Sadegh Rostamnia

Sadegh Rostamnia
Iran University of Science and Technology · Department of Chemistry

Professor
Mesoporous Material, Metal-organic Framework (MOF), H2 generation, Covalent Organic Framework (COF), Energy & Photocat.

About

236
Publications
28,148
Reads
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6,331
Citations
Citations since 2016
124 Research Items
5382 Citations
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201620172018201920202021202202004006008001,0001,200
201620172018201920202021202202004006008001,0001,200
Introduction
2021--->Adjunct Prof.Adjunct Prof. Tbilisi, Georgia 2020--->Adjunct Prof. Lublin University, Poland 2016-->Visiting Prof. NIMS, Japan 2011--->PostDoc- TMU- Prof. Ali Morsali 2009--->Visiting scholar at DICP-China 2010 Ph.D (honor)--->Tarbiat Modares University (TMU) 2006 MSc (honor)--->Tarbiat Modares University Res.: Mesoporous material, Magnetic nanocomposites, catalyst http://www.iust.ac.ir/content/65286/Rostamnia
Additional affiliations
September 2020 - present
Iran University of Science and Technology
Position
  • Professor (Full)
Description
  • Mesoporous Materials, Metal-organic Frameworks (MOFs), H2 generation, Covalent Organic Frameworks (COFs), Energy & Photocatalysis, Water splitting/Oxidation, 2D Nanomaterials, Organic-Inorganic Hybrid Catalysis, Photodegradation, Sustainable & Green Chemistry, Drug-like organic molecules.
January 2020 - October 2021
The University of Georgia (Tbilisi)
Position
  • Professor
Description
  • Nanomedicine, Drug-like Multicomponent reaction process
January 2020 - present
John Paul II Catholic University of Lublin
Position
  • Professor (Associate)
Description
  • Mesoporous Polymers, Surface-active Nanomaterials, Nanocatalysis, Hybrid Nanocomposites.
Education
September 2011 - October 2021
Tarbiat Modares University
Field of study
  • Metal-Organic Frameworks (MOFs) & Porous materials
October 2009 - July 2010
Dalian Institute of Chemical Physics
Field of study
  • Nanochemistry, Mesoporous materials, SBA-15, Cross-coupling reactions, Sustainable Energy.
September 2006 - November 2010
Tarbiat Modares University
Field of study
  • Organic Chemistry (Multicomponent reactions)

Publications

Publications (236)
Article
Full-text available
Nowadays, organically modified hybrid silica mesostructures are increasingly developing as the promising candidate in catalysis of various kinds of organic reactions and green chemistry. Among them, organic moieties with amine and sulphonic acid basis have taken a major part of this class. In this review, we have discussed recent advances of most c...
Article
Full-text available
In addition to isocyanide-based Ugi, Passerini, van Leusen, and Orru multicomponent reactions (IMCRs), a new class of isocyanide/acetylene-based multicomponent reactions (IAMCRs), through a zwitterionic adduct, have emerged as powerful and elegant methods for the synthesis of biologically interesting molecules. Coupling reaction between “in situ” g...
Article
Full-text available
The one-pot conversion of aldehydes to their corresponding primary amides has been studied using SBA-15-grafted ethylenediamine copper complexes (En-Cu). The heterogeneous catalyst could be readily isolated from the reaction mixture and reused for at least fourteen times without significant loss in activity. The influence of reaction parameters and...
Article
IRMOF-3 is found to be an active, selective and stable solid catalyst for three-component, one-pot reaction of amines, aldehydes and dimethyl phosphite to form the corresponding α-aminophosphonates in high yields. The catalyst can be isolated from the reaction mixture and reused at least four times.
Article
A pluronic P123 surfactant was employed in the exfoliation and stabilization of Pd0-supported graphene oxide (PdNPs–GO; NPs=nanoparticles) nanosheets in aqueous solution during the oxidation of benzylic and aliphatic alcohols under aerobic conditions at 80 °C. Surfactants prevented the aggregation of PdNPs–GO sheets at 80 °C under aqueous condition...
