Article

Corrigendum to "Effect of Nano-gypsum on Mechanical Properties of Cement Admixed Marginal Silty Soil" [Construction and Building Materials 408 (2023) 133639]

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Abstract

Even though the chemical stabilization is by far the most common ground improvement technique, very few studies have been conducted on the joint incorporation of two or more additives (cement-nanogypsum mix) to stabilise soft soil. This study investigates the effect on the mechanical properties of cement-stabilised silty soft soil (CSS) using nano-gypsum (NG). Unconfined compression strength (UCS) test trials were conducted to achieve soft soil conditions. The effect of NG and cement on soft soil was investigated by performing Atterberg limit, compaction, UCS, and Direct shear tests. The soil was treated with four percentages (10%, 15%, 20%, and 25%) of cement and with three percentages (1%, 1.5%, and 2%) of NG by its dry unit weight. The test results showed that the plasticity index of the soil was reduced significantly by the addition of stabilizers (Cement-NG mix) making the soil stiffer. The compaction tests suggested that optimum cement content was 20% for CSS and for cement-NG mix maximum strength was achieved at cement: NG proportion of 20:1. The unconfined compression strength (UCS) was increased by 9.11 times in comparison to untreated soft soil at cement: NG proportion of 20:1.5. The direct shear test (DST) suggested that there was an increase in cohesion by 4.44 times in comparison to the untreated sample at the soil–cement-NG combination of 78.5: 20: 1.5. However, the angle of internal friction remained almost unchanged. The development of cementitious substances was confirmed through XRD spectroscopy. Microstructural and chemical properties were observed using combined FESEM-EDAX analysis and Fourier transform infrared spectroscopy (FTIR). The multivariate linear regression (MLR) predictive model was developed for the unconfined compressive strength and failure strain as a function of various parameters considered in the study. The test results demonstrated that the combination of cement and NG can result in remarkable improvement in the geotechnical properties of soft soil. The use of NG may also reduce the demand for cement in deep cement mixing technique, which eventually reduces the carbon footprint and renders the ground improvement technique, ecologically beneficial.

