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36
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January 2016 - July 2022
Publications
Publications (36)
There is enormous interest around the development of an electric semi truck, and in order to understand the practical limitations imposed by the battery pack, a rigorous and thorough analysis considering battery metrics as well as vehicle design parameters is required. In this study, we find that an electric semi truck, such as the envisioned Tesla...
Electric vertical takeoff and landing aircraft have a unique duty cycle characterized by high discharge currents at the beginning and end of the mission (corresponding to takeoff and landing of the aircraft) and a moderate power requirement between them with no rest periods during the mission. Here, we generated a dataset of battery duty profiles f...
Batteries are central to modern society. They are no longer just a convenience but a critical enabler of the transition to a resilient, low-carbon economy. Battery development capabilities are provided by communities spanning materials discovery, battery chemistry and electrochemistry, cell and pack design, scale-up, manufacturing, and deployments....
Solid electrolytes are widely considered as the enabler of lithium metal anodes for safe, durable, and high energy density rechargeable lithium-ion batteries. Despite the promise, failure mechanisms associated with solid-state batteries are not well-established, largely due to limited understanding of the chemomechanical factors governing them. We...
Lithium-ion batteries can last many years but sometimes exhibit rapid, nonlinear degradation that severely limits battery lifetime. Here, we review prior work on “knees” in lithium-ion battery aging trajectories. We first review definitions for knees and three classes of “internal state trajectories” (termed snowball, hidden, and threshold trajecto...
Lithium-ion batteries can last many years but sometimes exhibit rapid, nonlinear degradation that severely limits battery lifetime. In this work, we review prior work on "knees" in lithium-ion battery aging trajectories. We first review definitions for knees and three classes of "internal state trajectories" (termed snowball, hidden, and threshold...
Lithium-ion batteries are the ubiquitous energy storage device of choice in portable electronics and more recently, in electric vehicles. However, there are numerous lithium-ion battery chemistries and in particular, several cathode materials that have been commercialized over the last two decades, each with their own unique features and characteri...
Improvements in rechargeable batteries are enabling several electric urban air mobility (UAM) aircraft designs with up to 300 mi of range with payload equivalents of up to seven passengers. Novel UAM aircraft consume between 130 Wh/passenger-mi and ∼ 1,200 Wh/passenger-mi depending on the design and utilization, compared to an expected consumption...
This manuscript presents an algorithm for individual Lithium-ion (Li-ion) battery cell state of charge (SOC) estimation in a large-scale battery pack under minimal sensing, where only pack-level voltage and current are measured. For battery packs consisting of up to thousands of cells in electric vehicle or stationary energy storage applications, i...
Electrochemical energy storage is central to modern society -- from consumer electronics to electrified transportation and the power grid. It is no longer just a convenience but a critical enabler of the transition to a resilient, low-carbon economy. The large pluralistic battery research and development community serving these needs has evolved in...
There are two major trends in batteries, (i) the resurgence of lithium iron phosphate (LFP) as the cathode material of choice and (ii) lithium metal batteries with a foil or in the anode-free configuration emerging as a competitive option over the conventional anode of a Li-ion battery. In this study, we perform a techno-economic assessment of pair...
Solid state electrolytes are widely considered as the enabler of lithium metal anodes for safe, durable and high energy density rechargeable lithium ion batteries. Despite the promise, failure mechanisms associated with solid state batteries are not well-established, largely due to limited understanding of the chemomechanical factors governing them...
In this article, we explore the techno-economic promises and challenges related to iron electrode systems, specifically in the iron-air system. We study the discharge-charge products of an iron-air system in an aqueous electrolyte using an iron-water Pourbaix diagram. Using the discharge-charge products from the Pourbaix analysis, we construct a pr...
Improvements in rechargeable batteries are enabling several electric urban air mobility (UAM) aircraft designs with up to 300 miles of range with payload equivalents of up to 7 passengers. We find that novel UAM aircraft consume between 130 Wh/passenger-mile up to ~1,200 Wh/passenger-mile depending on the design and utilization, relative to an expe...
