaporize
lead (as in conventional full jacketed or lead bullets). In such cases, because lead is not a
component of the GSRs, lead patterns cannot be detected for firing distance determination. The
Zincon reagent that gives a blue-colored complex with elements zinc and titanium was proposed
for firing distance estimation in the case of lead-free ammunitions that have zinc and titanium in
the primer[16]. As a side reaction, copper, which among other metals comes from the projectiles
or cartridge cases, also forms a blue-colored complex with the reagent.
A modified sheet-printing method for the detection of lead patterns was reported by
Stahling[17]. Instead of using cellulose hydrate foil, a plastic-based photographic paper was used
as a substrate for transfer of metallic gunshot elements from cloth.
Alakija et al.[18] studied the damage to various cotton clothing targets from different
firearms as a function of shooting distance. They found, for example, that .22-caliber pistols
always produced “stellate” (“cruciform”) tears at tight contact and loose contact ranges;
nonstellate defects were produced by this pistol at ranges of 2 cm or greater. Stellate defects were
not produced by any studied firearm at ranges greater than 8 cm.
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FIGURE 2. The effect of machine washing on the total nitrite visualization on a white cotton cloth; ammunition 9-mm parabellum
GFL FMJ, 25-cm shooting distance. Black and white photograph of the target: (left) the target without washing, (right) after washing.
Persistence of GSR on Clothing
Several studies dealt with possible effects of various factors on clothing items after shooting with
regards to the shooting distance estimation[8,19,20,21,22,23]. Most of these found that
mechanical handling of clothing or soaking them in blood, still water, or running water
considerably decreases the amount of GSR around the bullet entrance holes. Thus Emonet et
al.[22] report that the medical manipulations of clothing lead to an increase of the loss of visible
and nitrated GSR of about 30 to 40%. Even et al.[19], on the other hand, did not find a significant
effect of soaking in still water on the obtained GSR patterns. Also L. Haag[20] found that a static
extraction procedure utilizing a 12- to 24-h immersion in an aqueous blood-removal solution does
not alter significantly the GSR patterns on the shot cloth targets. In casework, sometimes requests
are received to estimate shooting distance from clothing items that underwent machine washing.
Vinokurov et al.[23] conducted a study to assess the effect of machine washing or brushing of
clothing items on GSR patterns (gunpowder residues and lead and copper deposits) around bullet
entrance holes. Results show that those treatments decrease considerably (machine washing more
than brushing) the amount and density of GSR. However, for close shooting distances, not all of
the GSR deposits are removed. Remaining patterns can be visualized by specific color reactions
and used for shooting distance estimation. Figs. 2 and 3 illustrate some of the results. This study
shows that the absence of GSR patterns around the bullet entrance hole is a clear indication that
shooting was not at close range.
Exhibits that Cannot be Processed in the Laboratory
In our experience, casework mostly involves examining exhibits for shooting distance estimation
that are the victims’ clothing. Sometimes, however, we are asked to determine shooting distance
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FIGURE 3. The effect of brushing on the total nitrite visualization on a white polyester cloth. Same ammunition and distance as in
Fig. 2. Black and white photograph of the target: (left) the target without brushing.
from exhibits that cannot be processed in the laboratory, such as cars, walls, doors, windows, or
furniture (made of wood, plastic, leather or fabric).
Glattstein et al.[13] examined the feasibility of the method developed for clothing[12]
(described above) for additional materials: galvanized steel, glass, plywood, and high-pressure
laminated plastic sheets of melamine and phenolic materials (Formica). It was found for all tested
target materials and shooting distances that the amounts and densities of the discharge residues
detected visually (without any treatment) were considerably smaller than those obtained after
chemical treatments. This effect was particularly pronounced in the case of glass, where
blackening could hardly be observed even from contact shooting ranges. Total nitrite patterns
visualized on the lifters applied on the various targets were similar to those
obtained on the lifters
from the cotton cloth at relatively short shooting distances, i.e., up to about 25 cm. The patterns
were similar in terms of the amount of particles and their density around the entrance bullet hole.
Fig. 4 demonstrates this result on plywood and on glass. As shooting distances become greater,
the number and density of nitrite spots on the lifters from all the tested materials targets decrease
considerably in comparison to the lifters from the cotton cloth for the same distance, the plywood
target being the most similar. Based on the obtained results in this study, the recommended
method for determining shooting distance estimation from the objects that cannot be processed in
the laboratory is as follows:
1. Application of the adhesive lifter to the target.
2. Visualization of the lead deposits on the target by the rhodizonate test. It is recommended
to photograph the lead pattern because of the instability of the color.
