Jinhua li

Jinhua li
Xiamen University | XMU · Department of Chemistry

Doctor of Philosophy

About

13
Publications
1,071
Reads
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172
Citations
Citations since 2016
7 Research Items
154 Citations
2016201720182019202020212022010203040
2016201720182019202020212022010203040
2016201720182019202020212022010203040
2016201720182019202020212022010203040
Additional affiliations
June 2019 - present
Southern University of Science and Technology
Position
  • PostDoc Position
Education
September 2013 - June 2019
Xiamen University
Field of study
  • chemistry
September 2009 - June 2013
Nanchang University
Field of study
  • chemistry

Publications

Publications (13)
Article
Starting from an organic multiyne, three steps are normally needed for the preparation of non‐β‐phosphonium functionalized rhoda‐ and irida‐carbolong complexes. Herein, a one‐pot strategy, by mixing a multiyne, a nucleophile, and RhCl(CO)(PPh3)2/AgBF4 or [Ir(CH3CN)(CO)(PPh3)2]BF4, was developed to achieve a series of β‐functionalized rhoda‐ and iri...
Article
Full-text available
A carbolong derivative with a M-PCCO framework was employed as the cathode interlayer, boosting the performance and stability of inverted PSCs.
Article
Full-text available
The reactivity of the triflate functionalized iridapentalene 1, [Ir{[double bond, length as m-dash]CHC(CH2C(CO2Me)2CH2)[double bond, length as m-dash]CC[double bond, length as m-dash]CHC(OTf)[double bond, length as m-dash]CH}(CO)(PPh3)2]OTf, with C-, N-, O- and S-centered neutral nucleophiles was studied, leading to the isolation of a wide array of...
Article
Full-text available
Low-work-function (WF) metals (including silver (Ag), aluminum (Al), and copper (Cu)) used as external cathodes in inverted perovskite solar cells (PSCs) encounter oxidation caused by air exposure and halogen-diffusion-induced corrosion, which threaten the long-term stability of the device. The cathode interlayer (CIL) has shown promise in reducing...
Article
Treatment of osmacyclopentadiene derivatives 1 with phenyl or isopropyl isothiocyanate gave the fused five and six‐membered osmacycles 2‐5 via a formal [4+2] cyclization. The readily protonation of the newly generated exocyclic imine in complexes 2‐5 could afford conjugation‐extended osmacycle derivatives 6‐9. Compounds 2‐9 each contains two main‐g...
Article
Full-text available
The reaction of ruthenapentalyne with one equivalent of isocyanide led to the formation of a rare ruthenapentalene complex by nucleophilic addition. When excess isocyanides were used, the metal‐bridged ruthenaindene derivatives can be isolated and were formed by one carbon of isocyanide insertion into the ruthenacycle. Complexes 3 represent the fir...
Article
Full-text available
The concept of aromaticity has long played an important role in chemistry and continues to fascinate both experimentalists and theoreticians. Among the archetypal aromatic compounds, heteroaromatics are particularly attractive. Recently, substitution of a transition-metal fragment for a carbon atom in the anti-aromatic hydrocarbon pentalene has led...
Article
The transformations of metallabenzene to substituted benzenes have been achieved by reactions of osmabenzenes with silver/copper acetylides. In this investigation, novel tetraphenylphosphonium salts containing two phosphonium substituents on the same benzene ring are generated.
Article
Treatment of OsCl2(PPh3)(2)(CH=C(PPh3)CH(OH)-=2-C=CH) (1) with PPh3 and Bu4NCl in CH2Cl2 under air gave paramagnetic osmacyclopentene [OsCl2(PPh3)(2)(CH=C(PPh3)CH(OH)C(=CH(PPh3)))]Cl (5). Heating the suspension of 5 in CH2Cl2 under a nitrogen atmosphere led to the formation of =2-allene-coordinated osmacycle OsCl2(PPh3)(CH=C(PPh3)CH=C=CH(P(C6H4)Ph-...
Article
Treatment of ruthenabenzene [(C9H6NO)Ru{CC(PPh3)CHC(PPh3)CH}(C9H6NO)(PPh3)]Cl-2 (1) with NaBH4 produces the first ruthenacyclohexa-1,4-diene [(C9H6NO)Ru{CC(PPh3)CH2C(PPh3)CH}(C9H6NO)(PPh3)]Cl (2), which was fully characterized. Under an oxygen atmosphere, complex 2 can easily convert to complex 1. DFT calculations were carried out to rationalize th...
Article
Treatment of the osmium complex [Os{CHC-(PPh3 )CH(OH)-η(2) -C≡CH}(PPh3 )2 (NCS)2 ] (1) with excess triethylamine produces the first m-metallaphenol complex [Os{CHC(PPh3 )CHC(OH)CH}(PPh3 )2 (NCS)2 ] (2). The NMR spectroscopic and structural data as well as the nucleus-independent chemical-shift (NICS) values suggest that osmaphenol 2 has aromatic ch...
Article
Metallaaromatics are organometallic compounds derived from formal replacement of a carbon atom in organic aromatics with an isolobal transition-metal fragment. As a model compound for metallaaromatics, metallabenzene has been extensively investigated. In their Full Paper on page 4363 ff., H. Zhang, H. Xia et al. present the recent progress on the s...

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