Article
Two Cu(II) (C1) and Ni(II) (C2) complexes were designed through the one-pot reaction of pyridine-2,6-dicarboxylic acid and 2-aminobenzimidazole respectively with copper(II) nitrate hexahydrate and nickel(II) nitrate hexahydrate. Both complexes were characterized by single-crystal X-ray diffraction and the distorted octahedral geometry was recognize...
Article
Full-text available
This study focuses on synthesizing novel nanocomposites, zinc(II)tetrakis(4-phenyl)porphyrin/Cu nanoparticles (ZnTPP/Cu-NPs),with antibacterial activity, fabricated through a single-step green procedure. In this regard, the self-assembly of ZnTPP was carried out through an acid–base neutralization method to prepare ZnTPP nanoparticles. Then, the co...
Article
The hybrid periodic mesoporous organosilica (PMO) with APTES/DAR Schiff-based precursor 3-aminopropyltriethoxysilane (APTES) and 4,6-diacetylresorcinol (DAR) was synthesized in the presence of a structure-directing agent cetyltrimethylammonium bromide and tetraethoxysilane. Then, Pd (II) ions, as well as Pd nanoparticles, were incorporated inside t...
Article
The novel amide ligand, N,Nˊ–bis(2-hydroxy-5-methylphenyl) pyridine-2,6-dicarboxamide (L) was synthesized through the condensation reaction of pyridine-2,6-dicarbonylchloride with 2-amino-4-methylphenol (1:2). The new mixed-ligand complex [Sr(pydcH)2(H2O)3][Sr(pydcH2)(pydcH)(pydc)]2.[Sr(pydcH2)2(H2O)3].2H2O (C) (where pydc is pyridine-2,6-dicarboxy...
Article
Due to the increasing environmental pollution caused by human activities, environmental remediation has become an important subject for humans and environmental safety. The quest for beneficial pathways to remove organic and inorganic contaminants has been the theme of considerable investigations in the past decade. The easy and quick separation ma...
Article
Co3O4 NPs in N-doped porous carbon (Co3O4 [email protected]) materials were prepared by one-pot pyrolysis of a ZIF-67 powder under N2 atmosphere and followed by oxidation under air atmosphere (200 °C) toward promotion catalytic activity and activation of peroxymonosulfate (PMS) to degradation sulfamethoxazole (SMZ). 2-methylimidazole was used as a...
Article
Full-text available
In this study, a novel nano-magnetic metal–organic frameworks based on Fe3O4 namely Fe3O4@MIL-101(Cr)-N(CH2PO3)2 was synthesized and fully characterized. The prepared sample was used as catalyst in the synthesis of pyrazolo [3,4-b] pyridines as convenient medicine by condensation reaction of aldehydes, 5-(1H-Indol-3-yl)- 2H-pyrazol-3-ylamine and 3-...
Article
Full-text available
Plasmonic AgPd alloy nanoparticles (AgPdNPs) decorated on single-layer carbon nitride (AgPdNPs/SLCN) for the designing of the Mott-Schottky junction were constructed with the ultrasonically assisted hydrothermal method and used toward photo evolution H2 from formic acid (FA) at near room temperature (30 °C). The Pd atom contains active sites that a...
Article
Herein, an electrochemical sensor for detection of indole was fabricated based on Pd nanoparticles modified Metal-Organic Framework Cr-MIL-101 ([email protected]) and ionic liquid (IL). The electrochemical behavior of indole was investigated by cyclic voltammetry (CV) and differential pulse voltammetry (DPV) at the surface of the modified electrode...
Article
Full-text available
The current paper deals with the major causes of air pollution in the big cities of Azerbaijan. In this context, industrial gas wastes and transport systems are the most important sources of air pollution. Also, relevant factors following the intensity of air pollution have recently been recognized. The motor transport system and its detrimental ef...
