Mikhael Bechelany

Université de Montpellier | UM1 · Institut Européen des Membranes (IEM)

Chromium carbonitride (CrCN) coatings present the desired characteristics for improving the mechanical properties and the corrosion resistance of marine components. The purpose of this work is to investigate the effect of carbon insertion, using CH 4 gas flow as the carbon precursor in magnetron sputtering, on the mechanical and electrochemical pro...

Halloysite nanotubes (HNTs) are clay minerals with a tubular structure that can be used for many different applications in place of carbon nanotubes. Indeed, HNTs display low/non-toxicity, are biocompatible, and can be easily prepared. Moreover, the aluminum and silica groups present on HNTs' inner and outer surfaces facilitate the interaction with...

This work consists of optimizing TiN plasma-enhanced atomic layer deposition using two different N-sources: NH[Formula: see text] and N[Formula: see text]. In addition to maximizing the growth per cycle (GPC) and to shorten the deposition duration, comprehensive in situ and ex situ physicochemical characterizations give valuable information about t...

Here, we fabricated non-toxic composite nanofibers by including controlled amounts of boron nitride (BN) nanosheets (5%), titanium oxide (TiO2) nanofibers and halloysite nanotubes (HNT) with the aim of obtaining a good catalyst for acetaminophen (ACT) degradation. After annealing at 400 °C under air, we characterized the samples’ morphological, str...

3D bioprinted hydrogel constructs are advanced systems of a great drug delivery application potential. One of the bioinks that has recently gained a lot of attention is gelatin methacrylate (GelMA) hydrogel exhibiting specific properties, including UV cross-linking possibility. The present study aimed to develop a new bioink composed of GelMA and g...

Although lithium metal and anode-free rechargeable batteries (LMBs and AFBs) are phenomenal energy storage systems, the formation of lithium deposits with high surfaces during repeated plating–stripping cycles has hindered their practical applications. Recently, extensive efforts have been made to prevent the growth of high-surface lithium depositi...

The appearance of the biomarkers in body fluids like blood, urine, saliva, tears, etc. can be used for the identification of many diseases. This article aimed to summarize the studies about electrochemical biosensors with molecularly imprinted polymers as sensitive and selective layers on the electrode to detect protein-based biomarkers of such neu...

Electrospun fibers, often used as drug delivery systems, have two drawbacks - in the first stage of their action a sudden active substance burst release occurs and they have a relatively small capacity for a drug. In this work the fibers are modified by the addition of drug-loaded microspheres acting as micro-containers for the drug and increasing...

In this study, we combined electrospinning of a large amount of halloysite (HNT, 95%) with nitriding to produce N-HNT-TiO2 composite nanofibers (N-H95T5 hereafter) to be used for acetaminophen (ACT) photodegradation. Investigation of the morphological and structural properties of the obtained materials did not highlight any significant difference i...

In recent decades, much attention has been paid to using nanomaterials in the development of highly- sensitive sensors for environmental monitoring. This review describes how nanomaterials are being used to develop electrochemical sensing platforms for environmental analysis (air pollution, water quality, soil nutrients, and soil pathogens). In par...

Photocatalysis can be understood as the acceleration of chemical reactions by incident light. These reactions typically perform poorly without photoactivation and the presence of a catalyst. Photocatalysis could find applications in a wide range of fields, such as renewable energy and environmental remediation. The advance in the photocatalysis fie...

In this study, we designed a new structure based on Pd-decorated TiN-coated SnO2 nanowires (NWs), for selective detection of H2 gas. Initially, SnO2 NWs were prepared using a simple vapor-liquid-solid...

In this article, we report the development of an electrochemical biosensor for the determination of the SARS-CoV-2 spike protein (rS). A gold disc electrode was electrochemically modified to form the nanocrystalline gold structure on the surface. Then, it was further altered by a self-assembling monolayer based on a mixture of two alkane thiols: 11...

The 316L stainless steels, often used in turbine blades for naval and marine applications, usually suffer from localized pitting corrosion after long exposure to chlorinated environments. The aluminum-zirconium coatings deposited by magnetron sputtering technique can be used to ensure cathodic protection for steels. In this work, we study the influ...

Cellulose nanocrystals (CNC) are drawing increasing attention in the fields of biomedicine and healthcare owing to their durability, biocompatibility, biodegradability and excellent mechanical properties. Herein, we fabricated using fused deposition modelling technology 3D composite scaffolds from polylactic acid (PLA) and CNC extracted from Ficus...