3. Visualization of the copper deposits on the target by the rubeanic test.
4. Visualization of the total nitrite on the lifter in the laboratory.
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FIGURE 4. Black and white photograph of the visualized total nitrite patterns on the adhesive lifters applied to various target
materials after shooting (ammunition 9-mm parabellum FMJ, distance 25 cm). (a) White cotton cloth. (b) Plywood. (c) Glass.
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FIGURE 4c.
To improve the accuracy of the shooting distance estimation, test firings should be carried out
using target materials as similar as possible to the materials of the examined evidence. If there is
no possibility of conducting test firing at a material similar to the evidence, then test firings
should be carried out on cotton cloth. In such a case, the visualized pattern of the total nitrite will
be sufficient to demonstrate that the shooting distance on the evidence was equal to or below the
shooting distance at which similar visualized patterns of the total nitrite are obtained on the cotton
cloth
.
Human Body as a Target
In many shooting cases, bullets hit surfaces of various parts of the human body (mostly the head)
directly, without passage through any intermediate medium. For the purpose of assessing the
shooting distance, most of the forensic literature describes only visual/microscopic methods for
examination of the appearance of the wound and discharge particle patterns around it[1,4,24].
Shooting distances on human body surfaces can be divided roughly into four ranges: contact,
near contact range, intermediate range, and distant range[1,4]. In contact wounds, the muzzle of
the weapon is held against the surface of the body at the time of discharge. The appearance of
tearing, scorching, soot, or the imprint of the muzzle characterizes contact wounds. In near
contact wounds, the muzzle of the weapon is not in contact with the skin, being held a short
distance away (a few centimeters). At near contact range, a wide zone of powder soot overlaying
seared blackened skin surrounds the entrance wound. An intermediate range gunshot wound is
one in which the muzzle of the weapon is held away from the body at the time of discharge, yet is
sufficiently close so that gunpowder grains expelled from the muzzle along with the bullet
produce “powder tattooing” of the skin. Microscopic examination is conducted to verify the
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presence of partially burned or unburned gunpowder particles. In the distant range, no damage
effects or discharge particle patterns are observed around the gunshot wound.
Although sodium rhodizonate and rubeanic acid reagents were proposed for the visualization
of lead and copper patterns around the gunshot wounds[25,26], in practice, the authors are not
aware of any chemical tests that are conducted for the estimation of shooting distance on
cadavers.
As in cases of clothing and other objects, many problems can be encountered when the
assessment of shooting distance on cadavers is based merely on visual and microscopic
examinations. The typical problems are[1,4,24]:
1. When small-caliber ammunition (short .22 or .32 Smith & Wesson) is used, the
typical features of contact gunshot wounds may be absent.
2. Gunpowder tattooing may not be produced on the skin in hairy parts of a body, and
gunpowder particles will be hardly discernible.
3. Whenever shots were inflicted through glass panes, glass particles may produce
visual patterns that can be similar to the gunpowder tattooing around a gunshot
wound[3,6].
4. The discoloration characteristic of a decomposed body can be similar to the color of
soot. Furthermore, it may also mask tattoo marks.
5. In rare instances, insects may produce patterns that resemble gunpowder tattooing on
cadavers.
An additional unique problem pertaining only to the human body is that there is no possibility of
conducting test firing on the same material as in the case of other exhibits. The proposed solution
for test firings was to use various simulant materials. Recommendations for those materials were
based on the studies comparing those materials to the skin of some animals, like rabbits or
pigs[27]. The conclusions of this work were that blotter paper is an acceptable skin simulant at
ranges less than 18 in. Beyond this distance, the patterns on the blotter paper were smaller than
those on the rabbits, meaning that the blotter paper was less sensitive. In a quite exceptional
study, M. Haag and Wolberg conducted experiments on various simulant materials in comparison
to live human skin[28]. The comparison was based on various visual and microscopic
characteristics (without chemical treatment) of the GSR on the targets. A specially designed
experimental setup made it possible to expose part of an arm to the residues. Kevlar vests were
laid over each side of the arm to protect the remaining portions of the arm from the residues,
allowing for additional shots on fresh skin. The study was carried out at ranges of 2 to 4 ft. They
found that the simulants that most closely represent the human skin are fresh pig skin, twill jean
cloth, Whatman #1 blotter paper, and Whatman #10 Benchkote. Fresh pig skin was the most
accurate overall simulant tested, while the twill jean and blotter paper were more accurate from 2
to 3 ft, and the Benchkote was more accurate at 3 to 4 ft.
