
Michael James HenehanUniversity of Bristol | UB · School of Earth Sciences
Michael James Henehan
PhD, Palaeoclimate/Geochemistry
Senior Lecturer in Marine Geochemistry at the University of Bristol.
PI of the PETRARCH project.
About
78
Publications
22,665
Reads
How we measure 'reads'
A 'read' is counted each time someone views a publication summary (such as the title, abstract, and list of authors), clicks on a figure, or views or downloads the full-text. Learn more
1,886
Citations
Introduction
I study how the Earth's carbon cycle and silicate weathering feedback work, and the effect of carbon cycle changes on past climates. This scales from the mechanistic drivers of silicate weathering within the critical zone to the reconstruction of past pCO2 and biogeochemical cycling on global and multi-million year timescales.
My tools of choice are primarily B, Li, Mg isotopes, and carbonate trace element ratios.
Additional affiliations
August 2013 - February 2014
Education
December 2009 - September 2013
October 2005 - June 2009
Publications
Publications (78)
Reversible adsorption and isotope fractionation of boron on the surface of clay minerals is a key process that impacts boron isotope cycling in porewater, rivers and the ocean. However, the differences in boron isotope fractionation factors between various clay minerals and their dependence on fluid chemistry are not well known. We performed two se...
The boron isotope ratio of seawater (δ¹¹Bsw) is a parameter which must be known to reconstruct palaeo pH and CO2 from boron isotope measurements of marine carbonates. Beyond a few million years ago, δ¹¹Bsw is likely to have been different to modern. Palaeo δ¹¹Bsw can be estimated by simultaneously constraining the vertical gradients in foraminifera...
“X-ray diffraction (XRD)” rather than “X-ray fluorescence (XRF)” was printed in the captions to Figure 7, Figure 9, and Figure 10. See PDF file for details.
The geological record encodes the relationship between climate and atmospheric carbon dioxide (CO 2 ) over long and short timescales, as well as potential drivers of evolutionary transitions. However, reconstructing CO 2 beyond direct measurements requires the use of paleoproxies and herein lies the challenge, as proxies differ in their assumptions...
Astrochronologically calibrated deep‐sea records document the Cenozoic (66–0 Ma) global climatic cooling in great detail, but the magnitude of sea‐level fluctuations of the middle Eocene Warmhouse state (47.8–37.7 Ma) and the ∼40.3 Ma warming event of the Middle Eocene Climatic Optimum (MECO) is not well constrained. Here, we present a sequence str...
The boron isotope ratio of seawater (δ11Bsw) is a parameter which must be known to reconstruct palaeo pH and CO2 from boron isotope measurements of marine carbonates. Beyond a few million years ago, δ11Bsw is likely to have been different to modern. Palaeo δ11Bsw can be estimated by simultaneously constraining the vertical gradients in foraminifera...
The chemical weathering of silicate rocks plays a central role in stabilizing our climate through CO2 drawdown. Li isotopic evidence from a prolonged Eocene warming event suggests clay formation may disrupt this feedback on intermediate timescales.
Few hypotheses in geoscience have had as lasting an impact as the Earth’s silicate weathering feedba...
Green et al. apply new statistical methods to a long-noted temporal correlation between mass extinctions and continental large igneous province (LIP) eruptions. Having concluded that the probability of said temporal coincidence by chance alone is extremely low, like others before them, Green et al. cite this correlation as evidence for causation. T...
The Cretaceous/Paleogene (K/Pg) boundary is marked by one of the largest mass extinctions in Earth’s history, with geological evidence for this event being expressed in hundreds of locations worldwide. An extensively studied section located near El Kef, northwestern Tunisia, is characterized by the classic iridium-rich K/Pg boundary layer, abundant...
Paleotemperature proxy data form the cornerstone of paleoclimate research and are integral to understanding the evolution of the Earth system across the Phanerozoic Eon. Here, we present PhanSST, a database containing over 150,000 data points from five proxy systems that can be used to estimate past sea surface temperature. The geochemical data hav...
Lithium isotopes are used to trace weathering intensity, but little is known about the processes that fractionate them in highly weathered settings, where secondary minerals play a dominant role in weathering reactions. To help fill this gap in our knowledge of Li isotope systematics, we investigated Li isotope fractionation at an andesitic catchme...
