Paul Rimmer

• PhD, Physics. Ohio State University
• PostDoc Position at University of St Andrews

Ozone is a potential biosignature and disambuguator between Earth-like and Venus-like exoplanets due to its association on Earth with photosynthetically produced oxygen (O2). However, the existence of ozone in Venus’s observable atmosphere, a planet with no known life, raises the possibility of ozone biosignature false-positives on Venus-like exopl...

Stellar irradiation is thought to be a significant contributor to the origin of life. UV light inter- acting with iron cyanide complexes plays an important role in prebiotic chemistry. The UV-Vis spectra of these iron cyanide complexes can be measured by the same source that drives the chemistry, providing a real-time in-situ quantitative analysis...

The inner regions of planet-forming disks are warm and dense. The chemical networks used for disk modelling so far were developed for a cold and dilute medium and do not include a complete set of pressure-dependent reactions. The chemical networks developed for planetary atmospheres include such reactions along with the inverse reactions related to...

The inner regions of planet-forming disks are warm and dense. The chemical networks used for disk modelling so far were developed for a cold and dilute medium and do not include a complete set of pressure-dependent reactions. The chemical networks developed for planetary atmospheres include such reactions along with the inverse reactions related to...

The discovery of inhabited exoplanets hinges on identifying biosignature gases. JWST is revealing potential biosignatures in exoplanet atmospheres, though their presence is yet to provide strong evidence for life. The central challenge is attribution: how to confidently identify biogenic sources while ruling out, or deeming unlikely, abiotic explan...

At visible wavelengths, Venus appears serene and pale-yellow, but since the 1920s, observers have noted high-contrast features in the ultraviolet. These features track the about 4-day superrotation of the upper cloud deck and vary widely over time and space. The identity of the UV absorber(s)-active between at least 280 and 500 nm-remains unknown,...

Context. Cosmic rays, both solar and Galactic, have an ionising effect on the Earth’s atmosphere and are thought to be important in the production of prebiotic molecules. In particular, the H 2 -dominated atmosphere that follows an ocean-vaporising impact is considered favourable to prebiotic molecule formation. As a first step in determining the r...

Cosmic rays (CR), both solar and Galactic, have an ionising effect on the Earth's atmosphere and are thought to be important for prebiotic molecule production. In particular, the $\rm{H_2}$-dominated atmosphere following an ocean-vaporising impact is considered favourable to prebiotic molecule formation. We model solar and Galactic CR transport thr...

Cometary impacts play an important role in the early evolution of Earth, and other terrestrial exoplanets. Here, we present a numerical model for the interaction of weak, low-density cometary impactors with planetary atmospheres, which includes semi-analytical parameterisations for the ablation, deformation, and fragmentation of comets. Deformation...

Cometary impacts play an important role in the early evolution of Earth, and other terrestrial exoplanets. Here, we present a numerical model for the interaction of weak, low-density cometary impactors with planetary atmospheres, which includes semi-analytical parametrizations for the ablation, deformation, and fragmentation of comets. Deformation...

The circumstellar liquid-water habitable zone guides our search for potentially inhabited exoplanets but remains observationally untested. We show that the inner edge of the habitable zone can now be mapped among exoplanets using their lack of surface water, which, unlike the presence of water, can be unambiguously revealed by atmospheric sulfur sp...

Hydrogen cyanide delivered by cometary impactors can be concentrated as ferrocyanide salts, which may support the initial stages of prebiotic chemistry on the early Earth. One way to achieve the conditions required for a variety of prebiotic scenarios, requiring, for example, the formation of cyanamide and cyanoacetylene, is through the arrival of...

The circumstellar liquid-water habitable zone guides our search for potentially inhabited exoplanets, but remains observationally untested. We show that the inner edge of the habitable zone can now be mapped among exoplanets using their lack of surface water, which, unlike the presence of water, can be unambiguously revealed by atmospheric sulfur s...

High-resolution transmission spectroscopy of the warm gas-giant WASP-69b has revealed the presence of H2O, CO, CH4, NH3, and C2H2 in its atmosphere. This study investigates the impact of vertical diffusion and photochemistry on its atmospheric composition, with a focus on the detected species plus HCN and CO2, to constrain the atmospheric C/O ratio...