Glattstein et al.[14] examined the feasibility of applying adhesive lifters to the entrance
bullet wound on human body surfaces to visualize the total nitrite patterns, as was reported for
clothing and other exhibits above[12,13]. Figs. 5, 6, 7, and 8 demonstrate two cases in which it
was impossible to observe visually/microscopically gunpowder residues around bullet entrance
holes in the cadavers; however, total nitrite patterns were visualized on the adhesive lifters. In the
case of a decomposed body (Fig. 5), a gunshot wound was found in the neck. Due to the blackish
discoloration of the skin, the presence of soot or gunpowder tattooing could not be observed.
However, the visualized total nitrite pattern of about 5 cm in diameter (Fig. 6) indicated a close-
range shot. In the second case (Fig. 7), an entrance gunshot wound was found to the left parietal
of the cadaver. No gunpowder particles were observed visually on hair before shaving, and no
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FIGURE 5. The head of a decomposed corpse; the arrow indicates the gunshot wound.
FIGURE 6. Black and white photograph of the visualized total nitrite pattern on the adhesive lifter applied to the gunshot wound of
Fig. 5. The location of the bullet entrance hole is marked with a circle.
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FIGURE 7. Gunshot wound at the head after shaving.
gunpowder tattooing was observed after shaving. The total nitrite pattern (Fig. 8) that was
visualized on the adhesive lifter (that was applied before shaving) indicated a close-shot range.
Stahling and Karlsson reported a similar method for lifting and visualizing gunpowder residues
from skin[29].
INSTRUMENTAL METHODS
X-ray fluorescence (XRF), atomic absorption spectroscopy (AAS), and neutron activation
analysis (NAA) are the instrumental methods used by some laboratories to estimate the range of
shooting[2].
In recent years, with the advent of the micro-XRF technology and its increasing use in
forensic science for the elemental analysis of trace evidence, some of the laboratories examined
its feasibility for shooting distance estimation[30,31]. Flynn et al.[30] evaluated the technique
(Kevex Omicron micro-XRF) for the elemental analysis of GSR. They found that micro-XRF can
detect GSR particles on the target substrate if the shooting distance is less than 30 cm. At greater
distances, they could not detect GSR particles by this technique around the bullet wipe.
Charpentier and Desrochers[31] used a similar instrument to analyze GSR from lead-free
ammunition in which the lead in the primer was replaced with strontium and the bullet was plated
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FIGURE 8. Black and white photograph of the visualized total nitrite pattern on the adhesive lifter applied on the hairy area of the
wound (before shaving) in the Fig. 7. The location of the bullet entrance hole is marked with a circle.
with copper (TMJ). They found that the method allows the detection and quantification of
strontium residues on the target up to a distance of 45 cm.
Brown et al.[32,33] studied the feasibility of an automated image analysis (IA) technique for
shooting distance estimation. In the first study[32], they developed an IA procedure to measure
the amount (number and area) of GSR particles around a gunshot wound. Measurements of GSR
from test firings into goat hide were enhanced by using Alizarin Red S to stain the barium and
lead components. A comparison was made between the amount of GSR detected on the stained
skin sections and backscatter electron micrographs of the same sections. No significant
differences were found between the two. Preliminary results indicated that there was a nonlinear,
decreasing relationship between firing range and the amount of deposited GSR and that there was
significant variation in the amount of GSR from shot to shot for firing ranges up to 20 cm. The
second study[33] using the IA method was conducted on pig skin with a Ruger .22 semiautomatic
rifle with CCI solid point for shooting ranges between contact and 45 cm.
CONCLUSION
Recent developments in the methods of shooting distance estimation were primarily concentrated
on the proposed protocols for combining color tests for metal deposits (mostly lead and copper)
and for gunpowder residues around the bullet entrance holes. Lifting of the gunpowder residues
by an adhesive lifter from the targets and applying the color test (Griess test or its modifications)
on the lifter improves the methodology for clothing and introduces a new methodology for
powder patterns on the human body and on exhibits that cannot be processed in the laboratory.
Applying alkaline hydrolysis of the gunpowder residues before the color test may improve the
results dramatically for some brands of ammunition. Specific color tests and the application of
micro-XRF technique may assist in estimating shooting distances when lead-free ammunition is
used. Fresh pig skin was found to be the most accurate simulant for human skin with regards to
visual/microscopic examinations of the GSR residues.
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In spite of those developments, some major inherent problems remain unsolved. Among
these are, first, the maximum shooting distance that may be estimated is limited by the maximum
range of GSR particles reaching the target and, second, the large variation in the amount of GSR
from shot to shot is reflected in poor precision of the methodology. There is also a need to
continue research on the assessment of the most accurate simulant materials for human skin with
regards to all possible tests for shooting distance estimation.
ACKNOWLEDGMENT
The authors would like to express their gratitude to A. Chaikovsky for his photography
assistance.
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100, 179–186.