In a small, forested catchment underlain by gneiss (Conventwald, Black Forest, Germany), we found that the magnesium isotope composition (δ²⁶Mg) of creek water did not show seasonal variability, despite variations in dissolved Mg concentrations. To investigate the potential controlling factors on water δ²⁶Mg values, we studied the Mg isotope compos...
Boron isotope ratios – as measured in marine calcium carbonate – are an established tracer of past seawater and calcifying fluid pH, and thus a powerful tool for probing marine calcifier physiology and reconstructing past atmospheric CO2 levels. For such applications, understanding the inorganic baseline upon which foraminiferal vital effects or co...
The stable isotopes of lithium (Li) serve as a robust proxy of silicate weathering. The fate and transport of these isotopes in the dissolved load of major rivers have been characterized to infer changes in both contemporary weathering regimes and paleo-conditions. In this contribution, we deconvolve this integrated signal into the individual proce...
seacarbx is a seacarb extension written in R, which enables to use seacarb (Gattuso et al., 2019) for deep-time carbonate system calculations or for culturing studies carried out in seawater with modified [Mg2+] and [Ca2+]. For this, the functions carb, K0, K1, K2, Ks, Kw, Kb, Kspa, and Kspc were modfied to account for the effect of seawater [Mg2+]...
In this study, to better understand the factors controlling the concentration and isotope composition of lithium (Li) in the ocean, we investigated the behaviour of Li during interaction of kaolinite with artificial seawater. Dissolution of kaolinite in Li-free seawater at acidic conditions (exp. 1) results in a strong preferential release of light...
The boron isotopic (δ11BSRM951) and trace element composition of marine carbonates are key proxies for understanding carbon cycling (pH) and palaeoceanographic change. However, comparability of results between laboratories requires carbonate reference materials. Here we report results of an inter‐laboratory comparison study to both assign δ11BSRM95...
The early Paleogene represents the most recent interval in Earth's history characterized by global greenhouse warmth on multi-million year timescales, yet our understanding of long-term climate and carbon cycle evolution in the low latitudes, and in particular the Indian Ocean, remains very poorly constrained. Here we present the first long-term su...
The Middle Eocene Climatic Optimum (MECO) was a gradual warming event and carbon cycle perturbation that occurred between 40.5 and 40.1 Ma. A number of characteristics, including greater‐than‐expected deep‐sea carbonate dissolution, a lack of globally coherent negative δ¹³C excursion in marine carbonates, a duration longer than the characteristic t...
An impact with a dash of volcanism
Around the time of the end-Cretaceous mass extinction that wiped out dinosaurs, there was both a bolide impact and a large amount of volcanism. Hull et al. ran several temperature simulations based on different volcanic outgassing scenarios and compared them with temperature records across the extinction event. Th...
Boron incorporated in marine biogenic carbonates records the pH of seawater during precipitation. From reconstructing atmospheric CO2 beyond ice-core records to deciphering the ocean's role in storing and releasing carbon, boron is proving to be a vital tool in paleoclimate research.
Significance
Debate lingers over what caused the last mass extinction 66 million years ago, with intense volcanism and extraterrestrial impact the most widely supported hypotheses. However, without empirical evidence for either’s exact environmental effects, it is difficult to discern which was most important in driving extinction. It is also uncle...
In most chemical reactions, stable isotopes are fractionated in a mass-dependent manner, yielding correlated isotope ratios in elements with three or more stable isotopes. The proportionality between isotope ratios is set by the triple isotope fractionation exponent, θ, that can be determined precisely for e.g. sulfur and oxygen by IRMS, but not fo...
Planktonic foraminiferal species identification is central to many paleoceanographic studies, from selecting species for geochemical research to elucidating the biotic dynamics of microfossil communities relevant to physical oceanographic processes and interconnected phenomena such as climate change. However, few resources exist to train students i...
Paleoclimate records suggest that a rapid major transient Antarctic glaciation occurred across the Oligocene‐Miocene transition (OMT; ca. 23 Ma; ~50‐m sea level equivalent in 200–300 kyr). Orbital forcing has long been cited as an important factor determining the timing of the OMT glacial event. A similar orbital configuration occurred 1.2 Myr prio...
