F. Javier Hoyuelos

F. Javier Hoyuelos
Universidad de Burgos | UBU · Department of Chemistry

About

38
Publications
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296
Citations
Citations since 2017
15 Research Items
118 Citations
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20172018201920202021202220230510152025
20172018201920202021202220230510152025
20172018201920202021202220230510152025

Publications

Publications (38)
Article
El propósito de nuestro estudio es comprobar si el alumnado de la asignatura Química del Medio Ambiente del Grado en Química de la Universidad de Burgos arrastra conocimientos previos erróneos en temas medio ambientales antes de cursar la misma, y si estos errores conceptuales son subsanados una vez superada la asignatura. Para ello llevamos a cabo...
Conference Paper
Full-text available
En la presente comunicación científico-técnica se han analizado diferentes aspectos relacionados con las acciones que las Universidades Españolas están implementando en relación con la Emergencia Climática y, en especial, con las políticas de Adaptación al Cambio Climático. Se evalúan, en el ámbito de los Diagnósticos que realiza anualmente el Grup...
Conference Paper
Full-text available
En la presente Comunicación de Difusión de Proyectos se resumen las acciones realizadas a lo largo del periodo de realización del Proyecto de Investigación: INFORMACIÓN, COMUNICACIÓN, CONCIENCIACIÓN Y CAPACITACIÓN EN MATERIA DE ADAPTACIÓN AL CAMBIO CLIMÁTICO EN EL ÁMBITO DE LAS UNIVERSIDADES ESPAÑOLAS. Este proyecto cuenta con el apoyo del Minister...
Article
Full-text available
Factors that influence the explosiveness of wood dust, like particle size distribution, moisture content and microscopic structure, have been characterised. Sawdust flammability has been tested in a Hartmann tube. The Minimum Explosive Concentration and Minimum Ignition Temperature of dust clouds and layers have also been measured. Dust granulometr...
Book
Este estudio tiene como objetivo servir de herramienta para identificar la mayor o menor peligrosidad del polvo generado en la transformación de la madera en la industria. Este polvo es capaz de generar lo que se conoce como atmósferas explosivas (ATEX), lo cual sucede cuando existen sustancias inflamables que, mezcladas con el aire y en condicione...
Book
La presente guía se ha elaborado con el fin de ayudar a los profesionales de la industria de la madera y a los técnicos de prevención, para que conozcan el comportamiento del polvo de madera ya que, en determinadas condiciones, explota. Este polvo es capaz de generar lo que se conoce como atmósferas explosivas, lo cual sucede cuando sustancias infl...
Conference Paper
El Índice de Calidad del Aire Europeo se puso en marcha en noviembre de 2017 por la Agencia Europea del Medio Ambiente y la Comisión Europea. El índice Nacional se aprobó en la Orden TEC/351/2019 y en junio y julio de 2020 se ha sometido a opinión y participación pública para su actualización y visualización. Este Índice de Calidad del Aire se basa...
Conference Paper
El cálculo de la Huella de Carbono de productos alimentarios está cobrando cada vez más interés, ya que tanto empresas como consumidores desean conocer cuál es el impacto sobre el Cambio Climático del conjunto de productos agroalimentarios que constituyen la “cesta de la compra” diaria, a través de un indicador, como la Huella de Carbono que contab...
Article
Full-text available
Introduction. A key aspect of teaching is analyzed in the framework of Higher Education that is student satisfaction with the completion of Final-Year Degree Projects (FYDP). Method. A longitudinal study is conducted over three academic years on student satisfaction with FYDPs. The study involves a sample of 1331 students, 1014 undergraduate studen...
Conference Paper
Full-text available
La calidad del aire que respiramos está directamente relacionada con la cantidad de contaminantes emitidos a la atmósfera y su relación con los parámetros meteorológicos. Hemos realizado el estudio de los contaminantes químicos presentes en el aire que se miden en las estaciones de la red de Castilla y León junto con las variables meteorológicas en...
Conference Paper