Flow-electrode capacitive deionization (FCDI) is a potential energy-efficient electrochemical water desalination technology that combines ion-exchange membranes and flowable electrodes (FE). The performance of activated carbon (AC)-based FEs in FCDI systems is influenced by various factors, including particle size. Here, particle size commercial AC...

The SARS-CoV-2 spike glycoprotein (SARS-CoV-2-S) was used as a template molecule and polypyrrole (Ppy) was applied as an electro-generated conducting polymer, which was acting as a matrix for the formation of molecular imprints. Two types of Ppy-layers: molecularly imprinted polypyrrole (MIP-Ppy) and non-imprinted polypyrrole (NIP-Ppy) were electro...

This study describes the fabrication of an aflatoxin (AFB1) electrochemical immunosensor by immobilization of an anti-AFB1 antibody-bovine serum albumin (BSA) conjugate on a layer of L-cysteine (L-Cys) used to link the antibody to the palladium nanoparticle-boron nitride (PdNP-BN)-modified carbon felt (CF) electrode. Each step of the immunosensor f...

Titanium dioxide (TiO2) is widely used in photocatalysis applications for wastewater treatment. Investigations demonstrated that titanium dioxide structure strongly contributes to increase micropollutant degradation efficiency. Indeed, pollutant degradation rates are enhanced when using photocatalysts with highly ordered structures and high specifi...

Bio-based ceramic membranes were elaborated from kaolinite clays, coconut husks and eggshells to retain E. coli bacteria present in water intended for human consumption. Their characterization and removal performances are investigated in this work. These bio-ceramic membranes were obtained by heating the formulation containing 75% clay, 15% coconut...

Nanomaterials are materials with one or more nanoscale dimensions (internal or external) (i.e., 1 to 100 nm). The nanomaterial shape, size, porosity, surface chemistry, and composition are controlled at the nanoscale, and this offers interesting properties compared with bulk materials. This review describes how nanomaterials are classified, their f...

The 316L Stainless Steel is widely used as structural material in marine applications and is subject to localized pitting corrosion in chlorinated environments. The main aim of the present work is the development of coatings that are alternately deposited by a combination of Physical Vapor Deposition (PVD) and Atomic Layer Deposition (ALD) techniqu...

Polymer microspheres with controlled sizes have attracted interest due to their potential use in medical field. Therefore it is of great importance to be able to produce a large number of disaggregated microspheres with a narrow diameter distribution. This work describes the successful elaboration of the method combining electrospray and wet phase...

3D bioprinting uses bioink deposited directly on a collector to create any previously designed 3D model. One of the most common and the easiest to operate bioinks is gelatin-alginate hydrogel. The present study aimed to combine 3D bioprinting with different cross-linking techniques to develop a new stable and biodegradable gelatin-alginate hydrogel...

While lithium metal is considered an ideal anode for the next generation of high-energy-density batteries, some major issues such as huge volume change and continuous dendrite formation during lithium plating have hindered its practical applications. Zinc oxide (ZnO) modification of surfaces has shown great potential for inducing a homogeneous Li p...

Titanium oxide (TiO2) nanofibers are interesting for environmental applications, particularly solar energy and water treatment, due to their physical properties, chemical stability, high activity, and strong oxidation capacity. Here, we designed and synthesized halloysite-TiO2 nanocomposite fibers by combining the electrospinning and sol-gel method...

Cellulose nanocrystals (CNC) are drawing increasing attention in the fields of biomedicine and healthcare owing to their durability, biocompatibility, biodegradability and excellent mechanical properties. Herein, we fabricated using fused deposition modelling (FDM) technology 3D composite scaffolds from polylactic acid (PLA) and CNC extracted from...

The aim of this work was the development of injectable radio-opaque and macroporous calcium phosphate cement (CPC) to be used as a bone substitute for the treatment of pathologic vertebral fractures. A CPC was first rendered radio-opaque by the incorporation of zirconium dioxide (ZrO2). In order to create macroporosity, poly lactic-co-glycolic acid...

One-dimensional BN/Ce2O3/TiO2 heteroarchitectures with high visible-light photocatalytic activity have been successfully obtained by an electrospinning technique. The properties of the prepared nanofibers were controlled using different ratios of cerium. The results of XPS characterization revealed that the Ce element is present in the valence stat...