Article
Sub-micro and nanoparticles of silver (I) metal-organic coordination polymer [Ag2L]n (1) (H2L = 1,4-phenylenedipropionic acid) were fabricated using a sonochemical technique. X-ray powder diffraction (XRPD), Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), and elemental analyses, were employed to characterize the...
Preprint
Plasmonic AgPd alloy nanoparticles (AgPd NPs ) decorated on single-layer carbon nitride (AgPd NPs /SLCN) for the designing of Mott-Schottky junction were constructed with the ultrasonically assisted hydrothermal method and used toward photoevolution H 2 from formic acid (FA) at near room temperature (30 o C). The Pd atom contains active sites that...
Preprint
Full-text available
In biomedical applications, biocompatible and nontoxic compounds are the most important types of cytotoxic effects. In this work, the polyelectrolyte Cell/IL/Ag-AgCl NPs were fabricated by immobilizing of Ag-AgCl nanoparticles on the surface of organic biopolymer (cellulose) without using any reducing agent. The physical and chemical properties of...
Article
Full-text available
Chitosan is a biopolymer that is found in nature and is produced from chitin deacetylation. Chitosan has been studied thoroughly for multiple applications with an interdisciplinary approach. Antifungal antibacterial activities, mucoadhesion, non-toxicity, biodegradability, and biocompatibility are some of the unique characteristics of chitosan-base...
Article
Photocatalytic H2 generation has been considered as an effective method for H2 generation, in which the cocatalysts play a critical role. Here, we report highly reactive nanocomposites composed of two-dimensional triazine-based covalent organic Polymers (COPs), Pd and Au nanocomponents which is designed to benefit from the alloying and visible ligh...
Article
Full-text available
Here, we prepare an Au NP decorated dithiocarbamate functionalized boehmite (γ-AlO(OH)@C-NHCS2H·AuNPs). This stepwise synthetic method gives an efficient, cost-effective, and green heterogenous Au-based nanocatalyst for the A3-coupling preparation of the biologically essential propargylamines. Different characterization methods, including FT-IR, XR...
Article
Full-text available
A green and stable magnetic Fe3O4 core encapsulated in porous carbon shell was prepared. Then, the surface of as‐synthesized Fe3O4@meso‐C immobilized with activated 4‐aminobenzenesulfonic acid to achieve Fe3O4@C/Ph—SO3H. Structural, physico‐chemical, and magnetic properties of synthesized Fe3O4@C/Ph—SO3H catalyst using various analyses such as FT‐I...
Article
Full-text available
The stabilization of sub-nanometric metal particles (< 1 nm) with suitable distribution remained challenging in the catalytic arena. Herein, an intelligent strategy was described to anchoring and stabilizing sub-nanometric Pd colloids with an average size of 0.88 nm onto Kryptofix 23 functionalized MCM-41. Then, the catalytic activity of Pd@Kryf/MC...
Article
The magnetic DAR-chitosan was synthesized by condensation of magnetic chitosan [Fe3O4@CS] with freshly synthesized diacetylresorcinol (here calls DAR) as a cross-linking agent; the Schiff base precursor on the as-prepared magnetic DAR-chitosan polymer can be coordinated with Au (III) to give magnetic DAR chitosan-based Au (III) Schiff base complex...
Article
Over the past few decades, research on heterogeneous catalysts, especially metal-free catalysts in industrial and research transformations, has intensified. Despite the obvious benefits of heterogeneous transition metal catalysts in quick substrates activation and accelerate reactions, cost-effectiveness, high activity in harsh process conditions,...
Article
Novel core-shell carbon coated-magnetic (Fe3O4@Cg) nanoparticles supported MnO2 nanosheets (with α- and β-type structure) (Fe3O4@Cg/MnO2) are synthesized through a self-sacrificing templet method. The new hybrid material was fully characterized with Fourier transformed infrared spectroscopy, energy-dispersive X-ray spectroscopy, scanning electron m...
