Mattia Lopresti

• Doctor of Philosophy
• PhD at University of Piemonte Orientale Amedeo Avogadro

In this work, 37 enological tannins of different classes were studied to investigate whether linear sweep voltammetry (LSV) could be a method to determine the family of a sample and its antioxidant capacity. A "wholistic" approach was used, combining LSV data with nuclear magnetic resonance (NMR), polyphenol quantification (Folin-Ciocalteu method a...

The crystal structure of 4-methylcatechol (4MEC) has, to date, never been solved, despite its very simple chemical formula C7O2H8 and the many possible applications envisaged for this molecule. In this work, this gap is filled and the structure of 4MEC is obtained by combining X-ray powder diffraction and first principle calculations to carefully l...

In the original publication [...]

Salicylic and acetylsalicylic acids and ethacridine have complementary bioactive properties. They can be combined to obtain double-drug multicomponent crystals. Their reactivity in different environments was explored to obtain the possible compounds, stable at different hydration degrees. Solution, liquid-assisted grinding, and dry preparation appr...

Nanocrystalline powders of monometallic and bimetallic imidazolates of Co, Zn, and Ag were produced by a reaction carried out in water. The powders were characterized by powder X-ray diffraction and...

The RootProf computer program applies multivariate model-free analysis to crystallographic data and to any x, y experimental data in general. It has been enhanced with several new features, including a graphical user interface, multithreading implementation and additional pre-processing options. The program also includes novel qualitative analysis...

Eutectic mixtures are usually studied by differential scanning calorimetry (DSC), able to identify the transition temperatures, possible hysteresis, and investigate the energetic features of transformations. However, DSC is not able to give compositional, structural, or morphological information. A new approach is proposed exploiting powder X-ray d...

Sodium sebacate salts have several industrial applications as additives, lubricants, and a metal self-healing promoter in general industry, and some derivatives also have wide applications in cosmetics and pharmaceutical fields. Calcium sebacate formation and precipitation can be detrimental for the systems where sodium sebacate is used. It is thus...

The liquid-assisted grinding (LAG) approach was exploited to efficiently produce a new salt cocrystal with a minimum expenditure of reagents and energy, with possible application in the pharmaceutical field. LAG was applied to the acridine/diclofenac couple, and a new cocrystal was obtained with a 1:1 ratio of reagents and its structure resolved by...

Magnesium alloys in general, and AZ31 in particular, have huge potential as materials for energy saving and emissions reduction in the transportation of people and goods, because of their low density (about 1.7 g∙cm⁻³) coupled to good bulk mechanical properties. The main weakness is represented by the alloy surface, prone to corrosion and rather so...

In materials and earth science, but also in chemistry, pharmaceutics and engineering, the quantification of elements and crystal phases in solid samples is often essential for a full characterization of materials. The most frequently used techniques for this purpose are X-ray fluorescence (XRF) for elemental analysis and X-ray powder diffraction (X...

X-ray powder diffraction (XRPD) is an important technique for qualitative, quantitative and textural analyses, which exploits the scattering of X-rays by matter. The output of the method consists in a pattern, unique for each material, that can be analyzed to extract precious information on the investigated sample. When polycrystalline materials ar...

The co-crystallization of active pharmaceutical ingredient naproxen with some acridines (acridine, 9-aminoacridine, 6,9-diamino-2-ethoxyacridine) has been explored, as well as the conditions under which the crystallization can be carried out have...

Mechanical properties such as the Young modulus, shear modulus and Poisson’s coefficient are very important to define different materials applications, for basic research and for quality control procedures. Impulse excitation technique (IET) is a non-destructive, easy and fast method for material characterization of elastic and acoustic properties....

In the past twenty years, impulse excitation technique (IET) has become a widely diffused non-destructive technique in metal industry field. This success resides in its capability to determine with high precision and accuracy some elastic properties of materials, such as Young’s modulus, shear modulus and Poisson’s ratio. The technique, which is ve...

Low-cost, environmentally friendly and easily applicable coating for Mg alloys, able to resist in real world conditions, are studied. Coatings already used for other metals (aluminum, steel) and never tested on Mg alloy for its different surface and reactivity were deposited on AM60 magnesium alloys to facilitate their technological applications, a...

Micro-absorption (MA) and/or preferred orientations (PO) are two among the major problems affecting quantitative phase analysis (QPA) by X-ray Powder Diffraction Data (XRPD) in industrial samples such as minerals and ores, additives, cements, friction materials, coal combustion by-products. Typically XRPD data are coupled to elemental analysis by X...

Multivariate analysis (MA) is becoming a fundamental tool for processing in an efficient way the large amount of data collected in X-ray diffraction experiments. Multi-wedge data collections can increase the data quality in case of tiny protein crystals; in situ or operando setups allow investigating changes on powder samples occurring during repea...

Epoxy resins additivated by barium sulfate proved to be promising low cost, easy workable and environmentally friendly alternative to lead and steel as X-ray shielding materials, but the composites tends to be stratified, with the additive accumulating in the bottom side of the sample. This sedimentation process has been, at first, studied by in si...

New very fast and efficient detectors, installed both on laboratory instruments and synchrotron facilities, allow the monitoring of solid-state reactions from subsecond to minute scales with the production of large amounts of data. Traditional “one-by-one” pattern refinement needs complementary approaches, useful to handle hundreds to thousands of...

Composite lightweight materials for X-ray shielding applications were studied anddeveloped with the goal of replacing traditional screens made of lead and steel, with innovativematerials with similar shielding properties, but lighter, more easily formed and workable, with lowerimpact on the environment and reduced toxicity for human health. New epo...

Study of encapsulated systems for self-healing cementitious materials.