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Marble has been widely used as a construction material for many centuries. Due to its wide use, managing of marble wastes has become a pressing issue for authorities as of the environmental threat driven by its increased stockpiles in roadside or abandoned lands. This study investigates a new use of marble waste in weak field soils as subgrade application using additive based stabilization. Raw marble waste was first stabilized with Fly ash based – Portland Pozzolana Cement (PPC) having various PPC content (0.5 to 10%) to investigate the behaviour changes of physical and mechanical characteristics. Then, the modified matrix with cement (1% and 10%) was further stabilized using nano materials of 0.1% reduce Graphene Oxide (rGO) powder by weight in order to enhance the strength properties. The improvements in strengths and mechanisms were characterised using detailed morphological studies to identify new formations of elements, functional groups and microstructure changes during stabilization process. Results showed significant increase of strength in the modified matrix (800% increase of CBR and 3MPa increase of UCS from negligible strength) compared to raw marble waste due to the efficacy of adopted stabilization in the current study. Outcomes revealed that the novel marble matrix derived from this research using wastes and additives does not only indicate great potential in replacing weak subgrade soil which usually is the route problem for many road defects, but also provides an efficient solution for waste management crisis.
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Polymer-based nanocomposites due to their advantages such as corrosion resistance, adequate mechanical properties, and low cost are widely used in modern technologies. The increasing application of these nanocomposites, and hence their welding seems unavoidable. In this paper, a novel hot tool in the friction stir welding process is used for butt welding nanocomposite plates of 5 mm thick containing polypropylene, ethylene-propylene-diene monomerand Cloisite 15A. Response surface method is used to design experiments and determine the effect of process parameters such as tool rotational speed, welding speed, tool shoulder temperature, and clay content on weld tensile strength. The results show that although increasing clay content in the base material increases its tensile strength but decreases the weld tensile strength; such that in the specimens with 0, 3, and 6% clay content, the weld tensile strength equals 94, 80, and 61 percent of the respective base materials.
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The present study investigated the effect of zinc oxide (ZnO) nanoparticles on the geotechnical properties of lime-stabilized silty clay soil using uniaxial compressive strength, direct shear and Californian bearing ratio tests as well as scanning electron microscopy of the improved microstructure of the specimens. The optimum lime content of 6% increased the strength of the soil specimens. Tests on the specimens cured for 7 days showed that their strength increased with an increase in the soil cohesion and cement bonds. The ultimate strength was recorded at the optimum nano-ZnO content of 1.5. The nano-ZnO acted as a filler in the lime and ZnO-stabilized specimens, causing formation of smaller crystals and increasing reactivity, which increased the strength of the soil specimens. SEM micrographs revealed a more homogenous and finer microstructure with a lower surface porosity with the addition of nano-ZnO.
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In this study, the effect of nano-calcium carbonate (nano-CaCO3) as an additive to the cement paste was evaluated and quantified. Microstructure tests, experimental tests, and modeling were conducted to predict the cement paste’s rheological properties namely yield stress (yield point), shear stress limit, viscosity, and stress at the failure of cement at fresh and hardened stages. The cement paste modified with nano-CaCO3 was tested at a water-to-cement ratio of 0.35 with 0.45 and temperatures ranging from 25 to 75 ⁰C. The addition of nano-CaCO3 increased the shear stress limit and the yield stress (so) by 10.28 to 51.35% and 14.36 to 91.4%, based on the nano-CaCO3 content, w/c, and temperature of the test. TGA tests showed that the 1% nano-CaCO3 additive reduces the weight loss of the cement at 800 ⁰C by 76% due to interacting with the nano-CaCO3 with the cement paste. The nonlinear regressions (NLR) model and Artificial Neural Network (ANN) technical approaches were used for the qualifications of the flow of slurry and stress at the failure of the cement paste modified with nano-CaCO3. Based on the statistical assessments of R and RMSE, the rheological properties such as yield stress, plastic viscosity, shear stress limit and compressive strength of cement paste modified with nano-CaCO3 can be well predicted in terms of w/c, nano-CaCO3 content, temperature, and curing time using two different simulation techniques. Based on the statistical assessments such as coefficient of correlation (R), root mean square error (RMSE), the NLR model is the most effective model to estimate rheological properties and compressive strength of the cement and it is performing better than the ANN model.
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The durability and safety of cement-treated foundation in marine environment has been drawn close attention because many offshore, coastal and marine engineering are under construction in these years. Effect of compound nano-CaCO3 addition on strength development and microstructure of cement-stabilized soil in marine environment was studied in this paper by uniaxial compressive test and micro-structure analysis methods including X-ray Diffraction Analysis (XRD), Scanning Electron Microscopy (SEM) and Mercury Intrusion Porosimetry (MIP). Results showed that marine environment had great influence on the strength and durability of cement-stabilized soil and compound nano-CaCO3 addition could effectively improve the compressive strength of cement-stabilized soil at early and late age due to the nucleation and nano-filling function. Furthermore, compound nano-CaCO3 addition was helpful to reduce the corrosion speed and increase the compaction degree of cement-stabilized soil in marine environment.
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Various applications of nanocomposites were a good motivation to start a study on this wide spreading field of science. Current research is an investigation on incorporating different percentages of TiO2 nanoparticle as reinforcement to a base material which here is poly methyl methacrylate (PMMA). In this study various percentages of TiO2 (0.5, 1 and 2 wt%) were added to pure PMMA and effect of this combination on the mechanical properties of produced composite by performing several tests was investigated and compared to the base material. For producing samples, materials were compounded by melting compounding method using a twin screw extruder followed by injecting molding process. SEM images showed that almost all percentage of TiO2 nanoparticles have been mixed suitably through base matrix. Rockwell hardness R, impact and tensile tests were carried out on all specimens. Almost all of the results illustrated that combination of TiO2 nanoparticle with PMMA, improves mechanical properties of composite. The results also indicated amazing effect of TiO2 nanoparticles on improvements of impact and flexural strengths. Highest recorded impact strength showed 229% increase in samples containing 2 wt% nanoparticles compared to the base material.
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Combinations of cement kiln dust and fly ash were used to develop cementitious material through mechanochemical activation. Mixture combinations made with two different proportions were subjected to various grinding regimes to activate the material. Properties, including particle size distribution, initial time of set, heat of hydration, and compressive strength of the new material were determined. Mechanical grinding resulted in mechanochemical activation of the material, with vibratory grinding more effective than ball mill grinding. Activation was confirmed through X-ray diffraction analysis and no correlation was found between activation and the mean particle size of the material. Although not all the properties of the material tested were comparable to those of portland cement, the results indicate the potential for significant improvement.
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The evolution of nanotechnology provides materials with new properties and over the last years a lot of effort has been put to introduce nano-particles into cement pastes in order to improve their properties and to produce materials of better performance. In the present research work, nano-SiO2 produced by pyrolysis and with specific area of 200 m2/g has been added at different percentages (0%, 0.5%, 1%, 2% and 5%) to high-strength cement pastes. These pastes were tested for their mechanical and structural properties at different ages. Nanoparticles act as nuclei for crystallization and large, idiomorphic crystals of Ca–Si composition were formed assisting, up to a certain percentage, in producing materials with dense structure, reduced porosity and improved strength.