This article should be referenced as follows:
Zeichner, A. and Glattstein, B. (2002) Recent developments in the methods of estimating shooting distance.
TheScientificWorldJOURNAL 2, 573–585.
Handling Editor:
Walter F. Rowe, Principal Editor for Forensics — a domain of TheScientificWorldJOURNAL.
... All types of smokeless gunpowder contain nitrogen, and its oxidation during the discharge of a firearm causes nitrites to form patterns of GSR at crime scenes. The most common test that forensic labs use to identify nitrite patterns when estimating shooting distance is the Modified Griess Test (2,3). ...
... The Modified Griess Test (MGT) is an indicator test that detects the presence of nitrite ions in a solution (1,2,4). This detection is marked by the formation of a pink violet color called an azo dye. ...
... The forensic examiner is called Emerging Investigators same fabric. Another study reviewed previous shooting distance research and concluded that the MGT was the most common and accepted way to analyze nitrite patterns on fabric (2). ...
Article
At a crime scene, the presence and pattern of gunshot residue can help forensic scientists piece together the events that occurred. To assist this, we determined the relationship between shooting distance and nitrite residue patterns left on fabric targets. Using the Modified Griess Test, we also investigated whether fabric type plays a role in gunshot residue (GSR) amounts. Cotton and polyester targets were shot from five different distances, and the targets were processed using the Modified Griess Test to measure the nitrite components of the GSR particles. An image processing program called ImageJ was used to approximate the total area of the residue. Results show that from 0 cm to 25 cm away, there was a rapid increase in GSR, but beyond 25 cm, there was a decrease in GSR, which is consistent with previous studies. Also, fabric type played a significant role in GSR patterns, with polyester fabrics holding more GSR on average than cotton at 25 cm, but less than cotton at 0 cm. The results of this study can potentially provide new and innovative ways to determine shooting distances and GSR patterns on different fabric types.
... GSR deposited around the opening at the entrance could be detected even visually, in cases, when the clothing is in bright colours. However, in majority cases the clothes or the objects in which the projectile penetrated are dark in colour, and hence the GSR pattern is difficult to be visualized, requires the application of colour chemical tests [25,26] or analytical instrumental techniques such as millimetre-X-ray spectrometry [27,28], imaging in infrared light [29,30] and SEM-EDX that proves the presence of GSR and reveals details about their content and distribution [31][32][33][34][35]. ...
... For this purpose, the reference test firing should be performed using the suspect weapons and ammunition of the same brand and production lot that was used in the event, whenever possible. Test firings should be preferably carried out on a target coated with the same or very similar material as the garment or the object, on which the firing was made [25]. In cases, when the firearm has not been found, it would be necessary to provide the projectile or the cartridge, to get some directions for the type of firearm used in the crime. ...
Article
The subject of this research was the inorganic gunshot residue component collected from shooting patterns obtained on woven cotton cloth using a Pietro Beretta model 70 pistol, cal. 7.65 mm and Serbian ammunition for the following muzzle-to-target distances: 25, 50, 75, 100 and 125 cm. For each distance, three rounds of shooting were performed. Particles were lifted within a 10 cm radius of the projectile entrance and automatically analyzed using a scanning electron microscope coupled with an energy dispersion X-ray spectrometry. The obtained data on the populations of particles were analyzed taking into account their numbers, chemical classes and sizes. The results showed an apparent maximum incidence within all particles containing barium at about 50 cm distance. Also, lead particles revealed a distinct behaviour, being dominant at a 25 cm distance, falling below the other chemical classes, and finally becoming dominant again at 125 cm. The analysis of the frequency of occurrence of particles sorted according to their sizes confirmed that the small particle population is the largest, and their distribution in function of the equivalent circle diameter is exponential-like. The obtained results provided knowledge on the distribution of particles in the vicinity of the tested firearm and ammunition cal. 7.65 mm which generally corroborates with similarly studied GSR distributions obtained for the use of pistols cal. 9 mm. This information, together with the examinations of gunshot damages and other types of residues such as soot or unburned propellant grains may support qualitative inferences on shooting distance estimation, especially in cases, when the firearm and cartridges are not available to perform test shooting. In such cases even roughly estimated shooting distance can be helpful, e.g. for confirming or excluding the possibility of self-inflicted injuries or suicide and infer on the mutual position of the shooting stage actors. An example of casework that illustrates intermediate shooting distance estimation is presented.
... This indicates that a person near the projectile or bullet path may be exposed to GSR. The GSR distribution and quantity on the target(s) is also influenced by the distance between the firearm and the impacted surface and can thus be used to estimate the shooting distance (Bartsch et al., 1996;Marty et al., 2002;Zeichner & Glattstein, 2002). Some GSR are additionally carried out with the bullet and can be found at entrance (and sometimes also at exit) holes (Brown et al., 1999;Merli et al., 2019; Box 1). ...