Abstract Atomic layer deposition (ALD) is a chemical vapour deposition (CVD) method that allows the layer-by-layer growth of functional materials by exposing a surface to different precursors in an alternative fashion. Thus, thanks to gas-solid reactions that are substrate-limited and self-terminating, precise control over thickness below the nano...

Flow capacitive deionization is a variant of capacitive deionization allowing continuous/semi continuous desalination. Performance of electrode is linked to factors such as applied voltage, feed electrode hydrophilicity, carbon loading, conductivity of the feed electrolyte, particle size, viscosity etc. In this paper, a new approach was adopted in...

Continuous painless glucose monitoring is the greatest desire of more than 422 million diabetics worldwide. Therefore, new non-invasive and convenient approaches to glucose monitoring are more in demand than other tests for microanalytical diagnostic tools. Besides, blood glucose detection can be replaced by continuous glucose monitoring of other h...

Recent challenges in the pharmaceutical and biomedical fields require the development of new analytical methods. Therefore, the development of new sensors is a very important task. In this paper, we are outlining the development of molecularly imprinted polymer (MIP) based sensors, which belongs to important branch of affinity sensors. In this revi...

The majority of proposed exotic applications employing 3D topological insulators require high-quality materials with reduced dimensions. Catalyst-free, PVD-grown Bi2Se3 nanoribbons are particularly promising for these applications due to the extraordinarily high mobility of their surface Dirac states, and low bulk carrier densities. However, these...

M In the last few decades, the vast potential of nanomaterialsfor biomedical and healthcare applications has been extensively investigated. Several case studies demonstrated that nanomateri-alscan offer solutions to the current challenges ofraw materials in the biomedicalandhealthcare fields. This review describes the different nanoparticles and na...

Additive manufacturing of Polymer-Derived Ceramics (PDCs) is regarded as a disruptive fabrication process that includes several technologies such as light curing and ink writing. However, 3D printing based on material extrusion is still not fully explored. Here, an indirect 3D printing approach combining Fused Deposition Modeling (FDM) and replica...

The demand for fresh and clean water sources is increasing globally, and there is a need to develop novel routes to eliminate micropollutants and other harmful species from water. Photocatalysis is a promising alternative green technology that has shown great performance in the degradation of persistent pollutants. Titanium dioxide is the most used...

Nanomaterials are becoming important materials in several fields and industries thanks to their very reduced size and shape-related features. Scientists think that nanoparticles and nanostructured materials originated during the Big Bang process from meteorites leading to the formation of the universe and Earth. Since 1990, the term nanotechnology...

Skin biocompatible materials are among the fastest-growing markets for nanocelluloses, with a growing number of patents published over the past ten years. This review highlights the recent developments, market trends, safety assessment, safety regulations, and challenges for different nanocellulose types used in skincare, cosmetics, and healthcare....

Flow capacitive deionization is a water desalination technique that uses liquid carbon-based electrodes to recover fresh water from brackish or seawater. This is a potential second-generation water desalination process, however it is limited by parameters such as feed electrode conductivity, interfacial resistance, viscosity, and so on. In this stu...

Nanocelluloses are promising bio-nano-materials for use as water treatment materials in environmental protection and remediation. Over the past decades, they have been integrated via novel nanoengineering approaches for water treatment processes. This review aims at giving an overview of nanocellulose requirements concerning emerging nanotechnologi...

This study describes the application of a polypyrrole-based sensor for the determination of SARS-CoV-2-S spike glycoprotein. The SARS-CoV-2-S spike glycoprotein is a spike protein of the coronavirus SARS-CoV-2 that recently caused the worldwide spread of COVID-19 disease. This study is dedicated to the development of an electrochemical determinatio...

Due to the global problem with plastic contaminating the environment, with bisphenol A (BPA) being one of the highest demand, effective monitoring and purification of the pollutants are required. The electrochemical methods constitute a good solution but, due to polymerization of electrochemical oxidation bisphenol A products and their adsorption t...

We developed free-standing nitrogen-doped carbon nanofiber (CNF) electrodes incorporating Co/CoOx nanoparticles (NPs) as a new cathode material for removing Acid Orange 7 (AO7; a dye for wool) from wastewater by the heterogeneous electro-Fenton reaction. We produced the free-standing N-doped CNF electrodes by electrospinning a polyacrylonitrile (PA...

