Cristina Alonso-Tristán

University of Burgos | UBU · Department of Electromechanical Engineering

Mixtures involving nitrobenzene and hydrocarbons, or 1-alkanols and 1-nitroalkane, or nitrobenzene have been investigated based on a whole set of thermophysical properties available in the literature: excess molar functions (enthalpies, entropies, isobaric heat capacities, and volumes), vapour-liquid and liquid-liquid equilibria, permittivities or...

The coexistence curves of liquid-liquid equilibrium (LLE) for the mixtures: phenylacetonitrile + heptane, + octane, + nonane, + cyclooctane, or + 2,2,4-trimethylpentane and for 3-phenylpropionitrile + heptane, or + octane are reported. Aromatic nitrile + alkane, + aromatic hydrocarbon or + 1 alkanol systems are investigated using a set of thermophy...

The liquid-liquid equilibrium (LLE) curves have been determined for the 2-hydroxyl-benzaldehyde (salicylaldehyde, SAC) + CH$_3$(CH$_2$)$_n$CH$_3$ mixtures ($n$ = 5,6,7,8,9). The equilibrium temperatures were determined observing, by means of a laser scattering technique, the turbidity produced on cooling when a second phase takes place. All the sys...

Interactions and structure of organic carbonate + alkane, and 1-alkanol + organic carbonate mixtures have been investigated by means of a set of molar excess functions: enthalpies, volumes, isobaric heat capacities, or entropies; and considering internal pressure, liquid-liquid equilibria or permittivity data. In addition, the mentioned systems hav...

Relative permittivities at 1 MHz, $\varepsilon_{\text{r}}$, and refractive indices at the sodium D-line, $n_{\text{D}}$, are reported at 0.1 MPa and at (293.15-303.15) K for the binary systems 1-alkanol + n-hexylamine (HxA). Also, their corresponding excess functions are calculated and correlated. Positive values of the excess permittivities, $\var...

Data on density, $\rho$, speed of sound, $c$, and refractive index, $n_{\text{D}}$, have been reported at (293-303.15) K for the N,N-dimethylacetamide (DMA) + CH$_3$CO(CH$_2$)$_{u-1}$CH$_3$ ($u$ = 1, 2, 3) systems, and at 298.15 K for the mixture with $u$ = 5. These data have been used to compute excess molar volumes, $V_{\text{m}}^{\text{E}}$, exc...

Interactions and structure of alkanone, or alkanal or dialkyl carbonate + alkane mixtures, or of 2-alkanone+ 2-alkanone, or of ketone + dialkyl carbonate systems have been investigated by means of a set of thermodynamic properties and by the application of the Flory model. The properties considered are excess molar quantities: enthalpies, $H_{\text...

Liquid-liquid equilibrium (LLE) phase diagrams have been determined, by means of the critical opalescence method with a laser scattering technique, for the mixtures 4-phenylbutan-2-one + CH$_3$(CH$_2$)$_n$CH$_3$ ($n = 10,12,14$) and for benzyl ethanoate + CH$_3$(CH$_2$)$_n$CH$_3$ ($n = 12,14$). The systems are characterized by having an upper criti...

Densities, $\rho$, speeds of sound, $c$, and refractive indices, $n_{\text{D}}$, have been measured for the systems N,N-dimethylformamide (DMF) + propanone, + 2-butanone, or + 2-pentanone in the temperature ($T$) range from 293.15 to 303.15 K and at 298.15 K for the DMF + 2-heptanone mixture. Due to the high volatility of acetone, the corresponding...

1-Alkanol + alkanenitrile systems have been studied by means of the DISQUAC, ERAS and UNIFAC (Dortmund) models. DISQUAC and ERAS parameters for the alkanol/nitrile interactions are reported. DISQUAC describes a whole set of thermodynamic properties: phase equilibria, vapour-liquid (VLE), liquid-liquid (LLE) and solid-liquid (SLE) equilibria, molar...

Agriculture is by far the most important economic activity in the Spanish autonomous region of Castilla y León. Numerous factors influence crop development but one of the most related variables to the photosynthetic process is Photosynthetically Active Radiation (PAR). Estimating Intercepted Photosynthetically Active Radiation (IPAR) in different c...

