Joseph R Mcconnell

Desert Research Institute | DRI · Division of Hydrologic Sciences

Ancient texts and archaeological evidence indicate substantial lead exposure during antiquity that potentially impacted human health. Although lead exposure routes were many and included the use of glazed tablewares, paints, cosmetics, and even intentional ingestion, the most significant for the nonelite, rural majority of the population may have b...

Polar ice cores and historical records evidence a large-magnitude volcanic eruption in 1831 CE. This event was estimated to have injected ~13 Tg of sulfur (S) into the stratosphere which produced various atmospheric optical phenomena and led to Northern Hemisphere climate cooling of ~1 °C. The source of this volcanic event remains enigmatic, though...

Climate-driven changes in high-elevation forest distribution and reductions in snow and ice cover have major implications for ecosystems and global water security. In the Greater Yellowstone Ecosystem of the Rocky Mountains (United States), recent melting of a high-elevation (3,091 m asl) ice patch exposed a mature stand of whitebark pine ( Pinus a...

The Millennium Eruption of Mt. Baekdu, one of the largest volcanic eruptions in the Common Era, initiated in late 946. It remains uncertain whether its two main compositional phases, rhyolite and trachyte, were expelled in a single eruption or in two. Investigations based on proximal and medial ash have not resolved this question, prompting us to t...

The Eldgjá eruption is the largest basalt lava flood of the Common Era. It has been linked to a major ice‐core sulfur (S) spike in 939–940 CE and Northern Hemisphere summer cooling in 940 CE. Despite its magnitude and potential climate impacts, uncertainties remain concerning the eruption timeline, atmospheric dispersal of emitted volatiles, and co...

Three seasonally resolved ice core records covering the 20th century were extracted in 1994, 2004, and 2012 at a nearly identical location from the Col du Dôme (4250 m above sea level, m a.s.l.; Mont Blanc, French Alps) drill site. Here, we complete and combine chemical records of major ions and radiometric measurements of 3H and 210Pb obtained fro...

Estimating fire emissions prior to the satellite era is challenging because observations are limited, leading to large uncertainties in the calculated aerosol climate forcing following the preindustrial era. This challenge further limits the ability of climate models to accurately project future climate change. Here, we reconstruct a gridded datase...

Existing global volcanic radiative aerosol forcing estimates portray the period 700 to 1000 as volcanically quiescent, void of major volcanic eruptions. However, this disagrees with proximal Icelandic geological records and regional Greenland ice-core records of sulfate. Here, we use cryptotephra analyses, high-resolution sulfur isotope analyses, a...

Tropospheric reactive bromine (Bry) influences the oxidation capacity of the atmosphere by acting as a sink for ozone and nitrogen oxides. Aerosol acidity plays a crucial role in Bry abundances through acid‐catalyzed debromination from sea‐salt‐aerosol, the largest global source. Bromine concentrations in a Russian Arctic ice‐core, Akademii Nauk, s...

Black carbon emitted from incomplete combustion of biomass and fossil fuel burning is an important aerosol; however, available long-term black carbon data are limited to remote polar and high-alpine ice cores from few geographic regions. Black carbon records from lake sediments fill geographic gaps but such records are still scarce, particularly in...

Rapid warming and human exploitation threaten boreal forests. Understanding links among vegetation, climate, and people in this vast biome requires highly resolved long‐term records that integrate regional inputs. We developed an 850‐year pollen‐based record of supraregional vegetation change using a southern Greenland ice core and atmospheric mode...

Growing season temperatures play a crucial role in controlling treeline elevation at regional to global scales. However, understanding of treeline dynamics in response to long-term changes in temperature is limited. In this study, we analyze pollen, plant macrofossils, and charcoal preserved in organic layers within a 10,400-year-old ice patch and...