Conspectus Origin of Life research is a fast growing field of study with each year bringing new breakthroughs. Recent discoveries include novel syntheses of life’s building blocks, mechanisms of activation and interaction between molecules, and newly identified environments that provide promising conditions for these syntheses and mechanisms. Even...

Venus’s climatic history provides powerful constraints on the location of the inner edge of the liquid-water habitable zone. However, two very different histories of water on Venus have been proposed: one where Venus had a temperate climate for billions of years with surface liquid water and the other where a hot early Venus was never able to conde...

Venus's climatic history provides powerful constraint on the location of the inner-edge of the liquid-water habitable zone. However, two very different histories of water on Venus have been proposed: one where Venus had a temperate climate for billions of years, with surface liquid water, and the other where a hot early Venus was never able to cond...

Hydrogen cyanide delivered by cometary impactors can be concentrated as ferrocyanide salts, which may support the initial stages of prebiotic chemistry on the early Earth. One way to achieve the conditions required for a variety of prebiotic scenarios, requiring for example the formation of cyanamide and cyanoacetylene, is through the arrival of a...

One way in which we can attempt to relate chemical pathways to geochemical environments is by studying the kinetics of a given sequence of reactions and identifying the conditions under which this chemistry is the most productive. Many prebiotic reactions rely on a source of fixed carbon, therefore chemical pathways that suggest prebiotically plaus...

Giant impacts can generate transient hydrogen-rich atmospheres, reducing atmospheric carbon. The reduced carbon will form hazes that rain out onto the surface and can become incorporated into the crust. Once heated, a large fraction of the carbon is converted into graphite. The result is that local regions of the Hadean crust were plausibly saturat...

The tentative detection of ppb levels of phosphine (PH 3 ) in the clouds of Venus was extremely surprising, as this reduced gas was not expected to be a component of Venus’ oxidized atmosphere. Despite potential confirmation in legacy Pioneer Venus mass spectrometry data, the detection remains controversial. Here we review the potential production...

This work reviews possible signatures and potential detectability of present-day volcanically emitted material in the atmosphere of Venus. We first discuss the expected composition of volcanic gases at present time, addressing how this is related to mantle composition and atmospheric pressure. Sulfur dioxide, often used as a marker of volcanic acti...

Recent ground-based observations of Venus have detected a single spectral feature consistent with phosphine (PH3) in the middle atmosphere, a gas which has been suggested as a biosignature on rocky planets. The presence of PH3 in the oxidized atmosphere of Venus has not yet been explained by any abiotic process. However, state-of-the-art experiment...

Long-standing unexplained Venus atmosphere observations and chemical anomalies point to unknown chemistry but also leave room for the possibility of life. The unexplained observations include several gases out of thermodynamic equilibrium (e.g., tens of ppm O2, the possible presence of PH3 and NH3, SO2 and H2O vertical abundance profiles), an unkno...

The clouds of Venus are believed to be composed of sulfuric acid (H 2 SO 4 ) and minor constituents including iron-bearing compounds, and their respective concentrations vary with height in the thick Venusian atmosphere. This study experimentally investigates possible iron-bearing mineral phases that are stable under the unique conditions within Ve...

As the characterization of exoplanet atmospheres proceeds, providing insights into atmospheric chemistry and composition, a key question is how much deeper into the planet we might be able to see from its atmospheric properties alone. For small planets with modest atmospheres and equilibrium temperatures, the first layer below the atmosphere will b...

In this work, we consider the potential of cometary impacts to deliver complex organic molecules and the prebiotic building blocks required for life to rocky exoplanets. Numerical experiments have demonstrated that for these molecules to survive, impacts at very low velocities are required. This work shows that for comets scattered from beyond the...

It has been suggested that a ‘Shadow Biosphere’ could exist adjacent to the life we see on Earth [1, 2]. This alternate biosphere, with vastly different molecular biochemistries (e.g., opposing chirality, novel genetic nucleobases) would be co-existing and co-evolving with life as we know it through over geological time. This idea has been suggeste...

The search for biosignatures on exoplanets connects the fields of biology and biochemistry to astronomical observation, with the hope that we might detect evidence of active biological processes on worlds outside the solar system. Here we focus on a complementary aspect of exoplanet characterization connecting astronomy to prebiotic chemistry: the...