Carbon nanomaterials (CNMs) have received tremendous interest in the area of nanotechnology due to their unique properties and flexible dimensional structure. CNMs have excellent electrical, thermal, and optical properties that make them promising materials for drug delivery, bioimaging, biosensing, and tissue engineering applications. Currently, t...

Several strategies are currently available to improve the photocatalytic response and performance of materials and devices. Despite this, the most common strategies are still based on the promotion of efficient carrier transfer/lifetime of photo-exited electrons and bandgap tailoring. In this work, we present conclusive experimental evidence of the...

In this report, lanthanum strontium manganite at different Sr2+ ion concentrations, as well as Gd3+ or Sm3+ ion substituted La0.5−YMYSr0.5MnO3 (M = Gd and Sm, y = 0.2), have been purposefully tailored using a sol gel auto-combustion approach. XRD profiles confirmed the formation of a monoclinic perovskite phase. FE-SEM analysis displayed a spherica...

Constant, real-time temperature monitoring of the supercapacitors for efficient energy usage is in high demand and seems to be crucial for further development of those elements. A fiber-optic sensor can be an effective optoelectronic device dedicated for in-situ temperature monitoring of supercapacitors. In this work, the application of the fiber-o...

In this paper, we are relating a significant improvement of the SERS effect achieved with assembled Au/ZnO nano-urchins. This improvement is realized thanks to an excellent capacity of adsorption (denoted K) for thiram molecules on these plasmonic nano-urchins, which is a key point to be taken into account for obtaining a SERS spectrum. Moreover, t...

The yield and morphology (length, width, thickness) of stoichiometric Bi2Se3 nanoribbons grown by physical vapor deposition is studied as a function of the diameters and areal number density of the Au catalyst nanoparticles of mean diameters 8–150 nm formed by dewetting Au layers of thicknesses 1.5–16 nm. The highest yield of the Bi2Se3 nanoribbons...

The presence of pharmaceuticals in water bodies has become a major concern in recent years. An efficient and innovative way of eliminating these pollutants is through photoelectrocatalytic (PEC) degradation owing to its environmental sustainability and its ability to remove recalcitrant pollutants. In this study, palladium loaded zinc oxide/carbon...

This study presents the microsphere-based fiber-optic sensor with the ZnO Atomic Layer Deposition coating thickness of 100 nm and 200 nm for temperature measurements. Metrological properties of the sensor were investigated over the temperature range from 100 °C to 300 °C, with a 10 °C step. The interferometric signal was used to monitor the integri...

The development of heterogeneous nanomaterials with high surface to volume ratio is crucial for enhancing the adsorption of water pollutants, such as toxic organic dyes. Here, we describe the synthesis of polyacrylonitrile (PAN) nanofibers coated with porous alumina nanolayers, and their application for adsorption of the organic dye methylene blue...

Zinc oxide (ZnO) and porous anodic aluminum oxide (PAAO) are technologically important materials, rich with features that are of interest in optical applications, for example, in light-emitting and sensing devices. Here, we present synthesis method of aligned ZnO nanorods (NR) with 40 nm diameter and variable length in 150 to 500 nm range obtained...

Designing efficient electrode materials for electrochemical water splitting is the most critical challenge for next-generation hydrogen fuel production. This study describes the development of free-standing nitrogen-doped carbon nanofiber (N-CNF) electrodes...

We report a novel route for enhancing the humidity resistance of SnO2 nanowires (NWs; widely used metal oxide semiconductor gas sensors) based on their coating with a humidity-resistant nanomembrane. A conformal thin film was deposited by Molecular Layer Deposition (MLD) on the SnO2 NWs using trimethylaluminum and ethylene glycol as precursors (100...

In recent years, the study of modified-TiO2 based electrodes has gained great attention to help improve its photo-electrochemical performance. Modifications with metals [1,2], non-metals [3,4], transition metals [5,6] and rare-earth metals [7,8] have been studied; however, research in alkali-modified TiO2 is limited when compared to the aforementio...

Levofloxacin (LF) is a medically important antibiotic drug that is used to treat a variety of bacterial infections. In this study, three highly sensitive and selective carbon paste electrodes (CPEs) were fabricated for potentiometric determination of the LF drug: (i) CPEs filled with carbon paste (referred to as CPE); (ii) CPE coated (drop-casted)...