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Introduction
Paleo-climate, stable isotopic geochemistry, atmopsheric chemistry
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Publications (18)
Atmospheric reactive nitrogen cycling is crucial for maintaining the atmospheric oxidation capacity of background atmosphere on the Tibetan Plateau , with nitrous acid (HONO) and particulate nitrite (NO2-) as important intermediates. During an eleven-day field campaign at the Base Camp of Mt. Qomolangma in spring of 2022, we observed significant en...
Stable isotopes of atmospheric nitrate (NO3−) are valuable tools for tracing nitrogen sources and processes; however, their signals in ice core records are often disrupted by post-depositional processes. The ice core from the southeastern Dome (SE-Dome) in Greenland is a potential record of variations in atmospheric chemistry that has experienced l...
Ice-core water isotopes contain valuable information on past climate changes. However, such information can be altered by post-depositional processing after snow deposition. Atmosphere–snow water vapor exchange is one such process, but its influence remains poorly constrained. Here we constructed a box model to quantify the atmosphere–snow water va...
Comprehensive evaluation of the effects of post-depositional processing is a prerequisite for appropriately interpreting ice-core records of nitrate concentration and isotopes. In this study, we developed an inverse model that uses archived snow/ice-core nitrate signals to reconstruct primary nitrate flux (i.e., the deposition flux of nitrate to su...
The fine particulate matter (PM2.5) in Chinese megacities has declined significantly after the implementation of strict mitigation strategies since 2013. However, the concentration of wintertime nitrate in PM2.5 (p‐NO3‐) has only changed slightly and became the dominant inorganic component despite considerable precursor emission reductions. Discern...
The air quality in Chinese megacities has been improved as indicated by large decreases in fine particulate matter (PM2.5) due to remarkable decreases in key precursors (e.g., SO2, NOx) after the implementation of strict mitigation strategies. However, nitrate concentrations in PM2.5 (p-NO3-) have not decreased and mass fractions of p-NO3- in PM2.5...
Ice-core water isotopes contain valuable information on past climate changes. However, such information can be altered by post-depositional processing after snow deposition. Atmosphere-snow water vapor exchange is one of such processes, but its influence remains poorly constrained. Here we constructed a box model to quantify the atmosphere-snow wat...
Comprehensive evaluation of the effects of post-depositional processing is a prerequisite for appropriately interpreting ice-core records of nitrate concentration and isotopes. In this study, we developed an inverse model that uses archived snow/ice-core nitrate signals to reconstruct primary nitrate flux and its isotopes (δ15N and Δ17O). The model...
Column ozone variability has important implications for surface photochemistry and the climate. Ice-core nitrate isotopes are suspected to be influenced by column ozone variability and δ15N(NO3-) has been sought to serve as a proxy of column ozone variability. In this study, we examined the ability of ice-core nitrate isotopes to reflect column ozo...
Being major species of atmospheric reactive nitrogen, nitrogen oxides (NOx = NO + NO2) have important implications for ozone and OH radical formation in addition to nitrogen cycles. Stable nitrogen isotopes (δ15N) of NOx have been sought to track NOx emissions and NOx chemical reactivities in the atmosphere. The current atmospheric NOx collection m...
The effect of post-depositional processing on the preservation of snow nitrate isotopes at Summit, Greenland, remains a subject of debate and is relevant to the quantitative interpretation of ice-core nitrate (isotopic) records at high snow accumulation sites. Here we present the first year-round observations of atmospheric nitrate and its isotopic...
Column ozone variability has important implications for surface photochemistry and climate. Ice-core nitrate isotopes are suspected to be influenced by column ozone variability and δ15N(NO3-) has been sought to serve as a proxy of column ozone variability. In this study, we examined the ability of ice-core nitrate isotopes to reflect column ozone v...
The effect of post–depositional processing on the preservation of snow nitrate isotopes at Summit, Greenland remains a subject of debate which hinders the interpretations of ice–core nitrate concentrations and isotope records. Here we present the first year–round observations of atmospheric aerosol nitrate and its isotopic compositions at Summit, a...
Stable isotopic constraint and observationally coupled atmospheric chemistry model are two robust means to identify the oxidation mechanisms for atmospheric particulate nitrate (NO3⁻) production. However, large discrepancies between the two approaches have been noted in the heavily polluted environments of North China Plain (NCP). Herein, daily PM2...
Atmospheric information embedded in ice-core nitrate is disturbed by post-depositional processing. Here we used a layered snow photochemical column model to explicitly investigate the effects of post-depositional processing on snow nitrate and its isotopes (δ15N and Δ17O) at Summit, Greenland, where post-depositional processing was thought to be mi...
Atmospheric information embedded in ice-core nitrate is disturbed by post-depositional processing. Here we used a layered snow photochemical column model to explicitly investigate the effects of post-depositional processing on snow nitrate and its isotopes (δ15N and Δ17O) at Summit, Greenland where post-depositional processing was thought to be min...
We investigated the acidity and concentrations of water-soluble ions in PM2.5 aerosol samples collected from an urban site in Beijing and a rural site in Gucheng, Hebei Province from November 2016 to January 2017 to gain an insight into the formation of secondary inorganic species. The average SO42–, NO3–, and NH4⁺ concentrations were 8.3, 12.5, an...