The search for biosignatures on exoplanets connects the fields of biology and biochemistry to astronomical observation, with the hope that we might detect evidence of active biological processes on worlds outside the solar system. Here we focus on a complementary aspect of exoplanet characterisation connecting astronomy to prebiotic chemistry: the...

I show that exoplanets can be used to test origins scenarios. Origins scenarios start with certain initial conditions, proceed via a network of chemical reactions and, if successful, result in a chemistry that is closer to a living system than the initial conditions. Exoplanet environments can be applied to test each of these three aspects of origi...

A key first step to constrain the impact of energetic particles in exoplanet atmospheres is to detect the chemical signature of ionisation due to stellar energetic particles and Galactic cosmic rays. We focus on GJ 436, a well-studied M dwarf with a warm Neptune-like exoplanet. We demonstrate how the maximum stellar energetic particle momentum can...

Volcanism is a major and long‐term source of volatile elements such as C and H to Earth's atmosphere, likely has been to Venus's atmosphere, and may be for exoplanets. Models simulating volcanic growth of atmospheres often make one of two assumptions: either that atmospheric speciation is set by the high‐temperature equilibrium of volcanism or that...

A key first step to constrain the impact of energetic particles in exoplanet atmospheres is to detect the chemical signature of ionisation due to stellar energetic particles and Galactic cosmic rays. We focus on GJ$\,$436, a well-studied M dwarf with a warm Neptune-like exoplanet. We demonstrate how the maximum stellar energetic particle momentum c...

I show that exoplanets can be used to test origins scenarios. Origins scenarios start with certain initial conditions, proceed via a network of chemical reactions, and if successful result in a chemistry that is closer to a living system than the initial conditions. Exoplanet environments can be applied to test each of these three aspects of origin...

It is challenging to evaluate the relevance of any given chemical system or geological environment to the origin of life. At the same time, life is the product of prebiotic chemistry that took place in some environment. We may attempt to quantify the probability landscape of organic systems and their host environments on prebiotic worlds as a preli...

We are of the opinion that several anomalies in the atmosphere of Venus provide evidence of yet-unknown processes and systems that are out of equilibrium. The investigation of these anomalies on Venus should be open to a wide range of explanations, including unknown biological activity. We provide an overview of two anomalies, the tentative detecti...

We are of the opinion that several anomalies in the atmosphere of Venus provide evidence of yet-unknown processes and systems that are out of equilibrium. The investigation of these anomalies on Venus should be open to the wide range of explanations, including unknown biological activity. We provide an overview of two anomalies, the tentative detec...

Volcanism is a major and long-term source of volatile elements such as C and H to Earth's atmosphere, likely has been to Venus's atmosphere, and may be for exoplanets. Models simulating volcanic growth of atmospheres often make one of two assumptions: either that atmospheric speciation is set by the high temperature equilibrium of volcanism; or, th...

The geology of Earth and super‐Earth sized planets will, in many cases, only be observable via their atmospheres. Here, we investigate secondary volcanic atmospheres as a key base case of how atmospheres may reflect planetary geochemistry. We couple volcanic outgassing with atmospheric chemistry models to simulate the growth of C‐O‐H‐S‐N atmosphere...

Life in the clouds of Venus, if present in sufficiently high abundance, must be affecting the atmospheric chemistry. It has been proposed that abundant Venusian life could obtain energy from its environment using three possible sulfur energy-metabolisms. These metabolisms raise the possibility of Venus’s enigmatic cloud-layer SO2-depletion being ca...

Life in the clouds of Venus, if present in sufficiently high abundance, must be affecting the atmospheric chemistry. It has been proposed that abundant Venusian life could obtain energy from its environment using three possible sulfur energy-metabolisms. These metabolisms raise the possibility of Venus's enigmatic cloud-layer SO$_2$-depletion being...

The elemental ratios of carbon, nitrogen, and oxygen in the atmospheres of hot Jupiters may hold clues to their formation locations in the protostellar disk. In this work, we adopt gas-phase chemical abundances of C, N, and O from several locations in a disk chemical kinetics model as sources for the envelope of the hot Jupiter HD 209458b and evolv...

New analysis is presented of the 1.1 mm wavelength absorption lines in Venus’ atmosphere that suggested the presence of phosphine. We retrieve a sulphur dioxide observation from the JCMT archive that was simultaneous within a few days of the PH3 1-0 spectrum obtained in June 2017, and demonstrate via a radiative transfer calculation that contaminat...

