Inmaculada Pascual

• PhD
• Research Director at University of Alicante

This book chapter provides an overview of how holographic lenses (HLs) applied as anidolic systems (solar concentrators) have evolved to optimize the characteristics of current photovoltaic devices. The main parameters to be considered in the design of these HLs are described, such as average diffraction efficiency, acceptance angle, angular and sp...

The development and optimization of holographic materials represent a great challenge today. These materials must be synthesized according to the characteristics that are desirable in photonic devices whose application is the object of investigation. In certain holographic sensors and biosensors, it is essential that the recording material be stabl...

Holographic lenses (HLs) are part of holographic optical elements (HOE), and are being applied to concentrate solar energy on a focal point or focal line. In this way, the concentrated energy can be converted into electrical or thermal energy by means of a photovoltaic cell or a thermal absorber tube. HLs are able to passively track the apparent mo...

Low-toxicity solar concentrator systems represent an important challenge for outstanding photovoltaic applications. Particularly, Multiplexed Holographic Lenses (MHL) as Holographic Solar Concentrators (HSC) provide insight into promising possibilities for Building-Integrated Concentrating Photovoltaics. This technology does not affect crucial ecos...

We present the characterization results for an analogically addressed vertically aligned liquid crystal on silicon microdisplay (VA-LCoS). We show that it covers more than 360º phase modulation range at 1550 nm, and that in the visible the range available enables the generation of multiorder DOEs. There are basically no studies dealing with the cha...

The phase-shift exhibited by liquid crystal on silicon devices (LCoS) depends on the voltage applied and the illumination wavelength. Most of the LCoS used in the labs are digitally addressed using a binary pulse width modulated signal. Usually, these devices are characterized for a very small range of the available binary voltage values and for sp...

We print a tunable photopolymer (photopolymer dispersed liquid crystal -PDLC), using the laser-induced direct transfer technique without absorber layer, which was a challenge for this technique given the low absorption and high viscosity of PDLC, and which had not been achieved so far to our knowledge. This makes the LIFT printing process faster an...

The similarity between object and image of negative asymmetrical holographic lenses (HLs) stored in a low-toxicity photopolymer has been evaluated theoretically and experimentally. Asymmetrical experimental setups with negative focal lengths have been used to obtain HLs. For this purpose, the resolution of the HLs was calculated using the convoluti...

Liquid crystal on silicon (LCoS) microdisplays are an element commonly found in advanced photonic applications. Phase-only modulation and spatial light modulators (SLMs) use parallel-aligned LCoS (PA-LCoS) microdisplays due to their large resolution and small pixel size. However, the crosstalk between neighbouring pixels induces several phenomena,...

A low-toxicity photopolymer was employed to prepare holographic solar concentrators (HSCs). The main aim of this study is to obtain a versatile holographic element to concentrate the sunlight from different relative positions of the Sun during the day, avoiding the need of expensive tracking systems. Multiplexed holographic elements that combine sy...

The study of the optical properties and behaviour of holograms stored in hydrogel matrices when the material is immersed in liquid medium represent a very important challenge currently. Hydrogels are 3D polymer networks capable of undergoing reversible volume changes. These hydrogels can be chemically modified to obtain materials with different pro...

The storage of time-stable holographic gratings in hydrogel matrices when the material is immersed in aqueous media is a real challenge at present. The optimization of the storage stages of the holograms must be properly investigated to identify the most suitable development processes. For this reason, this work is focused on the study of the optim...

Diffraction gratings are recorded in a holographic photopolymer containing nematic liquid crystal and peppermint oil. The presence of the oil modifies the polymerization and the holographic response. The composite containing oil adulterated with triethyl citrate obtains a diffraction efficiency related to the oil's purity. The results obtained sugg...

An advanced polarimetric model for liquid crystal devices is presented and the sources of uncertainty to determine the values of its parameters are evaluated using a Monte-Carlo approach.

A numerical formulation based on the precise-integration time-domain (PITD) method for simulating periodic media is extended for overcoming the Courant-Friedrich-Levy (CFL) limit on the time-step size in a finite-difference time-domain (FDTD) simulation. In this new method, the periodic boundary conditions are implemented, permitting the simulation...

Spatial light modulation with liquid crystal on silicon microdisplays is at the heart of a wide range of modern optics and photonics areas. We show how to model these devices with a focus on applications.

The holographic principle, discovered by Gabor, and realized by Leith & Upatnieks and Denisyuk is discussed. The intrinsic value of this idea and its continuing ability to motivate and inspire engineers and applied physicists is reviewed.

A historical review of the origins of holography is presented. Special emphasis is placed on the contributions of Gabor, Denisyuk and Leith to the development of holography, to motivate and inspire students and young researchers.

Precise characterization of parallel-aligned liquid crystal on silicon microdisplays has an important impact in many advanced photonics applications. We show liquid crystal on silicon (LCoS) modeled as a non-absorbent reciprocal device. Combined with time-average Stokes polarimetry, LCoS enables us to demonstrate robust measurements across the whol...

