Liam Bullock

Liam Bullock
Spanish National Research Council | CSIC · Geosciences Barcelona

Doctor of Philosophy

About

46
Publications
20,558
Reads
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314
Citations
Citations since 2017
37 Research Items
314 Citations
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Introduction
I currently work at the University of Oxford on an enhanced weathering processes project investigating feasibility of using silicate and carbonate materials as a source of cations to remove carbon from the atmosphere into carbonate minerals and ocean alkalinity.
Additional affiliations
July 2010 - July 2014
Keele University
Position
  • Laboratory Assistant
July 2010 - July 2014
Keele University
Position
  • Laboratory Demonstrator
Description
  • Practical assistance and leading, lecturing, fieldwork supervision, assistance and leading
Education
September 2006 - July 2009
Keele University
Field of study
  • Geology and Geography

Publications

Publications (46)
Article
Full-text available
Many countries have made pledges to reduce CO2 emissions over the upcoming decades to meet the Paris Agreement targets of limiting warming to no >1.5 °C, aiming for net zero by mid-century. To achieve national reduction targets, there is a further need for CO2 removal (CDR) approaches on a scale of millions of tonnes, necessitating a better underst...
Article
Chemically reactive mine tailings are a potential resource for drawing down carbon dioxide out of the atmosphere in mineral weathering schemes. Such carbon dioxide removal (CDR) systems, applied on a large scale, could help to meet internationally agreed targets for minimising climate change, but crucially we need to identify what materials could r...
Article
Enhanced weathering of minerals is one option being considered for removing CO2 from the atmosphere to help combat climate change. In this work, we consider the weathering of calcite with seawater in a reactor using air enriched with CO2. A mathematical model of the packed bubble column reactor was constructed with the key mass transfer and chemica...
Article
Full-text available
There is growing urgency for CO2 removal strategies to slow the increase of, and potentially lower, atmospheric CO2 concentrations. Enhanced weathering, whereby the natural reactions between CO2 and silicate minerals that produce dissolved bicarbonate ions are accelerated, has the potential to remove substantial CO2 on decadal to centennial timesca...
Article
We welcome the comments of Smith and Rippon (2021) about our map of vitrinite reflectance data derived from Carboniferous coal in Britain. The essence of their contribution is that our map is based upon a limited database (103 samples). We are well aware that data is available for other localities, at a range of depths within mines, and in some cas...
Article
Full-text available
Gold grains, up to 40 μm in size and containing variable percentages of admixed platinum, have been identified in coals from the Leinster Coalfield, Castlecomer, SE Ireland, for the first time. Gold mineralisation occurs in sideritic nodules in coals and in association with pyrite and anomalous selenium content. Mineralisation here may have reflect...
Article
Full-text available
Microbial reduction of soluble selenium (Se) or tellurium (Te) species results in immobilization as elemental forms and this process has been employed in soil bioremediation. However little is known of direct and indirect fungal interactions with Se/Te-bearing ores. In this research, the ability of Phoma glomerata to effect transformation of seleni...
Article
Full-text available
The West Cumbria iron ore field exhibits kilometre-scale compartmentalization of fluid sources, as evidenced by sulphur isotope data. Barite accompanying haematite ore from 13 mines in an along-strike width of 5 km has δ34S(VCDT) isotopic compositions ranging from +7.9 to +23.6‰. The large variation is strongly controlled by NNW-SSE faulting, in wh...
Article
Full-text available
p>The fixation and accumulation of critical elements in the near surface environment is an important factor in understanding elemental cycling through the crust, both for exploration of new resources and environmental management strategies. Carbonaceous black shales are commonly rich in trace elements relative to global crustal averages, many of wh...
Article
Full-text available
Thanks to the pioneering research of Paul Younger over the past 20 years, acid mine drainage in the UK has been recognized as a major environmental issue. Acid mine drainage and hydrous ferric oxide deposition are environmental hazards resulting from centuries of extensive coal mining activities across the UK. Oxidative weathering of pyrite in coal...
Article
Full-text available
A compilation of new and previously published vitrinite reflectance (Ro) data from Carboniferous coals constitutes the most comprehensive map of reflectance across Great Britain. Values of Ro range from 0.38 to 3.29 %, recording an ambient thermal maturity in the early oil window, modified by elevated heat flow in northern England and along the Var...
Article
Full-text available
A method for ultra-trace determination of Se and Te in coal by inductively coupled plasma mass spectrometry (ICP-MS) was developed. Samples (up to 500 mg) were digested by microwave-induced combustion (MIC) in a closed system pressurized with 20 bar of oxygen. Inorganic acids or their mixtures were evaluated as absorbing solution. Using HNO3 + HCl...
Article
Textural evidence from occurrences of mingled magmas in lava flows often yields insights into chemical and thermal disequilibrium between multiple magma batches at depth. An understanding of these interactions is key as they can occur on short timescales and may act as eruption triggers, particularly important in very active volcanic settings. This...
Article
Textural evidence from occurrences of mingled magmas in lava flows often yields insights into chemical and thermal disequilibrium between multiple magma batches at depth. An understanding of these interactions is key as they can occur on short timescales and may act as eruption triggers, particularly important in very active volcanic settings. This...
Article
Full-text available
The former mining site at Kisgruva near Kongsberg, Norway, is primarily composed of worked sulphide ore deposits, of hydrothermal origin, which occur within Precambrian metamorphic basement. Though the original targets at the Kisgruva mine site were extraction of copper (Cu), sulphur (S) and iron (Fe), the sulphide ore also contains exceptionally h...
Article
Full-text available
The Bowland Shale Formation is anomalously rich in selenium (Se) at levels an order of magnitude greater than other black shales. The Mam Tor landslide, Derbyshire, England, offers an opportunity to measure whether the Se anomaly is conferred to the alteration products formed by oxidative water flow through the shale. Selenium in the shale is conce...
