Raquel Hernández RuizUniversidad de Burgos | UBU · Department of Chemistry
Raquel Hernández Ruiz
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Introduction
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Publications
Publications (4)
![Synthesis of pyrrolo[1,2-a]quinoxalines 3. [a]](publication/353373680/figure/tbl2/AS:1048186248511488@1626918484030/Synthesis-of-pyrrolo1-2-aquinoxalines-3-a_Q320.jpg)
![Synthesis of indolo[1,2-a]quinoxalines 5. [a]](publication/353373680/figure/tbl3/AS:1048186248503296@1626918484065/Synthesis-of-indolo1-2-aquinoxalines-5-a_Q320.jpg)
![Synthesis of pyrrolo and indolo[3,2-c]quinoline derivatives 8 and 10. [a]](publication/353373680/figure/tbl4/AS:1048186248511489@1626918484103/Synthesis-of-pyrrolo-and-indolo3-2-cquinoline-derivatives-8-and-10-a_Q320.jpg)
A catalytic domino reduction−imine formation−intramolecular cyclization−oxidation for the general synthesis of a wide variety of biologically relevant N‐polyheterocycles, such as quinoxaline‐ and quinoline‐fused derivatives, and phenanthridines, is reported. A simple, easily available, and environmentally friendly dioxomolybdenum(VI) complex has pr...
The synthesis of aromatic amines is of utmost importance in a wide range of chemical contexts. We report a direct amination of boronic acids with nitro compounds to yield (hetero)aryl amines. The novel combination of a dioxomolybdenum(VI) catalyst and triphenylphosphine as inexpensive reductant has revealed to be decisive to achieve this new C‐N co...
The synthesis of aromatic amines is of utmost importance in a wide range of chemical contexts. We report a direct amination of boronic acids with nitro compounds to yield (hetero)aryl amines. The novel combination of a dioxomolybdenum(VI) catalyst and triphenylphosphine as inexpensive reductant has revealed to be decisive to achieve this new C‐N co...
Molybdenum(VI) dichloride dioxide (MoO2Cl2), and its addition complexes [MoO2Cl2(L)n; L = neutral ligand], are commercially or easily available and inexpensive transition-metal complexes based on a non-noble metal that can be applied as catalysts for various organic transformations. This short review aims to present the most significant breakthroug...