Article
Full-text available
Gunshot residues (GSR) are routinely exploited by forensic scientists in the investigation of firearm‐related events. While many new techniques are daily reported in the literature for the analysis of GSR, there is still a significant lack of data on the transfer, persistence, and prevalence of GSR. Such fundamental knowledge is essential to fully exploit the information potential of GSR for investigation or in Court. This article provides an overview of the relevant questions related to GSR, more particularly to infer about the trace's origin (i.e., is it from a firearm discharge?) and the activity that caused transfer (e.g., primary, secondary, or subsequent transfer). GSR production and composition will be briefly described, considering both inorganic and organic components. Then, the available knowledge about the primary transfer, the secondary transfer, and the persistence of GSR will be outlined, as well as the prevalence (background level) of the targeted elements and/or compounds in the environment, more particularly on the hands of people unrelated to firearm incidents. Finally, the methods developed for the collection, analysis, and interpretation of GSR will be discussed. A holistic approach combining fundamental forensic science knowledge about GSR transfer, persistence, and prevalence together with other available information is discussed as a path forward to increase the relevance and value of the GSR trace in practice. This article is categorized under: Crime Scene Investigation > From Traces to Intelligence and Evidence Forensic Chemistry and Trace Evidence > Trace Evidence Forensic Chemistry and Trace Evidence > Explosive Analysis
... [16]. Research with the diffusion-contact method [17] is based on the qualitative determination of metallization products formed as a result of high temperatures and pressures and deposited on the target [18]. This method allows you to determine most of the known metals: copper, nickel, iron, lead, and several others. ...
Article
Full-text available
A method of mathematically processing the digital images of targets is developed. The theoretical and mathematical justification and the experimental validation of the possibility of estimating the amount of gunshot residue (GSR) and determining the GSR distribution over the target on the basis of its digital image is provided. The analysis of the optical density in selected concentric rings in the images reveals the radial dependence of soot distribution in the cross section of a gas–gunpowder jet. The analysis of the optical density in selected sectors of the circle reveals the angular dependence of the soot distribution in the gas–gunpowder jet cross section. It is shown that the integral optical density averaged over a selected area in the target image characterizes the mass of GSP deposited on it. It is possible to quantify the differences in the radial and angular distributions of the thickness of the GSR layer on various targets obtained both with the help of weapons of different types at the same distances and with the help of weapons of the same type at different distances, by calculating the distribution of optical density on their digital images.
... Analytical techniques based on spectroscopy have found utility in GSR analysis with promising results (Barth et al. 2012;Zuzanna Brozek-Mucha 2014;Cecchetto et al. 2011;Leiva et al. 2019;Santos et al. 2007;Zeichner 2003;Zeichner and Glattstein 2002). Particularly, the coupling of scanning electron microscope with energy-dispersive X-ray spectroscopy (SEM-EDS) has emerged as the technique of choice (Zuzanna Brozek-Mucha 2014;French and Morgan 2015). ...
Article
Full-text available
Background The determination of the shooting distance using gunshot residue (GSR) analysis is crucial in the investigation and reconstruction of firearm-related crimes. However, the conventional chemographic method for GSR analysis is destructive and has limited sensitivity and selectivity. While the spectroscopic method has potential in GSR analysis for crime investigation, there is a current lack of consistency in the spectroscopic results obtained for shooting distance estimation via GSR analysis. Addressing such limitations will enhance the forensic capabilities of law enforcement and provide an added advantage to crime laboratories during an investigation. It will also reinforce the use of such spectroscopic data in a criminal investigation. Main text We obtained all peer-reviewed articles relevant to shooting distance estimation from searching Scopus, Web of Science, PubMed, and Google Scholar databases. We specifically searched the databases using the keywords “shooting distance,” “range of fire,” “gunshot residue,” “firearm discharge residue,” and “firearm-related crime” and obtained 3811 records. We further filtered these records using a combination of two basic keywords “gunshot residue” and “shooting distance estimations” yielding 108 papers. Following a careful evaluation of the titles, abstracts, and full texts, 40 original peer-reviewed articles on shooting distance estimation via GSR analysis were included in the study. The forgoing included additional sources ( n = 5) we obtained from looking through the reference lists of the forensic articles we found. Short conclusion This paper discusses the current scope of research concerning the chemographic and spectroscopic analysis of GSR for shooting distance estimation. It also examines the challenges of these techniques and provides recommendations for future research.