El presente estudio analiza la Huella de Carbono de tres empresas españolas del sector lácteo, como instrumento de utilidad para identificar el grado de sostenibilidad ambiental de sus procesos productivos. Se procede en primer lugar a calcular la Huella de Carbono generada por cada una de las actividades productivas de estas empresas del sector lá...
Article
Full-text available
La intención de nuestro trabajo es detectar y analizar las características y prácticas docentes preferidas por el alumnado de primer curso de grado comparando las titulaciones de Química y Ciencia y Tecnología de los Alimentos de la Universidad de Burgos, en la docencia que recibirán en sus asignaturas. Para ello hemos analizado los datos obtenidos...
Article
La intención de nuestro trabajo es detectar y estudiar las características y prácticas docentes deseadas por el alumnado de primer curso de Grado en la docencia que recibirá en sus asignaturas, comparando las titulaciones en Maestro de Educación Infantil y Primaria de la Universidad de Burgos. Para ello hemos analizado los datos obtenidos en 120 en...
Article
This work deals with the structure and solvation ability of the binary mixtures of the essential oil 1,8-cineole with n-hexane, n-octane and n-decane. The relevant derived properties excess isobaric heat capacity, molar excess volume, mixing viscosity, excess isentropic compressibility and activation Gibbs free energy were calculated from the measu...
Article
La intención de nuestro trabajo es detectar y estudiar las características y prácticas docentes preferidas por el alumnado de primer curso de Grado de las titulaciones en Maestro de Educación Infantil y Primaria de la Universidad de Burgos, en la docencia recibida en sus asignaturas. Para ello hemos analizado los datos obtenidos en 120 encuestas (6...
Article
Ethanol affects unequally the thermal stability of DNA and RNA. The slopes of the melting temperature (Tm) versus ethanol/water content (v/v) was negative for [poly(dA-dT)]2 and positive for poly(rA)•poly(rU); for ct-DNA, the sign of the slope depends on the scan rate of heating and the ethanol concentration. The increase in Tm when the ethanol con...
Article
Full-text available
El objetivo de nuestro trabajo es conocer las preferencias que los estudiantes de primer curso de grado tienen sobre el profesor universitario ideal, el que desearían que les impartiera docencia en la universidad. Para ello, encuestamos a 947 estudiantes pre-universitarios pertenecientes a cuatro universidades diferentes y abordamos los principales...
Article
Spectrophotometric, circular dichroism, calorimetric, displacement assay and kinetic analyses of the binding of the fluorescent dye coralyne to poly(A)2poly(U) have served to enlighten the ability of the dye to produce dramatic changes in the RNA structure. The sets of data assembled convey that coralyne is able to induce the triplex-to-duplex conv...
Article
The objective of this study is to discover the preferences of students in the first course of university degrees about their ideal university teacher, the one that students would like as their teachers at the university. To that aim, we interviewed 947 pre-university students belonging to four different universities dealing with the main aspects re...
Article
The structure and dynamics of alkan-1-ol/alkylbenzoate binary mixtures have been studied by microwave dielectric relaxation spectroscopy in the 200 MHz-20 GHz frequency range. The binary mixtures of methanol, ethanol, propan-1-ol, butan-1-ol and pentan-1-ol with methyl, ethyl, propyl and butyl benzoates were studied at 298.15 K. The relaxational re...
Article
Heat capacities for the binary mixtures of methanol with (C(1)-C(4)) alkylbenzoates and methylbenzoate with (C(1)-C(11)) alkan-1-ols have been measured over the whole composition range at 298.15 K under atmospheric pressure. From the experimental measurements, the derived excess molar heat capacities and partial excess molar heat capacities at infi...
Article
The binary mixtures of methanol with (C(1)-C(4)) alkylbenzoates and of (C(1), C(3), C(5), C(7), C(9), C(11)) alkan-1-ols with methylbenzoate were used as solvents to look into the preferential solvation and intermolecular interactions of the solvatochromic indicators 2-nitroanisole, 4-nitroaniline, 4-nitrophenol, and Reichardt's dye by UV-vis measu...
