Pierre Burdet

La Haute Ecole d'Ingénierie et de Gestion du Canton de Vaud | HEIG-VD · Department of Industrial Technologies (TIN)

The performance of solid oxide cells is known to be dependent upon the density of three phase boundaries (TPB), but the potential for improving their effective electrocatalytic activity by morphological adjustments is imprecisely known. A spilling algorithm was developed to characterize the surfaces available for diffusion at TPBs. It scans each sl...

This paper addresses the fabrication of vertically aligned [email protected]2 multishell nanotubes by a combined full vacuum-plasma approach at mild temperatures. The growth is carried out within the premises of a one-reactor approach, i.e. minimizing the number of vacuum chambers and sample transferences. In this way, the interface between ZnO and...

Electron Microscopy (Big and Small) Data Analysis With the Open Source Software Package HyperSpy - Volume 23 Issue S1 - Francisco de la Pena, Tomas Ostasevicius, Vidar Tonaas Fauske, Pierre Burdet, Petras Jokubauskas, Magnus Nord, Mike Sarahan, Eric Prestat, Duncan N. Johnstone, Joshua Taillon, Jan Caron, Tom Furnival, Katherine E. MacArthur, Alber...

A solid oxide short stack composed of 6 Ni-YSZ supported cells, YSZ electrolyte and GDC-LSC oxygen electrode has been tested for 10,700 hours in steam electrolysis. Initial degradation was followed by a global stabilization of the performance after lowering the current density, with a degradation rate below 0.5% kh−1. Post-test analysis has been co...

FIB-tomography is used in materials science for 3D-analysis of nanostructured materials [1]and in life science for the analysis of complex structures like brain tissue [2]. This presentation summarizes recent technological improvements, which include advancements in detector technology for electron imaging and elemental analysis, scan generator tec...

div class="title">Improved Data Analysis and Reconstruction Methods for STEM-EDX Tomography - Volume 22 Issue S3 - Zineb Saghi, Joshua Einsle, Roberts Blukis, Ansis Strodahs, Rowan Leary, Pierre Burdet, Richard Harrison, Paul Midgley

Despite the availability of elaborate varieties of nanoparticles, their assembly into regular superstructures and photonic materials remains challenging. Here we show how flexible films of stacked polymer nanoparticles can be directly assembled in a roll-to-roll process using a bending-induced oscillatory shear (BIOS) technique. For sub-micron sphe...

The γ′ strengthening phase in an advanced nickel-based superalloy, ATI 718Plus, was characterized using a blind source separation applied to a four dimensional X-ray microanalysis dataset obtained by scanning transmission electron microscopy. Selected patterns in the X-ray spectra identified by independent component analysis were found to be spatia...

A three-step vacuum procedure for the fabrication of vertical TiO2 and ZnO nanotubes with three dimensional walls is presented. The method combines physical vapor deposition of small-molecules, plasma enhanced chemical vapor deposition of inorganic functional thin films and layers and a post-annealing process in vacuum in order to remove the organi...

This paper presents a novel 3D method to correct for absorption in energy dispersive X-ray (EDX) microanalysis of heterogeneous samples of unknown structure and composition. By using STEM-based tomography coupled with EDX, an initial 3D reconstruction is used to extract the location of generated X-rays as well as the X-ray path through the sample t...

div class="title">Multi-Dimensional Machine Learning Aided Analysis of a Nickel-Based Superalloy - Volume 21 Issue S3 - David Rossouw, Robert Krakow, Zineb Saghi, Catriona S M Yeoh, Pierre Burdet, Rowan K Leary, Paul A Midgley

div class="title">Overcoming Traditional Challenges in Nano-scale X-ray Characterization Using Independent Component Analysis - Volume 21 Issue S3 - David Rossouw, Pierre Burdet, Francisco de la Pena, Caterina Ducati, Benjamin R. Knappett, Andrew E. H. Wheatley, Paul A. Midgley

A simple model is proposed to account for the loss of collected X-ray signal by the shadowing of X-ray detectors in the scanning transmission electron microscope. The model is intended to aid the analysis of three-dimensional elemental data sets acquired using energy-dispersive X-ray tomography methods where shadow-free specimen holders are unsuita...

The chemical composition of core–shell nanoparticle clusters have been determined through principal component analysis (PCA) and independent component analysis (ICA) of an energy-dispersive X-ray (EDX) spectrum image (SI) acquired in a scanning transmission electron microscope (STEM). The method blindly decomposes the SI into three components, whic...

An enhanced method to quantify energy dispersive spectra recorded in 3D with a scanning electron microscope (3D SEM–EDS) has been previously demonstrated. This paper presents an extension of this method using all the available X-ray lines generated by the beam. The extended method benefits from using high energy lines, that are more accurately quan...

This paper presents a method developed to quantify three-dimensional energy dispersive spectrometry (3D EDS) data with voxel size smaller than the volume from which X-rays are emitted. The influence of the neighboring voxels is corrected by applying recursively a complex quantification, improving thereby the accuracy of the quantification of critic...

The biomedical industry has an increasing demand for processes to join dissimilar metals, such as laser welding of NiTi and stainless steel wires. A region of the weld close to the NiTi interface, which previously was shown to be prone to cracking, was further analyzed by energy dispersive spectrometry (EDS) extended in the third dimension using a...

of a paper presented at Microscopy and Microanalysis 2012 in Phoenix, Arizona, USA, July 29 – August 2, 2012.

of a paper presented at Microscopy and Microanalysis 2012 in Phoenix, Arizona, USA, July 29 – August 2, 2012.

This thesis is focused on a combined microscopy technique: energy dispersive spectrometry (EDS) is extended to a three dimensional (3D) microanalysis using a so-called "dual-beam microscope": a scanning electron microscope (SEM) equipped with a focused ion beam (FIB). In the sequential acquisition, the surface freshly milled by the FIB is character...

The favorable growth kinetics of twinned dendrites can be explained by their complex morphology, multiple side branching mechanisms, growth undercooling and tip morphology. Three models were proposed for the twinned dendrite tip shape: (i) a grooved tip [1] satisfying the Smith condition at the triple line; (ii) a doublon [2], i.e. a double-tip den...

of a paper presented at Microscopy and Microanalysis 2011 in Nashville, Tennessee, USA, August 7–August 11, 2011.

of a paper presented at Microscopy and Microanalysis 2011 in Nashville, Tennessee, USA, August 7–August 11, 2011.

1.5 µm-Ni55Mn23Ga22 ferromagnetic thin films were deposited onto silicon substrates and silicon single beam cantilever using radio-frequency magnetron sputtering. As-deposited sample and heat-treated thin films were studied on their silicon substrates and peeled off to determine the influence of the stress. Post-heat treatment process allows at the...

Compared with traditional drug solutions or suspensions, polymeric microparticles represent a valuable means to achieve controlled and prolonged drug delivery into joints, but still suffer from the drawback of limited retention duration in the articular cavity. In this study, our aim was to prepare and characterize magnetic biodegradable microparti...

1.5mm–Ni55Mn23Ga22 ferromagnetic thin films were deposited onto silicon substrates and silicon single beam cantilever using radio-frequency magnetron sputtering. As-deposited sample and heat-treated thin films were studied on their silicon substrates and peeled off to determine the influence of the stress. Post-heat treatment process allows at the...