Carbon monoxide (CO) is a naturally occurring atmospheric trace gas, a regulated pollutant, and one of the main components determining the oxidative capacity of the atmosphere. Evaluating climate–chemistry models under different conditions than today and constraining past CO sources requires a reliable record of atmospheric CO mixing ratios ([CO])...

Stable water isotope records of six firn cores retrieved from two adjacent plateaus on the northern Antarctic Peninsula between 2014 and 2016 are presented and investigated for their connections with firn-core glacio-chemical data, meteorological records and modelling results. Average annual accumulation rates of 2500 kg m ⁻² a ⁻¹ largely reduce th...

The 540s, 1450s, and 1600s represent three of the five coldest decades in the Common Era (CE). In each of these cases, the cause of these cold pulses has been attributed to large volcanic eruptions. However, the provenance of the eruption and magnitude of the volcanic forcing remains uncertain. Here, we use high-resolution sulfur isotopes in Greenl...

Phosphorus (P) is a key nutrient for many organisms but its global atmospheric budget is largely unconstrained. Estimates of major emissions sources such as fossil‐fuel combustion range from ∼0.02 to 1.1 Tg yr⁻¹, and primary biogenic emissions range from 0.16 to 1.0 Tg yr⁻¹. Here we used detailed measurements of phosphorus in Alpine ice cores extra...

Stratospheric sulfate aerosols from explosive volcanic eruptions reflect incoming solar radiation and cool the planet, leading to the hypothesis that the largest volcanic events triggered millennial-scale cold periods over the last ice age. Here, we identify tephra shards from the Atitlán Los Chocoyos supereruption (LCY), one of the largest Quatern...

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Changes in sea ice conditions and atmospheric circulation over the Southern Ocean play an important role in modulating Antarctic climate. However, observations of both sea ice and wind conditions are limited in Antarctica and the Southern Ocean, both temporally and spatially, prior to the satellite era (1970 onwards). Ice core chemistry data can be...

The temperature of the Earth is one of the most important climate parameters. Proxy records of past climate changes, in particular temperature, represent a fundamental tool for exploring internal climate processes and natural climate forcings. Despite the excellent information provided by ice core records in Antarctica, the temperature variability...

Carbon monoxide (CO) is a naturally occurring atmospheric trace gas, a regulated pollutant and one of the main components determining the oxidative capacity of the atmosphere. Evaluating climate-chemical models under different conditions than today and constraining past CO sources requires a reliable record of atmospheric CO mixing ratios ([CO]) si...

Cosmic rays entering the Earth's atmosphere produce showers of secondary particles such as protons, neutrons, and muons. The interaction of these particles with oxygen-16 (16O) in minerals such as ice and quartz can produce carbon-14 (14C). In glacial ice, 14C is also incorporated through trapping of 14C-containing atmospheric gases (14CO2, 14CO, a...

Polar ice cores provide long, continuous and well-dated records of past volcanism and have contributed significantly to our understanding of volcanic impacts on climate and society. Sulphate aerosols deposited in the ice are essential for determining the effective radiative forcing potential of past eruptions, but calculations are improved with kno...

Three seasonally-resolved ice-core records covering the 20th century were extracted in 1994, 2004 and 2012 at a nearly identical location at the Col du Dôme (4250 m above sea level, m asl, Mont Blanc, French Alps) drill site. Here we complete and combine chemical records of major ions and radiometric measurements of 3H and 210Pb obtained on these t...

Military conflicts result in local environmental damage, but documenting regional and larger scale impacts such as heavy metal pollution has proven elusive. Anthropogenic emissions of bismuth (Bi) include coal burning and various commodity productions but no emission estimates over the past century exist. Here we used Bi measurements in ice cores f...

Black carbon emitted by incomplete combustion of fossil fuels and biomass has a net warming effect in the atmosphere and reduces the albedo when deposited on ice and snow; accurate knowledge of past emissions is essential to quantify and model associated global climate forcing. Although bottom-up inventories provide historical Black Carbon emission...