... As of today, the macroscopic and morphologic evaluation of the bullet wound and the surrounding skin and tissue for imprints, soot, powder tattooing, bruises, etc. in combination with a gunshot residue (GSR) analysis still appears to be the most productive approach for reliable differentiation between certain distances [11]. Particularly, the detection, quantification, and correlation of GSR with the shooting distance has been (with a focus on staining, e.g., [27]) and still is a promising field of research, including GSR detection via micro-CT [28] and the analysis of inorganic GSR [29] by emission spectrometry and mass spectroscopy, which, however, require advanced lab equipment. Hlavaty et al. performed a microscopic, histological analysis of the tissue surrounding the bullet entry site to estimate the shooting distance but also concluded that this approach is not suitable for forensic routine analysis [30]. ...
Article
Full-text available
In molecular ballistics, where traces originating from the use of firearms against biological targets are investigated, “backspatter” traces are of particular importance. This biological material comprising blood and tissue from the victim is propelled back from the bullet entry site towards the direction of the shooter and can consolidate and persist on the inner and outer surfaces of the firearm, from where it can be collected and analyzed. Thus, a connection between the weapon and the victim can be established solely by molecular biological trace analysis. For the criminalistic investigation of gun-related crimes, the determination of the distance between the weapon and the victim can be of critical importance in reconstructing the circumstances of a crime. In this study, we investigated possible correlations between the shooting distance and the amount of backspatter in/on the used firearm. To this purpose, we employed a previously established skull model and performed shootings in triplicates from various distances up to 50 cm with two types of handguns (pistol and revolver). Backspatter was collected from various sampling locations, and DNA contents were quantified. A post-shooting wound channel evaluation was conducted by optical and radiological evaluation. The obtained DNA yields varied considerably between replicates from the same and from different distances. In contrast, apart from contact shots, no meaningful differences were observable in wound channel evaluations. In summary, no meaningful correlation between backspatter distribution and DNA yields, the shooting distance and the condition of the wound channel could be established.
... Intermediate range gunshot wound is one in which the muzzle of the weapon is held away from the body at the time of discharge, but is still close so that gunpowder expelled from the muzzle can produce "powder tattooing" of the skin [4]. ...
Article
Full-text available
Introduction/Objective. Gunshot residue (GSR) on the skin of a victim are important evidence, with far better precision, for reconstructive questions in the forensic investigation of cases involving gunshot wounds. The aim of this experimental study was to analyze if there was any significant difference in macroscopic characteristics of wounds that were caused with different types of weapons from three different distances. Methods. This study was conducted at the Department of Ballistic and Mechanoscopic Expertise, Federal Police Directorate. Experiments were done on pigskin and 55 samples were made. Shooting was conducted using a system for safe firing. Samples of the pigskin were shot by firing projectiles from four different weapons and from three different distances, (contact wound, five centimetres and 10 centimetres). Results. At the contact range, wounds caused by automatic rifle had horizontal, vertical diameters larger than those made by pistols. Diameters on the wounds that were caused with different pistols, were similar. At the range of five centimetres, the narrowest part of contusion ring significantly differs even through pistol wounds. Diameters at the range of 10 centimetres are in favor of these results. Gunpowder residue scattering area was statistically different depending of type of weapon (p = 0.004). Conclusion. Wound diameters and surface area are useful for differentiation between pistol and rifle caused wounds. It is unsecure method for determination of pistol caliber or fire range. GSR have much greater potential for future analyses, but even GSR cannot be used to determine pistol caliber.
Chapter
Full-text available
Criminal activities have their footprints from time immemorial and nature of crime has drastically changed over a period of time. There is neither a geographical boundary, nor technical limitations. Moreover terrorist’s activities, drug trafficking eco-crimes, high-profile crimes, robbery hit and run cases, building collapse, petroleum products adulteration are some of latest forms of crimes. In last 20 years, scanning probe microscopes have emerged as an essential technique in various fields, and atomic force microscope (AFM) is most commonly used scanning probe technique which has shown its wide range of application in examination of various evidences encountered on crime scene. Major advantages of AFM involve its high resolution in three dimensions, and sample is not necessary to be conductive and it does not need to be operated within a vacuum. It helps in studying a large range of topographies and many types of materials can be imaged under it. Evidences such as blood, fibers, hair, soil, finger prints, gunshot residue, pollen, etc. found on crime scene at nano- or micro-level can be examined under AFM. The chapter describes applications of AFM with respect to its application in examination of evidences that can help in bringing justice.