The clustering of mitochondria near pores in the test walls of foraminifera suggests that these perforations play a critical role in metabolic gas exchange. As such, pore measurements could provide a novel means of tracking changes in metabolic rate in the fossil record. However, in planktonic foraminifera, variation in average pore area, density,...
The clustering of mitochondria near pores in the test walls of foraminifera suggests that these perforations play a critical role in metabolic gas exchange. As such, pore measurements could provide a novel means of tracking changes in metabolic rate in the fossil record. However, in planktonic foraminifera, variation in pore size, density, and poro...
The response of the marine carbon cycle to changes in atmospheric CO2 concentrations will be determined, in part, by the relative response of calcifying and non-calcifying organisms to global change. Planktonic foraminifera are responsible for a quarter or more of global carbonate production, therefore understanding the sensitivity of calcification...
The boron isotope-pH proxy has been widely used to reconstruct past ocean pH values. In both planktic foraminifera and corals, species-specific calibrations are required in order to reconstruct absolute values of pH, due to the prevalence of so-called vital effects — physiological modification of the primary environmental signals by the calcifying...
Boron isotope ratios, as measured in planktic foraminifera, can be a useful tracer of past ocean pH, and hence help to discern the concentration of CO2 in the ancient atmosphere. However, different species of planktic foraminifera demonstrate different patterns of boron isotope variation with ambient seawater pH. Therefore when applying the proxy t...
The chromium isotope system ((53) Cr/(52) Cr expressed as δ(53) Cr relative to NIST SRM 979) is potentially a powerful proxy for the redox state of the ocean-atmosphere system, but a lack of temporally continuous, well-calibrated archives has limited its application to date. Marine carbonates could potentially serve as a common and continuous Cr is...
One contribution of 17 to a theme issue 'Biodiversity and ecosystem functioning in dynamic landscapes'.
Pelagic ecosystem function is integral to global biogeochemical cycling, and plays a major role in modulating atmospheric CO2 concentrations (pCO2). Uncertainty as to the effects of human activities on marine ecosystem function hinders projectio...
Much of our knowledge of past ocean temperatures comes from the
foraminifera Mg / Ca palaeothermometer. Several nonthermal controls
on foraminifera Mg incorporation have been identified, of which
vital effects, salinity, and secular variation in seawater Mg / Ca are
the most commonly considered. Ocean carbonate chemistry is also known
to influence...
Pelagic ecosystem function is integral to global biogeochemical cycling, and plays a major role in modulating atmospheric CO2 concentrations (pCO2). Uncertainty as to the effects of human activities on marine ecosystem function hinders projection of future atmospheric pCO2. To this end, events in the geological past can provide informative case stu...
B/Ca ratios in foraminifera have attracted considerable scientific attention as a proxy for past ocean carbonate system. However, the carbonate system controls on B/Ca ratios are not straightforward, with Δ[CO32−] ([CO32−]in situ – [CO32−]at saturation) correlating best with B/Ca ratios in benthic foraminifera, rather than pH, or (as a simple model...
Atmospheric CO2 fluctuations over glacial–interglacial cycles remain a major challenge to our understanding of the carbon cycle and the climate system. Leading hypotheses put forward to explain glacial–interglacial atmospheric CO2 variations invoke changes in deep-ocean carbon storage1, 2, probably modulated by processes in the Southern Ocean, wher...
Biweekly sediment trap samples and concurrent hydrographic measurements collected between March 2005 and October 2008 from the Cariaco Basin, Venezuela, are used to assess the relationship between [CO32−] and the area densities (ρA) of two species of planktonic foraminifera (Globigerinoides ruber (pink) and Globigerinoides sacculifer). Calcificatio...
Biweekly sediment trap samples and concurrent hydrographic measurements collected between March 2005 and October 2008 from the Cariaco Basin, Venezuela, are used to assess the relationship between [CO3]2- and the area densities (ho A) of two species of planktonic foraminifera (Globigerinoides ruber (pink) and Globigerinoides sacculifer). Calcificat...
Questions
Question (1)
Unfortunately the Clay Mineral Society (clays.org) no longer have any pure illite in stock, and we need some for some experiments. If anyone knows where to find some, or has any of the old IMt-1 or IMt-2 CMS reference materials gathering dust in their lab, I'd really appreciate the input.
Thanks all,
Michael