Ice deposits on Earth provide an extended record of volcanism, planetary climate, and life. On Mars, such a record may extend as far back as tens to hundreds of millions of years (My), compared to only a few My on Earth. Here, we propose and demonstrate a compact instrument, the Melter-Sublimator for Ice Science (MSIS), and describe its potential u...

The temperature of the earth is one of the most important climate parameters. Proxy records of past climate changes, in particular temperature, are a fundamental tool for exploring internal climate processes and natural climate forcings. Despite the excellent information provided by ice core records in Antarctica, the temperature variability of the...

Changes in sea ice conditions and atmospheric circulation over the Southern Ocean play an important role in modulating Antarctic climate. However, observations of both sea ice and wind conditions are limited in Antarctica and the Southern Ocean, both temporally and spatially. Ice core chemistry data can be used to reconstruct changes over annual, d...

Volatile metals are emitted at significant rates as gases and particulates from volcanoes, although their speciation, bioreactivity and longevity during atmospheric transport are essentially unknown. Ice cores provide detailed yet largely unexplored long-term records of volcanogenic volatile metals in air and precipitation. Here we evaluate the sou...

Warming temperatures and prolonged drought periods cause rapid changes of fire frequencies and intensities in high-latitude ecosystems. Associated smoke plumes deposit dark particles from incomplete combustion on the Greenland ice sheet that reduce albedo but also provide a detailed record of paleofire history. Here, we apply an emerging microscopi...

The radiative effect of anthropogenic aerosols is one of the largest uncertainties in Earth's energy budget over the industrial period. This uncertainty is in part due to sparse observations of aerosol concentrations in the pre‐satellite era. To address this lack of measurements, ice cores can be used, which contain the aerosol concentration record...

Plain Language Summary Although less prevalent in the environment than toxic metals such as lead and cadmium, thallium is a highly toxic metal even at very low levels. Because reliable measurements are difficult at such low concentrations, thallium pollution is far less documented than other toxic metals. Cement production originally was estimated...

The injection of sulfur into the stratosphere by volcanic eruptions is the dominant driver of natural climate variability on interannual to multidecadal timescales. Based on a set of continuous sulfate and sulfur records from a suite of ice cores from Greenland and Antarctica, the HolVol v.1.0 database includes estimates of the magnitudes and appro...

The mid-17th century is characterized by a cluster of explosive volcanic eruptions in the 1630s and 1640s, climatic conditions culminating in the Maunder Minimum, and political instability and famine in regions of western and northern Europe as well as China and Japan. This contribution investigates the sources of the eruptions of the 1630s and 164...

Cosmic rays entering the Earth’s atmosphere produce showers of secondary particles such as neutrons and muons. The interaction of these neutrons and muons with oxygen-16 (16O) in minerals such as ice and quartz can produce carbon-14 (14C). Analyses of in situ produced cosmogenic 14C in quartz are commonly used to investigate the Earth’s landscape e...

Volcanic fallout in polar ice sheets provides important opportunities to date and correlate ice-core records as well as to investigate the environmental impacts of eruptions. Only the geochemical characterization of volcanic ash (tephra) embedded in the ice strata can confirm the source of the eruption, however, and is a requisite if historical eru...

The injection of sulfur into the stratosphere by volcanic eruptions is the dominant driver of natural climate variability on interannual-to-multidecadal timescales. Based on a set of continuous sulfate and sulfur records from a suite of ice cores from Greenland and Antarctica, the HolVol v.1.0 database includes estimates of the magnitudes and appro...

The mid-17th century is characterized by a cluster of explosive volcanic eruptions in the 1630s and 1640s, deteriorating climatic conditions culminating in the Maunder Minimum as well as political instability and famine in regions of Western and Northern Europe as well as China and Japan. This contribution investigates the sources of the eruptions...

High-accumulation sites are crucial for understanding the patterns and mechanisms of climate and environmental change in Antarctica since they allow gaining high-resolution proxy records from firn and ice. Here, we present new glacio- and isotope-geochemical data at sub-annual resolution from a firn core retrieved from an ice cap on Plateau Laclave...