Impacts may have had a significant effect on the atmospheric chemistry of the early Earth. Reduced phases in the impactor (e.g., metallic iron) can reduce the planet’s H 2 O inventory to produce massive atmospheres rich in H 2 . While previous studies have focused on the interactions between the impactor and atmosphere in such scenarios, we investi...

Impacts may have had a significant effect on the atmospheric chemistry of the early Earth. Reduced phases in the impactor (e.g., metallic iron) can reduce the planet's H$_2$O inventory to produce massive atmospheres rich in H$_2$. Whilst previous studies have focused on the interactions between the impactor and atmosphere in such scenarios, we inve...

The initial reports of the presence of phosphine in the cloud decks of Venus have led to the suggestion that volcanism is the source of phosphine, through volcanic phosphides ejected into the clouds. Here, we examine the idea that mantle plume volcanism, bringing material from the deep mantle to the surface, could generate observed amounts of phosp...

Significance This research provides a transformative hypothesis for the chemistry of the atmospheric cloud layers of Venus while reconciling decades-long atmosphere anomalies. Our model predicts that the clouds are not entirely made of sulfuric acid, but are partially composed of ammonium salt slurries, which may be the result of biological product...

The atmosphere of Venus remains mysterious, with many outstanding chemical connundra. These include: the unexpected presence of ~10 ppm O2 in the cloud layers; an unknown composition of large particles in the lower cloud layers; and hard to explain measured vertical abundance profiles of SO2 and H2O. We propose a new hypothesis for the chemistry in...

The initial reports of the presence of phosphine in the cloud decks of Venus has led to the suggestion that volcanism was the source of phosphine, through volcanic phosphides ejected into the clouds. Here we examine the idea that mantle plume volcanism, bringing material from the deep mantle to the surface, could generate observed amounts of phosph...

The potential detection of ppb levels phosphine (PH3) in the clouds of Venus through millimeter-wavelength astronomical observations is extremely surprising as PH3 is an unexpected component of an oxidized environment of Venus. A thorough analysis of potential sources suggests that no known process in the consensus model of Venus' atmosphere or geo...

The geology of Earth and super-Earth sized planets will, in many cases, only be observable via their atmospheres. Here, we use the creation of volcanic atmospheres as a key window into planetary geochemistry. We couple volcanic outgassing with atmospheric chemistry models to simulate the growth of C-O-H-S-N atmospheres in thermochemical equilibrium...

The potential detection of ppb levels phosphine (PH3) in the clouds of Venus through millimeter-wavelength astronomical observations is extremely surprising as PH3 is an unexpected component of an oxidized environment of Venus. A thorough analysis of potential sources suggests that no known process in the consensus model of Venus’ atmosphere or geo...

We predict that cyanoacetylene (HC3N) is produced photochemically in the atmosphere of GJ 1132 b in abundances detectable by the James Webb Space Telescope (JWST), assuming that the atmosphere is hydrogen dominated and rich in molecular nitrogen (N2), methane (CH4), and hydrogen cyanide (HCN), as described by Swain et al. First, we construct line l...

Compared to the diversity seen in exoplanets, Venus is a veritable astrophysical twin of the Earth; however, its global cloud layer truncates features in transmission spectroscopy, masking its non-Earth-like nature. Observational indicators that can distinguish an exo-Venus from an exo-Earth must therefore survive above the cloud layer. The above-c...

The origin of life occurred by a series of prebiotic reaction pathways (collectively a system) hosted in one or more geochemical environments (together forming an origin of life scenario). State-of-the-art prebiotic chemistry links together reactions to create systems, intended to be more representative of the diverse chemical pathways that may hav...

The origin of life occurred by a series of prebiotic reaction pathways (collectively a system) hosted in one or more geochemical environments (together forming an origin of life scenario). State-of-the-art prebiotic chemistry links together reactions to create systems, intended to be more representative of the diverse chemical pathways that may hav...

New analysis is presented of the 1.1 mm wavelength absorption lines in Venus' atmosphere that suggested the presence of phosphine. We confirm that ALMA detected absorption at the PH3 1-0 wavelength in 2019, from an optimised spectrum covering half of the planetary disc. Sulphur dioxide line-contamination was then <10%, from modelling of a simultane...

