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Rates of detritiation from the C-2 position of [2-3H]histidine, histamine, and N-acetylhistidine as well as a number of histidine-containing peptides (glycyl-L-histidine, glycyl-L-histidylglycine, β-alanylhistidine, histidylserine, and histidyltyrosine) have been measured over a pH range at 85°. For both histidine and histamine the rate–pH profiles...
Rates of detritiation from the C-8 position of puromycin, mercaptopurine, and mercaptopurine riboside have been measured over a pH range at 85 °C. For the first two compounds two mechanisms, one involving the protonated molecule and hydroxide ion at low pH, the other the neutral molecule and the hydroxide ion at high pH, are operative. In the case...