Article
Full-text available
The Neoproterozoic Dalradian Supergroup contains widespread diagenetic sulphides present as pyrite. The sulphides occur in both carbonaceous shales and glacial diamictites, that were deposited in relatively reducing and oxidising conditions respectively. The trace element compositions of the pyrite, and consequently the whole rock compositions, con...
Article
Full-text available
The Carboniferous Lower and Middle Coal Measures coals of the Northumberland Coalfield are anomalously rich in selenium (Se) content (up to 62 ppm) compared to the averages for the common UK and worldwide coals. As well as posing an environmental toxicity threat, Se is now regarded as an important resource for alloys, photovoltaic products and nano...
Article
Full-text available
Standard mode and collision/reaction cell mass spectroscopy methods have been utilised in order to overcome spectral interferences and provide ultra-low quantification of selenium (Se) and tellurium (Te) in British coals for the first time. The accurate detection of Se and Te in coals is becoming increasingly important, as coals and pyrite have bee...
Article
Full-text available
The Rocche Rosse lava flow marks the most recent rhyolitic extrusion on Lipari island (Italy), and preserves evidence for a multi-stage emplacement history. Due to the viscous nature of the advancing lava (10^8 to 10^10 Pa s), indicators of complex emplacement processes are preserved in the final flow. This study focuses on structural mapping of th...
Article
Full-text available
Black shales of the late Neoproterozoic Gwna Group (570–580 Ma), UK, contain enrichments of tellurium (Te), selenium (Se) and cobalt (Co) relative to average shale compositions. The Te and Co enrichments bear comparison with those of ferromanganese crusts in the modern deep ocean. Gwna Group deposition coincides with the Second Great Oxidation Even...
Article
A method is proposed for the determination of selenium at low concentration in coal by collision/reaction cell technology inductively coupled plasma mass spectrometry (CRC-ICP-MS). Samples were decomposed by high pressure microwave-assisted wet digestion (MAWD) using 250 mg of coal, a mixture of 5 mL of 14.4 mol L⁻¹ HNO3 and 1 mL of 40% HF and 70 m...
Article
Full-text available
Gold mining has a legendary history in Ethiopia, with Ethiopian mines providing gold to the ancient Egyptian empire and possibly even King Solomon’s Mines and the Queen of Sheba. Today, gold occurs in the Pan-African age schist belt and Tertiary basaltic lavas of the Asosa region of Benishangul-Gumuz, western Ethiopia. There is widespread artisanal...
Article
Full-text available
Carboniferous coals of the Ayrshire Coalfield are enriched in selenium (Se) relative to average UK and world compositions, substituting for sulphur in pyrite. Greenburn surface mine coals are characterized by syngenetic concretionary pyrite (c. 15% total area), occurring as bedding-parallel banding, and later-formed (epigenetic) cross-cutting pyrit...
Article
Full-text available
The Dalradian Supergroup of Britain and Ireland is mineralised by gold-tellurium vein deposits. The host succession includes carbonaceous, pyritic shales (pelites) which were a source of trace elements, including gold and tellurium. LA-ICP-MS mapping of pyrite crystals shows that late stages are enriched in gold, tellurium and lead, representing co...
Article
Full-text available
Mid-Jurassic pyritic coals exposed at the village of Brora, northern Scotland, UK, contain a marked enrichment of tellurium (Te) relative to crustal mean, average world coal compositions and British Isles Carboniferous coals. The Te content of Brora coal pyrite is more than one order of magnitude higher than in sampled pyrite of Carboniferous coals...
Article
Full-text available
Mid-Jurassic pyritic coals exposed at the village of Brora, northern Scotland, UK, contain a marked enrichment of tellurium (Te) relative to crustal mean, average world coal compositions and British Isles Carboniferous coals. The Te content of Brora coal pyrite is more than one order of magnitude higher than in sampled pyrite of Carboniferous coals...
Article
Full-text available
Black sediment veins up to 2 cm width penetrate the Caledonian Helmsdale Granite in the vicinity of the Helmsdale Fault, onshore Moray Firth. The black colour and geochemistry of the veins reflect a high content of organic carbon. Both Devonian and Jurassic shales are conceivable available sources, but sterane compositions relate the organic matter...
Article
Full-text available
Sandstone uranium (U) roll-front deposits of Wyoming and Colorado (USA) are important U resources, and may provide a terrestrial source for critical accessory elements, such as selenium (Se), molybdenum (Mo), and tellurium (Te). Due to their associated toxicity, Mo-Se-Te occurrences in roll-fronts should also be carefully monitored during U leachin...
Article
Full-text available
Spherulites in obsidian lavas of Lipari and Vulcano (Italy) are characterised by spatial, textural and geochemical variations, formed by different processes. Spherulites vary in size from <1 mm to 8 mm, are spherical to elongate in shape, and show variable radial interiors. Spherulites occur individually or in deformation bands, and some are surrou...
Article
Full-text available
The Parys Mountain copper mining district (Anglesey, North Wales) hosts exposed pyritic bedrock, solid mine waste spoil heaps, and acid drainage (ochre sediment) deposits. Both natural and waste deposits show elevated trace element concentrations, including selenium (Se), at abundances of both economic and environmental consideration. Elevated conc...
Poster
The global trend in environmental awareness and search for low carbon energy sources has led to an increasing interest in certain ‘strategic elements’, including Selenium (Se) and Tellurium (Te), which are seen as essential in future green energy technologies, e.g. photovoltaic solar panels. Increasing our understanding of these elements is key to...
Article
Full-text available
The Assosa region of western Ethiopia hosts newly discovered and potentially highly economic graphite-bearing schist units. Due to its unique physical and chemical properties, graphite is quickly becoming an increasingly important economic resource. Graphite occurs over much of the area, and is hosted predominantly by quartz-graphitic schist, quart...
Thesis
Silicic volcanism defines the recent volcanic activity in the Aeolian Islands, Italy. Such activity on the islands of Lipari and Vulcano has generally involved an explosive phase, ending with viscous lava extrusion and a period of quiescence. This late effusive extrusion has resulted in a number of obsidian lava flows and domes. Obsidian lavas on...

