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Citations since 2017
4 Research Items
Supporting information for "A 4H+/4e– Electron-Coupled-Proton Buffer Based on a Mononuclear Cu Complex" (10.1021/jacs.2c05454)
In this research article, we describe a 4H+/4e– electron-coupled-proton buffer (ECPB) based on Cu and a redox-active ligand. The protonated/reduced ECPB (complex 1: [Cu(8H+/14e–)]1+), consisting of CuI with 2 equiv of the ligand (catLH4: 1,1′-(4,5-dimethoxy-1,2-phenylene)bis(3-(tert-butyl)urea)), reacted with H+/e– acceptors such as O2 to generate...
In this research article, we report the synthesis and structural characterization of a family of first-row metal complexes bearing redox-active ligands with tunable H-bonding donors. We observed that these coordination complexes can adopt three different geometries and that they are stabilized by intramolecular multicenter H-bonding interactions, w...
In this research article, we describe the structure, spectroscopy and reactivity of a family of copper complexes bearing bidentate redox-active ligands that contain H-bonding donor groups. Single crystal X-ray crystallography shows that these tetracoordinate complexes are stabilized by intramolecular H-bonding interactions between the two ligand sc...