
Dan DanielKing Abdullah University of Science and Technology | KAUST · Department of Mechanical Engineering
Dan Daniel
PhD in Applied Physics, Harvard University, 2017
Looking for bright, motivated PhD students!
About
50
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Introduction
My personal website is https://dropletlab.science/
Skills and Expertise
Publications
Publications (50)
Droplets adhere to surfaces due to their surface tension γ and understanding the vertical
force Fd required to detach the droplet is key to many technologies (e.g., inkjet printing, optimal
paint formulations). Here, we predicted Fd on different surfaces by numerically solving the Young-Laplace equation. Our numerical results are consistent with pr...
Droplets residing on textured oil-impregnated surfaces form a wetting ridge due to the imbalance of interfacial forces at the contact line, leading to a wealth of phenomena not seen on traditional lotus-leaf-inspired non-wetting surfaces. Here, we show that the wetting ridge leads to long-range attraction between millimeter-sized droplets, which co...
Controlling the wetting and spreading of microdroplets is key to technologies such as microfluidics, ink-jet printing, and surface coating. Contact angle goniometry is commonly used to characterize surface wetting by droplets, but the technique is ill-suited for sub-millimetric droplets. Here, we attach a micrometric-sized droplet to an Atomic Forc...
Surface wetting is a multiscale phenomenon where properties at the macroscale are determined by features at much smaller length scales, such as nanoscale surface topographies. Traditionally, the wetting of surfaces is quantified by the macroscopic contact angle that a liquid droplet makes, but this approach suffers from various limitations. In rece...
A water droplet can bounce off superhydrophobic surfaces multiple times before coming to a stop. The energy loss for such droplet rebounds can be quantified by the ratio of the rebound speed UR and the initial impact speed UI; i.e., its restitution coefficient e = UR/UI. Despite much work in this area, a mechanistic explanation for the energy loss...
Hypothesis:
Underwater oil-repellency of polyelectrolyte brushes has been attributed mainly to electric double-layer repulsion forces based on Derjaguin-Landau-Verwey-Overbeek (DLVO) theory. Many non-polyelectrolyte materials also exhibit oil-repellent behaviour, but it is not clear if there exist similar electric double-layer repulsion and if it...
Various forms of ecological monitoring and disease diagnosis rely upon the detection of amphiphiles, including lipids, lipopolysaccharides, and lipoproteins, at ultralow concentrations in small droplets. Although assays based on droplets' wettability provide promising options in some cases, their reliance on the measurements of surface and bulk pro...
Oil sands adhered on truck bed reduce transport capacity of the truck, require manual cleaning, and create hurdles for automated surface mining. Study on the adhesion properties of oil sands to solid substrates is important to minimize the fouling of substrates during mining operation. In this work, we study the influence of hydrophobicity and mech...
A water droplet can bounce off superhydrophobic surfaces multiple times before coming to a stop. The energy loss for such droplet rebounds can be quantified by the ratio of the rebound speed UR and the initial impact speed UI , i.e., its restitution coefficient e = UR/UI . Despite much work in this area, there is still incomplete mechanistic explan...
Liquid metal droplets, such as eutectic gallium-indium (EGaIn), are important in many research areas, such as soft electronics, catalysis, and energy storage. Droplet contact on solid surfaces is typically achieved without control over the applied force and without optimizing the wetting properties in different environments (e.g., in air or liquid)...
Liquid metal droplets, such as eutectic Gallium-Indium (EGaIn), are important in many research areas, such as soft electronics, catalysis, and energy storage. Droplet contact on solid surfaces is typically achieved without control over the applied force and without optimizing the wetting properties in different environments (e.g., in air or liquid)...
Frozen oil sands adhere to the walls of mining fleets in winter, which is an undesirable phenomenon that reduces the delivery capacity of vehicles and wastes fuel for in-land transportation. For automated surface mining, an effective and scalable approach is needed to replace the current method for removing adhered oil sands by shovelling or steam...
Oil sands adhered on truck bed reduce transport capacity of the truck, require manual cleaning, and create hurdles for automated surface mining. Study on the adhesion properties of oil sands to solid substrates is important to minimize the fouling of substrates during mining operation. In this work, we study the influence of hydrophobicity and mech...
We evaluate the outward and inward protection efficiencies of different mask types (N95, surgical and two cloth mask designs) taking into account the imperfect fit on the wearer. To this end, we built a manikin to simulate exhaling, coughing and inhaling of aerosol droplets 0.3–5.0μm in diameters. The protection efficiencies depend on many factors,...