Article
Full-text available
A new Ag(I) metal-organic framework (Ag-MOF) [Ag(p-OH-C6H4COOH)2(NO3)]n ([Ag(PHBA)2(NO3)]n, (1) (PHBA: C8H6O4 {p-hydroxybenzoic acid}) was synthesized using two different methods; laying method (single crystal) and sonochemical irradiation (nanostructures). Scanning electron microscopy (SEM), powder XRD, and FT-IR spectroscopy were used to characte...
Article
Herein, we describe an intelligent strategy to fabricate nanosheets of graphitic carbon nitride (g-C3N4) decorated with nanorods copper oxide (CuO NRs). Then, the catalytic activity of CuONRs/g-C3N4-NS was developed for the synthesis of primary amides in water. The morphology of CuO and its synergetics effect with nanosheets g-C3N4 a major role in...
Article
This work reports the electrochemical detection of bisphenol A (BPA) using a novel and sensitive electrochemical sensor based on the Cu functionalized SBA-15 like periodic mesoporous organosilica-ionic liquid composite modified glassy carbon electrode ([email protected]/IL/GCE). The structural morphology of [email protected] is characterized by X-r...
Article
A novel strategy was described to fabricate GO/CuBDC-Fe3O4 ternary nanocomposite using a green solvothermal method. The physicochemical properties of the ternary nanocomposite were probed by ATR-FTIR, WA-XRD, Raman, FE-SEM, TEM/HRTEM, STEM/mapping, and EDS spectroscopy. In this nanocomposite, graphene oxide (GO) nanosheets were used as an ideal pla...
Article
Full-text available
Herein, a new magnetic metal–organic frameworks based on Fe3O4 (NMMOFs) with porous and high surface area materials were synthesized. Then, NMMOFs were characterized by FT-IR, XRD, SEM, elemental mapping, energy dispersive X-ray (EDS), TG, DTG, VSM, and N2 adsorption–desorption isotherms (BET). Fe3O4@Co(BDC)-NH2 as a magnetic porous catalyst was ap...
Article
Full-text available
Microcystin-leucine arginine (MC-LR) is a carcinogenic toxin, produced by cyanobacteria. The release of this toxin into drinking water sources can threaten public health and environmental safety. Therefore, effective MC-LR removal from water resources is necessary. In the present study, the hydrothermal method was used to synthesize a novel ternary...
Article
Full-text available
In this study two hybrid organic–inorganic ureasilicate monomers with different length of polymer segments were chosen for preparation of sol–gel material that includes two moieties blended on the molecular scale. The first monomer was obtained by crosslinking a double terminated polyoxyalkyleneamine with an isocyanate modified silicone ethoxide an...
Article
Au nanorods (AuNRs) decorated phosphorus doped graphitic carbon nitride AuNRs/g-C3N(4-x)Px-NS catalyst have been designed and prepared by a facile hydrothermal approach, which is useful for the efficient reduction of nitroaromatics in aqueous solution using NaBH4- as reductant. A series of conventional characterizations like X-ray diffraction, scan...
Article
Full-text available
Daunorubicin is a famous anthracycline anticancer chemotherapy drug with many side effects that is very important to measure in biological samples. A daunorubicin electrochemical biosensor was fabricated in this study using ds-DNA as the biorecognition element and glassy carbon electrode (GCE) amplified by Pt/SWCNTs as a sensor. The synthetization...
Article
Full-text available
In this paper, a novel porous polymer capable of coordinating to bismuth (PCPs-Bi) was synthesized. The Bi-PCPs was then reacted with phosphorous acid to produce a novel polymer PCPs(Bi)N(CH2PO3H2)2 which is shown to act as an efficient and recyclable catalyst. The mentioned catalyst was applied for the efficient synthesis of new mono and bis napht...
Article
Over the past few decades, research on heterogeneous catalysts, especially metal-free catalysts in industrial and research transformations, has intensified. Despite the obvious benefits of heterogeneous transition metal catalysts in quick...