The 2018/844 Energy Performance of Buildings Directive (EU) has widened the scope of appropriate design of buildings from a pure energy performance and carbon emissions perspective to a wider scope that includes indoor comfort, and indoor air quality among others. To this effect, external parameters, especially solar energy, have a strong impact on...

Different strategies for modeling Global Horizontal UltraViolet Erythemal irradiance (GHUVE) based on meteorological parameters measured in Burgos (Spain) have been developed. The experimental campaign ran from September 2020 to June 2022. The selection of relevant variables for modeling was based on Pearson’s correlation coefficient. Multilinear R...

In the present study, different models constructed with meteorological variables are proposed for the determination of horizontal ultraviolet irradiance (IUV), on the basis of data collected at Burgos (Spain) during an experimental campaign between March 2020 and May 2022. The aim is to explore the effectiveness of a range of variables for modellin...

Solar Ultraviolet Radiation (UVR), which is identified as a major environmental health hazard, is responsible for a variety of photochemical reactions with direct effects on urban and aquatic ecosystems, human health, plant growth, and the deterioration of industrial systems. Ground measurements of total solar UVR are scarce, with low spatial and t...

En este trabajo se ha realizado una comparación de la radiación solar captada por un seguidor solar a dos ejes orientado a la producción de energía fotovoltaica considerando tres estrategias de seguimiento: (1) orientación del seguidor perpendicularmente a los rayos del sol, (2) posicionamiento horizontal del seguidor y (3) orientación del seguidor...

El aprovechamiento de la iluminación natural permite aumentar la calidad de vida y desarrollar la actividad humana. Para modelar la luminancia, la Comisión Internacional de Iluminación (CIE) propone una clasificación estándar que comprende quince clases de cielos. Sin embargo, la aplicación de este estándar requiere entradas que solo pueden obtener...

The melting process of lauric acid in a square container heated from the top surface was numerically studied from an experimental case. Knowledge of this process is of special interest for computationally efficient modeling systems, such as PCM-enhanced photovoltaic panels in horizontal positions or energy storage using PCM embedded on flat surface...

Four models for predicting Photosynthetically Active Radiation (PAR) were obtained through MultiLinear Regression (MLR) and an Artificial Neural Network (ANN) based on 10 meteorological indices previously selected from a feature selection algorithm. One model was developed for all sky conditions and the other three for clear, partial, and overcast...

Digital sky images are studied for the definition of sky conditions in accordance with the CIE Standard General Sky Guide. Likewise, adequate image-processing methods are analyzed that highlight key image information, prior to the application of Artificial Neural Network classification algorithms. Twenty-two image-processing methods are reviewed an...

In this study, ten-minute meteorological data-sets recorded at Burgos, Spain, are used to develop models of Photosynthetic Active Radiation (PAR) following two different procedures: multilinear regression and Artificial Neural Networks. Ten Meteorological Indices (MIs) are chosen as inputs to the models: clearness index (kt), diffuse fraction (kd),...

Prediction of energy production is crucial for the design and installation of PV plants. In this study, five free and commercial software tools to predict photovoltaic energy production are evaluated: RETScreen, Solar Advisor Model (SAM), PVGIS, PVSyst, and PV*SOL. The evaluation involves a comparison of monthly and annually predicted data on energ...

There are several compilations of sky classifications that refer to Meteorological Indices (MIs) (variables usually recorded at meteorological ground stations), due to the scarcity of sky scanner devices that can supply the experimental data needed to apply the CIE standard sky classification. The use of one rather than another MI is never justifie...

Plant growth is directly related to levels of photosynthetic photon flux density, Qp. The improvement of plant-growth models therefore requires accurate estimations of the Qp parameter that is often indirectly calculated on the basis of its relationship with solar irradiation, RS, due to the scarcity of ground measurements of photosynthetic photon...

The new European directives focused to achieve public Net-Zero Energy Buildings require for their application the knowledge of the potential of photovoltaics (PV) generation of these buildings. The available building surfaces (façades and roofs) for PV integration depend on the building's location and orientation, and relative position of the nearb...