Adhesion of frozen granular materials on solid surfaces creates various problems for surface cleaning, reduces the carrying capacity of vehicles, and increases energy consumption for in-land transportation. Here we report that water content determines the adhesion strength of oil sands on solid surfaces at temperature of -2.5 ◦C to -20 ◦C. Our meas...
Adhesion of frozen granular materials on solid surfaces creates various problems for surface cleaning, reduces the carrying capacity of vehicles, and increases energy consumption for in-land transportation. Here we report that water content determines the adhesion strength of oil sands on solid surfaces at temperature of -2.5 ◦C to -20 ◦C. Our meas...
An aqueous suspension of silica nanoparticles or nanofluid can alter the wettability of surfaces, specifically by making them hydrophilic and oil-repellent under water. Wettability alteration by nanofluids have important technological applications, including for enhanced oil recovery and heat transfer processes. A common way to characterize the wet...
The COVID-19 pandemic has led to many countries oscillating between various states of lock-down as they seek to balance keeping the economy and essential services running and minimizing the risk of further transmission. Decisions are made about which activities to keep open across a range of social settings and venues guided only by ad hoc heuristi...
Objectives
There is a lack of evidence-based guidelines with regard to eye protection for aerosol-generating procedures in otolaryngology practice. In addition, some recommended personal protective equipment (PPE) is not compatible with commonly used ENT equipment. This study aims to investigate the degree of eye protection that commonly used PPE g...
We evaluate the outward and inward protections of different mask types (N95, surgical and two cloth mask designs) taking into account the imperfect fit on the wearer. To this end, we built a manikin to simulate exhaling, coughing and inhaling of aerosol droplets 0.3–5.0 µ m in diameters. The outward and inward protections depend on many factors, in...
Facing shortages of personal protective equipment, some clinicians have advocated the use of barrier enclosures (typically mounted over the head, with and without suction) to contain aerosol emissions from coronavirus disease 2019 (COVID‐19) patients. There is, however, little evidence for its usefulness. To test the effectiveness of such a device,...
Small-sized droplets/aerosol transmission is one of the factors responsible for the spread of COVID-19, in addition to large droplets and surface contamination (fomites). While large droplets and surface contamination can be relatively easier to deal with (i.e., using mask and proper hygiene measures), aerosol presents a different challenge due to...
Facing shortages of personal protective equipment, some clinicians have advocated the use of barrier enclosures (typically mounted over the head, with and without suction) to contain aerosol emissions from coronavirus disease 2019 (COVID-19) patients. There is however little evidence for its usefulness. To test the effectiveness of such a device, w...
When submerged under water, polyelectrolyte brush surfaces become highly oil‐repellent. This is due to the ability of the charged moieties on the polymer backbone to retain strong hydration shells. Despite their technological relevance, there is no rational design principle for optimizing the oil‐repellent performance of hydrophilic polyelectrolyte...
The functional properties of a surface, such as its anti-fogging or anti-fouling performance, are influenced by its wettability. To quantify surface wettability, the most common approach is to measure the contact angles of a liquid droplet on the surface. While well-established and relatively easy to perform, contact angle measurements were develop...
Respiratory particle generation and dispersal during nasoendoscopy and swab testing is studied with high‐speed video and laser light illumination. Video analysis reveals droplet formation in three manoeuvres during nasoendoscopy ‐ sneezing, vocalization, and nasal decongestion spray. A capillary bridge of mucus can be seen when a nasoendoscope exit...
Surface wettability has a huge influence on its functional properties. For example, to minimize smudging, surfaces should be able to repel oil droplets. To quantify surface wettability, the most common approach is to measure the contact angles of a liquid droplet on the surface. While well-established and relatively easy to perform, contact angle m...
Hypothesis:
Marine biofouling is a global, longstanding problem for maritime industries and coastal areas arising from the attachment of fouling organisms onto solid immersed surfaces. Slippery Liquid Infused Porous Surfaces (SLIPS) have recently shown promising capacity to combat marine biofouling. In most SLIPS coatings, the lubricant is a silic...
There is a huge interest in developing superrepellent surfaces for antifouling and heat-transfer applications. To characterize the wetting properties of such surfaces, the most common approach is to place a millimetric-sized droplet and measure its contact angles. The adhesion and friction forces can then be inferred indirectly using Furmidge’s rel...
Altering the wetting state of a rock surface to more water-wet has been proposed as an enhanced oil recovery (EOR) mechanism for nanoparticles. However, how nanoparticles achieve this is not well understood. The objective of this study is to fill this knowledge gap by using advanced 2D and 3D visualization techniques.
In this study, advanced visual...
There is a huge interest in developing super-repellent surfaces for anti-fouling and heat transfer applications. To characterize the wetting properties of such surfaces, the most common approach is to place a millimetric-sized droplet and measure its contact angles. The adhesion and friction forces can then be indirectly inferred from the Furmidge'...