This work presents recent results derived from the rigorous modelling of holographic polymer-dispersed liquid crystal (H-PDLC) gratings. More precisely, the diffractive properties of transmission gratings are the focus of this research. This work extends previous analysis performed by the authors but includes new features and approaches. More preci...

Photopolymers can be used to fabricate different holographic optical elements, although maximization of the phase-shift in photopolymers has been a challenge for the last few decades. Different material compositions and irradiation conditions have been studied in order to achieve it. One of the main conclusions has been that with continuous laser e...

Aberrations and the image quality of holographic lenses were evaluated by a Hartmann–Shack (HS) wavefront sensor. Two lenses, one recorded with a symmetrical configuration and the other with an asymmetrical one, were stored in a photopolymer called Biophotopol. Each was reconstructed with two different wavelengths, 473 nm and 633 nm. Different metr...

Holographic gratings stored in low-toxicity photopolymer, Biophotopol, have been analyzed to achieve stable and efficient holograms. A curing process allows the hologram stabilization, but at the same time, it could produce a diffraction efficiency (DE) reduction. Here, a detailed low-cost LED curing protocol is shown to stabilize over time 1205 l/...

The storage of volume holographic reflection gratings in low-toxicity photopolymers represents a challenge at present since they can be used in many important applications such as biosensors and holographic optical elements. In this context, an acrylate-based photopolymer developed in our research group was employed to study the recording of unslan...

A holographic polymer dispersed liquid crystal (HPDLC) is used to record holographic diffraction gratings. Several mixtures of nematic liquid crystals (LC) are used as components of the HPDLC to evaluate their influence in static and dynamic basic properties. The diffraction efficiency obtained in the reconstruction of the holograms is evaluated to...

We demonstrate a complete semiphysical and analytical model describing the angular and wavelength dependencies not only of retardance, but also its flicker, in parallel aligned liquid crystal (PA-LC) devices. It relies on the fitting of the molecules’ equivalent tilt angle as a function of applied voltage. The wide range of calculations it offers w...

Tert-Butylthiol (TBT) and tetrahydrothiophene (THT) are odorant substances added to natural gas and liquefied petroleum gas to help their detection by the human smell. In this research, TBT and THT are incorporated into a holographic polymer-dispersed liquid crystal and their influence in the main holographic characteristics of the photopolymer are...

The possibilities that offer the holographic optical elements for photovoltaic and “see through display” applications open new windows for holographic recording materials. In this sense, some specific characteristics are required for each particular application. Waveguides are one of the key elements for these applications. Photopolymers are one of...

In this paper, we present a method to characterize a complete optical Holographic Data Storage System (HDSS), where we identify the elements that limit the capacity to register and restore the information introduced by means of a Liquid Cristal on Silicon (LCoS) microdisplay as the data pager. In the literature, it has been shown that LCoS exhibits...

We study the behavior of a nanoparticle-polymer composite (NPC) material, based on a thiol-ene monomer system, working with long grating spacing. Thus, we evaluate the suitability of the NPC for storing complex diffractive optical elements with sharp profiles, such as blazed gratings. Using holographic methods, we measure the “apparent” diffusion o...

In recent works, we demonstrated the accuracy and physical relevance of a highly simplified reverse-engineering analytical model for a parallel-aligned liquid crystal on silicon devices (PA-LCoS). Both experimental measurements and computational simulations applying the rigorous split-field finite difference time domain (SF-FDTD) technique led to t...

In this work, an accurate numerical modeling of the diffraction properties of transmission holographic polymer dispersed liquid crystal (H-PDLC) gratings is presented. The method considers ellipsoid geometry-based liquid crystal (LC) droplets with random properties regarding size and location across the H-PLDC layer and also the non-homogeneous ori...

Simplified analytical models with predictive capability enable simpler and faster optimization of the performance in applications of complex photonic devices. We recently demonstrated the most simplified analytical model still showing predictive capability for parallel-aligned liquid crystal on silicon (PA-LCoS) devices, which provides the voltage-...

In this paper, we theoretically and experimentally evaluated the quality of volume phase transmission lenses stored in an environmentally friendly photopolymer. Holographic lenses (HLs) were obtained using symmetrical and asymmetrical experimental setups with the same positive and negative focal length and pupil diameter. The image quality was eval...

Holographic polymer dispersed liquid crystals (HPDLCs) are the result of the optimization of the photopolymer fabrication techniques. They are made by recording in a photopolymerization induced phase separation process (PIPS) in which the liquid crystal molecules diffuse to dark zones in the diffraction grating originated. Thanks to the addition of...

Two holographic optotypes have been designed and fabricated using polyvinyl alcohol/acrylamide photopolymer in order to measure visual acuity and stereopsis. One of them was a multivergence target for subjective measurements to determine the spherical refractive error of the human eye in the range −5 to +4 diopters (D) in a single step. The amplitu...

Schiff's bases with specific π-electron system have been synthesized and used as additives in holographic polymer-dispersed liquid crystals. It was observed that these substances modify different parameters such as current intensity, voltage, and diffracted light intensity. In addition, the maximum diffraction efficiency obtained in the reconstruct...

