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The selective photodeprotection of the NVoc-modified FGG tripeptide yields the transformation of its 1:1 receptor-ligand complex with cucurbituril into a homoternary FGG2@CB8 assembly. The resulting light-induced dimerization of the model peptide provides a tool for the implementation of stimuli-responsive supramolecular chemistry in biologicall...
A combination of a chalcone/flavylium photoswitch with a supramolecular host–guest complex that can be used to phototrigger the logically-controlled and selective release of cargo was devised.