The study of origins of life on Earth and the search for life on other planets are closely linked. Prebiotic chemical scenarios can help prioritize planets as targets for the search for life as we know it and can provide informative priors to help us assess the likelihood that particular spectroscopic features are evidence of life. The prerequisite...

Compared to the diversity seen in exoplanets, Venus is a veritable astrophysical twin of the Earth, however its global cloud layer truncates features in transmission spectroscopy, masking its non-Earth-like nature. Observational indicators that can distinguish an exo-Venus from an exo-Earth must therefore survive above the cloud layer. The above-cl...

The depletion of SO2 and H2O in and above the clouds of Venus (45-65 km) cannot be explained by known gasphase chemistry and the observed composition of the atmosphere. We apply a full-atmosphere model of Venus to investigate three potential explanations for the SO2 and H2O depletion: (1) varying the below-cloud water vapor (H2O), (2) varying the b...

The study of the origin(s) of life on Earth and the search for life on other planets are closely linked. Prebiotic chemical scenarios can help priori-tize target planets for the search for life (as we know it) and can provide informative prior probabilities to help us assess the likelihood that particular spectroscopic features are evidence of life...

We predict that cyanoacetylene (HC$_3$N) is produced photochemically in the atmosphere of GJ 1132 b in abundances detectable by the James Webb Space Telescope (JWST), assuming that the atmosphere is as described by Swain et al. (2021). First, we construct line list and cross-sections for HC$_3$N. Then we apply these cross-sections and the model atm...

The recent candidate detection of ∼1 ppb of phosphine in the middle atmosphere of Venus is so unexpected that it requires an exhaustive search for explanations of its origin. Phosphorus-containing species have not been modeled for Venus' atmosphere before, and our work represents the first attempt to model phosphorus species in the venusian atmosph...

Measurements of trace gases in planetary atmospheres help us explore chemical conditions different to those on Earth. Our nearest neighbour, Venus, has cloud decks that are temperate but hyperacidic. Here we report the apparent presence of phosphine (PH3) gas in Venus’s atmosphere, where any phosphorus should be in oxidized forms. Single-line milli...

We present and validate a new network of atmospheric thermo-chemical and photo-chemical sulfur reactions. We use a 1-D chemical kinetics model to investigate these reactions as part of a broader HCNO chemical network in a series of hot and warm Jupiters. We find that temperatures approaching 1400 K are favourable for the production of H2S and HS ar...

Ultraviolet (UV) light has long been invoked as a source of energy for prebiotic chemical synthesis, but experimental support does not involve sources of UV light that look like the young Sun. Here we experimentally investigate whether the UV flux available on the surface of early Earth, given a favorable atmosphere, can facilitate a variety of pre...

We recover PH3 in the atmosphere of Venus in data taken with ALMA, using three different calibration methods. The whole-planet signal is recovered with 5.4{\sigma} confidence using Venus bandpass self-calibration, and two simpler approaches are shown to yield example 4.5-4.8{\sigma} detections of the equatorial belt. Non-recovery by Villanueva et a...

The depletion of SO$_2$ and H$_2$O in and above the clouds of Venus (45 -- 65 km) cannot be explained by known gas-phase chemistry and the observed composition of the atmosphere. We apply a full-atmosphere model of Venus to investigate three potential explanations for the SO$_2$ and H$_2$O depletion: (1) varying the below-cloud water vapor (H$_2$O)...

https://arxiv.org/abs/2012.12132 Hot Jupiters provide valuable natural laboratories for studying potential contributions of high-energy radiation to prebiotic synthesis in the atmospheres of exoplanets. In this fourth paper of the MOVES (Multiwavelength Observations of an eVaporating Exoplanet and its Star) programme, we study the effect of differe...

Hot Jupiters provide valuable natural laboratories for studying potential contributions of high-energy radiation to prebiotic synthesis in the atmospheres of exoplanets. In this fourth paper of the MOVES (Multiwavelength Observations of an eVaporating Exoplanet and its Star) programme, we study the effect of different types of high-energy radiation...

We published spectra of phosphine molecules in Venus' clouds, following open-science principles in releasing data and scripts (with community input leading to ALMA re-processing, now benefiting multiple projects). Some misconceptions about de-trending of spectral baselines have also emerged, which we address here. Using the JCMT PH3-discovery data,...

