Stefano Dell'Orco

National Renewable Energy Laboratory | NREL

Co-processing bio-oils with petroleum derived feeds in the existing multi-trillion dollar refining and distribution infrastructure is an attractive option for introducing renewable energy into the fuels marketplace. Considerable research on co-processing bio-oils and vacuum gas oil (VGO) in fluid catalytic cracking units (FCC) using equilibrium cat...

To mitigate green-house gas (GHG) emissions, governments around the world are enacting legislation to reduce carbon intensity in transportation fuels. Coprocessing biomass and petroleum-derived liquids in existing refineries is a near-term, cost-effective approach for introducing renewable carbon in fuels and enabling refineries to meet regulatory...

A promising approach for supplementing petroleum-derived fuels to support reductions in green-house gas emissions is to convert abundant biomass feedstocks into renewable carbon-rich oils using pyrolysis. However, the resultant bio-oils contain various oxygenated compounds that can impart acidity, chemical and thermal instability, and immiscibility...

The scope of this work rests at the interface between food and energy sustainability. Thermochemical conversion of biomass is an attractive strategy for the production of low-cost biofuels, and bio-based...

Exploring the dynamic interaction of non-thermal plasma (NTP) with catalytic processes is critical to unravelling elusive catalyst structure–function relationships under NTP conditions, specifically dielectric barrier discharges (DBD). This study investigates the efficacy of operando diffuse reflectance infrared Fourier transform spectroscopy (DRIF...

Fast pyrolysis of biomass is a well-known opportunity for sustainable alternative fuel production for transport and energy. However, bio-oils from biomass pyrolysis are viscous, acidic bio-crudes that need further steps of upgrading before being used either as fuels or chemicals. A process that is complementary to bio-oil hydrotreatment or co-proce...

Slow pyrolysis of biomass represents a renewed opportunity to produce both bioenergy and high value co-products using modern technologies. The present work aims at valorizing the total outputs from slow oxidative pyrolysis: a process that convert the lignocellulosic feedstock without an external heat supply (hence an autothermal pyrolysis process)...

The quality of biocrudes from fast pyrolysis of lignocellulosic biomass can be improved by optimizing the downstream condensation systems to separate and concentrate selected classes of compounds, thus operating different technological solutions and condensation temperatures in multiple condensation stages. Scientific literature reports that fracti...

Hydrothermal depolymerization of lignin-rich streams (LRS) from lignocellulosic ethanol was successfully carried out in a lab-scale batch reactors unit. A partial depolymerization into oligomers and monomers was achieved using subcritical water as reaction medium. The influence of temperature (300–350–370 °C) and time (5–10 minutes) was investigate...

During ex situ catalytic fast pyrolysis (CFP) of biomass, the separation of reactive char and alkali/alkaline particulates from biomass pyrolysis vapors by hot-gas filtration (HGF) leads to improved vapor stability and quality. HGF in tandem with chemical tailoring (e.g., partial deoxygenation) of the clean pyrolysis vapors, denoted as catalytic ho...

Hydrothermal liquefaction of lignin-rich stream from lignocellulosic ethanol production at an industrial scale was carried out in a custom-made batch test bench. Light and heavy fractions of the HTL biocrude were collected following an ad-hoc developed two-steps solvent extraction method. A full factorial design of experiment was performed, investi...

The production of ethanol from no-food lignocellulosic material has now achieved full industrial scale, but a large amount of a very wet lignin-rich stream is also produced, which today is dried and burnt for heat and power generation. Finding a more profitable way to exploit this co-product stream is fundamental in order to improve the overall bio...

The present paper reports on the design of a pilot circulating fluidized bed combustor (CFB) for the conversion of lignin-rich residue derived from a second-generation bioethanol production plant. The designed combustor aims to improve the combustion efficiency of the lignin-rich residue, therefore increasing the heat recovery to partially cover th...

The study reported in this paper aims to valorize lignin-rich co-product from 2G ethanol processes as precursor in activated carbon (AC) manufacturing. In particular, hydrothermal carbonization (HTC) was investigated as a pretreatment step for producing suitable AC precursor, and to this end HTC of lignin-rich co-product was performed in a lab-scal...

Conversion of carbon contained in the solid residues (tars + biochar) derived from urban biomass gasification named herein TC would allow enhancing the yield of carbon species (CO/CO2) in synthetic gas. For this purpose, three low cost materials have been tested as possible catalysts: iron species (reduced Fe), bone meal (BM), and ashes (ash) recov...