The improvements made in diffusion models simulating phase image recording in photopolymers enable the optimization of a wide range of complex diffractive optical elements (DOEs), while the miniaturization of spatial light modulators makes it possible to generate both symmetric and non-symmetric DOEs. In addition, there is increasing interest in th...

Multiplexed diffraction gratings were recorded in 300 μm thick layers of Biophotopol photopolymer by using peristrophic multiplexing schema. Thirteen sinusoidal phase gratings were stored in a low toxicity recording medium. The diffraction efficiency conservation of the multiplexed diffraction efficiency obtained was studied along the time.

The parallel-aligned liquid crystal on silicon (PA-LCoS) microdisplay has become a widely used device for the photonics community. It is a very versatile tool that can perform several tasks which transforms it into a key element in many different photonics applications. Since our group is interested in holography, in this chapter, we want to use th...

Multiplexed diffraction gratings were recorded in 300 μm thick layers of biophotopol photopolymer by using two peristrophic multiplexing schemes separately and in combination. In addition, it was shown that riboflavin may be used as polymer initiator in acrylamide photopolymer films and the holographic properties of these films such as diffraction...

Photopolymers are appealing materials for many optical applications. For most of them, shrinkage plays an important role in the final properties of the display, especially in holographic data storage applications. In this paper, we demonstrate that to quantify correctly the shrinkage, it is mandatory to measure the angle of propagation for both dif...

We introduce a polyvinil alcohol/acrylamide (PVA/AA) photopolymer compound in a holographic memory testing platform to provide experimental results for storage and retrieval of information. We also investigate different codification schemes for the data pages addressed onto the parallel-addressed liquid crystal on silicon (PA-LCoS) device, used as...

Photopolymers are classical holographic recording materials. Recently their chemical composition and the fabrication techniques have been optimized for many new applications such as interconnectors, solar concentrations, 2-D photonic structures, or wave-guides. Their potential usefulness has been drastically increased by the introduction of dispers...

The measurement of accommodative response is usually performed by means of the Nott method. The accommodative response values were obtained as described in the bibliography and considering that the neutralizing lens shapes the target image. The values in accommodative response differ according to the calculation method utilized. The accommodation a...

Holographic data storage systems (HDSS) have been a promising and very appealing technology since the first laser developments in the sixties. Impact of ongoing advances in the various components needs to be explored in its specific application to HDSS. In this sense, continuous progress is being produced in spatial light modulator (SLM) technology...

Photopolymers are optical recording materials appealing for many different applications such as holography, data storage, interconnectors, solar concentrations, or wave-guides fabrication. Recently the capacity of photopolymers to record diffractive optical elements (DOE’s) has been investigated. Different authors have reported proposes to record D...

Holographic transmission gratings with a spatial frequency of 2658 lines/mm and reflection gratings with a spatial frequency of 4553 lines/mm were stored in a polyvinyl alcohol (PVA)/acrylamide (AA) based photopolymer. This material can reach diffraction efficiencies close to 100% for spatial frequencies about 1000 lines/mm. However, for higher spa...

In order to obtain a highly environmentally compatible photopolymer to replace the well-known acrylamide photopolymer we optimized the previously developed Biophotopol composition to obtain volume transmission gratings in 300 μm layers, at a recording wavelength of 488 nm. The results obtained show an improved energetic sensitivity with similar dif...

Photopolymers can be appealing materials for diffractive optical elements fabrication. In this paper, we present the recording of diffractive lenses in PVA/AA (Polyvinyl alcohol acrylamide) based photopolymers using a liquid crystal device as a master. In addition, we study the viability of using a diffusion model to simulate the lens formation in...

The push-up method is routinely used to measure the amplitude of accommodation. In this method the diopter value corresponding to the nearest point that the eye can focus is determined, wearing his neutralizing lens, but not the value of the maximum diopter variation that makes the eye. The aim of this paper is to review the calculation described i...

Parallel aligned liquid crystal (PA-LC) devices are widely used in many optics and photonics applications to control the amplitude, phase and/or state of polarization (SOP) of light beams. Simplified models yet with a good predictive capability are extremely useful in the optimal application of these devices. In this paper we propose and demonstrat...

Phase-only modulation is necessary in a great number of modern spatial light modulation applications, and the spatial light modulator (SLM) technology of choice is usually the parallel-aligned liquid crystal on silicon (PA-LCoS) microdisplay. Various degradation effects have been analyzed in the literature which may be introduced by SLMs and whose...

One of the most promising phase optical recording mediums are photopolymers. In these materials, the use of an index matching component permits a better conservation of the stored information and, additionally, the study of the molecules migration and shrinkage/swelling phenomena separately. In general, the transmitted beam has the information of t...

We focus on the novelty of three elements in holographic data storage systems (HDSS): the data pager, where we introduce a parallel-aligned liquid crystal on silicon (PA-LCoS) microdisplay; the recording material, where we consider the highly versatile PVA/AA photopolymer; and also in the architecture of the object arm, where a convergent correlato...