Dana Vasiljevic-RadovicInstitute of Chemistry, Technology and Metallurgy, University of Belgrade · Centre of Microelectronic Technologies
Dana Vasiljevic-Radovic
Full Research Professor
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208
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1,223
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Introduction
Additional affiliations
March 2003 - present
Institute of Chemistry, Technology and Metallurgy, University of Belgrade
Position
- Head of Department
Publications
Publications (208)
The aim of this study is to provide tailored alumina particles suitable for reinforcing the metal matrix film. The sol–gel method was chosen to prepare particles of submicron size and to control crystal structure by calcination. In this study, copper-based metal matrix composite (MMC) films are developed on brass substrates with different electrode...
In this study, the multifunctional potential of conductive textile fibres based on natural bamboo metalized with chemical/electrochemical deposits and copper particles/layers was investigated. The synthesis was done in three steps: pre-treatment of nonconductive textiles; chemical deposition of Cu particles by the cyclic dipping method; and obtaini...
Developing novel electrocatalysts for energy conversion applications is of utmost importance for reaching the energy security of modern society. Here we present a comprehensive investigation of rhodium-modified polycrystalline nickel as an electrocatalyst for hydrogen and oxygen electrode reactions in alkaline media. The surface modification of nic...
Lab-made biosilica (SiO2) nanoparticles were obtained from waste biomass (rice husks) and used as eco-friendly fillers in the production of nickel matrix composite films via the co-electrodeposition technique. The produced biosilica nanoparticles were characterized using XRD, FTIR, and FE-SEM/EDS. Amorphous nano-sized biosilica particles with a hig...
The lab-made ferrite-aluminium layered double oxide (Fe/Al LDO) nanoparticles were used as reinforcement in the production of copper matrix composite coatings via the electrodeposition route in this study. The Cu coatings electrodeposited galvanostatically without and with low concentrations of Fe/Al LDO nanoparticles were characterized by SEM (mor...
Correlation between morphology of electrolytically produced copper thin films and their hardness has been considered. The Cu films were electrodeposited by galvanostatic (DC) and by the pulsating current (PC) regimes on cathodes of limiting values of hardness (Cu, brass, and Si(111)) from the basic sulfate electrolytes without and with addition of...
Metasurfaces are currently among the most attractive research fields, in no small measure due to their usability as refractometric sensors, offering unparalleled sensitivity up to sensing single atoms or molecules. This is rooted in their ability to localize electromagnetic fields in volumes orders of magnitude below the diffraction limit. Numerous...
The discovery of the large group of 2D materials called MXenes has gathered much attention due to their potential applications in various fields as well as the evergrowing discoveries about their nature. One of the most interesting applications is energy storage devices. Herein, we demonstrated the impact of the functionalization with two different...
Copper from sulfate baths without and with added inorganic pigment particles based on strontium aluminate doped with europium and dysprosium (SrAl2O4: Eu2+, Dy3+) was electrodeposited on a brass cathode by a galvanostatic regime. Morphological, structural, and roughness analysis of the pigment particles, the pure (pigment-free) Cu coating, and the...
Electrochemically deposited nickel coatings from sulfamate baths without/with lab-made biosilica (SiO2) particles on the Si(100) substrate were produced. Different galvanostatic regimes were used: direct current (DC), pulse current (PC), and pulse-reverse current (PRC) regimes. The phase structure of the synthesized silica nanoparticles from rice h...
The present study reports on the preparation of nanocomposites consisting of polyurethane (PU) as the matrix and Ti3C2Tx MXene as the nanofiller, utilizing an in-situ polymerization method. The synthesis parameters of polyurethane remained constant, while the method of adding and preparing MXene was varied. The MXene content was maintained at 1 wt....
Interdigitated electrodes with integrated heaters fabricated on a Si platform were investigated in this study. The electrodes and heaters were made of gold, using standard photolithography processes. The primary objective was to analyze the maximum temperature achievable on the microheater and characterize its temperature distribution. The integrat...
Citation: Stevanović, J.N.; Petrović, S.P.; Tadić, N.B.; Cvetanović, K.; Silva, A.G.; Radović, D.V.; Sarajlić, M. Mechanochemical Synthesis of TiO 2-CeO 2 Mixed Oxides Utilized as a Screen-Printed Sensing Material for Oxygen Sensor. Sensors 2023, 23, 1313. Abstract: TiO 2 and CeO 2 are well known as oxygen sensing materials. Despite high sensitivit...
Self-powered sensors are gaining a lot of attention in recent years due to their possible application in the Internet of Things, medical implants and wireless and wearable devices. Human breath detection has applications in diagnostics, medical therapy and metabolism monitoring. One possible approach for breath monitoring is detecting the humidity...