Article
This work presents two simple methods for estimating the firing distance from the gunshot residues (GSRs) on fabric targets. Four types of fabric targets, namely twill weave denim cotton-polyester (80/20), jersey knitting 100% cotton, plain weave cotton-polyester (80/20) and plain weave cotton-polyester (60/40), were employed. The firing tests were carried out using these white fabrics as targets at distances of 5 to 100 cm, respectively. In the first method, digital images of the black GSRs on fabric materials were recorded inside an illuminated box and the inverted gray intensity values were plotted against the firing distances. Since the plots of all fabrics are not significantly different, the estimation of firing distance employs the same exponential curve for all test fabrics. Although simple, the imaging method is not suitable for dark-colored materials. A chemical-based method was therefore developed as an alternative method. In the second method, a small disposable microfluidic paper-based analytical device (μPAD) was employed for detecting Pb(II) extracted from the GSRs. The μPAD method uses the measurement of the length of a narrow band of a pink color resulting from reaction between rhodizonate reagent and the Pb(II) extract. The plots indicated that the data of thick denim material are significantly different to other test fabrics which are much thinner. These three fabrics share the same estimation curve. However, it is recommended that the separate estimation curve for denim materials must be used. Both methods are suitable for short range firing distance, no further than 60 cm, since at greater distances the inverted gray intensity and the ‘band-length’ methods are unable to detect the GSRs.
Article
Full-text available
Le but de cette recherche est d'étudier les phénomènes physiques affectant les résidus de tir et engendrés lors de la manipulation des habits par le personnel médical. Une standardisation précise de tous les aspects des manipulations effectuées sur un blessé étant difficile à définir, les essais ont été réalisés en laboratoire en tenant compte le plus possible des conditions d'une intervention réelle. Les résidus de tir ont, dans un premier'temps, été observés à l'oeil nu, puis mis en évidence au moyen du test de Griess modifié; le test au rhodizonate de sodium s'étant révélé inadapté à l'évaluation de la distance de tir. Les manipulations médicales entraînent des pertes des résidus visibles à l'oeil nu et des résidus nitrés de l'ordre de 30 à 40%; de plus on n'observe pas de différence entre le devant et le dos du vêtement et la densité des particules nitrées est plus importante que celle des particules visibles à l'oeil nu. Les résultats indiquent que l'évaluation de la distance de tir après les manipulations médicales doit être faite prioritairement aux abords de l'orifice d'entrée du projectile.
Book
1 Introduction.- 2 General Section.- 2.1 Ammunitions.- 2.1.1 Normal Ammunition.- 2.1.1.1 Primer Ingredients.- 2.1.1.2 Powder.- 2.1.1.3 Bullets and Cases.- 2.1.2 Shot Shells (Shotgun Cartridges).- 2.2 Sequence of Events During Firing.- 2.2.1 Diagonal Shots, Deviations from the Normal Pattern of Powder Soot Blackening.- 3 Classification of Shot Range Zones.- 3.1 Contact Gunshot (Shot with Muzzle Contact).- 3.1.1 Contact Shot on Naked Skin.- 3.1.1.1 Muzzle Imprint.- 3.1.1.2 Soot in the Bullet's Track.- 3.1.1.3 Powder Particles in the Entrance Hole and the Bullet's Track.- 3.1.1.4 Remarks on the Ranges at Which the Term Contact Shot is Valid.- 3.2 Intermediate Range Gunshot.- 3.3 Distant Gunshot.- 4 Qualitative Detection of the Signs of a Close Range Shot.- 4.1 Detection of Powder Tattooing.- 4.1.1 Diphenylamine-Sulphuric Acid (DS) Reaction.- 4.1.2 Lunges Reagent.- 4.2 Detection of the Soot Element Pb.- 5 Morphological Methods of Shot Range Determination.- 5.1 General Principles.- 5.2 Infrared Photography.- 5.3 Sheet Printing Methods, Chemical.- 5.3.1 Sheet Printing Method After Walker and also Mayer and Wolkart.- 5.3.2 Sheet Printing Method After Leszczinski.- 5.3.3 Sheet Printing Method After Suchenwirth.- 5.4 Sheet Printing Method, Physical (Autoradiography).- 5.5 Determination from Powder Tattooing.- 5.6 Imaging with X-Ray, X-Ray Fluorescence.- 6 The Sampling Test Method for the Quantitative Determination of Shot Range.- 6.1 Initial Remarks and Underlying Principles.- 6.2 Emission Spectrum Analysis (ESA).- 6.2.1 General Comments.- 6.2.2 Choice of Lines for Antimony and Iron.- 6.2.3 Sample Taking.- 6.2.4 Carbon Electrodes, Excitation Conditions.- 6.2.5 Spectrograph.- 6.2.6 Extending the Distance of the Shot Range Determination.- 6.3 Atomic Absorption Spectrography (AAS).- 6.3.1 General Comment.- 6.3.2 Apparatus, Detection Limits.- 6.3.3 Taking the Samples, Preparation for Testing.- 6.3.4 Comments on the Measuring Technique, Producing a Calibration Curve.- 6.4 Neutron Activation Analyses (NAA).- 6.4.4 General Comments and Principle.- 6.4.2 Method, Results.- 6.5 Polarography.- 6.6 Other Methods of Shot Range Determination.- 6.6.1 Range Determination using the Bullet-Wipe Ring.- 6.7 Possible Errors in Shot Range Determination.- 6.7.1 The Vinogradov Phenomenon.- 6.7.2 Back-Scattering Effect.- 6.7.3 "Powder Soot Blackening" from Fragmentation of Bullets ("Ghost Powder Soot Blackening").- 6.7.4 Interference with the Detection of Soot Elements due to Various Physical and Chemical Effects.- 6.7.5 Changes in the Pattern of Powder Soot due to a Muzzle Silencer.- 7 Shot Range Determination for Shotguns.- 7.1 General Remarks.- 7.2 Characteristics of the Barrel, Choke.- 7.3 Shot Patterns-The Diameter of the Shot Pattern as a Function of the Range and Other Parameters.- 7.3.1 Theory.- 7.3.2 Experimentally Determinated Values of ? as a Function of the Shot Range and Other Parameters.- 7.4 Practical Procedures of Shot Range Determination for Shotguns.- 8 References and Further Readings.- 9 Subject Index.