We first respond to two points raised by Villanueva et al. We show the JCMT discovery spectrum of PH3 can not be re-attributed to SO2, as the line width is larger than observed for SO2 features, and the required abundance would be an extreme outlier. The JCMT spectrum is also consistent with our simple model, constant PH3-abundance with altitude, w...

Hydrogen in rocky planet atmospheres has been invoked in arguments for extending the habitable zone via N2-H2 and CO2-H2 greenhouse warming, and providing atmospheric conditions suitable for efficient production of prebiotic molecules. On Earth and Super-Earth-sized bodies, where hydrogen-rich primordial envelopes are quickly lost to space, volcani...

A plausible explanation for the origin of life must satisfy constraints imposed by both organic chemistry and early Earth geochemistry. However, the full scope of geochemical parameter space is rarely considered by either theoretical or experimental models of abiogenesis. Here we propose a novel approach, which can make maximum use of available dat...

The recent candidate detection of 20 ppb of phosphine in the middle atmosphere of Venus is so unexpected that it requires an exhaustive search for explanations of its origin. Phosphorus-containing species have not been modelled for Venusian atmosphere before and our work represents the first attempt to model phosphorus species in Venusian atmospher...

Measurements of trace-gases in planetary atmospheres help us explore chemical conditions different to those on Earth. Our nearest neighbor, Venus, has cloud decks that are temperate but hyper-acidic. We report the apparent presence of phosphine (PH3) gas in Venusian atmosphere, where any phosphorus should be in oxidized forms. Single-line millimete...

Hydrogen in rocky planet atmospheres has been invoked in arguments for extending the habitable zone via N2-H2 and CO2-H2 greenhouse warming, and providing atmospheric conditions suitable for efficient production of prebiotic molecules. On Earth and Super-Earth-sized bodies, where H2-rich primordial envelopes are quickly lost to space, volcanic outg...

2020. The American Astronomical Society. All rights reserved.. We perform a study of stellar flares for the 24,809 stars observed with 2 minute cadence during the first two months of the TESS mission. Flares may erode exoplanets' atmospheres and impact their habitability, but might also trigger the genesis of life around small stars. TESS provides...

The study of the composition of brown dwarf atmospheres helped to understand their formation and evolution. Similarly, the study of exoplanet atmospheres is expected to constrain their formation and evolutionary states. We use results from three-dimensional simulations, kinetic cloud formation and kinetic ion-neutral chemistry to investigate ioniza...

Chemical compositions of exoplanets can provide key insights into their physical processes and formation and evolutionary histories. Atmospheric spectroscopy provides a direct avenue to probe exoplanetary compositions. However, whether obtained in transit or thermal emission, spectroscopic observations probe limited pressure windows of planetary at...

A key challenge in origins-of-life studies is estimating the abundances of species relevant to the chemical pathways proposed to have contributed to the emergence of life on early Earth. Dissolved nitrogen oxide anions (NO ⁻x ), in particular nitrate (NO ⁻3 ) and nitrite (NO ⁻2 ), have been invoked in diverse origins-of-life chemistry, from the oli...

The study of the composition of brown dwarf atmospheres helped to understand their formation and evolution. Similarly, the study of exoplanet atmospheres is expected to constrain their formation and evolutionary states. We use results from 3D simulations, kinetic cloud formation and kinetic ion-neutral chemistry to investigate ionisation processes...

Hydrogen cyanide (HCN) is a key feedstock molecule for the production of life's building blocks. The formation of HCN in an N 2 -rich atmospheres requires first that the triple bond between N≡N be severed, and then that the atomic nitrogen find a carbon atom. These two tasks can be accomplished via photochemistry, lightning, impacts, or volcanism....

Hydrogen cyanide (HCN) is a key feedstock molecule for the production of life's building blocks. The formation of HCN in an N$_2$-rich atmospheres requires first that the triple bond between N$\equiv$N be severed, and then that the atomic nitrogen find a carbon atom. These two tasks can be accomplished via photochemistry, lightning, impacts, or vol...

A key challenge in origins-of-life studies is estimating the abundances of species relevant to the chemical pathways proposed to have contributed to the emergence of life on early Earth. Dissolved nitrogen oxide anions (NO$_{X}^{-}$), in particular nitrate (NO$_{3}^{-}$) and nitrite (NO$_{2}^{-}$), have been invoked in diverse origins-of-life chemi...