Recently, there has been much progress in the design and application of oil-repellent superoleophobic surfaces. Polyzwitterionic brush surfaces are of particular interest, because of their ability to repel oil under water, even in the absence of micro-/nanostructures. The origin of this underwater superoleophobicity is attributed to the presence of...
Recently, there has been much progress in the design and application of oil-repellent superoleophobic surfaces. Polyzwitterionic brush surfaces are of particular interest, because of their ability to repel oil under water, even in the absence of micro-/nano-structures. The origin of this underwater superoleophobicity is attributed to the presence o...
Significance
Driving liquid microdroplets has been challenging due to the large contact angle hysteresis and insufficient driving force at microscale. We designed a strategy to directionally transport water and oil microdroplets. By simply mounting hydrogel dots on a slippery surface to arrest lubricant menisci, spontaneously formed capillary force...
Lubricated surfaces have shown promise in numerous applications where impinging foreign droplets must be removed easily; however, before they can be widely adopted, the problem of lubricant depletion, which eventually leads to decreased performance, must be solved. Despite recent progress, a quantitative mechanistic explanation for lubricant deplet...
Lubricated surfaces have shown promise in numerous applications where impinging foreign droplets must be removed easily; however, before they can be widely adopted, the problem of lubricant depletion, which eventually leads to decreased performance, must be solved. Despite recent progress, a quantitative mechanistic explanation for lubricant deplet...
Physical interpretation of contact angle hysteresis on lubricated surfaces
Lubricated surfaces have shown promise in numerous applications where impinging foreign droplets must be removed easily; however, before they can be widely adopted, the problem of lubricant depletion, which eventually leads to decreased performance, must be solved. Despite recent progress, a quantitative mechanistic explanation for lubricant deplet...
There are currently three main classes of liquid-repellent surfaces: micro- or nanostructured superhydrophobic surfaces, flat surfaces grafted with “liquidlike” polymer brushes, and lubricated surfaces. Despite recent progress, the mechanistic explanation for the differences in droplet behavior on such surfaces is still under debate. Here, we measu...
There are currently three main classes of high-performance liquid-repellent surfaces: micro-/nano-structured lotus-effect superhydrophobic surfaces, flat surfaces grafted with 'liquid-like' polymer brushes, and various lubricated surfaces. Despite recent progress, the mechanistic understanding of the differences in droplet behavior on such surfaces...
A liquid jet can stably bounce off a sufficiently soft gel by following the contour of the dimple created upon impact. This new phenomenon is insensitive to the wetting properties of the gels and was observed for different liquids over a wide range of surface tensions, γ=24−72 mN/m. In contrast, other jet rebound phenomena are typically sensitive t...
Recently, there has been much interest in using lubricated flat and nano-/micro-structured surfaces to achieve extreme liquid-repellency: any foreign droplet immiscible with the underlying lubricant layer was shown to slide off at a small tilt angle $<$ 5$^{\circ}$. This behavior was hypothesized to arise from a thin lubricant overlayer film sandwi...
Significance
Inspection devices are frequently occluded by highly contaminating fluids that disrupt the visual field and their effective operation. These issues are particularly striking in endoscopes, where the diagnosis and treatment of diseases are compromised by the obscuring of the operative field by body fluids. Here we demonstrate that the a...
A liquid jet can stably bounce off a sufficiently soft gel, by following the
contour of the dimple created due to pressure upon impact. This phenomenon is
relatively insensitive to the wetting properties of the liquid and was observed
for different liquids over a wide range of surface tensions, $\gamma$ = 24-72
mN/m. In contrast, other jet rebound...
Approaches for regulated fluid secretion, which typically rely on fluid encapsulation and release from a shelled compartment, do not usually allow a fine continuous modulation of secretion, and can be difficult to adapt for monitoring or function-integration purposes. Here, we report self-regulated, self-reporting secretion systems consisting of li...
Omniphobic surfaces that can repel fluids at temperatures higher than 100 °C are rare. Most state-of-the-art liquid-repellent materials are based on the lotus effect, where a thin air layer is maintained throughout micro/nanotextures leading to high mobility of liquids. However, such behavior eventually fails at elevated temperatures when the surfa...
Gold micro-electrodes with various diameters (25, 50, 75, 100 and 250 μm) were manufactured using standard micro-fabrication techniques and optimized for counting of MCF-7 cells (breast tumor cells) with single cell resolution. For specific cell capture, anti-EpCAM was immobilized on 11-mercaptoundecanoic acid (11-MUA)-3-mercaptopropionic acid (3-M...