Daylight availability knowledge is the first step for an energetic and visually efficient building and city design. It can be estimated with the Vertical Sky Component (VSC), which is defined as the ratio of the vertical diffuse illuminance over the unobstructed horizontal diffuse illuminance, simultaneously measured at the same point. These illumi...

A new design for the use of photovoltaic and thermal (PV/T) technology with thermal storage is reported in this work. In the new design, a phase change material (PCM) tank is added to the backside of the photovoltaic panel. The advantages of this design are the storage of thermal energy and the efficiency improvement of the photovoltaic (PV) panel...

Spain is among the European countries with the greatest photovoltaic potential. During the first decade of the 2000s, Spain was a European leader in installed photovoltaic power and job creation in the renewable energy sector, strongly influenced by a very favorable regulatory framework and public subsidies at a time of economic growth. That situat...

Sky classification is a complex problem, due in part to such abstract conceptual definitions as clear, intermediate, and overcast, as well as other intermediate ranges. The CIE (Commission Internationale de L’Éclairage) Standard classification offers a solution to this problem, although its application requires data on the luminance distribution of...

La radiación diurna es considerada como uno de los recursos más va- liosos que la naturaleza ofrece. Correctamente aprovechada permite aumentar la calidad de vida y desarrollar la actividad humana a la vez que se convive en armonía con el resto de los seres vivos del planeta. No obstante, presenta el inconveniente de ser altamente dependiente de la...

The determination of optimal illumination conditions in buildings is of great interest both for reducing energy consumption and for exploiting solar resources with greater efficiency and sustainability. The most commonplace method of estimating daylight is the luminous efficacy approach, using the more widely measured solar irradiance. In this pres...

The climate change has led to consider the Energy Efficiency (EE) as an important goal in the policies of many companies. Basically, the prime task is to reduce the energy consumption. There have been many investments and studies to improve EE in all the fields of human activities. The existing guidelines, recommendations, standards and legislation...

With the arrival of the economic crisis in Spain, and later, with the change of the government of the country in 2011, there was a brake in the energy policy that financially supported the installation of photovoltaic plants in plots of Spanish territory. This change implied a massive reduction in the bonus attributed to entrepreneurs who produce s...

Computational Fluid Dynamic (CFD) software is a really useful tool for both engineering and researching. With the only use of a computer it is possible to compare different geometries, material, contour parameters… Moreover, the software can show all parameter for each cell of the geometry, so the capacity to know the behaviour of the system in eve...

The liquid-liquid equilibrium (LLE) curves have been determined for the 2-hydroxyl-benzaldehyde (salicylaldehyde, SAC) + CH 3 (CH 2 ) n CH 3 mixtures (n = 5,6,7,8,9). The equilibrium temperatures were determined observing, by means of a laser scattering technique, the turbidity produced on cooling when a second phase takes place. All the systems sh...

Potential photovoltaic (PV) production from vertical façades facing the four cardinal points of the compass are calculated from daily average vertical global insolation readings measured in Burgos, Spain. Ten-minute data sets are collected over forty-five months, from January 2014 to September 2017, in the experimental campaign to produce estimates...

Para el estudio de la eficiencia energética en edificios, conocer los valores de irradiación e iluminación solar es de crucial importancia, sobre todo en países con frecuencias muy elevadas de cielos despejados, como es el caso de España. La estimación de la luz que llega a una determinada zona de trabajo en el interior de un edificio requiere del...

Liquid-liquid equilibria (LLE) phase diagrams have been determined for the systems: 2-ethoxy-benzenamine + octane, or +decane, or +dodecane, or +tetradecane and for 4-ethoxy-benzenamine + heptane, or +octane. The experimental method used is based on the observation, by mean of a laser scattering technique, of the turbidity produced on cooling when...

Daily data of Global, Diffuse and Beam Horizontal Insolation and Global Vertical (North, South, East and West orientations) insolation recorded in Burgos, Spain, are presented in this paper. Ten-minute irradiance data sets are collected over forty-five months in the experimental campaign to produce estimates of daily insolation levels. This data wa...

Daylighting is recognized as an important and useful strategy in the design of energy efficient buildings. Daylight is still the best source of light for good colour rendering and visual comfort. In this study, a new model of global luminous efficacy over a horizontal surface is proposed. A comparative study of eighteen classic models is presented,...

