Zahra Mazloomi

Zahra Mazloomi
Chimie ParisTech · Institut de Recherche de Chimie Paris

Postdoctoral Researcher

About

7
Publications
357
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119
Citations

Publications

Publications (7)
Article
Full-text available
We report the effect of replacing the pyridine group in the chelating trz Ir–water oxidation catalysts by a benzoxazole and a thiazole moiety. We have also evaluated if the presence of bidentate ligands is crucial for high activities and to avoid the decomposition into undesired heterogeneous layers. The catalytic performance of these benzoxazole/t...
Article
We studied for the first time the potential of novel and simple Ir/thioether-NHC complexes in the asymmetric hydrogenation of unfunctionalized olefins and cyclic β-enamides. For comparison, we prepared and applied the analogues thioether-phosphinite/phosphite complexes. We found that the efficiency of the new Ir/thioether-NHC catalyst precursors va...
Article
The inside cover picture, provided by Oscar Pàmies, Piet W. N. M. van Leeuwen, Montserrat Diéguez and co‐workers, illustrates that chiral palladium complexes containing phosphite‐oxazoline ligands enable the effective asymmetric intermolecular Heck coupling of several substrates and triflate sources. The kinetic studies and the Hammett plot analysi...
Article
This study identifies new phosphite-oxazoline ligands that have been successfully applied in the palladium-catalyzed intermolecular asymmetric Heck reaction. The design of the new phosphite-oxazoline ligands derives from a previous successful generation of phosphine-oxazoline ligands, by replacing the phosphine group with several π-acceptor biaryl...
Article
A set of iridium(I) and iridium(III) complexes is reported with triazolylidene ligands that contain pendant benzoxazole, thiazole, and methyl ether groups as potentially chelating donor sites. The bonding mode of these groups was identified by NMR spectroscopy and X-ray structure analysis. The complexes were evaluated as catalyst precursors in tran...
Article
The synthesis and characterisation of iridium(III) and ruthenium(II) complexes bearing pendant hydroxy- and ether-wingtip substituents is described. Both monodentate and C,O-bidentate binding modes were observed for these O-functionalised triazolylidene complexes. The two bonding modes are interconvertible, which demonstrates the hemilability of th...
Article
A variety of vinylic bromides and iodides undergo smooth trifluoromethylation and pentafluoroethylation with RfH-derived CuRf (Rf = CF3, C2F5) to give the corresponding fluoroalkylated olefins. These reactions employing the low-cost CuRf reagents occur in high yield with excellent chemo- and stereoselectivity under mild conditions (23–80 °C). Cryst...

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