Article
A novel, efficient, and core/shell nanosphere catalyst (Fe3O4@C-NHCS-Au⁰) was successfully synthesized with a movable magnetite core encapsulated in a carbon shell. It was modified using APTES (3-aminopropyltriethoxysilane) to convert dithiocarbamate (DTC) functional group in the carbon surface though post-modification with CS2 (carbon disulfide)....
Article
A novel, efficient, and core/shell nanosphere catalyst (Fe3O4@C-NHCS-Au0) was successfully synthesized with a movable magnetite core encapsulated in a carbon shell. It was modified using APTES (3-aminopropyltriethoxysilane) to convert dithiocarbamate (DTC) functional group in the carbon surface though post-modification with CS2 (carbon disulfide)....
Article
Nano-size silver particles were stabilized on the inner surfaces of urea based periodic mesoporous organosilica (Ur-PMO). Aqueous extract of Euphorbia leaves as a sustainable and green reducing agent was applied for Ag-nanoparticles growth into the Ur-PMO channels. Physical and chemical properties of organosilica materials synthesized using various...
Article
A series of mercury(II) metal-organic coordination polymers (Hg-MOCPs) with a general chemical formula [Hg(PicA)(N3)]n (PicA=2-picolinic acid) were synthesized by controlling their morphology using two methods including the branched tube and sonochemical ultrasonic-assisted (US). The effects of the sonication, the reaction time, the reactant concen...
Article
Formic acid (FA) has long been regarded as a cheap and non-toxic hydrogen storage material due to its effective production of hydrogen in mild conditions. Though the development of heterogeneous catalysts has received much progress, their catalytic activity remains insufficient. Here, a porous Triazine-based covalent organic polymer (TA-COP) was fa...
Article
Full-text available
A new porous triazine‐based covalent organic polymer (Triazine‐COP) was prepared through the Schiff‐base condensation of 2,4,6‐tris(4‐formyl phenoxy)‐1,3,5‐triazine and 4,4′‐oxydianiline, under sonication. The synthesized Triazine‐COP with a high surface area was stable in water and other organic solvents. In the next step, Au (III) ions were immob...
Article
Designing a photocatalytic system with complementary properties including high surface area, high loading, extraordinary electronic properties, and easy separation for increases photocatalytic performance has remained a challenge in photocatalytic applications. Herein, an environmentally benign approach was developed to fabricate graphitic carbon n...
Article
Anchoring and stabilization of colloidal noble metal particles (CNMPs) with good distribution have remained an enormous challenge in catalytic applications. However, designing a catalytic system with complementary properties including high surface area, high loading, extraordinary electronic properties, and easy separation offers a promising route...
Article
In this work, we introduce a novel bipyridinium ionic liquid bridged periodic mesoporous organosilicas (Bipy-PMOs-IL) which is used as the support to immobilize oxygenrich Molybdenum (VI)-based oxido-peroxido complex (MoO(O2)2@Bipy-PMO-IL). Several techniques such as Small-angle X-ray scattering (SAXS, low angle XRD, FE-SEM (field emission scanning...
Article
In this work, we introduce a novel bipyridinium ionic liquid bridged periodic mesoporous organosilicas (Bipy-PMOs-IL) which is used as the support to immobilize oxygenrich Molybdenum (VI)-based oxido-peroxido complex (MoO(O2)2@Bipy-PMO-IL). Several techniques such as Small-angle X-ray scattering (SAXS, low angle XRD, FE-SEM (field emission scanning...
Article
In this work, we introduce a novel bipyridinium ionic liquid bridged periodic mesoporous organosilicas (Bipy-PMOs-IL) which is used as the support to immobilize oxygenrich Molybdenum (VI)-based oxido-peroxido complex (MoO(O2)2@Bipy-PMO-IL). Several techniques such as Small-angle X-ray scattering (SAXS, low angle XRD, FE-SEM (field emission scanning...
