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A novel ionic liquid EMIMBF3Cl that contains a BF3Cl− anion has been synthesized. This is the first report of an ionic liquid with a BF3Cl− anion. It was found that CO2 gas can be dissolved and electrochemically reduced at ambient pressure, and room temperature in the ionic liquid EMIMBF3Cl. The reduction of CO2 occurred at a relatively less negati...
In a systematic search for an oxygen-stoichiometric phase, Sr{sub 3}(FeMo)O{sub 7}, in a range of iron-to-molybdenum ratios greater than 1:1 that typically give phase mixtures, we have found an n = 2 Ruddlesden-Popper phase, Sr{sub 3}Fe{sub 5/4}Mo{sub 3/4}O{sub 6.9}, as supported by synchrotron powder X-ray diffraction (SPXD), high-resolution trans...
In a systematic search for an oxygen-stoichiometric phase, Sr{sub 3}(FeMo)O{sub 7}, in a range of iron-to-molybdenum ratios greater than 1:1 that typically give phase mixtures, we have found an n = 2 Ruddlesden-Popper phase, Sr{sub 5}Fe{sub 5/4}Mo{sub 3/4}O{sub 6.9}, as supported by synchrotron powder X-ray diffraction (SPXD), high-resolution trans...
Alkali metal cation transport across porous polypropylene-supported liquid membranes containing a lipophilic crown ether carboxylic acid in a series of alkyl 2-nitrophenyl ethers has been studied. Both the efficiency and selectivity of cation transport are influenced by alkyl group variation in the membrane solvent. For homologous series of normal...
Thesis (M.S.)--Texas Tech University, 1990. Spine title: Complexing agents for metal ions. Includes bibliographical references (leaves 85-89).