Polymers and polymer matrix composites are commonly used materials with applications extending from packaging materials to delicate electronic devices. Epoxy resins and fiber-reinforced epoxy-based composites have been used as adhesives and construction parts. Fractal analysis has been recognized in materials science as a valuable tool for the micr...
Composite systems of electrodeposited 10 µm Cu coatings on Cu foils and 30 µm Cu coatings on brass foils were obtained in direct current regimes (DC) from electrolytes without/with additives. Different regimes of stirring electrolytes were investigated: stationary, magnetic, and ultrasonic. Also, multilayered Cu coating was successfully obtained by...
PdPt bimetallic nanoparticles on carbon-based supports functioning as advanced electrode materials have attracted attention due to their low content of noble metals and high catalytic activity for fuel cell reactions. Glassy carbon (GC)-supported Pt and PdPt nanoparticles, as promising catalysts for the oxygen reduction reaction (ORR), were prepare...
BaTiO 3 (BTO) is considered the most commonly used ceramic material in multilayer ceramic capacitors due to its desirable dielectric properties. Considering that the miniaturization of electronic devices represents an expanding field of research, modification of BTO has been performed to increase dielectric constant and DC bias characteristic/sensi...
In this investigation, nickel coatings were electrodeposited on brass substrate. The effects of electrodeposition process parameters such as, current density and deposition time (coatings thickness), on surface morphology and composite hardness values were studied. The value of the measured composite hardness by Vickers microindentation technique o...
The influence of various intensities of ultrasound applied for the electrolyte stirring on morphological and mechanical characteristics of electrolytically produced copper coatings has been investigated. The copper coatings produced by the galvanostatic regime of the electrodeposition from the basic sulphate electrolyte and the electrolyte with add...
Mechanical (hardness and adhesion) and electrical (sheet resistance) characteristics of electrolytically produced copper coatings have been investigated. Morphologies of Cu coatings produced galvanostatically at two current densities from the basic sulfate electrolyte and from an electrolyte containing levelling/brightening additives without and wi...
Graphene has become a material of choice for an increasing number of scientific and industrial applications. It has been used for gas sensing due to its favorable properties, such as a large specific surface area, as well as the sensitivity of its electrical parameters to adsorption processes occurring on its surface. Efforts are ongoing to produce...
The world is facing serious issues regarding fossil fuels consumption. As it's known, the
remaining quantities of these energy sources are small, and also there is an undesirable effect
on the environment. Dye Sensitized Solar cells (DSSC) have vast potential as one of the key
solutions in the future due to their easy and unexpensive fabrication an...
The adsorption of Ni2+ ions from water solutions by using hydrogels based on 2-hydroxyethyl acrylate (HEA) and itaconic acid (IA) was studied. Hydrogel synthesis was optimized with response surface methodology (RSM). The hydrogel with the best adsorption capacity towards Ni2+ ions was chosen for further experiments. The hydrogel was characterized b...
The influence of various electrolysis parameters, such as the type of cathode, composition of the electrolyte and electrolysis time, on the morphology, structure and hardness of copper coatings has been investigated. Morphology and structure of the coatings were analyzed by scanning electron microscope (SEM), atomic force microscope (AFM) and X-ray...
Influence of an intensity of ultrasonic mixing of electrolyte in a temperature range of 27-37 °C and ultrasonic power intensity in the range of 3.77-18.84 W/cm 2 (10-50 %) on a synthesis of fine-grained copper deposits was examined. Copper coatings were electrodeposited on a brass substrate in direct current (DC) regime with an applied current dens...
A detailed examination of the principle of operation behind the functioning of the full-self-powered humidity sensor is presented. The sensor has been realized as a structure consisting of an interdigitated capacitor with aluminum thin-film digits. In this work, the details of its fabrication and activation are described in detail. The performed XR...
A merger of organocatalysis and visible light photoredox catalysis performed in flow allowed access to a wide range of functionalized N-aryl-substituted tetrahydroisoquinolines (THIQs) in a formal C-H oxidation/Mannich reaction. Strecker type functionalization and copper-catalyzed alkynylation of several N-aryl-substituted THIQs were also successfu...
The mechanical characteristics of electrochemically deposited copper coatings have been examined by application of two hardness composite models: the Chicot-Lesage (C-L) and the Cheng-Gao (C-G) models. The 10, 20, 40 and 60 µm thick fine-grained Cu coatings were electrodeposited on the brass by the regime of pulsating current (PC) at an average cur...
In this study, a novel procedure based on application of the Chicot?Lesage (C?L) composite hardness model was proposed for determination of an absolute hardness of electrolytically produced copper coatings. The Cu coatings were electrodeposited on the Si(111) substrate by the pulsating current (PC) regime with a variation of the following parameter...