Article
In this study the sheet printing method (SPM) for determination of shooting distance has been modified. Instead of cellulose hydrate foil, a plastic-based photographic paper was used as a substrate for transfer of metallic gunshot elements from cloth. The modified sheet printing method (MSPM) has been successfully tested in more than 100 shooting experiments. This technique saves time and has several additional advantages in comparison with the SPM method.
Article
The effects of water-soaking on firing distance estimations, employing quantitative determinations of gunpowder and metals around the bullet's entrance hole, were studied. The main finding was that, since the precision of the quantitative determination is poor, the existing statistical spread cancels out a potential effect of the target soaking. None the less, the prevailing factor is the firing distance, when increments of about 25 cm are clearly distinguishable, in both dry and water-soaked targets.
Article
'Stellate' or 'cruciform' tears of clothing are conventionally believed due to contact or close-range firearm entrance wounds. However, there are no published studies that actually document and confirm this observation. A Remington Nylon 11 .22-caliber rimfire bolt-action rifle, a Colt Woodsman .22-caliber rimfire auto-loading pistol, a Winchester Model 94 .30-30 Winchester lever-action rifle, and a Remington Model 870 12-gauge pump- action shotgun were test-fired at tight contact, loose contact, 2 cm, 4 cm, 8 cm, 15 cm, 30 cm, and 6 m ranges, using cotton denim, cotton broadcloth, and cotton jersey as targets. The .22-caliber rifle did not produce stellate tearing in these fabrics at any range. The .22-caliber pistol always produced stellate tears at tight contact and loose contact ranges; non-stellate defects were produced by this pistol at ranges of 2 cm or greater. The .30- 30 Winchester rifle produced stellate tears at all contact and close ranges up to and including 8 cm. The 12-gauge shotgun only produced stellate tears at loose contact, but was not tested at all ranges. Stellate defects were not produced by any firearm, in any fabric, at ranges greater than 8 cm. These results are specific to the firearms, ammunition, fabric, and conditions selected, and may not reflect findings in situations involving other firearms, projectiles, ranges, or fabrics.
Article
In the Dutch Forensic Laboratory firing range is determined by means of a chemographical method. The applied method produces colors with the elements lead and barium in conventional ammunition. This method cannot be applied for the determination of the firing range of leadfree ammunition. Because of developments in the eighties and the increasing use of leadfree ammunition, a new method with another coloring reagent has been developed. Elements present in the gunshot residues of, for example, 9 mm para Action-3 Sintox ammunition used by the Dutch police forces, are copper, zinc and titanium. Our contribution to the method for the determination of the firing range is a combination of the material cellophane film, the coloring reagent zincon and the design of a simple stretching device. Dependent on weapon, ammunition and clothing a firing range up to about 1.5 m can be determined by means of this method. To conclude, a survey is given of the shoot-outs investigated in The Netherlands in which leadfree ammunition was used.
Article
The review deals with scientific methods for determining shooting distance. The different procedures are explained, their advantages and disadvantages are discussed. The methods are divided into chemographical processes and spectroscopic techniques. Special emphasis is given to the methods proven to be especially useful in daily work, but methods used in basic research are briefly described as well. Furthermore, attention is paid to newly developed ammunitions. In addition, a survey is given on the chemical elements found in gunshot residences (GSR). Copyright © 1990 Central Police University.