New Zealand was among the last habitable places on earth to be colonized by humans¹. Charcoal records indicate that wildfires were rare prior to colonization and widespread following the 13th- to 14th-century Māori settlement², but the precise timing and magnitude of associated biomass-burning emissions are unknown1,3, as are effects on light-absor...

Ice core archives are well suited for reconstructing rapid past climate changes at high latitudes. Despite this, few records currently exist from coastal Greenlandic ice caps due to their remote nature, limiting our long-term understanding of past maritime and coastal climate variability across this rapidly changing Arctic region. Here, we reconstr...

Significance The North Atlantic jet stream impacts North American and European societies and is expected to be influenced by ongoing 21st-century warming. To better contextualize recently observed and model-projected jet stream changes, long-term records are required. We use insights from a state-of-the-art water isotope–enabled climate model and a...

Tropospheric reactive gaseous chlorine (Cly) impacts the atmosphere's oxidation capacity with implications for chemically reduced gases such as methane. Here we use Greenland ice-core records of chlorine, sodium, and acidity, and global model simulations to show how tropospheric Cly has been impacted by anthropogenic emissions since the 1940s. We s...

Volcanic signatures archived in polar ice sheets provide important opportunities to date and correlate ice-core records as well as to investigate the environmental impacts of eruptions. Only the geochemical characterization of volcanic ash (tephra) embedded in the ice strata can confirm the source of the eruption, however, and is a requisite if his...

We present polar ice core organic matter (OM) fluorescence signatures to reconstruct ancient and modern atmospheric compositions and relate OM signals to past ecological changes. OM composition from three Arctic ice cores (Canada and Greenland) was characterized by fluorescence spectroscopy and compared to an Antarctic OM record. Diverse OM was mea...

Fire plays a pivotal role in shaping terrestrial ecosystems and the chemical composition of the atmosphere and thus influences Earth’s climate. The trend and magnitude of fire activity over the past few centuries are controversial, which hinders understanding of preindustrial to present-day aerosol radiative forcing. Here, we present evidence from...

Total bromine (Br) was investigated in seasonally resolved alpine ice cores covering the 20th century. Results revealed increased Br concentrations in summer (from 0.7 ng g⁻¹ in the late 1940s to 1.6 ng g⁻¹ in the mid 1970s), followed by a slight decrease to 1.25 ng g⁻¹ during the last decade of the 20th century. In winter, a more moderate increase...

A comprehensive record (WHV2020) of explosive volcanic eruptions in the last 11,000 years is reconstructed from the West Antarctica Ice Sheet Divide deep ice core (WDC). The chronological list of 426 large volcanic eruptions in the Southern Hemisphere and the low latitudes during the Holocene are of the highest quality of all volcanic records from...

Carbon monoxide (CO) is a regulated pollutant and one of the key components determining the oxidizing capacity of the atmosphere. Obtaining a reliable record of atmospheric CO mixing ratios since pre-industrial times is necessary to evaluate climate-chemistry models in conditions different from today and to constrain past CO sources. We present hig...

Volcanic eruptions are a key source of climatic variability, and reconstructing their past impact can improve our understanding of the operation of the climate system and increase the accuracy of future climate projections. Two annually resolved and independently dated palaeoarchives – tree rings and polar ice cores – can be used in tandem to asses...

Pollutants emitted by industrial processes are deposited across the landscape. Ice core records from mid‐latitude glaciers located close to emission sources document the history of local‐to‐regional pollution since preindustrial times. Such records underpin attribution of pollutants to specific emission sources critical to developing abatement poli...

Paleoclimate records from ice cores generally are considered to be the most direct indicators of environmental change, but are rare from mid-latitude, continental regions such as the western United States. High-elevation ice patches are known to be important archaeological archives in alpine regions and potentially could provide records important f...