The coexistence curves of liquid-liquid equilibrium (LLE) for the mixtures: phenylacetonitrile + heptane, + octane, + nonane, + cyclooctane, or + 2,2,4-trimethylpentane and for 3-phenylpropionitrile + heptane, or + octane are reported. Aromatic nitrile + alkane, + aromatic hydrocarbon or + 1 alkanol systems are investigated using a set of thermophy...

This paper presents a methodology to design and to predict the behaviour of electronic circuits, which combines artificial neural networks and design of experiments. This methodology can be used to model output variables in electronic circuits either with similar features to the circuit configuration that is analysed in this study or with more comp...

Outdoor daylight conditions in Burgos, Spain, are studied throughout a full year. The CIE standard sky type is selected in accordance with the lowest RMSD (Root Mean Square Deviation) following the comparison of both the theoretical and the experimental luminance distributions in the sky hemisphere. The selection is based on luminance distribution...

Relative permittivities at 1 MHz, εr, and refractive indices at the sodium D-line, nD, are reported at 0.1 MPa and at (293.15–303.15) K for the binary systems 1-alkanol + n-hexylamine (HxA). Also, their corresponding excess functions are calculated and correlated. Positive values of the excess permittivities, εrE, are encountered for the methanol s...

Mixtures involving nitrobenzene and hydrocarbons, or 1-alkanols and 1-nitroalkane, or nitrobenzene have been investigated on the basis of a whole set of thermophysical properties available in the literature. The properties considered are: excess molar functions (enthalpies, entropies, isobaric heat capacities, and volumes), vapour-liquid and liquid...

An exhaustive evaluation of the performance of decomposition models to estimate direct and diffuse components from the global horizontal solar irradiance has been carried out in this work. The main objective of this work has been to compare the model performance for two different time bases, hourly and monthly average hourly bases. An extensive dat...

The liquid–liquid equilibrium (LLE) curves for 2-phenylethan-1-ol (2-phenylethanol, 2PhEtOH) + octane, + decane, + dodecane, + tetradecane or + 2,2,4-trimethylpentane have been determined by a method of turbidimetry using a laser scattering technique. Experimental results reveal that the systems are characterized by an upper critical solution tempe...

Dielectric and refractive study of 1-alkanol + triethylamine systems. Experimental results are reported and analysed according to thermodynamic relations. The Kirkwood-Fröhlich model is applied and and the Kirkwood correlation factors are calculated.

Data on density, ρ, speed of sound, c, and refractive index, nD, have been reported at (293–303.15) K for the N,N-dimethylacetamide (DMA) + CH3CO(CH2)u − 1CH3 (u = 1, 2, 3) systems, and at 298.15 K for the mixture with u = 5. These data have been used to compute excess molar volumes, VmE, excess adiabatic compressibilities, κSE, and excess speeds o...

Renewable energies, including photovoltaic energy, are attracting widespread international attention, in reaction to worsening environmental problems and the diminishing long-term sustainability of fossil fuel energies. In this work, the potential benefits of installing photovoltaic panels on several buildings at the Spanish Naval Military School (...

Four spatial interpolation methods (Inverse Distance Weighted, Spline, Kriging and Natural Neighbor) and their different variations are employed to map Global Horizontal Irradiation (GHI) in Castilla-León, Spain. The work has been performed using the software ArcGis, widely used in geostatistical applications, showing the versatility of the system...

Dielectric and refractive study of 1-alkanol + hexan-1-amine systems.

LLE of mixtures containing phenyl acetonitrile and n-alkanes.

Interactions and structure of organic carbonate + alkane, and 1-alkanol + organic carbonate mixtures have been investigated by means of a set of molar excess functions, enthalpies ( ), volumes ( ), isobaric heat capacities, ( ) or entropies; and considering internal pressure ( ); liquid-liquid equilibria or permittivity data. In addition, the menti...

Investigation of orientational effects by means of experimental data, the Flory model and the concentration-concentration structure factor formalism.

Dielectric study of some N,N-dimethylacetamide + linear amine systems.

Study of orientational effects by means of experimental data and the application of the Flory model.