Kyle Aronson Williams

Malvern Panalytical · Applications Lab

Grape variety has a significant impact on wine flavan-3-ol and polysaccharide profile. The main objective of this work was to study differences in flavan-3-ol and polysaccharide diffusion from grape to wine during the fermentative alcoholic maceration of three Vitis sp. varieties: the cold-hardy hybrid varieties Frontenac and Frontenac blanc, and t...

Alginates gel rapidly under ambient conditions and have widely documented potential to form protective matrices for sensitive bioactive cargo. Most commonly, alginate gelation occurs via calcium mediated electrostatic crosslinks between the linear polyuronic acid polymers. A recent breakthrough to form crosslinked alginate microcapsules (CLAMs) by...

The sections in this article areIntroduction to CarbenesCarbenes as Structural Components of MacromoleculesCarbenes as Monomers for Polymerizations (Type 1)NHCs as Monomers for Polymerizations (Type 1)Carbenes as Polymer Side Groups (Type 2)Carbene-Based Polymerization CatalystsNHCs as Ring-Opening Polymerization Catalysts (Type 3)NHCs as Group-Tra...

The utilities of benzobis(imidazolium) salts (BBIs) as stable and fluorescent components of supramolecular assemblies involving the macrocyclic host, cucurbit[8]uril (CB[8]), are described. CB[8] has the unusual ability to bind tightly and selectively to two different guests in aqueous media, typically methyl viologen (MV) as the first guest, follo...

The synthesis and characterization of tris(N-heterocyclic carbene)s with D(3h)-symmetry is reported; these tritopic molecules feature three independent carbene moieties that are geometrically isolated to prevent chelation.

Over the past ten years, a broad range of self-healing materials, systems that can detect when they have been damaged and heal themselves either spontaneously or with the aid of a stimulus, has emerged. Although many unique compositions and components are used to create these materials, they all employ basic chemical reactions to facilitate repair...

Main-chain organometallic polymers utilize transition metal-organic ligand complexes as primary components of their backbones. These hybrid materials effectively integrate the physical and electronic properties of organic polymers with the physical, electronic, optical, and catalytic properties of organometallic complexes. Combined with the rich an...

A novel class of organometallic polymers comprising N-heterocyclic carbenes and transition metals was shown to have potential as an electrically conductive, self-healing material. These polymers were found to exhibit conductivities of the order of 10(-3) S cm-1 and showed structurally dynamic characteristics in the solid-state. Thin films of these...

A highly efficient route to a new class of organometallic polymers containing difunctional N-heterocyclic carbenes has been developed. Bis(imidazolium) halides and divalent group X metals were copolymerized to afford organometallic polymers in up to quantitative yields and with molecular weights up to 10(6) Da, depending on the structure of the N-h...