Modern aircraft designs for “more electric” and “fully electric” aircraft have large battery packs ranging from tens of kWh for urban aviation to hundreds or thousands of kWh for commercial aviation. Such large battery packs require careful consideration of the safety concerns unique to aviation. The most pertinent safety concerns related to batter...
As the electrification of the transportation industry and growing adoption of these electric vehicles continues, the demand for charging infrastructure is increasing concurrently. Properly deploying this infrastructure requires that there exist models which can adequately estimate the performance of these vehicles under real scenarios. While there...
Electrodeposition and stripping are fundamental electrochemical processes for metals and have gained importance in rechargeable Li-ion batteries due to lithium metal electrodes. The electrode kinetics associated with lithium metal electrodeposition and stripping is crucial in determining the performance at fast discharge and charge, which is import...
Electrodeposition and stripping are fundamental electrochemical processes for metals and have gained importance in rechargeable Li-ion batteries due to lithium metal electrodes. The electrode kinetics associated with lithium metal electrodeposition and stripping is crucial in determining performance at fast discharge and charge which is important f...
In this work, we generate a battery performance and thermal dataset specific to eVTOL use-cases and develop a fast and accurate performance and degradation model around that dataset. We use a machine-learning based physics-informed battery performance model to break the typically observed accuracy-computing cost trade-off. We fit the aging paramete...
Weight, computing load, sensor load and possibly higher drag may increase the energy use of automated electric vehicles relative to human-driven electric vehicles, although this increase may be offset by smoother driving. Here, we use a vehicle dynamics model to evaluate the trade-off between automation and electric vehicle range and battery longev...
Weight, computational load, sensor load, and possibly higher drag may increase the energy use of automated electric vehicles (AEVs) relative to human-driven electric vehicles (EVs), although this increase may be offset by smoother driving. We use a vehicle dynamics model to show that automation is likely to impose a minor penalty on EV range and ha...
There has been considerable interest in the electrification of freight transport, however, there is uncertainty in the technological and economic competitiveness due to the size and the substantial costs associated with large battery packs. Here we analyze the trade-off between the initial investment and the operating costs to compare a Class 8 die...
There has been considerable interest in the electrification of freight transport, particularly heavy-duty trucks to downscale the greenhouse-gas (GHG) emissions from the transportation sector. However, the economic competitiveness of electric semi-trucks is uncertain as there are substantial additional initial costs associated with the large batter...
Modern automobiles are entirely controlled by electronic circuits and programs which undoubtedly exposes them to the threat of cyberattacks. Alongside, there is a potential for massive growth in electric vehicle (EV) adoption. The cyber vulnerabilities are magnified with electric vehicles because of the unique and critical risks that entail most EV...
There is an explosion of interest in the potential of developing a long-haul electric semi-truck, and this interest has been amplified by Elon Musk outlining potential plans for long-haul electric semi-trucks. In an earlier Viewpoint, we delineated the performance requirements of the batteries to enable long-range electric semi-trucks. We identified...
While the electrification of the transportation sector is underway with a consistently increasing market share, segments like light commercial vehicles (LCVs) have not seen any significant market penetration. The major barriers are primarily in the shortcomings in specific energy, power, and cost associated with Li-ion batteries. With an initiative...
While the electrification of the transportation sector is underway with a consistently increasing market share, segments like light commercial vehicles (LCVs) have not seen any significant market penetration. The major barriers are primarily in the shortcomings in specific energy, power, and cost associated with Li-ion batteries. With an initiative...
Electrical double layer capacitors (supercapacitors) were fabricated using activated carbon as the active material and polyvinylidine fluoride (PVDF) as a binder with a suitable conductive additive (MWCNTs) together in an optimized ratio. The supercapacitor cells were assembled using an aqueous solution of 0.5M Na2SO4 as the electrolyte. These cell...
Questions
Question (1)
I am asking in the context of capacity fade measurements.