Article
Full-text available
The excess volumes VE of the binary mixtures 2-pyrrolidinone–(C6–C10) n-alkanols have been calculated from density measurements over the whole composition range and the 298.15–318.15 K temperature range. The excess volumes were independent of temperature, but changed noticeably with the chain length of the alkanol. The VE values were only positive...
Article
The mechanisms for the hydrolysis of organopalladium complexes [Pd(CNN)R]BF(4) (R=P(OPh)(3), PPh(3), and SC(4)H(8)) were investigated at 25 °C by using UV/Vis absorbance measurements in 10 % v/v ethanol/water mixtures containing different sulphuric acid concentrations in the 1.3-11.7 M range. In all cases, a biphasic behavior was observed with rate...
Article
The decomposition reaction of the purple dye murexide in acidic media is used as a probe indicator for protons in nonionic microemulsions. The reaction kinetics primarily rely on the proton concentration and permit assessment of the proton activity in the nonionic microemulsions of water/cyclohexane/Igepal and water/heptane/Igepal. The experiments...
Article
The acid-catalyzed hydrolysis of the organopalladium complex [Pd(CNN)P(OMe)3]BF4 species was monitored spectrophotometrically at different sulfuric acid concentrations (3.9 and 11.0 M) in 10% v:v ethanol-water over the 25-45 degrees C temperature range and in 30% and 50% (v/v) ethanol-water at 25 degrees C. Two acidity regions (I and II) could be d...
Article
The acid-base behavior and self-aggregation of salicylhydroxamic (SHA) and p-hydroxybenzohydroxamic acids (PHBHA)have been investigated by UV and 1HNMR spectroscopy, respectively. The acid-base parameters, measured in H2O at 25 degrees C and I=0.1 M, were pK1=7.56, pK2=9.85 for SHA and pK1=8.4, pK2=9.4 for PHBHA. The 1H NMR signals for salicylhydro...
Article
The kinetics and the equilibria of Ni(II) binding to p-hydroxybenzohydroxamic acid (PHBHA) and salicylhydroxamic acid (SHA) have been investigated in an aqueous solution at 25 degrees C and I=0.2 M by the stopped-flow method. Two reaction paths involving metal binding to the neutral acid and to its anion have been observed. Concerning PHBHA, the ra...
Article
The acid-catalyzed hydrolysis reactions of the antiinflammatory drugs indomethacin and acemethacin were investigated at 25.0 degrees C in a number of strongly concentrated perchloric acid media. The reaction rates were evaluated by UV measurements, and the intermediate species were detected by UV-vis, 1H NMR, 13C NMR, and mass spectroscopy measurem...
Article
Indomethacine (1) and acemethacine (2) contain the substituents -OCH3, -CH2COOH, -CH2COOCH2COOH, C-indole and O-benzoyl, which are susceptible to protonation in highly acidic media. To determine the protonation sites and the substituent effects reliably, the dissociation constants of the set of structurally related compounds 1-benzoyl-3-methylindol...
Article
Full-text available
Protonation of the orthopalladated carbon of the cyclometallated complex [Pd(CNN)L]+, where L = P(OMe)3 and HCNN is the C-deprotonated form of the tricoordinated chelant donor ligand 2-acetylpyridinephenylhydrazone, has been studied at 25, 35, 40 and 45 °C in highly acidic 10% v∶v ethanol–water, and at 25 °C in 30% and 50% v∶v ethanol–water. The ac...
Article
Full-text available
The protonation equilibria of N-phenylbenzohydroxamic, benzohydroxamic, salicylhydroxamic, and N-p-tolylcinnamohydroxamic acids have been studied at 25 degrees C in concentrated sulfuric, hydrochloric, and perchloric acid media; the UV-vis spectral measurements were analyzed using the Hammett equation and the Bunnett-Olsen and excess acidity method...
Article
Excess viscosities and excess Gibbs energies of activation for viscous flow at five temperatures have been calculated for binary liquid mixtures of pyrrolidin-2-one with (C6–C10) alkan-1-ols from the experimental densities and viscosities of the mixed fluids. The excess viscosities and excess Gibbs energies of activation were negative, and increase...

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Projects (3)
Project
1. To study the evaluation rubric process for the resolution of a programming problem. 1. To analyse the collaborative work on resolving programming problems.