Plasmonic metamaterials open a pathway to a multitude of different applications, from ultrasensitive sensors to merging the packaging density of electronics and the speed of photonics in a single all-optical device. A severe limitation to their wider use is high absorption due to the mandatory presence of free electron-containing conductive parts w...
Fine-grained nickel coatings were electrodeposited by direct current (dc) regime onto different substrates: polycrystalline cold-rolled copper, polycrystalline brass and single crystal (100)-oriented silicon. These composite structures belong to different type of laminated composite systems. The influence of the substrate material and coating plati...
Humidity sensing is important to a variety of technologies and industries, ranging from environmental and industrial monitoring to medical applications. Although humidity sensors abound, few available solutions are thin, transparent, compatible with large-area sensor production and flexible, and almost none are fast enough to perform human respirat...
Mechanical features of the Cu coatings produced by the pulsating current (PC) regime on Si(111) substrate have been investigated. The Cu coatings were electrodeposited by varying duty cycle (15−50 %) and keeping the current density amplitude constant (100 mA cm −2), and by keeping duty cycle constant (50 %) but varying the current density amplitude...
Humidity sensing is important to a variety of technologies and industries, ranging from environmental and industrial monitoring to medical applications. Although humidity sensors abound, few available solutions are thin, transparent, compatible with large-area sensor production and flexible, and almost none are fast enough to perform human respirat...
Copper coatings are produced on silicon wafer by electrodeposition (ED) in pulsating current (PC) regime. Electrodeposition was performed at various current density amplitudes in the range of 80−140 mA cm-2 , frequency in the range of 30−100 Hz and coating thickness in the range of 10−60 µm. The resulting composite systems consist of monolayered co...
Dye Sensitized Solar cells (DSSC) are very attractive due to their low cost fabricating methods and used materials. One of the most important parts of the cells is the photoanode. Many semiconducting materials are used for this purpose, but most common one is titanium dioxide (TiO2). Optimal sintering temperature of anode plays important role in pe...
We present the design, simulation, fabrication and characterization of monolithically integrated high resistivity p-type boron-diffused silicon two-zone heaters in a model high temperature microreactor intended for nanoparticle fabrication. We used a finite element method for simulations of the heaters’ operation and performance. Our experimental m...
Surface density of adsorption sites on an adsorbent (including affinity-based sensors) is one of the basic input parameters in modeling of process kinetics in adsorption based devices. Yet, there is no simple expression suitable for fast calculations in current multiscale models. The published experimental data are often application-specific and re...
An aluminum-based, self-powered, miniaturized sensor for breath humidity detection is presented. The sensor is designed as an interdigitated capacitor made out of sputtered aluminum 1% silicon (Al 1%Si) thin film, 700 nm thickness, with digits 1.5 mm long, 0.01 mm wide and 0.01 mm clearance between them. The voltage on the open end of the sensor is...
Copper electrodeposition on (111)-oriented Si substrate was performed by the pulsating current (PC) regime at various average current densities in the range of 15–70 mA·cm−2, obtained by varying either the frequency (30, 50, 80 and 100 Hz for the current density amplitude of 100 mA·cm−2) or the current density amplitude (120 and 140 mA·cm−2 at 100...
Plasmonic materials, stochastically roughened, can provide localized field enhancement under optical irradiation (light trapping). The use of plasmonic materials in semiconductor photocatalists also leads to drastic enhancement of their photoreactivity. Plasmonic enhancement can be seen in an extension of the useful range of solar spectrum, and in...
In this contribution we propose, design and numerically analyze a plasmonic metamaterial for enhanced optical absorption, based on 100 nm thick titanium carbide (Ti3C2Tx) MXene sheets. The analyzed metamaterial is built as a sandwich with a solid MXene bottom (ground) layer, a lossless dielectric middle layer and an MXene mesh top layer. The unit c...
A temperature sensor based on four thin-film resistors is presented. Four resistors are made in the form of thin metal layer meanders on the surface of a silicon chip. Two resistors are covered with a layer of 2.3 µm thick hard baked photoresist. Two other resistors are exposed to ambient air. The photoresist cover on two of the resistors makes a m...
Rising demands for renewable energy sources have led to the development of dye sensitized solar cells. It is a challenge to find a good and low cost sensitizer, which has a low environmental impact. In this work, we conducted spectroscopic and electrochemical experiments, as well as quantum-chemical calculations of the natural pigment hypericin, in...
This work is focused on preparation of poly(urethane-siloxane)/titanium-dioxide nanocomposites (PUSNs) with enhanced features. PUSNs were prepared by the in situ polymerization reaction using titanium-dioxide as a nano-filler in different amounts (1, 2, 3 and 5 wt.%) with
respect to the poly(urethane-siloxane) (PUS) matrix. PUS copolymer was based...