Article
Full-text available
We designed and synthesized a novel catalyst consisting of ordered mesoporous silica (SBA‐15) functionalized with bis(thiourea) (BTU) linker. The regular and unique pore channels of BTU‐SBA‐15 ensure proper control of the size and homogeneous distribution of palladium nanoparticles. The physiochemical properties of the hybrid Pd@BTU‐SBA‐15 pre‐cata...
Article
Full-text available
In this study, a novel electrochemical method as a conductive voltammetric sensor for determination of N-hydroxysuccinimide was developed. The N-hydroxysuccinimide sensor was achieved by carbon paste electrode (CPE) amplified with tri-component nanohybrid composite (Platinum nanoparticle/Polyoxometalate/Two-dimensional hexagonal boron nitride nanos...
Article
In the current paper, we successfully developed and used metal–organic frameworks (MOFs) based on MIL-101(Cr)-NH2 with phosphorus acid functional groups MIL-101(Cr)-N(CH2PO3H2)2. The synthesized metal–organic frameworks (MOFs) as a multi-functional heterogeneous and nanoporous catalyst were used for the synthesis of N-amino-2-pyridone and pyrano [2...
Article
Full-text available
Fabrication of a nanocomposite catalyst via a novel and efficient strategy remains a challenge; Fe3O4 nanoparticles anchored on graphene oxide (GO) sheet-supported metal-organic frameworks (MOFs). In this study, the physicochemical properties of the ensuing Fe3O4/Cu-BDC/GO are investigated using Fourier transform infrared spectrum, scanning electro...
Article
Ultra-small nano-sized palladium particles were successfully stabilized within the pores of diamine groups grafted open metal site metal-organic frameworks of Cr-MIL-101; coordinated diamine groups of ethylene diamine (ED) and propyl diamine (PD) on the active site of chromium units of Cr-MIL-101. The physiochemical properties of the Pd@Cr-MOFs wer...
Article
Full-text available
Thiourea-bridged organosiloxane is used to synthesize a periodic mesoporous organosilica (PMO). Since this PMO has an S-enriched surface, owing to thiourea functional groups, it exhibits strong coordination toward Pt ions, and it shows a high tunability in the Pt nanoparticles size. This hybrid mesoporous material is employed as a catalyst in the e...
Article
A green and cost-effective protocol developed using covalently bonded sulfamic acid graphitic carbon nitride (g-C3N4/NHSO3H) for the synthesis of quinazoline derivatives using three-component condensation reaction of benzaldehyde, 2‐aminotetrazole and dimedone. The XRD, TEM, SEM, EDX and FT-IR techniques were used to identify the physical and chemi...
Article
Mesoporous aluminosilica is a unique structure for catalysis due to Lewis acidity of aluminum. Here, we design a new catalyst by merging periodic mesoporous organosilica with aluminosilica into its structure instead of mere silica. The employed organosilica bridge in this synthesis is a thiourea based organosiloxane precursor which has a unique fea...
Article
In this work, SBA-15/PrN(CH2PO3H)2 as a novel and heterogeneous catalyst containing of phosphorous acid groups was fully characterized by using various analysis techniques. A good range of novel pyrido[2,3-d]pyrimidines and pyrimido[4,5-b]quinolines were synthesized in the presence of SBA-15/PrN(CH2PO3H)2 under solvent-free condition. The major adv...
Article
The synthesis of mesoporous organosilicas (MOs) using co-condensation for a high ratio of a long and flexible chained organosiloxane bridge with silica precursor (e.g. tetraethylorthosilicate (TEOS)) is a complex and challenging task. By complementing the experimental characterisations with density functional calculations, The critical ratio of the...
Article
Full-text available
The design of hydroxyapatite (HA) nanoarchitecture is critical for fabricating artificial bone tissues as it dictates the biochemical and the mechanical properties of the final product. Herein, we incorporated a simple hard-template approach to synthesise single crystal nanoplates of HA. We used the 2D graphitic nitride (g-C3N4) material to prepare...