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Projects

Projects (6)
Project
EU HORIZON 2020 project at GEO3BCN-CSIC. Enhanced weathering and carbonation strategies for mine wastes, where the natural process of rock weathering and carbonate precipitation is sped up to uptake CO2, is a potentially significant sequestration method. However, on-site pilot schemes are required to fully realise the high CO2 storage potential. The EU-funded DETAILS project will address this challenge by implementing new technologies in mine wastes to reduce CO2 emissions by initiating enhanced weathering and carbonation in mine wastes through novel bioreactor technologies. This will surpass current state-of-the-art technologies by focusing on delivering on-site testing on a range of voluminous and suitable materials with industry partners. The new bioreactor system will work to modify pH and harness heat and CO2 point sources at mine sites.
Project
This project aims to gather the lived experiences of autistic individuals within the context of geoscience-based higher education, highlighting some of the complex enablers and challenges/barriers to learning that they face. This broad discipline is incredibly diverse in its sub-disciplines, themes, nomenclatures, activities, expectations, and teaching styles/environments, creating a subject area where different learners can have significantly different journeys. Through this dataset, we aim to identify key areas of success and difficulty, as perceived by autistic individuals, and create guidance and resources to support geoscience educators in the consideration and mitigation of challenges for autistic individuals.
Project
To limit the increase in global temperature to less than 2 °C, “negative emissions”, or the active removal of carbon dioxide from the atmosphere, are required. Weathering, the chemical breakdown (dissolution) of rocks at the Earth’s surface, is a natural process that converts atmospheric carbon dioxide into carbonate minerals or hydrogen carbonate and carbonate ions (“alkalinity”). If the weathering process can be speeded up, or enhanced, then levels of atmospheric carbon dioxide would fall. Mining of precious commodities, such as diamonds and gold, provides a continuous supply of freshly ground up rock material which, under the right conditions, could be easily weathered, removing atmospheric CO2 in the process. Our project aims to provide critical knowledge to answer the following questions: Are rocks left over from extracting precious metals suitable for capturing carbon dioxide on human timescales? Are there low-cost engineering solutions that can be used to accelerate the weathering process? How much carbon dioxide could potentially be captured? We are addressing these questions through identification of the most easily weatherable mine waste materials, the testing of physical, chemical and biological methods for speeding up weathering kinetics, and an investigation into the availability of (suitable) rock materials at mine sites on a national and global scale. Our work will assess the technical, environmental and societal challenges involved in assessing the potential of enhanced weathering as a carbon sequestration technology. We will do this through: 1. Assessment of the worldwide potential of the mining sector for carbon dioxide removal through enhanced weathering based on a global industry desktop study. 2. Development of a detailed dataset for the enhanced weathering and carbon dioxide storage potentials of chemically-favourable mine waste material in South Africa. 3. Characterisation of available rock waste material (quantity, location, mineralogy, geochemistry, and grainsize) and naturally occurring microbial communities naturally thriving in a platinum mine in South Africa. 4. Laboratory experimentation and assessment of the rates of break-down of representative rock waste material. 5. Developing a biotechnological approach to harness naturally occurring microbial processes to enhance weathering rates of mine waste material.