Margarita Jambrina-Enríquez

University of La Laguna | ULL · Biología Animal Edafología y Geología

The molecular biomarker composition of two sediment cores from Sanabria Lake (NW Iberian Peninsula) and a survey of modern plants in the watershed provide a reconstruction of past vegetation and landscape dynamics since deglaciation. During a proglacial stage in Lake Sanabria (prior to 14.7 cal ka BP), very low biomarker concentration and carbon pr...

Mountain lakes are particularly sensitive to global change as their oligotrophic conditions may be rapidly altered after reaching an ecological threshold, due to increasing human impact and climate change. Sanabria Lake, the largest mountain lake in the Iberian Peninsula and with a recent history of increased human impact in its watershed, provides...

Leaf waxes have been assumed to be the dominant source of wax delivered to sediment. However, wooden branches and twigs have not been widely considered in this context and could be a potential source of wax lipids in fire places or combustion structures. Black sedimentary layers are the main material of open-air archaeological combustion structures...

Molecular and isotopic approaches offer the chance to identify combustion residues and substrate components of archaeological combustion features to infer past fire-related activities. Analysis of fatty acid methyl esters by gas chromatography-combustion-isotope ratio mass spectrometry have been successfully used to distinguish among different anim...

The Northern Iberian Plateau during the Early Iron Age witnessed the proliferation of villages, showcasing well-preserved earthen architectural remains that offer valuable insights into past daily life practices. However, the application of high-resolution geoarchaeological approaches to these contexts has been largely overlooked, despite their sig...

Archaeological research has increasingly focused on studying combustion features as valuable sources of information regarding past technological and cultural aspects. The use of microstratigraphic and biomolecular techniques enables the identification of combustion residues and substrate components, and infer about past fire-related activities and...

Tar or pitch produced from pine resin and wood played an important role in the past as an adhesive, waterproofing and medicinal product. However, the formation and biomolecular composition of pine tar produced only from resin under different combustion conditions (i.e., temperature and oxygen availability during heating) has not been as widely inve...

The indigenous populations of La Palma (Canary Islands), who arrived on the island from Northwest Africa ca. 2000 years B.P., were predominantly pastoralists. Yet, many aspects of their subsistence economy such as the procurement, management, and use of wild plant resources remain largely unknown. To explore this, we studied the 600–1100‐year‐old a...

Unlabelled: Different types of plant tissues and resin can account for the wax lipids found in sedimentary contexts and archaeological samples. Consequently, there is increasing research to characterize the fatty acid carbon isotope ratios of different plant anatomical parts and their plant exudates (resin). With the aim to explore isotopic differ...

This study presents a hydroclimatic reconstruction from Crvena Stijena (Montenegro, Balkan Peninsula), a rock shelter that has yielded evidence for Middle Paleolithic human occupation. The integration of lipid biomarkers, hydrogen (δD) isotopic compositions of n-alkanes, and organic elemental geochemistry in the 7-m deep vertical sedimentary sequen...

The isotopic composition of matter is controlled by different physical, chemical, and biological mechanisms [...]

High-altitude island environments, with their characteristic strong seasonal contrast and limited resources, are challenging contexts for human subsistence. However, although archaeological contexts in this kind of setting hold great potential to explore the diversity of human biological and cultural adaptations, such sites are rare. In this paper,...

This paper reports on a series of heating experiments that focus on n-alkanes extracted from leaf, bark, and xylem tissues of the Celtis australis plant. These lipid biomarkers were analysed for their compound-specific hydrogen isotopic composition (δ2Hwax) under limited oxygen conditions at 150, 250, 350, and 450 °C. Our results reveal isotopic va...

Burned or charred organic matter in anthropogenic combustion features may provide important clues about past human activities related to fire. To interpret archaeological hearths, a correct identification of the organic source material is key. In the present work, Raman spectroscopy is applied to characterise the structural properties of char produ...

Characterizing organic matter preserved in archaeological sediment is crucial to behavioral and paleoenvironmental investigations. This task becomes particularly challenging when considering microstratigraphic complexity. Most of the current analytical methods rely on loose sediment samples lacking spatial and temporal resolution at a microstratigr...

By studying combustion structures, which conceal information about anthropogenic activity, we might learn about their makers. This is especially important for remote time periods like the Middle Paleolithic, whose archaeological record comprises numerous combustion structures. The majority of these are simple, flat, open hearths, although a small n...

The Carbon Preference Index (CPI) is a molecular ratio often used to assign the biological source and maturity of organic matter. This parameter is frequently employed in paleoenvironmental studies and archaeological applications. In this paper, we have evaluated the different results for this index using peak areas or concentrations from calibrati...

This paper presents a multiproxy palaeoenvironmental study from Abric del Pastor (Alcoy, Spain), a rock shelter which has yielded evidence for Middle Palaeolithic human occupation. The sedimentary sequence has been analysed for lipid biomarker n-alkane abundances (ACL, CPI), compound specific leaf wax δ2H and δ13C, and bulk organic geochemistry (TO...

Middle Paleolithic lithic and faunal assemblages throughout Eurasia reflect short-term Neanderthal occupations, which suggest high group mobility. However, the timing of these short-term occupations, a key factor to assess group mobility and territorial range, remains unresolved. Anthropogenic combustion structures are prominent in the Middle Paleo...

Micromorphological description of MFU with accompanying MFT. (PDF)

Thin sections of the sample set with indication on the position of the combustion structure. Sample set divided into inner area and outer area according to the provenience of the samples (see Fig 2). (TIF)

This is a protocol of a method used to obtain the total lipid extract (TLE) from archaeological sediment samples and the further elution of the TLE into different fraction and their preparation for GC-MS analysis.

The present multi-isotopic study (δ18O–δDwater, δ34S–δ18Odissolved-sulphate, δ13Cdissolved-inorganic-carbon, δ13C–δ18Oshells-modern-gastropods, δ13Cplants, and δ13Csedimentary-organic-matter) is aimed at assessing the hydrogeochemical changes and biogeochemical dynamics in a Mediterranean shallow lake fed by a Quaternary–Tertiary aquifer, the “Lagu...

We present a source-to-sink environmental magnetic study of a sediment core from Lake Sanabria (north-west Iberian Peninsula) and rocks of its catchment. The results indicate the occurrence of magnetite, and probably also pyrrhotite, in sediments accumulated between ca. 26 and 13 cal ka BP in a proglacial lake environment. These minerals also appea...

by fluctuations in the seasonal precipitation and wind, and the primary ACMs associated with the winter limnological processes are the NAO and the SCAND modes, whereas only the EA mode appears to weakly influence processes during the summer. However, Lake Las Madres is affected by precipitation, wind and, to a lesser extent, temperature, whereas th...

The Cristo lagoon, situated on Neogene deposits in the northern Spanish Meseta, occupies a shallow depression on a Pleistocene piedmont. The development of the lacustrine depression on the piedmont was favoured by the fault network, reinforced by substrateloss by weathering, probably during the late Quaternary. Even during the hot summer season, sa...

Lakes are one of the best continental sensors for reconstructing past environmental and climatic changes. Recent lacustrine systems may be used for reconstructing with high-temporal resolution past climate parameters (e.g. precipitation, temperature, wind), land management changes and limnological conditions such as pH, salinity, or nutrients conce...